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At least 343 records · Page 19

Membrane Adsorbents Comprising Self-Assembled Inorganic Nanocages (SINCs) for Super-fast Direct Air Capture Enabled by Passive Cooling

The objectives of the proposed project were to develop highly porous membrane adsorbents comprising CO 2 -philic polymers and self-assembled inorganic nanocages (SINCs) for rapid temperature swing adsorption using electricity-free solar heating and radiative cooling, enabling an economically viable approach for direct air capture (DAC). Our core technical activities combine three key innovations. (1) Highly porous flat-sheet membrane adsorbents contain CO 2 -philic amines that can be easily produced using a phase inversion method. (2) CO 2 -philic SINCs can be easily dispersed in the polymers with great stability (compared with the metal-organic frameworks or MOFs). (3) The adsorption and desorption are integrated with solar heating and radiative cooling for rapid continuous operation, in contrast to traditional long-cycle separate operation. The membrane adsorbents containing amines, polymers, and SINCs were produced using a one-step industrial process. The porous membranes coupled with porous SINCs offer low resistance for gas flow and fast CO 2 sorption/desorption cycles, while the incorporation of the additional amine groups provides high CO 2 sorption capacity. The key achievements are summarized below. (1) Membrane adsorbents with high PEI loading (>40%), high porosity of >80%, and low gasflow resistance were prepared in one step using commercially available, low-cost materials. (2) Membrane adsorbents based on Solupor and PEI show CO 2 sorption capacity of >1.5 mmol/g using air containing 400 ppm at a relative humidity of 15%. (3) Effect of the adsorbent compositions (such as PEI type, PEI content, SINC content, porosity) on the CO 2 sorption was systematically investigated. (4) Effect of the processing conditions (such as CO 2 content, temperature, and relative humidity) on the CO 2 sorption was systematically investigated; (5) The stability of the membrane adsorption against many cycles of sorption and desorption was studied. The higher molecular weight of PEI (PEI25k) shows better stability than PEI800. (6) Advanced materials with radiative cooling were developed, which can decrease the temperature by 5-7 °C compared to the ambient temperature. (7) Preliminary techno-economic analysis shows that our process may achieve a capture cost of $1,343/tonne CO 2 with a total OPEX cost of $1,112/tonne CO 2 . The adsorbent replacement cost accounted for 52% of the total OPEX cost. Membrane adsorbents with lower costs and longer operation life can significantly decrease the cost. The proposed project directly addresses the requirement of DE-FOA-0002188, i.e., novel materials with CO 2 adsorption capacity for direct air capture with integrated solar heating and radiative cooling to reduce the cost of the DAC. Our future work will focus on the development of low-cost adsorbents that can be stable at the sorption and desorption conditions for long term.

14 SOLAR ENERGY↗

Potential impacts of climate change on wind and solar electricity generation in Texas

Wind and solar energy sources are climate and weather dependent, therefore susceptible to a changing climate. in this paper, we quantify the impacts of climate change on wind and solar electricity generation under high concentrations of greenhouse gases in Texas. We employ mid-twenty-first century climate projections and a high-resolution numerical weather prediction model to generate weather variables in the future and produce wind and solar generation time series. We find that mid-twenty-first century projections based on five global climate models agree on the multiyear average increases across Texas in direct normal irradiance, global horizontal irradiance, surface air temperature, and 100-m wind speed of up to 5%, 4%, 10%, and 1%, respectively. These changes lead to multiyear average relative changes across Texas of -0.6 to + 2.5% and of + 1.3 to + 3.5% in solar and wind capacity factors, respectively, with significant regional, seasonal, and diurnal differences. Areas with low solar resource show an increase in solar capacity factors but reductions in wind capacity factors. Areas with high solar resource show reductions in solar capacity factors. The spatial and temporal differences in our results highlight the importance of using high-resolution data sets to study the potential impacts of climate change on wind and solar power.

14 SOLAR ENERGY↗

The Role of Snowmelt Temporal Pattern in Flood Estimation for a Small Snow‐Dominated Basin in the Sierra Nevada

Abstract Prior research confirmed the substantial bias from using precipitation‐based intensity‐duration‐frequency curves (PREC‐IDF) in design flood estimates and proposed next‐generation IDF curves (NG‐IDF) that represent both rainfall and snow processes in runoff generation. This study improves the NG‐IDF technology for a snow‐dominated test basin in the Sierra Nevada. A well‐validated physics‐based hydrologic model, the Distributed Hydrology Soil Vegetation Model (DHSVM), is used to continuously simulate snowmelt and streamflow that are used as benchmark data sets to systematically assess the NG‐IDF technology. We find that, for the studied small snow‐dominated basin, the use of standard rainfall hyetographs in the NG‐IDF technology leads to substantial underestimation of design floods. Thus, we propose probabilistic hyetographs that can represent unique patterns of events with different underlying mechanisms. For the test basin where flooding events are generated entirely by snowmelt, we develop a hyetograph that characterizes snowmelt temporal patterns, which greatly improves the performance of NG‐IDF technology in design flood estimates. In contrast to the standard rainfall hyetographs characterized by a symmetrically peaked, bell‐shaped curve, the snowmelt hyetograph displays a more rapid rise (i.e., greater intensity) and a distinct diurnal pattern influenced by solar energy input. The results also show that the uncertainty of hyetography plays an important role in design flood estimation and can have important implications for future flood projections.

54 ENVIRONMENTAL SCIENCES↗

Fabrication, Modeling, and Testing of a Prototype Thermal Energy Storage Containment

Increasing penetration of variable renewable energy resources requires the deployment of energy storage at a range of durations. Long-duration energy storage (LDES) technologies will fulfill the need to firm variable renewable energy resource output year round; lithium-ion batteries are uneconomical at these durations. Thermal energy storage (TES) is one promising technology for LDES applications because of its siting flexibility and ease of scaling. Particle-based TES systems use low-cost solid particles that have higher temperature limits than the molten salts used in traditional concentrated solar power systems. A key component in particle-based TES systems is the containment silo for the high-temperature (>1100 degrees C) particles. This study combined experimental testing and computational modeling methods to design and characterize the performance of a particle containment silo for LDES applications. A laboratory-scale silo prototype was built and validated the congruent transient finite element analysis (FEA) model. The performance of a commercial-scale silo was then characterized using the validated model. The commercial-scale model predicted a storage efficiency above 95% after 5 days of storage with a design storage temperature of 1200 degrees C. Insulation material and concrete temperature limits were considered as well. The validation of the methodology means the FEA model can simulate a range of scenarios for future applications. This work supports the development of a promising LDES technology with implications for grid-scale electrical energy storage, but also for thermal energy storage for industrial process heating applications.

clean energy↗

The physiological basis for estimating photosynthesis from Chl>em>a fluorescence

We report solar-induced Chl fluorescence (SIF) offers the potential to curb large uncertainties in the estimation of photosynthesis across biomes and climates, and at different spatiotemporal scales. However, it remains unclear how SIF should be used to mechanistically estimate photosynthesis. In this study, we built a quantitative framework for the estimation of photosynthesis, based on a mechanistic light reaction model with the Chla fluorescence of Photosystem II (SIFPSII) as an input (MLR-SIF). Utilizing 29 C 3 and C 4 plant species that are representative of major plant biomes across the globe, we confirmed the validity of this framework at the leaf level. The MLR-SIF model is capable of accurately reproducing photosynthesis for all C 3 and C 4 species under diverse light, temperature, and CO 2 conditions. We further tested the robustness of the MLR-SIF model using Monte Carlo simulations, and found that photosynthesis estimates were much less sensitive to parameter uncertainties relative to the conventional Farquhar, von Caemmerer, Berry (FvCB) model because of the additional independent information contained in SIF PSII . Once inferred from direct observables of SIF, SIF PSII provides ‘parameter savings’ to the MLR-SIF model, compared to the mechanistically equivalent FvCB model, and thus avoids the uncertainties arising as a result of imperfect model parameterization. Our findings set the stage for future efforts to employ SIF mechanistically to improve photosynthesis estimates across a variety of scales, functional groups, and environmental conditions.

59 BASIC BIOLOGICAL SCIENCES↗

PV Module Design for Recycling Guidelines

The global growth of clean energy technology deployment will be inexorably followed by a parallel growth of end-of-life (EOL) products that bring both challenges and opportunities. Cumulatively, by 2050, estimates project 78 million tonnes of raw materials embodied in the mass of EOL photovoltaic (PV) modules. Owing partly to concern that the projected growth of clean energy technologies could become constrained by availability of raw materials, despite ongoing dematerialization efforts, significant attention under the umbrella of circular economy has been brought to recycling these technologies at EOL. Yet PV has not been designed with recycling at EOL in mind, and it presents challenges to returning embodied raw materials back to use in new products through recycling. This study aims to inform future designs to improve recyclability through synthesis of prior published works augmented by novel recommendations that result in a set of general design for recycling (DfR) guidelines, with a subset specific to PV modules. We further discuss how established trends in design of PV modules could affect recyclability. If adopted today, application of these DfR guidelines could help to mitigate tomorrow's resource scarcity, lower the barriers and cost for PV recycling, and enable a circular economy during the energy transition.

14 SOLAR ENERGY↗

Measurements of aerosol microphysical and chemical properties in the central Arctic atmosphere during MOSAiC

The Arctic environment is transforming rapidly due to climate change. Aerosols’ abundance and physicochemical characteristics play a crucial, yet uncertain, role in these changes due to their influence on the surface energy budget through direct interaction with solar radiation and indirectly via cloud formation. Importantly, Arctic aerosol properties are also changing in response to climate change. Despite their importance, year-round measurements of their characteristics are sparse in the Arctic and often confined to lower latitudes at Arctic land-based stations and/or short high-latitude summertime campaigns. Here, we present unique aerosol microphysics and chemical composition datasets collected during the year-long Multidisciplinary drifting Observatory for the Study of Arctic Climate (MOSAiC) expedition, in the central Arctic. These datasets, which include aerosol particle number concentrations, size distributions, cloud condensation nuclei concentrations, fluorescent aerosol concentrations and properties, and aerosol bulk chemical composition (black carbon, sulfate, nitrate, ammonium, chloride, and organics) will serve to improve our understanding of high-Arctic aerosol processes, with relevance towards improved modelling of the future Arctic (and global) climate.

54 ENVIRONMENTAL SCIENCES↗

Transformational Opacity Platforms on the Z Facility: A Design Study

The goal of this one-year LDRD is to study novel experimental approaches to provide benchmark spectral opacity measurements at the most extreme conditions beyond existing measurements (i.e. 2x temperature, ~5x density). These conditions correspond to those at half the solar radius and would provide a unique and novel test for stellar physics. These conditions are also relevant to advance stockpile stewardship research. The basic idea is to embed a sample inside the z-pinch dynamic hohlraum on the Z facility and obtain its opacity from either 1) its self-emission or 2) its absorption from using a capsule backlighter. This study evaluates the feasibility, limitations to these two approaches from a design approach. We found that emission-based perspective gives, at best, an opacity accuracy of about 20% for the current studied pinch conditions due to the limit of LTE approximation and radiation transport effects. The capsule-backlighter-based approach overcomes this limitation although some specific design questions remain to be answered. Promising designs are proposed for follow-on Z experiments. Future designs would help maintain Z relevancy in relation to ignition-enabled platforms at NIF.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Impact of the Latest 22 Ne+ α Reaction Rates on Nucleosynthesis in Massive Stars and Galactic Chemical Evolution

In massive stars (initial mass of ≳9 M ⊙ ), the weak s- (slow neutron capture) process produces elements between Fe and Zr, enriching the Galaxy with these elements through core-collapse supernova explosions. The weak s-process nucleosynthesis is driven by neutrons produced in the 22 Ne(α, n) 25 Mg reaction during convective He core and C shell burning. The yields of heavy elements thus depend on the 22 Ne(α, n) 25 Mg and the competitive 22 Ne(α, γ) 26 Mg reaction rates, which are dominated by several narrow-resonance reactions. While the accuracy of these rates has been under debate for decades, recent experimental efforts, including ours, drastically reduced these uncertainties. In this work, we use a set of 280 massive star nucleosynthesis models calculated using different 22 Ne(α, n) 25 Mg and 22 Ne(α, γ) 26 Mg rates and a galactic chemical evolution (GCE) study to probe their impact on the weak s-process elemental abundances in the Galaxy. The GCE was computed with the OMEGA+ code, using the new sets of stellar yields with different 22 Ne+α rates. From GCE, we find that these rates are causing up to 0.45 dex of variations in the [Cu/Fe], [Ga/Fe], and [Ge/Fe] ratios predicted at solar metallicity. The greatest impact on the stellar nucleosynthesis and GCE results derives from uncertainties in the (α, n) strength (ωγ (α,n) ) of the E x = 11.32 MeV resonance. We show that variations observed in the GCE calculations for weak s-process elements become negligibly smaller than dispersions found in observations once the ωγ (α,n) is accurately determined within the uncertainty of 10%–20% (typically reported experimental errors for the resonance) in future nuclear physics experiments.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Thermal Ratcheting Analysis of TEDS Packed-bed Thermocline Energy Storage Tank - Modeling Methodology and Data Validation

This report investigates numerical modeling methods for thermal ratcheting analysis of packed-bed thermal energy storage (TES) tank and discusses the validation results via comparison with experimental data. The experimental data obtained from various design characteristics of packed-bed thermocline tanks, including the Thermal Energy Distribution System (TEDS) TES tank at Idaho National Laboratory (INL), were used to validate thermal and mechanical models developed in this study to evaluate the thermal ratcheting potential. The thermal model was shown to predict the transient thermal propagation through the packed-bed thermocline tanks generally well. However, a larger discrepancy was observed during the comparison with the data from TEDS, presumably due to the uncertainty of boundary conditions given from the experiment. Based on the comparative study between the thermal model predictions and experimental data of various packed-bed thermocline tanks, potential improvements were suggested for the future TEDS experiments for more precise validation study. For mechanical (thermally induced stress) analysis, two different modeling approaches were tested to evaluate hoop stress applied to the packed-bed TES tank wall, which is a major cause of thermal ratcheting process: (i) infinite rigidity model and (ii) Drucker-Prager (DP) model. The ‘model (i)’ is a conservative method with infinite rigidity assumption of granular filler inside a TES tank, whereas the ‘model (ii)’ is a method that takes into account more realistic processes such as thermal expansion of filler and tank wall as well as inter-particle interactions during the cyclic operation of a packed-bed TES tank. The validity of each modeling method was examined by comparing the numerical simulation with the experimental data obtained from the packed-bed TES tank for Solar One pilot plant. Then, the effects of various model parameters were discussed to evaluate the thermal ratcheting potential of the TEDS TES tank. The preliminary thermal ratcheting analysis implies that the TEDS TES tank will hold its structural integrity during the normal operation cycles.

25 ENERGY STORAGE↗

Comprehensive techno-economic and life cycle greenhouse gases analysis of green ammonia production utilizing PV and wind energy: Jordan as a case study

Ammonia (NH 3 ) has emerged as a critical player in the global energy transition due to its potential as a low-carbon fuel. Conventional ammonia production methods, primarily through steam methane reforming, are significant contributors to global CO 2 emissions. This study investigates the potential of green ammonia production in Jordan by leveraging the country's abundant solar photovoltaic and wind energy resources. A comprehensive techno-economic and life cycle greenhouse gas analysis was conducted to compare green ammonia production with conventional grey and blue ammonia pathways. Here, the study utilized spatial mapping to assess renewable energy capacity factors across Jordan and optimized the integration of hybrid PV/wind systems with proton exchange membrane (PEM) electrolyzers. The results indicate that the levelized cost of green ammonia (LCOA) in Jordan varies between 900 USD/kg NH 3 and 2500 USD/kg NH 3 which is significantly higher than grey ammonia (similar to 360 USD/kg NH 3 ). Nevertheless, the carbon intensity of green ammonia production (between 0.1 kg CO 2eq /kg NH 3 and 0.5 kg CO 2eq /kg NH 3 ) is much lower than the grey ammonia (1.8 kg CO 2eq /kg NH 3 ). Finally, the results indicate that considering future reductions in capital costs and advancement in renewable energy systems and PEM electrolyzers as well as the ability to sell the co-product O 2 can reduce the LCOA by up to 92 % and make it competitive with grey ammonia.

Green Ammonia↗

The Composite Spectrum of QSO Absorption Line Systems in DESI DR2

We present details regarding the construction of a composite spectrum of quasar (QSO) absorption line systems. In this composite spectrum we identify more than 70 absorption lines, and observe oxygen and hydrogen emission features at a higher signal-to-noise ratio than in any previous study. As the light from a distant quasar travels towards an observer, it may interact with the circumgalactic medium environment of an intervening galaxy, forming absorption lines. In order to maximize the signal of these absorption lines, we have selected a sample of 238,838 quasar spectra from the second data release of the Dark Energy Spectroscopic Instrument (DESI), each identified to have absorption lines resulting from such an interaction. By stacking these spectra in the restframe of the absorption, and calculating a median composite spectrum, we are able to isolate and enhance these absorption lines. We provide a full atlas of all detected absorption and emission lines as well as their fit centroids and equivalent width values. This atlas should aid in future studies investigating the compositions and physical conditions of these absorbers.

Napolitano, Lucas [Wyoming U.] (ORCID:000000025166↗

Optoelectronic and material properties of solution-processed Earth-abundant Cu 2 BaSn(S, Se) 4 films for solar cell applications

Copper barium thioselenostannate, Cu 2 BaSnS 4-x Se x (CBTSSe), absorbers employ low-toxicity and abundant metals while offering low-cost manufacturing options, controllable stoichiometry and band gap tunability (from 2 eV at x = 0 to 1.55 eV at x = 3). CBTSSe can therefore be considered a prospective candidate for maintaining or improving upon the advantages of already commercialized Cu(In,Ga)(S,Se) 2 (CIGSSe) and CdTe absorbers. Here, we focus on solution-deposited stoichiometric CBTSSe films with band gap of 1.59 eV (x ≈ 3) and explore the fundamental film properties. Temperature- and excitation-dependent photoluminescence studies reveal a dominant defect emission at ~1.5 eV and a second deep defect feature at 1.15 eV. From time-resolved terahertz measurements, we find a charge carrier (electron and hole sum) mobility of ~140 cm 2 /Vs—i.e., comparable to values in CIGSSe or Cu 2 ZnSnS 4-x Se x (CZTSSe)—as well as a two-component minority carrier lifetime. A longer-lived lifetime component (~2 ns) arises from bulk recombination. However, strong recombination at the (bare) surface leads to a ~50 ps lifetime, inferior to state-of-the-art CIGSSe or CZTSSe absorbers. This recombination issue may worsen for CBTSSe/CdS interfaces, due to a cliff-like band alignment with 0.6 eV band offset, as revealed by ultraviolet photoemission spectroscopy. A low number of charge carriers within the absorber further contributes to a high series resistance. Employing these films, we also report the highest performance achieved from solution-processed trigonal CBTSSe thin-film photovoltaic devices, with open circuit voltage, short-circuit current density, fill factor and efficiency of 470 mV, 14.3 mA/cm 2 , 43.6% and 2.9%, respectively. The physical measurements provided on the stoichiometric solution-processed CBTSSe absorber further point to critical areas for future improvement of CBTSSe and related photovoltaic cells in the quest for higher efficiency devices based on earth abundant metals.

14 SOLAR ENERGY↗

Community-Centric Microgrid Feasibility Analysis Framework to Accelerate Resilience of Island Communities

Marine energy offers a reliable energy solution for island and coastal communities, which often lack traditional local generation, to support their transition to energy independence and reduce reliance on externally imported fuels. Successful deployment of new technologies in these isolated locations requires community acceptance and approval from the outset, as these communities typically lack the financial and technical resources to operate and maintain new systems. This report presents a community-centric microgrid planning framework for remote coastal and island communities. Community engagement is integrated as the first step in the planning process, incorporating community profiles and visions into energy development scenarios. A case study was conducted in St. George, Pribilof Islands, Alaska, which relies entirely on diesel yet has significant wind and wave energy potential. Community engagement revealed a unique history and current economic status, with an interest in adopting advanced energy technologies despite past failures. Various microgrid configurations were optimized, considering different technologies to meet current and future energy needs while balancing cost and energy resilience. Wave energy converters (WECs) were a key component, integrated with other energy sources using the Xendee optimization tool. The Marine Energy Microgrid Toolkit, developed as part of this work, uses commercial power system analysis tools to optimize and analyze microgrid scenarios. The developed framework and toolkit can be applied to island and coastal communities to enhance resilience and support microgrid deployments. Future enhancements will include incorporating new marine resources, developing dynamic models, and automating the integration of Xendee and PowerFactory simulations.

02 PETROLEUM↗

Estimation of solar photovoltaic energy curtailment due to volt–watt control

The widespread deployment of autonomous inverter‐based solutions for mitigating voltage and frequency excursions caused by high‐penetration photovoltaic (PV) systems has drawn increased attention due to their potential impact on PV production. It is now important to quantify the amount of solar energy curtailed as a result of the activation of inverter‐based grid support functions (GSFs). This study proposes a methodology for estimating the impact of volt–watt on customer PV energy curtailment using smart meter voltage data. This method estimates maximum possible curtailment for a given volt–watt curve based on the customer smart meter voltage during the time period of interest. This study compares the proposed methodology with field measurements using irradiance and customer inverter data from Hawaii as well as with results from a previous simulation‐driven study on the impact of advanced inverter GSF activation on PV energy curtailment. Results show that the proposed method for estimating lost PV production caused by volt–watt control aligns reasonably well with field measurements and computer simulations for hundreds of customers. The proposed method could be used to estimate customer energy curtailment, which could inform future compensation mechanisms for utilities leveraging customer‐sited resources to mitigate high voltage and defer infrastructure upgrades.

Emmanuel, Michael↗

High-Resolution WRF-Based Downscaling of Earth System Model Projections for Energy Applications across CONUS

Evaluating energy resources under future scenarios requires meteorological information that adequately resolves regional-scale variability and is suitable for regional energy system studies. Although Earth system model (ESM) outputs provide essential large-scale context, their coarse resolution and inherent biases limit direct use in energy system applications. This work presents a high-resolution dynamical downscaling framework using the Weather Research and Forecasting (WRF) model to generate energy-relevant regional fields for future scenarios over the contiguous United States (CONUS). The framework first identifies an optimal WRF configuration through sensitivity experiments, then evaluates raw and bias-corrected ESM initial and boundary conditions, with soil moisture and soil temperature bias correction implemented as an integral component of the bias-corrected ESM atmospheric forcing prior to WRF dynamical downscaling to improve land-atmosphere interactions. Simulations performed at 4-km resolution show that uncorrected ESM forcing leads to systematically dry and cold soil states, which propagate into elevated near-surface air temperature and solar irradiance biases, particularly during summer for the period 2000-2014. Incorporating bias-corrected atmospheric forcing together with soil state bias correction substantially reduces these errors and improves the representation of surface energy processes in WRF simulations. The results highlight the importance of bias-aware initialization strategies in high-resolution dynamical downscaling for future energy system analysis and planning.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Addressing energy storage needs at lower cost via on-site thermal energy storage in buildings

Cost-effective energy storage is a critical enabler for the large-scale deployment of renewable electricity. Significant resources have been directed toward developing cost-effective energy storage, with research and development efforts dominated by work on lithium ion (Li-ion) battery technology. Though Li-ion batteries have many attractive qualities, it is not clear whether they can provide an affordable levelized cost of storage (LCOS) for certain applications, such as buildings. Buildings consume most of the world's electricity, and as much as 50% of their consumption goes toward meeting thermal loads. Thermal energy storage (TES) can provide a cost-effective alternative to Li-ion batteries for buildings; however, two questions remain to be answered. First, how much of total building energy storage requirements can be met via thermal storage for building loads? Second, can the LCOS for TES be favorable compared with Li-ion batteries? In this perspective, using the United States as a case study, we show that the total requirement for TES in buildings is in the range of ~1200–4500 electrical GW h, depending on the fraction of solar versus wind in the generation mix. Furthermore, we show that with at least 25% wind generation, all of the storage needed by buildings to support the grid can be met by TES. We also introduce a framework to calculate LCOS for on-site TES in buildings to enable a direct comparison with electrical storage technologies such as Li-ion batteries. This is not trivial, because the input energy type for TES (electricity) differs from the output energy type (thermal energy), and the efficiency can depend on ambient conditions. Our LCOS analysis shows that in many situations, TES can be more cost-effective for buildings than Li-ion batteries. We conclude our perspective by discussing future research and development opportunities that can significantly advance the deployment of TES for buildings to help enable a renewable electricity-dependent grid.

25 ENERGY STORAGE↗