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At least 343 records · Page 19

Growth of Solid Solution Single Crystals

The objective of the study is to establish the effects of processing semiconducting, solid solution, single crystals in a microgravity environment on the metallurgical, compositional, electrical, and optical characteristics of the crystals. The alloy system being investigated is the solid solution semiconductor Hg(1-x)Cd(x)Te, with x-values appropriate for infrared detector applications in the 8 to 14 mm wavelength region. Both melt and Te-solvent growth are being performed. The study consists of an extensive ground-based experimental and theoretical research effort followed by flight experimentation where appropriate. The ground-based portion of the investigation also includes the evaluation of the relative effectiveness of stabilizing techniques, such as applied magnetic fields, for suppressing convective flow during the melt growth of the crystals.

Lehoczky, Sandor L.↗

Thermoelectric materials development

A systematic search for advanced thermoelectric materials was initiated at JPL several years ago to evaluate candidate materials which includes consideration of the following property attributes: (1) semiconducting properties; (2) large Seebeck coefficient; (3) high carrier mobility and high electrical conductivity; (4) low lattice thermal conductivity; and (5) chemical stability and low vapor pressure. Through this candidate screening process, JPL identified several families of materials as promising candidates for improved thermoelectric materials including the skutterudite family. As part of an ongoing effort to develop skutterudite materials with lower thermal conductivity values, several solid solutions and filled skutterudite materials were investigated under the effort sponsored by DOE. The efforts have primarily focused on: (1) study of existence and properties of solid solutions between the binary compounds CoSb3 and IrSb3, and RuSb2Te, and (2) CeFe(4-x)Sb12 based filled compositions. For the solid solutions, the lattice thermal conductivity reduction was expected to be reduced by the introduction of the Te and Ru atoms while in the case of CeFe(4-x)Ru(x)Sb12 based filled compositions. For the solid solutions, the lattice thermal conductivity reduction was expected to be reduced by the introduction of the Te and Ru atoms while in the case of CeFe(4-x)Ru(x)Sb12 filled compositions, the reduction would be caused by the rattling of Ce atoms located in the empty voids of the skutterudite structure and the substitution of Fe for Ru. The details of the sample preparation and characterization of their thermoelectric properties are reported in this report.

Fleurial, J. P.↗

Efficient IR Transmission Diffraction Grating for Circularly Polarized Light

Numerical methods, using rigorous coupled wave theory, are used to design rectangular relief diffraction gratings for an infrared application which requires comparable first order efficiencies in the TE and TM polarization states. The depth, period, and fill factor of the grating are varied to identify optimal two level binary lamellar grating profiles which predict efficiencies for individual TM and TE polarizations above 75 percent, while keeping the difference between the two efficiencies within 10 percent. The application at hand is a rotating, transmissive diffractive scanner for space-based coherent lidar. The operating wavelength is 2.0 microns. A collimated, circularly polarized beam is incident on the diffractive scanner at the Bragg angle; 30 and 45 degree beam deflection angles being studied. Fused silica is the substrate material of choice. Selected designs are fabricated on 3 inch fused silica substrates using lithographic methods. The performance of the test pieces is measured and compared to theoretical predictions.

Cole, Helen↗

Effect of a Nonplanar Melt-Solid Interface On Lateral Compositional Distribution During Unidirectional Solidification of a Binary Alloy with a Constant Growth Velocity V: Theory - Pt. 1

Infrared detected materials, such as Hg(1-x)Cd(x)Te, Hg(1-x)Zn(x)Te have energy gaps almost linearly proportional to their composition. Due to the wide separation of liquidus and solidus curves of their phase diagram, there are compositional segregation in both of the axial and radial directions of these crystals grown in the Bridgman system unidirectionally with constant growth rate. It is important to understand the mechanisms, which affect lateral segregation such that large radially uniform composition crystal can be produced. Following Coriel, etc's treatment, we have developed a theory to study the effect of a curved melt-solid interface shape on lateral composition distribution. The model is considered to be a cylindrical system with azimuthal symmetry and a curved melt-solid interface shape which can be expressed as a linear combination of a series of Bessell's functions. The results show that melt-solid interface shape has a dominant effect on the lateral composition distribution of these systems. For small values of beta, the solute concentration at the melt-solid interface scales linearly with interface shape with a proportional constant of the produce of beta and (1 -k), where beta = VR/D, with V as growth velocity, R as the sample radius, D as the diffusion constant and k as the distribution constant. A detailed theory will be presented. A computer code has been developed and simulations have been performed and compared with experimental results. These will be published in another paper.

Wang, Jai-Ching↗

Effect of a Nonplanar Melt-Solid Interface on Lateral Compositional Distribution during Unidirectional Solidification of a Binary Alloy with a Constant Growth Velocity V: Theory - Part 1

Infrared detector materials, such as Hg(1-x)Cd(x)Te, Hg(1-x)Zn(x)Te have energy gaps almost linearly proportional to its composition. Due to the wide separation of liquidus and solidus curves of their phase diagram, there are compositional segregations in both of axial and radial directions of these crystals grown in the Bridgman system unidirectionally with constant growth rate. It is important to understand the mechanisms which affect lateral segregation such that large uniform radial composition crystal is possible. Following Coriell, etc's treatment, we have developed a theory to study the effect of a curved melt-solid interface shape on the lateral composition distribution. The system is considered to be cylindrical system with azimuthal symmetric with a curved melt-solid interface shape which can be expressed as a linear combination of a series of Bessell's functions. The results show that melt-solid interface shape has a dominate effect on lateral composition distribution of these systems. For small values of b, the solute concentration at the melt-solid interface scales linearly with interface shape with a proportional constant of the product of b and (1 - k), where b = VR/D, with V as growth velocity, R as sample radius, D as diffusion constant and k as distribution constant. A detailed theory will be presented. A computer code has been developed and simulations have been performed and compared with experimental results. These will be published in another paper.

Wang, Jai-Ching↗

Gas Sensors Based on Single-Arm Waveguide Interferometers

Various optical technologies can be implemented in chemical sensing. Sensitive, rugged, and compact systems will be more likely built using interferometric waveguide sensors. Currently existing sensors comprise dual-arm systems with external reference arm, dual-arm devices with internal reference arm such as integrated Mach-Zehnder interferometer, and single-arm systems which employ the interference between different waveguide modes. These latter ones are the most compact and rugged but still sensitive enough to monitor volatile pollutants such as NH3 coming out of industrial refrigerators and fertilizer plants and stocks, NO, NO2, SO2, emitted by industrial burning processes. Single-arm devices in planar waveguide configuration most frequently use two orthogonally polarized modes TE (sub i) and TM (sub i) of the same order i. Sensing effect is based on the difference in propagation conditions for the modes caused by the environment. However, dual-mode single-order interferometers still have relatively low sensitivity with respect to the environment related changes in the waveguide core because of small difference between propagation constants of TE (sub i) and TM (sub i) modes of the same order. Substantial sensitivity improvement without significant complication can be achieved for planar waveguide interferometers using modes of different orders with much greater difference between propagation constants.

Sarkisov, Sergey↗

Emission Lines of O III in The Optical and Ultraviolet Spectra of Planetary Nebulae

Recent R-matrix calculations of electron impact excitation rates in 0 III are used to calculate electron temperature and density-dependent emission line ratios R (sub 1) = I(4363 Angstroms)/ I(4960 Angstroms + 5007 Angstroms), R (sub 2) = I(1661 Angstroms + 1667 Angstroms)/ I(4960 Angstroms + 5007 Angstroms) and R (sub 3)= I(2322 Angstroms)/ I(1661 Angstroms + 1667 Angstroms), for a range of electron temperatures (7500 less than or equal to Te less than or equal to 30 000 K) and densities (10 (exp 4) less than or equal to N (sub e) less than or equal to 10 (exp 7) per cubic centimeters) applicable to gaseous nebulae. The ratio-ratio diagrams (R (sub 1), R (sub 2)) and (R (sub 1), R (sub 3)) should, in principle, allow the simultaneous determination of T (sub e) and N (sub e) from measurements of the 0 III features in a spectrum. Plasma parameters derived for a sample of high-excitation planetary nebulae from (R (sub 1), R (sub 2)) and (R (sub 1), R (sub 3)) measurements, produced using a combination of ultraviolet spectra obtained with the International Ultraviolet Explorer (IUE) and optical data from a number of observing runs, are found to show excellent internal consistency. They also show, in general, good agreement with the values of Te and Ne estimated from other line ratios in the nebulae, therefore providing observational support for the accuracy of the theoretical ratios and hence the atomic data adopted in their derivation.

Crawford, F. L.↗

Maneuver Performance Enhancement for an Advanced Fighter/Attack Aircraft

A small scale wind tunnel test of a realistic fighter configuration has been completed in NASA Ames' 7'x10' wind tunnel. This test was part of the Fighter Lift and Control (FLAC) program, a joint NASA - USAF research program, involving small and large-scale wind-tunnel tests and computational analysis of unique lift augmentation and control devices. The goal of this program is to enhance the maneuver and control capability of next-generation Air Force multi-role fighter aircraft with low-observables geometries. The principal objective of this test was to determine the effectiveness of passive boundary layer control devices at increasing L/D at sustained maneuver lift coefficients. Vortex generators (VGs) were used to energize the boundary layer to prevent or delay separation. Corotating vanes, counter-rotating vanes, and Wheeler Wishbone VGs were used in the vicinity of the leading and trailing edge flap hinge lines. Principle test parameters were leading and trailing edge flap deflections, and location, size, spacing, and orientation for each VG type. Gurney flaps were also tested. Data gathered include balance force and moment data, surface pressures, and flow visualization for characterizing flow behavior and locating separation lines. Results were quite different for the two best flap configurations tested. All VG types tested showed improvement (up to 5%) in maneuver L/D with flaps at LE=20 degrees, TE=0 degrees. The same VGs degraded performance, in all but a few cases, with flaps at LE=15 degrees, TE=10 degrees.

Samuels, Jeff↗

Structural Fluctuations and Thermophysical Properties of Molten II-VI Compounds

The objectives of the project are to conduct ground-based experimental and theoretical research on the structural fluctuations and thermophysical properties of molten II-VI compounds to enhance the basic understanding of the existing flight experiments in microgravity materials science programs as well as to study the fundamental heterophase fluctuation phenomena in these melts by: 1) conducting neutron scattering analysis and measuring quantitatively the relevant thermophysical properties of the II-VI melts (such as viscosity, electrical conductivity, thermal diffusivity and density) as well as the relaxation characteristics of these properties to advance the understanding of the structural properties and the relaxation phenomena in these melts and 2) performing theoretical analyses on the melt systems to interpret the experimental results. All the facilities required for the experimental measurements have been procured, installed and tested. Thermal diffusivity of molten tellurium has been measured by a laser flash method in the temperature range of 500 C to 900 C. The measured diffusivity as a function of temperature agrees fairly well with published data. However, a relaxation phenomenon, which shows a slow drift of the measured thermal conductivity toward the equilibrium value after cooling of the melt, was observed for the first time. An apparatus based on the transient torque induced by a rotating magnetic field has been developed to determine the viscosity and electrical conductivity of semiconducting liquids. Viscosity measurements on molten tellurium showed a similar relaxation behavior to the measured diffusivity. The density and volume expansion coefficients for pure Te and HgTe melts were measured as a function of temperature using a pycnometric method. A density maximum was found for both melts but no relaxation behavior was observed. Neutron scattering experiments were performed on the HgTe and HgZnTe melts and the results on pair distribution showed better resolution than previously reported. A simple kinetic theory, which contains the formation reactions of Te polymerization that increases the molecular weight, was proposed to interpret the relaxation behavior of HgZnTe viscosity data.

Su, Ching-Hua↗

Development and Implementation of an Empirical Ionosphere Variability Model

Spacecraft designers and operations support personnel involved in space environment analysis for low Earth orbit missions require ionospheric specification and forecast models that provide not only average ionospheric plasma parameters for a given set of geophysical conditions but the statistical variations about the mean as well. This presentation describes the development of a prototype empirical model intended for use with the International Reference Ionosphere (IRI) to provide ionospheric Ne and Te variability. We first describe the database of on-orbit observations from a variety of spacecraft and ground based radars over a wide range of latitudes and altitudes used to obtain estimates of the environment variability. Next, comparison of the observations with the IRI model provide estimates of the deviations from the average model as well as the range of possible values that may correspond to a given IRI output. Options for implementation of the statistical variations in software that can be run with the IRI model are described. Finally, we provide example applications including thrust estimates for tethered satellites and specification of sunrise Ne, Te conditions required to support spacecraft charging issues for satellites with high voltage solar arrays.

Minow, Joesph I.↗

Effect of Residual Accelerations on the Crystal Growth of II-VI Semiconductors in Low Earth Orbit

The paper compares and summarizes the effects of residual acceleration during crystal growth on the compositional variation of two II-VI solid solution binary alloys (Hg(0.8)Cd(0.2)Te and Hg(0.84)Zn(0.16)Te). The crystals were grown by directional solidification on the second United States Microgravity Payload (USMP-2) and the first United States Microgravity Laboratory (USML-1) missions, respectively. For both alloys, changes in the direction and magnitude of the quasisteady acceleration vector (approximately 0.4- 1 mu g) caused large changes in the radial compositional distribution that demonstrates the importance of residual accelerations, even in the submicrogravity range, for large density gradients in the melt and slow solidification rates. The observed compositional variations will be correlated to changes in the radial flow velocities ahead of the solidification interface.

Gillies, D. C.↗

An Admittance Survey of Large Volcanoes on Venus: Implications for Volcano Growth

Estimates of the thickness of the venusian crust and elastic lithosphere are important in determining the rheological and thermal properties of Venus. These estimates offer insights into what conditions are needed for certain features, such as large volcanoes and coronae, to form. Lithospheric properties for much of the large volcano population on Venus are not well known. Previous studies of elastic thickness (Te) have concentrated on individual or small groups of edifices, or have used volcano models and fixed values of Te to match with observations of volcano morphologies. In addition, previous studies use different methods to estimate lithospheric parameters meaning it is difficult to compare their results. Following recent global studies of the admittance signatures exhibited by the venusian corona population, we performed a similar survey into large volcanoes in an effort to determine the range of lithospheric parameters shown by these features. This survey of the entire large volcano population used the same method throughout so that all estimates could be directly compared. By analysing a large number of edifices and comparing our results to observations of their morphology and models of volcano formation, we can help determine the controlling parameters that govern volcano growth on Venus.

Brian, A. W.↗

Calibration of the Galactic Cosmic Ray Flux

We report first Xe data on the cross-calibration of I-129-Xe-129(sub n) ages with conventional CRE ages, a method which is expected to provide information on the long-term constancy of the galactic cosmic ray (GCR) flux. We studied isotopic signatures of Xe released in stepwise heating, decomposition and melting of troilites in the Cape York iron meteorite to identify isotopic shifts in Xe-129 and Xe-131 due to neutron capture in Te-128 and Te-130. We also resolve components due to extinct 129I, spallation and fission Xe. There has recently been much speculation on the constancy of GCR over long time scales, as may be inferred from iron meteorites. If GCRs originate from supernova events, this provides the basis for postulating increased fluxes at locations with higher than average densities of supernovae, specifically in OB-associations. The solar system at present appears to be inside a local bubble between spiral arms and may experience an increased GCR flux.

Mathew, K. J.↗

HCO+ in the coma of comet Hale-Bopp

Maps of comet C/1995 O1 (Hale-Bopp) in the millimeter-wave emission of the ion HCO+ revealed a local minimum near the nucleus position, with a maximum about 100,000 km in the antisolar direction. These observed features of the HCO+ emission require a low abundance of HCO+ due to enhanced destruction in the inner coma of the comet, within a region of low electron temperature (Te). To set constraints on the formation of HCO+ in the coma, as well as the location and magnitude of the transition to higher Te, the data are compared with the results of ion-molecule chemistry models.

Non-NASA Center↗

Global Admittance Estimates of Elastic and Crustal Thickness of Venus: Results from Top, Hot Spot, and Bottom Loading Models

We have calculated admittance spectra using the spatio-spectral method [14] for Venus by moving the central location of the spectrum over a 1 grid, create 360x180 admittance spectra. We invert the observed admittance using top-loading (TL), hot spot (HS), and bottom loading (BL) models, resulting in elastic, crustal, and lithospheric thickness estimates (Te, Zc, and Zl) [0]. The result is a global map for interpreting subsurface structure. Estimated values of Te and Zc concur with previous TL local admittance results, but BL estimates indicate larger values than previously suspected.

Smrekar, S. E.↗

RACE and Calculations of Three-dimensional Distributed Cavity Phase Shifts

The design for RACE, a Rb-clock flight experiment for the ISS, is described. The cold collision shift and multiple launching (juggling) have important implications for the design and the resulting clock accuracy and stability. We present and discuss the double clock design for RACE. This design reduces the noise contributions of the local oscillator and simplifies and enhances an accuracy evaluation of the clock. As we try to push beyond the current accuracies of clocks, new systematic errors become important. The best fountain clocks are using cylindrical TE(sub 011) microwave cavities. We recently pointed out that many atoms pass through a node of the standing wave microwave field in these cavities. Previous studies have shown potentially large frequency shifts for atoms passing through nodes in a TE(sub 013) cavity. The shift occurs because there is a small traveling wave component due to the absorption of the copper cavity walls. The small traveling wave component leads to position dependent phase shifts. To study these effects, we perform Finite Element calculations. Three-dimensional Finite Element calculations require significant computer resources. Here we show that the cylindrical boundary condition can be Fourier decomposed to a short series of two-dimensional problems. This dramatically reduces the time and memory required and we obtain (3D) phase distributions for a variety of cavities. With these results, we will be able to analyze this frequency shift in fountain and future space clocks.

Li, Ruoxin↗

Discovery of an Afterglow Extension of the Prompt Phase of Two Gamma Ray Bursts Observed by Swift

Contemporaneous BAT and XRT observations of two recent well-covered GRBs observed by Swift, GRB 050315 and GRB 050319, show clearly a prompt component joining the onset of the afterglow emission. The rapid slewing capability of the spacecraft enables X-ray observations immediately after the burst, typically ~ 100 s following the initiation of the prompt y-ray phase. By fitting a power law form to the y-ray spectrum, we extrapolate the time dependent fluxes measured by the BAT, in the energy band 15 - 350 keV, into the spectral regime observed by the XRT 0.2 - 10 keV, and examine the functional form of the rate of decay of the two light curves. We find that the BAT and XRT light curves merge to form a unified curve. There is a period of steep decay up to ~ 300 s, followed by a flatter decay. The duration of the steep decay, ~ 100 s in the source frame after correcting for cosmological time dilation, agrees roughly with a theoretical estimate for the deceleration time of the relativistic ejecta as it interacts with circumstellar material. For GRB 050315, the steep decay can be characterized by an exponential form, where one e-folding decay time Te (BAT)~ = 24 f 2 s, and Te,(XRT)~ = 35 f 2 s. For GRB 050319, a power law decay - d l n f / d l n t = n, where n approx. ~ = 3, provides a reasonable fit. The early time X-ray fluxes are consistent with representing the lower energy tail of the prompt emission, and provide our first quantitative measure of the decay of the prompt y-ray emission over a large dynamic range in flux. The initial steep decay is expected due to the delayed high latitude photons from a curved shell of relativistic plasma illuminated only for a short interval. The overall conclusion is that the prompt phase of GRBs remains observable for hundreds of seconds longer than previously thought.

Bathelmy, S. D.↗

Progress towards high-performance thermopile imaging arrays

The purpose of this present work is to improve thermopile 2-D arrays substantially by combining Bi-Te and Bi-Sb-Te thermoelectric materials with a unique pixel structure and low-noise readout circuitry.

detector thermopile infrared uncooled array imagin↗