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At least 343 records · Page 19

Thermal-Structural Analysis of Sunshield Membranes

Future large infrared space telescopes, such as the James Webb Space Telescope (JWST), will require deployable sunshields to provide passive cooling for optics and instruments. Deployable sunshield structures for such applications typically consist of multiple thin-film membrane layers supported by deployable booms. The mechanical design of the sunshield must accommodate thermal strains due to layer-to-layer temperature differences as well as potentially large in-plane temperature gradients within individual film layers. This paper describes a thermal-structural analysis for predicting the stress state in a thin-film membrane subject to both mechanical thermal loads that could aid in the mechanical design of future sunshield structures. First the temperature field predicted by a thermal analysis is mapped to a structural finite element model, and then the structural response is predicted using a nonlinear static analysis. The structural model uses membrane elements in conjunction with a tension field material model to predict the response of the thin-film membrane layer. The tension field material model accounts for no-compression behavior associated with wrinkling and slackness. This approach was used to study the problem of a single membrane layer from the NASA reference concept for the JWST sunshield. Results from the analysis show that the membrane can experience a loss of tensile preload due to the presence of an in-plane temperature gradient representative of the cold-side layer temperature distribution predicted for the reference concept JWST.

Johnston, John↗

Thermocapillary migration of bubbles and droplets

A discussion is presented concerning the motion of droplets in a surrounding fluid induced by a temperature gradient. Such 'thermocapillary migration' may be characterized as the tangential stress at the interface that is induced by the temperature gradient's variation of interfacial tension, causing motion in the neighboring fluid both inside and outside the droplet. As a result, the droplet moves in the direction of the pole with the lower interfacial tension. An analysis is conducted in the creeping flow limit, for the case of small Marangoni number values. The method of matched asymptotic expansions is used for the solution of the field equations.

Subramanian, R. S.↗

Interpretation of electromagnetic modes in the sub-TAE frequency range in JET plasmas with elevated monotonic q-profiles

Recent JET deuterium experiments with an advanced tokamak scenario using an internal transport barrier (ITB) have been performed to clearly observe destabilized toroidicity-induced Alfvén eigenmodes (TAEs) by fast ions; interestingly, these also exhibit unstable electromagnetic (EM) perturbations in the sub-TAE frequency range. We identify such EM perturbations to be beta-induced ion temperature gradient (BTG) eigenmodes and not beta-induced Alfvén eigenmodes nor beta-induced Alfvén acoustic eigenmodes, which are often unstable in such high-beta plasmas with high-power neutral beam injection (NBI). The BTG modes are the most unstable modes due to the high thermal ion temperature gradient related to the ITB, high thermal ion temperature compared to thermal electron temperature (high T i /T⁠ e ), and a high ion beta regime. BTG mode experimental characteristics match the analytical theory, i.e., location in the vicinity of a rational magnetic surface with a low magnetic shear, mode frequency scaling with the ion diamagnetic frequency (⁠ω$^*_i$⁠), and a coupling among Alfvén and drift waves. We also perform linear gyrokinetic simulations with validated plasma profiles and equilibrium, and find a mode kinetically driven by thermal ions with similar characteristics as the experimental BTG modes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Geometrical evidence for dark matter: X-ray constraints on the mass of the elliptical galaxy NGC 720

We describe (1) a new test for dark matter and alternate theories of gravitation based on the relative geometries of the X-ray and optical surface brightness distributions and an assumed form for the potential, of the optical light, (2) a technique to measure the shapes of the total gravitating matter and dark matter of an ellipsoidal system which is insensitive to the precise value of the temperature of the gas and to modest temperature gradients, and (3) a new method to determine the ratio of dark mass to stellar mass that is dependent on the functional forms for the visible star, gas and dark matter distributions, but independent of the distance to the galaxy or the gas temperature. We apply these techniques to X-ray data from the ROSAT Position Sensitive Proportional Counter (PSPC) of the optically flattened elliptical galaxy NGC 720; the optical isophotes have ellipticity epsilon approximately 0.40 extending out to approximately 120 sec. The X-ray isophotes are significantly elongated, epsilon = 0.20-0.30 for semimajor axis a approximately 100 sec. The major axes of the optical and X-ray isophotes are misaligned by approximately 30 deg +/- 15 deg. Spectral analysis of the X-ray data reveals no evidence of temperature gradients or anisotropies and demonstrates that a single-temperature plasma (T approximately 0.6 keV) having subsolar heavy element abundances and a two-temperature model having solar abundances describe the spectrum equally well. Considering only the relative geometries of the X-ray and optical surface brightness distributions and an assumed functional form for the potential of the optical light, we conclude that matter distributed like the optical light cannot produce the observed ellipticities of the X-ray isophotes, independent of the gas pressure, the gas temperature, and the value of the stellar mass; this comparison assumes a state of quasi-hydrostatic equilibrium so that the three-dimensional surfaces of the gas emissivity trace the three-dimensional isopotential surfaces -- we discuss the viability of this assumption for NGC 720. Milgrom's Modification of Newtonian Dynamics (MOND) cannot dispel this manifestation of dark matter. Hence, geometrical considerations require, without mention of pressure or temperature, the presence of an extended, massive dark matter halo in NGC 720. Employing essentially the technique of Buote & Canizares (1992; Buote 1992) we use the shape of the X-ray surface brightness to constrain the shape of the total gravitating matter. The total matter is modeled as either an oblate or prolate spheriod of constant shape and orientation having either a Ferrers (rho approximately r(exp -n)) or Hernquist density. Assuming the X-ray gas is in hydrostatic equilibrium, we construct a model X-ray gas distribution for various temperature profiles. We determine the ellipticity of the total gravitating matter to be epsilon approximately 0.50-0.70. Using the single-temperature model we estimate a total mass approximately (0.41-1.4) x 10(exp 12) h(sub 80) solar mass interior to the ellipsoid of semimajor axis 43.6 h(sub 80) kpc. Ferrers densities as steep as r(exp -3) do not fit the data, but the r(exp -2) and Hernquist models yield excellent fits. We estimate the mass distributions of the stars and the gas and fit the dark matter directly. For a given gas equation of state and functional forms for the visible stars, gas, and dark matter, these models yield a distance-independent and temperature-independent measurement of the ratio of dark mass to stellar mass M(sub DM)/M(sub stars). We estimate a minimum M(sub DM)/M(sub stars) greater than or equal to 4 which corresponds to a total mass slightly greater than that derived from the single-temperature models for distance D = 20h(sub 80) Mpc.

Buote, David A.↗

Characterization of the Heat Extraction Capability of a Compliant, Sliding, Thermal Interface for Use in a High Temperature, Vacuum Microgravity Furnace

Much of the material science gained in microgravity research requires processing a sample in a high performance furnace. One such furnace currently being designed is the Quench Module Insert (QMI). The Principle Investigators, for whom the furnace is proposed, require high temperature gradients in their cylindrical samples to achieve the science objectives. One of the components critical to achieving high sample axial temperature gradients in the Quench Module Insert is a high performance cold zone to extract the heat from the sample. This cold zone employs a compliant, sliding thermal interface based on a Vel-Therm felt. This felt provides a conductive path between the Sample Cartridge Assembly (SCA) exterior surface and the interior surface of the water cooled chill block while allowing movement of the sample relative to the chill block. The Vel-Therm felt is composed of long polymer-based fibers affixed to a thin flexible substrate layer. The fibers are oriented perpendicular to this substrate giving the felt the appearance of a velvet fabric. The Vel-Therm felt heat extraction capability was quantified in earlier tests performed in an inert gas environment. The current activity, described in this paper, is intended to characterize the extraction capability of Vel-Therm felt in a vacuum environment similar to the QMI environment. This testing is necessary to quantify the thermal performance of the Vel-Therm felt and the sensitivity of that performance to key variables. The data derived from these tests will be incorporated into the current thermal models to improve the quality of the models and reduce uncertainty of the analytical results. In addition, the data will be used to help select the appropriate Vel-Therm felt and set proper operating limits as well as assess the performance range of the furnace. The objective of this test is to measure the heat extraction rate of the Vel-Therm felt as specified by the effective heat transfer coefficient. Therefore, the test setup was designed to force the bulk of the heat transfer through the area where the Vel-Therm felt was applied. A heat source, consisting of a ceramic heating element encased in a Copper (Cu) housing is mounted on four isolated support rods. A 6-layer molybdenum radiation shield is used to insulate against heat loss from the heater and prevent heat exchange between the hot and cold sides of the test apparatus. The Vel-Therm felt is affixed to the surface of the cold sink, a water-cooled Cu chill block. An adjustable plate supports and isolates the cold sink from above and is used to control the amount of the deflection of the Vel- Therm when in contact with the Cu heating element housing. The primary means of establishing the power being conducted through the felt is to measure the energy being transferred to the water passing through the chill block. Analysis was performed to support the assumption that the source and sink surfaces were approximately isothermal under the specific test conditions. As a check on the amount of power passing through the felt, the power supplied to the heater was also measured. Thermocouples were strategically located throughout the test apparatus for measurement purposes. A bell jar was lowered over the assembly to impose vacuum conditions. Currently, variables tested have been fiber compression and fiber type and surface temperatures (both the hot and cold side temperatures are hypothesized to be important to the performance of the Vel-Therm.) Selected runs were repeated to ensure consistency and repeatability. Results obtained thus far reveal that Vel-Therm performance is significantly degraded by fibers being exposed to high compression. It also shows that performance is somewhat negatively impacted by previous compression, thereby, raising the question of repeatability. In addition, early results show a significant dependence on temperature. A computer aided mathematical analysis of the test setup is ongoing. The results will be correlated to actual results. The correlation will examine such details as parasitic loses, conduction down the power leads and many other concerns.

Bellomy-Ezell, Jenny↗

Stellar model chromospheres. XIII - M dwarf stars

Single-component, homogeneous model chromospheres that are consistent with high-resolution profiles of the Ca II K line calibrated in surface flux units for three dMe and 2 dM stars observed at quiescent times are constructed. The models reveal several systematic trends. Large values of the ratio of T(min) to T(eff) are derived, indicating a large amount of nonradiative heating present in the upper photospheres of M dwarf stars. It is also found that the lower chromospheric temperature gradient is similar for all the M dwarf stars. Since for the models here the chromospheric K line emission strength is most sensitive to the total amount of chromospheric material present within the approximate temperature range T(min)-6000 K, increasing the emission strength is not simply due to increasing chromospheric temperature gradients. It is also found that both the electron density and electron temperature at one thermalization length in the K line below the top of the chromospheres are greater in the dMe stars than in the dM stars. The M dwarf models here have microturbulent velocities between 1 and 2 km/sec, which are much smaller than for solar chromosphere models.

Giampapa, M. S.↗

Observation and characterisation of trapped electron modes in Wendelstein 7-X

In the past, quasi coherent (QC) modes were reported for nearly all tokamaks. The general definition describes modes as QC when the magnitude squared coherence is in the range of 0.3 to 0.6. QC modes are observed in the plasma core as well as in the plasma edge and can have quite different physical origins. The one in the core are observed in plasmas with low collisionality, where the electron temperature exceeds the ion temperature in the plasma core. This is the case for electron cyclotron heating in general. The origin of these modes are electrons trapped within a magnetic mirror, as reported in the past from various fusion devices. The so-called trapped-electron modes (TEMs) belong to drift wave instabilities and can be destabilized by electron-temperature gradients in the plasma core. From the diagnostic point of view, QC modes appear as fluctuations in electron density and temperature. Therefore, the microwave reflectometer is very well suited to monitor these modes. This paper describes experiments, conducted at the Wendelstein 7-X stellarator (W7-X), which aim at detecting QC modes at low wave numbers. A poloidal correlation reflectometer installed at W7-X, is able to measure low wave numbers ($k_\perp\unicode{x2A7D}{3.5}\,\textrm{cm}^{-1}$). For medium line-averaged densities ($\int n_\textrm{e}\unicode{x2A7D}{6 \times10^{19}}\,\textrm{m}^{-2}$) the plasma core is accessible for this diagnostic. For different magnetic configurations and plasma parameters, broad QC structures are observed in the coherence spectra. From the analysis of the rotation and the poloidal structure, these QC modes show the properties of electron-temperature-gradient driven TEMs. A linear relation between the mode velocity and the rotation frequency is found. The relation is uniform and confirms the nature of QC-mode observation as TEM in tokamaks, too.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Turbulence-Driven Edge-Localized-Mode-Free High-Confinement Mode with Divertor Detachment in a Metal-Wall Tokamak

We report the first demonstration of a minute-scale, edge-localized-mode-free high-confinement plasma regime compatible with divertor partial detachment and enhanced pedestal performance in a metal-wall tokamak, the Experimental Advanced Superconducting Tokamak. This regime is enabled by a newly identified mechanism: during divertor partial detachment, reduced ionization and enhanced pumping in a closed divertor lead to less cooling of the pedestal by recycling neutrals and seeding impurities, resulting in an increased pedestal temperature gradient, which excites high-frequency broadband turbulence. Gyrokinetic simulations identify the high-frequency broadband turbulence as a temperature-gradient-driven trapped electron mode (𝜂 𝑒 -TEM), which drives outward transport of particles and heat, thereby maintaining the edge-localized-mode-free state. This pedestal regime is particularly promising for the International Thermonuclear Experimental Reactor, where the anticipated lower density gradient, reduced E×B shear, and lower collisionality in the pedestal will further facilitate 𝜂 𝑒 -TEM excitation. The achieved integrated scenario with a detached divertor and turbulence-dominated pedestal thus offers a compelling solution for managing heat loads and metal impurity sources for long-pulse high-performance operation in future fusion reactors.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

A compact furnace to support in situ neutron imaging of hydrogen dynamics in yttrium hydride moderators

A compact, nuclear microreactor that utilizes low-enriched uranium fuel is a promising solution to meet U.S. energy demands in nonconventional nuclear markets such as remote and decentralized energy grids. Yttrium hydride (YHx) is a potential moderator material for a microreactor design that reduces the amount of required fuel and provides superior retention of hydrogen at high reactor operating temperatures. Hydrogen diffusion properties in YHx are highly sought after for computer model validation and reactor prototyping. To characterize hydrogen diffusion, a compact dual-zone furnace was developed at Los Alamos National Laboratory and analyzed via neutron imaging at the Los Alamos Neutron Science Center (LANSCE). The goal of these measurements is to assess hydrogen diffusion in YHx samples as a function of applied temperature gradients. Included herein is recent progress in technique and furnace developments as well as initial results from concentration- and temperature-gradient measurements at LANSCE.

Torres, James↗

CODE-TO-CODE BENCHMARK STUDY FOR THERMAL STRESS MODELING AND PRELIMINARY ANALYSIS OF THE HIGH-TEMPERATURE SINGLE HEAT PIPE EXPERIMENT

Microreactors are very small nuclear reactors with typical thermal-energy output of up to 20 MWth. The microreactor concept is gaining more and more attention for safe, robust, and reliable supply of electricity for remote locations and to meet industrial process heat needs. Heat-pipe-cooled microreactor is one of the microreactors being investigated at Idaho National Laboratory. In the heat-pipe-cooled microreactor, heat pipes remove heat from the reactor core as a passive heat-transfer device, so the fluid circulation is not required for cooling, which can substantially simplify the overall reactor design. However, given the extremely high temperatures in the core region and potentially large temperature gradients across the structure materials, thermal stresses need to be well-analyzed to ensure structural integrity during normal operations and accident scenarios for the heat-pipe-cooled microreactor designs. This paper discusses finite element method-based thermal-stress analysis for the high-temperature single heat-pipe test article in the Single Primary Heat Extraction and Removal Emulator (SPHERE) facility at Idaho National Laboratory, using two commercial software packages, Abaqus and STAR-CCM+. A code-to-code benchmark study was performed to crosscheck the model setup and capability of each code and to gain insights into the potential thermal stress concerns from the current experimental setup. It is observed the significant thermal stresses happen at the locations where the largest temperature gradients appeared between heat pipe and electric heater. The temperature fields have good agreements between Abaqus and STAR-CCM+, while the induced thermal stresses show modest deviations probably due to differences of meshing engines used in these two codes.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

New understanding of inter-ELM pedestal turbulence, transport, and gradient behavior in the DIII-D tokamak

New observations of pedestal localized turbulence in the inter-ELM period of H-mode plasmas in DIII-D show that ion temperature gradient mode scale (ITG-scale) density fluctuation (ñ) increases immediately after each ELM crash and is quickly suppressed during the increase in local E × B shear. This excitation and subsequent suppression of ITG-scale ñ can explain the previously reported anomalous ion heat flux, Qi during the ELM (Viezzer et al 2017 Nucl. Fusion 57 022020). Shorter wavelength trapped electron mode scale (TEM-scale) ñ starts to increase at a critical pedestal temperature gradient (∇Te,ped) and saturates as local E × B shear, ${T}_{\mathrm{i}}^{\mathrm{C}\mathrm{6}+}/{T}_{\mathrm{e}}$ ratio, and ∇Te,ped saturate. This TEM-scale ñ, which has the potential to cause electron (and also ion) heat transport, is consistent with driving an anomalous electron heat flux Qe, where Qe is estimated between ELMs using experimental profiles and power balance. Both ITG- and TEM-scale ñ amplitude variations with background Ti/Te and ∇ne,ped are found to be consistent with theoretical predictions of these measured density fluctuations being ITG and TEM instabilities respectively. Furthermore, these new and unique observations on the nature of turbulence and their potential contributions to electron and ion heat fluxes at different ELM periods (i.e. collapse, recovery, and saturation phases of pedestal gradients) can significantly test and improve our pedestal predictive capabilities for ITER and other future fusion devices.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Comparison of U.K. Meteorological Office and U.S. National Meteorological Center Stratospheric Analyses During Northern and Southern Winter

Meteorological data from the United Kingdom Meteorological Office (UKMO), produced using a data assimilation system, and the U.S. National Meteorological Center (NMC), produced using an objective analysis procedure, are compared for dynamically active periods during the Arctic and Antarctic winters of 1992. The differences seen during these periods are generally similar to those seen during other winter periods. Both UKMO and NMC analyses capture the large-scale evolution of the stratospheric circulation during northern hemisphere (NH) and southern hemisphere (SH) winters. Stronger vertical and horizontal temperature gradients develop in the UKMO than in the NMC data during stratospheric warmings; comparison with satellite measurements with better vertical resolution suggests that the stronger vertical temperature gradients are more realistic. The NH polar vortex is slightly stronger in the UKMO analyses than in the NMC in the middle and upper stratosphere, and midstratospheric temperatures are slightly lower. The SH polar vortex as represented in the UKMO analyses is stronger and colder in the midstratosphere than its representation in the NMC analyses. The UKMO analyses on occasion exhibit some difficulties in representing cross-polar flow or changes in curvature of the wind field at very high latitudes. In addition to the above study of two wintertime periods, a more detailed comparison of lower-stratospheric temperatures is done for all Arctic and Antarctic winter periods since the launch of the Upper Atmosphere Research Satellite. In the NH lower stratosphere during winter, NMC temperatures are consistently lower than UKMO temperatures and closer to radiosonde temperatures than are UKMO temperatures. Conversely, in the SH lower stratosphere during winter, UKMO temperatures are typically lower than NMC and are closer to radiosonde temperature observations.

Manney, G. L.↗

A comparison between Nimbus 5 THIR and ITPR temperatures and derived winds with rawinsonde data obtained in the AVE 2 experiment

During the period of May 11 and 12, 1974, NASA conducted its second Atmospheric Variability Experiment (AVE II) over the eastern United States. In this time interval, two Nimbus 5 orbits crossed the AVE II area, providing a series of ITPR soundings as well as THIR data. Horizontal temperature mapping of the AVE II cloud field is examined using two grid print map scales. Implied cloud top heights are compared with maximum radar-echo top reports. In addition, shelter temperatures in areas of clear sky are compared with the surface temperatures as determined from 11.5 micrometer radiometer data of the THIR experiment. The ITPR sounding accuracy is evaluated using interpolated radiosonde temperatures at times nearly coincident with the ITPR soundings. It was found that mean differences between the two data sets were as small as 1.3 C near 500 mb and as large as 2.9 C near the tropopause. The differences between ITPR and radiosonde temperatures at constant pressure levels were sufficient to induce significant differences in the horizontal temperature gradient. Cross sections of geostrophic wind along the orbital tracks were developed using a thermal wind buildup based on the ITPR temperature data and the radiosonde temperature data. Differences between the radiosonde and ITPR geostrophic winds could be explained on the basis of differences in the ITPR and radiosonde temperature gradients.

Arnold, J. E.↗

Modeling of collision and coalescence of droplets during microgravity processing of Zn-Bi immiscible alloys

A population balance model is presented for the coarsening of the dispersed phase of liquid-liquid two-phase mixtures in microgravity due to gravity sedimentation and Marangoni migration, which lead to the collision and coalescence of droplets. The model is used to predict the evolution of the size distribution of the dispersed phase in a liquid-phase miscibility gap system, Zn-Bi, which has been used in a number of experimental microgravity processing studies in which significant phase segregation has been observed. The analysis shows that increasing the temperature gradient, gravity level, volume fraction of the dispersed phase, initial average drop radius, initial standard deviation of droplet radii, or the temperature coefficient of the interfacial tension leads to an increase in the rate of droplet growth due to collision and coalescence. Comparison of the distribution evolutions for unimodal and bimodal initial distributions shows that the latter yield significantly more rapid droplet growth. Finally, it is shown that droplet growth can be dramatically reduced with antiparallel orientation of the gravity vector and the temperature gradient, provided that the relative magnitude of these two vectors is properly chosen.

Davis, R. H.↗

Rheological Properties of Quasi-2D Fluids in Microgravity

Freely suspended smectic films of sub-micrometer thickness and lateral extensions of several millimeters are used to study thermally driven convection and diffusion in the film plane. The experiments were performed during a six minute microgravity phase of a TEXUS suborbital rocket flight (Texus 52, launched April 27, 2015). The project served as a preliminary test for a planned ISS Experiment with liquid crystal films (OASIS), and in addition it provided new experimental data on smectic films exposed to in-plane thermal gradients.We find an attraction of the smectic material towards the cold edge of the film in a temperature gradient, similar to a Soret effect. This process is reversed when this edge is heated up again. Thermal convection driven by two thermocontacts in the film is practically absent, even at temperature gradients up to 10 Kmm, thermally driven convection sets in when the hot post reaches the transition temperature to the nematic phase.An additional experiment was performed under microgravity conditions to test the stability of liquid crystal bridges in different smectic phases.

microgravity↗

Process-microstructure relationship of laser processed thermoelectric material Bi2Te3

Additive manufacturing allows fabrication of custom-shaped thermoelectric materials while minimizing waste, reducing processing steps, and maximizing integration compared to conventional methods. Establishing the process-structure-property relationship of laser additive manufactured thermoelectric materials facilitates enhanced process control and thermoelectric performance. This research focuses on laser processing of bismuth telluride (Bi 2 Te 3 ), a well-established thermoelectric material for low temperature applications. Single melt tracks under various parameters (laser power, scan speed and number of scans) were processed on Bi 2 Te 3 powder compacts. A detailed analysis of the transition in the melting mode, grain growth, balling formation, and elemental composition is provided. Rapid melting and solidification of Bi 2 Te 3 resulted in fine-grained microstructure with preferential grain growth along the direction of the temperature gradient. Experimental results were corroborated with simulations for melt pool dimensions as well as grain morphology transitions resulting from the relationship between temperature gradient and solidification rate. Samples processed at 25 W, 350 mm/s with 5 scans resulted in minimized balling and porosity, along with columnar grains having a high density of dislocations.

Oztan, Cagri↗

Thermal modeling of nickel-hydrogen battery cells operating under transient orbital conditions

An analytical study of the thermal operating characteristics of nickel-hydrogen battery cells is presented. Combined finite-element and finite-difference techniques are employed to arrive at a computationally efficient composite thermal model representing a series-cell arrangement operating in conjunction with a radiately coupled baseplate and coldplate thermal bus. An aggressive, low-mass design approach indicates that thermal considerations can and should direct the design of the thermal bus arrangement. Special consideration is given to the potential for mixed conductive and convective processes across the hydrogen gap. Results of a compressible flow model are presented and indicate the transfer process is suitably represented by molecular conduction. A high-fidelity thermal model of the cell stack (and related components) indicates the presence of axial and radial temperature gradients. A detailed model of the thermal bus reveals the thermal interaction of individual cells and is imperative for assessing the intercell temperature gradients.

Schrage, Dean S.↗

Behavior of a Salt Water Solution Near the Critical Point Under Microgravity Conditions

The Supercritical Water Mixture (SCWM) experiment conducted on the International Space Station (ISS) is designed to study a salt-water solution in the vicinity of the critical transition with a test cell filled with Na2SO4 (aq) 0.5-w. This salt is a Type II salt which undergoes a dramatic decrease in solubility past waters critical point. The paper discusses the liquid-vapor-salt distribution in the test cell for subcritical, trans-critical, and supercritical regimes. In 0-g, the vapor-liquid interface manifests itself by the presence of a large single vapor bubble that is flattened between the two windows. In contrast with pure water, the vapor bubble remains centered in the test cell and is stable for temperatures up to Tc - 50 mK. The processes leading to critical transition during heat-up, as marked by the break-up of the vapor bubble, depends on the applied heating rate. For temperature ramps 1 mKmin, the bubble interface begins to breakup with the formation of a large number of smaller bubbles. For larger temperature ramps (10mKmin), temperature gradients arise in the cell pushing the bubble toward a window surface. As the critical threshold is crossed small variations in cell temperature ( 1 mK) cause an observable spatial variation in density. However, this spatial variation is not discernible as the temperature is increased further into the supercritical regime. The salt precipitation in the vicinity of the critical crossing appears to be heterogeneous in nature with precipitates observable on the cell windows. Direct imaging as well as light scattering indicate a hexagonal structure of the precipitated salt crystals in the near critical regime. The salt deposition is not fully reversible as the temperature is reduced due to window corrosion effects which traps some of the precipitated salt. Critical temperatures as high as 1.9 K above the value for pure water (647.25 K) have been measured. Finally, results on the critical transition phenomena in the presence of an imposed temperature gradient, demonstrating the remarkable stability of the central bubble, are also presented.

near-critical↗