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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

Particle trapping, size-filtering, and focusing in the nonthermal plasma synthesis of sub-10 nanometer particles

Low-pressure nonthermal flowing plasmas are widely used for the gas-phase synthesis of nanoparticles and quantum dots of materials that are difficult or impractical to synthesize using other techniques. To date, the impact of temporary electrostatic particle trapping in these plasmas has not been recognized, a process that may be leveraged to control particle properties. Furthermore, we present experimental and computational evidence that, during their growth in the plasma, sub-10 nm silicon particles become temporarily confined in an electrostatic trap in radio-frequency excited plasmas until they grow to a size at which the increasing drag force imparted by the flowing gas entrains the particles, carrying them out of the trap. We demonstrate that this trapping enables the size filtering of the synthesized particles, leading to highly monodisperse particle sizes, as well as the electrostatic focusing of the particles onto the reactor centerline. Understanding of the mechanisms and utilization of such particle trapping will enable the design of plasma processes with improved size control and the ability to grow heterostructured nanoparticles.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Two-tone Doppler cooling of radial two-dimensional crystals in a radio-frequency ion trap

We study the Doppler-cooling of radial two-dimensional (2D) Coulomb crystals of trapped barium ions in a radiofrequency trap. Ions in radial 2D crystals experience micromotion of an amplitude that increases linearly with the distance from the trap center, leading to a position-dependent frequency modulation of laser light in each ion's rest frame. We use two tones of Doppler-cooling laser light separated by approximately 100 MHz to efficiently cool distinct regions in the crystals with differing amplitudes of micromotion. This technique allows us to trap and cool more than 50 ions populating 4 shells in a radial two-dimensional crystal, where with a single tone of Doppler cooling light we are limited to 30 ions in 3 shells. Here, we also individually characterize the micromotion of all ions within the crystals, and use this information to locate the center of the trap and to determine the Matthieu parameters q x and q y .

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

High-Fidelity Ion State Detection Using Trap-Integrated Avalanche Photodiodes

Integrated technologies greatly enhance the prospects for practical quantum information processing and sensing devices based on trapped ions. High-speed and high-fidelity ion state readout is critical for any such application. Integrated detectors offer significant advantages for system portability and can also greatly facilitate parallel operations if a separate detector can be incorporated at each ion-trapping location. Here, we demonstrate ion quantum state detection at room temperature utilizing single-photon avalanche diodes (SPADs) integrated directly into the substrate of silicon ion trapping chips. Furthermore, we detect the state of a trapped Sr + ion via fluorescence collection with the SPAD, achieving 99.92(1)% average fidelity in 450 μs, opening the door to the application of integrated state detection to quantum computing and sensing utilizing arrays of trapped ions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2019

Evaluation of Carrier Trapping in SiNx Towards Ion Migration Measurements

Sodium ion migration has been implicated in potential induced degradation of the shunting type. The kinetics of sodium migration in silicon nitride can be investigated using a simple capacitance-voltage characterization technique. However, we show that the charge trapping strongly affects the measurement and must be taken into consideration in the experimental approach. Furthermore, we perform a systematic analysis of charge carrier trapping in silicon nitride, allowing us to correct trapping effects that otherwise prevent sodium signal detection. We extract trapping and detrapping time constants both on the order of several hours. This shows that trapping cannot be ignored as it occurs relatively quickly and is constantly evolving in time. Accurate determination of sodium behavior in dielectric layers will facilitate robust co-optimization of these layers for optical, passivation, and barrier properties.

42 ENGINEERING↗
DOE OSTI2017

Stability of dust acoustic wavepackets suffering from polarization force due to the presence of trapped ions

The combined effects of the polarization force, free and trapped ions, and dust charge variation are incorporated in a rigorous study of the nonlinear dust acoustic waves (DAWs) propagating in an unmagnetized dusty plasma. Owing to the departure from the Boltzmann ion distribution, it is found that the nonlinear DAWs are governed by a modified Korteweg−de Vries (mKdV) equation. The association between the mKdV solitary wave and the DAW envelope in the system under consideration is discussed. A modified nonlinear Schrödinger equation appropriate for describing the modulated DAWs is derived. The modulation instability (MI) and the dependence of the system physical parameters on the polarization force, trapped ions, and dust charge variation have been analyzed. It is found that the critical curve separating the stable/unstable regions is strongly influenced by both of the polarization and the ion trapping parameters. Moreover, increasing the polarization leads to an increase of the critical wave number, while increasing the trapping parameter yields the opposite effect. The MI maximum growth rate decreases (increases) as the polarization (trapped ion) increases. The obtained results may be helpful in better understanding of space observations of the solar energetic particle flows in interplanetary space and the energetic particle events in the Earth’s magnetosphere.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
NASA NTRS1995

Progress Report on the Improved Linear Ion Trap Physics Package

This article describes the first operational results from the extended linear ion trap frequency standard now being developed at JPL. This new design separates the state selection/interrogation region from the more critical microwave resonance region where the multiplied local oscillator (LO) signal is compared to the stable atomic transition. Hg+ ions have been trapped, shuttled back and forth between the resonance and state selection traps. In addition, microwave transitions between the Hg+ clock levels have been driven in the resonance trap and detected in the state selection trap.

Linear Ion Trap↗
NASA NTRS2011

Dipole Field Effects on Ion Ejections from a Paul Ion Trap

Attempts at improving the quality of mass spectra obtained from a Paul trap mass spectrometer prompted an investigation of the effects of additional fields to supplement the primary rf quadrupole trapping field. Reported here are the results of the first in a series of tests that focuses on the application of a single dipole field to augment the trapping and subsequent ejections of ions stored within a Paul trap. Measurements are presented for a fixed quadrupole frequency with varying dipole frequencies. The presence of the dipole field during the quadrupole trapping phase causes ion ejections of single m/z species at discrete dipole frequencies. During the mass analysis phase, the varying dipole frequency produces a complex set of resonant structures that impact ejection time (mass range), as well as mass spectral peak intensity and width

dipole↗
NASA NTRS2022

Gas Trap Plug Design, Function and Performance

The cooling loops of the Internal Active Thermal Control System (IATCS) on the Node 3, Node 2 and US Laboratory (USL) Modules of the International Space Station (ISS) have been serviced by Gas Traps (GTs) since the onset of operations. These traps serve to protect the pumping function of the cooling loops by eliminating free gas that would otherwise impact the impellers and cause a loop shutdown. Gas Trap Plug Assemblies (GTPAs) have been designed, manufactured and tested, to permit function of the IATCS in the event of a loss of cabin atmosphere and long term decrew event. The GTPA also serve to give the crew additional time to evacuate the United States Operating Segment (USOS) in the unlikely event of an Ammonia breach of an Interface Heat Exchanger (IFHX). These GTPAs have been installed on the ISS IATCS since May 2019. This paper will address purpose, design and testing of the GTPA. The paper will also provide analyses showing residual trapping capability and free gas elimination of the GTs even while tightly plugged, for both the GTs and the Alternate Gas Trap Assemblies (AGTAs) ground spares.

Gas Trap Plugs↗
DOE OSTI2016

Intrinsic electron traps in atomic-layer deposited HfO{sub 2} insulators

Analysis of photodepopulation of electron traps in HfO{sub 2} films grown by atomic layer deposition is shown to provide the trap energy distribution across the entire oxide bandgap. The presence is revealed of two kinds of deep electron traps energetically distributed at around E{sub t} ≈ 2.0 eV and E{sub t} ≈ 3.0 eV below the oxide conduction band. Comparison of the trapped electron energy distributions in HfO{sub 2} layers prepared using different precursors or subjected to thermal treatment suggests that these centers are intrinsic in origin. However, the common assumption that these would implicate O vacancies cannot explain the charging behavior of HfO{sub 2}, suggesting that alternative defect models should be considered.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2015

Experimental study on effects of geologic heterogeneity in enhancing dissolution trapping of supercritical CO 2

Abstract Dissolution trapping is one of the primary mechanisms that enhance the storage security of supercritical carbon dioxide (scCO 2 ) in saline geologic formations. When scCO 2 dissolves in formation brine produces an aqueous solution that is denser than formation brine, which leads to convective mixing driven by gravitational instabilities. Convective mixing can enhance the dissolution of CO 2 and thus it can contribute to stable trapping of dissolved CO 2 . However, in the presence of geologic heterogeneities, diffusive mixing may also contribute to dissolution trapping. The effects of heterogeneity on mixing and its contribution to stable trapping are not well understood. The goal of this experimental study is to investigate the effects of geologic heterogeneity on mixing and stable trapping of dissolved CO 2 . Homogeneous and heterogeneous media experiments were conducted in a two‐dimensional test tank with various packing configurations using surrogates for scCO 2 (water) and brine (propylene glycol) under ambient pressure and temperature conditions. The results show that the density‐driven flow in heterogeneous formations may not always cause significant convective mixing especially in layered systems containing low‐permeability zones. In homogeneous formations, density‐driven fingering enhances both storage in the deeper parts of the formation and contact between the host rock and dissolved CO 2 for the potential mineralization. On the other hand, for layered systems, dissolved CO 2 becomes immobilized in low‐permeability zones with low‐diffusion rates, which reduces the risk of leakage through any fault or fracture. Both cases contribute to the permanence of the dissolved plume in the formation.

Agartan, Elif↗
DOE OSTI2026

Lewis Acid‐Activated Charge Trapping in Dielectric Polymers for Superior High‐Temperature Electrostatic Energy Storage

Dielectric polymer capacitors are essential for electrostatic energy storage but suffer from charge transport-induced energy losses, particularly at elevated temperatures where thermally activated charge carriers exacerbate conduction. Conventional mitigation strategies rely on introducing heterogeneous interfaces to create charge traps, complicating scalable film fabrication. A homogeneous molecular trapping mechanism would circumvent these complexities, yet remains underexplored. Herein, a charge trapping strategy is devised by modifying the lowest occupied molecular orbitals of dielectric polymers through Lewis acid-base adduct formation. The use of tris(pentafluorophenyl)boron (BCF) as a Lewis acidic molecular additive introduces deeper charge traps in commercial polyetherimide (PEI) while retaining homogeneity. With only 0.5 wt.% loading, the PEI-BCF film exhibits greatly improved breakdown strength, achieving an ultrahigh discharged energy density of 7.3 J cm-3 with excellent cycle stability at 200 °C. This work establishes a facile molecular approach to decoupling charge trapping from heterogeneous interfaces, enabling high-energy-density polymer capacitors operable under extreme thermal conditions.

Fan, Lu↗
DOE OSTI2020

Improving the accessibility and transferability of machine learning algorithms for identification of animals in camera trap images: MLWIC2

Motion-activated wildlife cameras (or “camera traps”) are frequently used to remotely and noninvasively observe animals. The vast number of images collected from camera trap projects has prompted some biologists to employ machine learning algorithms to automatically recognize species in these images, or at least filter-out images that do not contain animals. These approaches are often limited by model transferability, as a model trained to recognize species from one location might not work as well for the same species in different locations. Furthermore, these methods often require advanced computational skills, making them inaccessible to many biologists. We used 3 million camera trap images from 18 studies in 10 states across the United States of America to train two deep neural networks, one that recognizes 58 species, the “species model,” and one that determines if an image is empty or if it contains an animal, the “empty-animal model.” Our species model and empty-animal model had accuracies of 96.8% and 97.3%, respectively. Furthermore, the models performed well on some out-of-sample datasets, as the species model had 91% accuracy on species from Canada (accuracy range 36%–91% across all out-of-sample datasets) and the empty-animal model achieved an accuracy of 91%–94% on out-of-sample datasets from different continents. Our software addresses some of the limitations of using machine learning to classify images from camera traps. By including many species from several locations, our species model is potentially applicable to many camera trap studies in North America. We also found that our empty-animal model can facilitate removal of images without animals globally. We provide the trained models in an R package (MLWIC2: Machine Learning for Wildlife Image Classification in R), which contains Shiny Applications that allow scientists with minimal programming experience to use trained models and train new models in six neural network architectures with varying depths.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Holography abhors visible trapped surfaces

We prove that consistency of the holographic dictionary implies a hallmark prediction of the weak cosmic censorship conjecture: that in classical gravity, trapped surfaces lie behind event horizons. In particular, the existence of a trapped surface implies the existence of an event horizon, and that furthermore this event horizon must be outside of the trapped surface. More precisely, we show that the formation of event horizons outside of a strong gravity region is a direct consequence of causal wedge inclusion, which is required by entanglement wedge reconstruction. We make few assumptions beyond the absence of evaporating singularities in strictly classical gravity. We comment on the implication that spacetimes with naked trapped surfaces do not admit a holographic dual, note a possible application to holographic complexity, and speculate on the dual CFT interpretation of a trapped surface.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Simulation of Unidirectional Ion Ejection in an Asymmetric Half-Round Rod Electrode Linear Ion Trap Mass Analyzer

An asymmetric trapping field was generated from an asymmetric half-round rod electrode linear ion trap (A-HreLIT), and its performance of unidirectional ion ejection was studied. Two different asymmetric structures of A-HreLITs were constructed, one rotating y electrode pairs toward an x electrode with an angle θ, and the other stretching one x electrode with a distance α. The center of trapping field was displaced away from the geometrical center of the ion trap, defined to be the midpoint along the axis of y between x electrodes, which leads to unidirectional ion ejection through one x electrode. Computer simulations were used to investigate the relationship between asymmetric geometric parameter of θ (or α) and analytical performance. Both structures could result in similar asymmetric trapping fields, which mainly composed of dipole, quadrupole, and hexapole fields. The dipole and hexapole fields were approximately proportional to the asymmetric geometric parameter of rotation angle θ (or stretch distance α). In simulation, ion trajectories and ion kinetic energy were calculated. For ions with m/z 609 Th, the simulation results showed that mass resolution of over 2400 (FWHM) and ion unidirectional ejection efficiency of nearly 90% were achieved in an optimized A-HreLIT. Ion detection efficiency of A-HreLIT could be improved significantly with only one ion detector, while maintaining a considerable mass resolution. Furthermore, the A-HreLIT could be driven by a traditional balanced RF power supply. These advantages make A-HreLIT suitable for developing miniaturized mass spectrometer with high performance. .

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2016

Trapped bubbles keep pumice afloat and gas diffusion makes pumice sink

Pumice can float on water for months to years – long enough for pumice to travel across oceans and facilitate the spread of species. Long-lived pumice floatation is unexpected, however, because pumice pores are highly connected and water wets volcanic glass. As a result, observations of long floating times have not been reconciled with predictions of rapid sinking. We propose a mechanism to resolve this paradox – the trapping of gas bubbles by water within the pumice. Gas trapping refers to the isolation of gas by water within pore throats such that the gas becomes disconnected from the atmosphere and unable to escape. We use X-ray microtomography to image partially saturated pumice and demonstrate that non-condensable gas trapping occurs in both ambient temperature and hot (500 °C) pumice. Furthermore, we show that the size distribution of trapped gas clusters matches predictions of percolation theory. Finally, we propose that diffusion of trapped gas determines pumice floatation time. Experimental measurements of pumice floatation support a diffusion control on pumice buoyancy and we find that floatation time τ scales as τ∝L2Dθ2 where L is the characteristic length of pumice, D is the gas–water diffusion coefficient, and θ is pumice water saturation. A mechanistic understanding of pumice floatation is a step towards understanding how pumice is partitioned into floating and sinking components and provides an estimate for the lifetime of pumice rafts in the ocean.

58 GEOSCIENCES↗
DOE OSTI2022

Diffusional lithium trapping as a failure mechanism of aluminum foil anodes in lithium-ion batteries

Aluminum foils are an appealing anode for lithium-ion batteries due to high capacity and low-cost, but their viability has been limited due to poor cyclability arising from pulverization and solid-electrolyte interphase growth. Here, we show that significant capacity degradation of aluminum foil anodes during electrochemical cycling also occurs due to diffusional lithium trapping. Scanning electron microscopy of cross-sectioned, cycled foils in the delithiated state reveals large regions of β-LiAl that are passivated by a surface layer of α-Al, which has poor Li + diffusivity. It is found that lithium diffusion occurs preferentially along the β-LiAl grain boundaries, so the grain structure after initial lithiation significantly affects the trapping behavior. Diffusional lithium trapping is exacerbated by both higher delithiation rates and higher areal capacity, presenting a challenge towards commercialization of aluminum foil anodes. We further demonstrate that diffusional trapping in aluminum foil anodes can be mitigated through alloy design, with the addition of 2–3 wt% Li yielding improved first cycle efficiency, and the addition of 1 wt% Si yielding improved cycle life. These results provide a mechanistic understanding of diffusional lithium trapping in aluminum foil anodes and highlight compositional design of alloys as a promising strategy to overcome it.

25 ENERGY STORAGE↗
DOE OSTI2016

Mobility-Selected Ion Trapping and Enrichment Using Structures for Lossless Ion Manipulations

The integration of ion mobility spectrometry (IMS) with mass spectrometry (MS) and the ability to trap ions in IMS-MS measurements is of great importance for performing reactions, accumulating ions, and increasing analytical measurement sensitivity. The development of Structures for Lossless Ion Manipulations (SLIM) offers the potential for ion manipulations in a more reliable and cost-effective manner, while opening opportunities for much more complex sequences of manipulations. Here, we demonstrate an ion separation and trapping module and a method based upon SLIM that consists of a linear mobility ion drift region, a switch/tee and a trapping region that allows the isolation and accumulation of mobility-separated species. The operation and optimization of the SLIM switch/tee and trap are described and demonstrated for the enrichment of the low abundance ions. Lastly, we observed a linear increase in ion intensity with the number of trapping/accumulation events using the SLIM trap, illustrating its potential for enhancing the sensitivity of low abundance or targeted species.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Trap-clearing Spectroscopy in Perylene Diimide Derivatives

Perylene diimide (PDI) derivatives are important components of organic circuits and photovoltaic systems, but the electron trapping mechanism(s) in higher-LUMO PDIs (–3 to –4 eV, where radical anions are expected to react with atmospheric water and oxygen) are not well characterized. In this work, we examine the spatial distribution of traps in transistors made from PDIs with these higher LUMO levels and measure trap-clearing spectra in n-type organic materials using time- and wavelength-resolved frequency-modulated Kelvin probe force microscopy (FM-KPFM). We find that the rate of trap-clearing under visible light does not follow a LUMO-level trend, and we observe spectral evidence for different trapping mechanisms on bare versus HMDS-treated SiO 2 .

36 MATERIALS SCIENCE↗