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At least 343 records · Page 19

Development of in-situ polymerized intrinsically conductive resin and low-cost carbon pigments offering high conductivity for sensing, EMI shielding and lighting protection

Electrically conductive composites are emerging across diverse industries such as electronic, automotive, aerospace, advanced air mobility, biomedical, infrastructure, defense and security offering static charge dissipation, electromagnetic interference shielding, lighting protection, sensing, dicing, corrosion monitoring, etc. Conductivity enhanced composites provide several advantages compared to conventional metals including weight reduction, corrosion resistance, energy efficient processability, tunable properties and multifunctionality. Polymers are typically insulating in nature and require conducting filler for electron transport. However, dispersion and polymer-filler interphases are critical and often disrupt conducting pathways. Besides, conductive fillers such as graphene, carbon nanotube, MXene, silver nanowire, etc. are expensive, limiting their wide adoption in composite industry. On the other hand, a limited number of intrinsically conductive polymers are available among which polyaniline (PANI) has been widely studied due to its high conductivity, thermal and chemical stability. However, PANI is difficult to process and exhibits weak mechanical properties. In brief, there is a significant demand for electrically conductive polymer formulation with cost-effective conducting fillers that offer processability in scale to expand the market of conductivity enhanced materials.

Kumar, Vipin [Oak Ridge National Laboratory (ORNL)↗

Applying Web-Based Tools for Research, Engineering, and Operations

Personnel in the NASA Glenn Research Center Network and Architectures branch have performed a variety of research related to space-based sensor webs, network centric operations, security and delay tolerant networking (DTN). Quality documentation and communications, real-time monitoring and information dissemination are critical in order to perform quality research while maintaining low cost and utilizing multiple remote systems. This has been accomplished using a variety of Internet technologies often operating simultaneously. This paper describes important features of various technologies and provides a number of real-world examples of how combining Internet technologies can enable a virtual team to act efficiently as one unit to perform advanced research in operational systems. Finally, real and potential abuses of power and manipulation of information and information access is addressed.

Ivancic, William D.↗

Brazil is in water crisis–it needs a drought plan

To avoid crop failures and soaring power costs, Brazil needs to diversify sources, monitor soil moisture, model local hydroclimate dynamics and treat water as a national security priority.

Augusto Getirana↗

The Nature and State of Groundwater Contamination at the Nevada National Security Site: What Have We Learned from Decades of Groundwater Analysis? - 20337

The regulatory framework for remediating radionuclide contamination from underground nuclear testing at the Nevada National Security Site (NNSS) is based on a combination of characterization and modeling studies, monitoring, and institutional controls [1]. Currently, tritium is the largest contributor (∼90%) to the estimated 44.6 million-curie radionuclide inventory resulting from underground testing [2]. Because of its short half-life (12.32 years), its relative contribution reduces below 10% of the total radiologic inventory over the next 120 years as a result of radioactive decay. Although tritium levels are observed well above the Safe Drinking Water Act (SDWA) maximum contaminant levels (MCLs) in groundwater, other radionuclides are well below their MCLs except within the nuclear test near-field (nuclear test cavity and chimney) environment. In fact, most device-derived radionuclides are below their MCL in groundwater even in samples collected from this near-field environment. The distribution of radionuclides following the nuclear detonation greatly influences the availability of potential contaminants for groundwater transport. Tritium is initially distributed in the gas phase, later as tritiated water in steam, and finally as liquid water, and is available to groundwater transport away from the near-field environment. Other radionuclides that are mobile in groundwater are {sup 14}C, {sup 36}Cl, {sup 99}Tc, and {sup 129}I though their radiologic inventory is small when compared to tritium. Many radionuclides (e.g. U, Pu, Am) are incorporated to a significant extent into the melt glass at the bottom of the cavity and are accessible to groundwater primarily through the slow process of glass dissolution. These radionuclides are also adsorbed to the surfaces of the crushed rock within the cavity and chimney which limits their migration in groundwater. Although colloid facilitated transport of radionuclides at the NNSS has been observed [3], radionuclide concentrations decrease with time and migration distances due to desorption and colloid filtration processes. Current studies indicate that radionuclides associated with colloids are unlikely to migrate downgradient from NNSS underground nuclear tests at concentrations above the SDWA MCL [4][5]. The results of over 50 years of sampling, along with an understanding of these post detonation processes, indicate that tritium is the only contaminant of concern downgradient of testing and that even tritium will not exceed its MCL in groundwater after ∼120 years. Although other longer-lived radionuclides may continue to be released slowly from the near-field environment they will likely never reach levels exceeding their MCLs in groundwater downgradient of the NNSS. Groundwater monitoring will continue to verify these observations. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Analyzing Risks of Virtual Private Network Connections

The use of Splunk for analyzing VPN logs is an effective approach for identifying vulnerabilities in network endpoints. Splunk, a powerful platform for searching, monitoring, and analyzing machine-generated data, enables organizations to aggregate VPN logs in real-time, providing insights into network activity, user behavior, and potential security risks. By indexing VPN traffic and authentication logs, security teams can track abnormal patterns such as multiple failed login attempts, unusual IP addresses, or unexpected changes in bandwidth usage, all of which could indicate potential vulnerabilities or breaches. With Splunk’s advanced search and reporting capabilities, users can create custom dashboards and alerts to detect suspicious activities. Automated searches can flag endpoints exhibiting unusual behavior, while correlation analysis can identify links between compromised devices and broader network vulnerabilities. In particular, Splunk's machine learning capabilities can be leveraged to predict and prevent threats by identifying trends that might otherwise be missed in traditional log analysis. This proactive approach to monitoring VPN logs allows for the early detection of security weaknesses, enabling rapid response and minimizing potential damage to network integrity. By enhancing endpoint visibility, Splunk plays a crucial role in securing remote connections and safeguarding sensitive information. Additionally, Splunk’s automation and alerting features allow teams to create custom workflows that notify them of vulnerable or misconfigured endpoints identified through Shodan. This synergy between Splunk’s log analysis and Shodan’s device intelligence enhances an organization’s ability to proactively identify and mitigate security risks, improving the overall resilience of their VPN infrastructure.

97 MATHEMATICS AND COMPUTING↗

Underground Test Area (UGTA) Sampling Plan for Corrective Action Units 101 and 102: Central and Western Pahute Mesa, Nevada National Security Site, Nevada

The purpose of this groundwater sampling plan (referred to herein as “the Plan”) is to describe the approach for collecting and analyzing groundwater samples to meet the objectives of the U.S. Department of Energy (DOE), Environmental Management (EM) Nevada Program’s Underground Test Area (UGTA) Activity. The Plan is focused on the Central and Western Pahute Mesa corrective action units (CAUs 101 and 102). The remaining UGTA CAUs are in the final stage of the UGTA strategy (Closure Report [CR] stage), and monitoring requirements for these CAUs are described in their respective CRs. The Plan supersedes the Nevada National Security Site Integrated Groundwater Sampling Plan and its ensuing Record of Technical Change (ROTC) (DOE/EMNV, 2019b). The Plan is designed to ensure compliance with the UGTA Quality Assurance Plan (QAP) and its ensuing ROTC (DOE/EMNV, 2018), and the Federal Facility Agreement and Consent Order (FFACO) (1996, as amended). The Plan is implemented by the Environmental Program Services (EPS) contractor. Implementation of the Plan provides data to complete corrective actions prescribed by the FFACO to protect the public from groundwater contaminated by historical underground nuclear testing. The Plan’s scope comprises sample collection and analysis requirements for assessing the extent of groundwater contamination from underground nuclear testing. Sampling wells located in the communities surrounding the Nevada National Security Site (NNSS) is performed by other organizations (e.g., management and operating [M&O] contractor) and is therefore not included within the Plan. The results of the community sampling are presented in the annual NNSS environmental reports.

54 ENVIRONMENTAL SCIENCES↗

Development of a Nuclear Fuel Dissolution Monitor Based on Raman Spectroscopy

The processing of spent nuclear fuel and other nuclear materials is a critical component of nuclear material management with implications for global security. The first step of fuel processing is dissolution, with several charges of fuel sequentially added to a batch of solvent. The incomplete dissolution of a charge precludes the addition of the next charge. As the dissolution takes place in a heated, highly corrosive and radiological vessel, direct monitoring of the process is not possible. We discuss the use of Raman spectroscopy to indirectly monitor dissolution through an analysis of the gaseous emissions from the dissolver. Challenges associated with the implementation of Raman spectroscopy include the composition and physical characteristics of the offgas stream and the impact of operating conditions. Nonetheless, we observed that NO2 concentrations serve as a reliable indicator of process activity and correlate to the amount of fuel material that remains undissolved. These results demonstrate the promise of the method for monitoring nuclear material dissolution.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Draft Methodology for Cybersecurity Analysis for Adoption of Wireless Technology in Nuclear Power Plants

The report is delivered as DOE-NE Cybersecurity Program Milestone M2CT-22IN1104014-Industry cybersecurity guidance adoption status. The milestone is specifically to document the process and the status of the efforts towards developing guidance in support of industry’s adoption of wireless communication technologies. To transform the operation of nuclear power plants, including domestic light-water reactors, advanced reactors, microreactors, and fission battery, for grid and non-grid applications, secure and resilient wireless capabilities are required. In addition, to realize new operational concepts such as autonomous operation and remote monitoring, advanced sensor, and instrumentation, wireless technology is essential. However, industry implementation is low, and there is no technical basis for how to understand and address potential risks for wireless communications for critical plant functions. A methodology with a technical basis for implementing secure wireless communication is crucial. This wireless adoption methodology is intended to assist a licensee in identifying an appropriate technological approach for securing wireless communications in nuclear power plant. However, this methodology does not provide guidance for addressing wireless design criteria or for addressing all the cybersecurity commitments in licensees’ cybersecurity plans (CSPs) including addressing security impact analysis that a licensee must perform before an update to a Critical Digital Asset (CDA). This methodology guides a licensee through a process of evaluating a proposed wireless implementation and drafting a plant change notification for an example use case. The example is a generic/nonproprietary version of the first test case of the methodology, which, if successfully implemented, is part of the consideration for protecting other functions’ use of wireless in a cybersecure manner.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

A Review of Visualization Methods for Cyber-Physical Security: Smart Grid Case Study

Cyber-Physical Systems (CPSs) are becoming increasingly complex and interconnected as they attempt to meet the demands of evolving society. As a result, monitoring and maintaining them becomes a more complex and demanding task for control system operators and cyber defenders. While the literature on visualization techniques in the context of cybersecurity is extensive, the same cannot be said for studies on visualization for the security of cyber-physical systems. This paper aims to fill that gap by: 1) defining the main features of a visualizations workflow for security visualizations in cyber-physical systems. The workflow includes the acquisition of cyber and physical data, processing of data, selection, and configuration of both visualization tools and end-user interactions. 2) Providing an overview of cyber-physical security visualization systems, with a focus on smart grids as a case study. Finally, we use the perspectives gained from this analysis to provide insights and directions for future research and design of cyber-physical visualization techniques.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Underground Test Area (UGTA) Sampling Plan for Corrective Action Units 101 and 102: Central and Western Pahute Mesa, Nevada National Security Site, Nevada, Revision 2

The purpose of this groundwater sampling plan (referred to herein as “the Plan”) is to describe the approach for collecting and analyzing groundwater samples to meet the objectives of the U.S. Department of Energy (DOE), Environmental Management (EM) Nevada Program’s Underground Test Area (UGTA) Activity. The Plan is focused on the Central and Western Pahute Mesa corrective action units (CAUs 101 and 102), which are currently in the Corrective Action Decision Document (CADD)/Corrective Action Plan (CAP) stage of the Federal Facility Agreement and Consent Order (FFACO) UGTA Strategy. The remaining UGTA CAUs are in the final stage of the UGTA strategy (Closure Report [CR] stage), and monitoring requirements for these CAUs are described in the Federal Facility Agreement and Consent Order Nevada National Security Site Use Restriction Management Plan (DOE/EMNV, 2024a). The Plan supersedes the Nevada National Security Site Integrated Groundwater Sampling Plan and its ensuing Record of Technical Change (ROTC) (DOE/EMNV, 2019b).

54 ENVIRONMENTAL SCIENCES↗

Codes for "Shallow Soil Response to a Buried Chemical Explosion with Geophones and Distributed Acoustic Sensing" DAG - 01101646

The codes reproduce the figures of the manuscript entitled "Shallow Soil Response to a Buried Chemical Explosion with Geophones and Distributed Acoustic Sensing" submitted to Journal of Geophysical Research - Solid Earth. Geophone data and Distributed acoustic sensing (DAS) data recorded during the Phase II of the The Source Physics Experiment (SPE) along a fiber-optic cable offshore were processed to understand the response of the shallow subsurface to an explosion. This Ground-based Nuclear Detonation Detection (GNDD), Low Yield Nuclear Monitoring (LYNM), and Source Physics Experiment (SPE) research was funded by the National Nuclear Security Administration, Defense Nuclear Nonproliferation Research and Development (NNSA DNN R&D).

Viens, Loic↗

Monitoring urban hydrological environment monitoring using fiber optical sensing

The goal of this research is to develop an innovative approach to monitoring urban dynamic hydrological environment using optical-fiber-based distributed acoustic sensing (DAS). We propose to employ surface-wave dispersion inversion and coda-wave interferometry inversion based on natural and anthropogenic seismic ambient noises acquired using a DAS array to accurately invert for time-lapse changes of groundwater in urban areas. Through this work, we aim to provide the first cost-effective, city-scale, high-resolution approach to monitoring urban groundwater changes that is otherwise difficult or expensive to achieve using conventional techniques. This work will create LANL’s DAS-based near-surface and groundwater monitoring capability, which can also be leveraged in solving relevant applied energy and national security problems.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Opportunities, Challenges, and Research Needs for Remote Microreactor Operations

As the nuclear industry develops new advanced reactor technologies, many companies are embracing this advancement by pursuing the development of microreactors. The term microreactor generally refers to a nuclear reactor with an operating power of 20 MW(thermal) or less. The power range of microreactors makes them appealing for many use cases, such as powering remote communities, mining sites, and military bases. Most of the microreactor designs being pursued are expected to incorporate remote facility operations into the final product. However, no framework has yet been developed to determine what remote operations systems require for reliable, resilient, and secure operation of a microreactor. Here, this work identifies the research needs for challenges that are unique to remote operations and monitoring for microreactors, specifically regarding instrumentation and control, communication methods, regulatory requirements, and operational policies. The types of commands and sensor measurements that must be transmitted between the facilities, as well as methods for verifying the trustworthiness of these signals, are assessed. This work evaluates the security, reliability, and performance requirements that must be met when considering the selection of communication hardware and protocols for use in remote operations. Also, an assessment was performed to study how remote operations fit within current regulatory requirements and what may need to be updated in regulatory policy to allow for remote operation. Finally, the operational contingencies unique to remote operations that must be in place for responses to abnormal events are identified. This paper identifies the challenges and research opportunities within the areas of importance for the design of remote operation systems.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Developing a Community of Practice for Applied Uses of Future PACE Data to Address Marine Food Security Challenges

External interaction:The Plankton, Aerosol, Cloud, ocean Ecosystem (PACE) mission will include a hyperspectral imaging radiometer to advance ecosystem monitoring beyond heritage retrievals of the concentration of surface chlorophyll and other traditional ocean color variables, offering potential for novel science and applications. PACE is the first NASA ocean color mission to occur under the agency's new and evolving effort to directly engage practical end users prior to satellite launch to increase adoption of this freely available data toward societal challenges. Here we describe early efforts to engage a community of practice around marine food-related resource management, business decisions, and policy analysis. Obviously one satellite cannot meet diverse end user needs at all scales and locations, but understanding downstream needs helps in the assessment of information gaps and planning how to optimize the unique strengths of PACE data in combination with the strengths of other satellite retrievals, in situ measurements, and models. Higher spectral resolution data from PACE can be fused with information from satellites with higher spatial or temporal resolution, plus other information, to enable identification and tracking of new marine biological indicators to guide sustainable management. Accounting for the needs of applied researchers as well as non-traditional users of satellite data early in the PACE mission process will ultimately serve to broaden the base of informed users and facilitate faster adoption of the most advanced science and technology toward the challenge of mitigating food insecurity.

Schollaert Uz, Stephanie↗

IT Security Support for the Spaceport Command Control System Development

My job title is IT Security support for the Spaceport Command & Control System Development. As a cyber‐security analyst it is my job to ensure NASA's information stays safe from cyber threats, such as, viruses, malware and denial-of-service attacks by establishing and enforcing system access controls. Security is very important in the world of technology and it is used everywhere from personal computers to giant networks ran by Government agencies worldwide. Without constant monitoring analysis, businesses, public organizations and government agencies are vulnerable to potential harmful infiltration of their computer information system. It is my responsibility to ensure authorized access by examining improper access, reporting violations, revoke access, monitor information request by new programming and recommend improvements. My department oversees the Launch Control System and networks. An audit will be conducted for the LCS based on compliance with the Federal Information Security Management Act (FISMA) and The National Institute of Standards and Technology (NIST). I recently finished analyzing the SANS top 20 critical controls to give cost effective recommendations on various software and hardware products for compliance. Upon my completion of this internship, I will have successfully completed my duties as well as gain knowledge that will be helpful to my career in the future as a Cyber Security Analyst.

IT Security↗

FRMAC Laboratory Analysis Manual Volume 1, Revision 0

The Federal Radiological Monitoring and Assessment Center (FRMAC) is an operational center, available on request by the Department of Homeland Security (DHS) to respond to nuclear and radiological incidents as described in the National Response Framework (NRF). Under the Federal Interagency Operational Plan for Response and Recovery’s Nuclear/Radiological Annex, the U.S. Department of Energy (DOE) has the responsibility to maintain the operational readiness of the FRMAC during the emergency phase of an event. FRMAC is initially established and managed by the Nuclear Emergency Support Team (NEST) and serves as an interagency operations center with representatives from various federal, state, and local radiological response organizations. The purpose of the FRMAC is to assist state, local, tribal, and territorial governments (SLTT) in their mission to protect the health and well-being of their citizens with: • Verified radiation measurements. • Interpretations of radiation distributions based on Environmental Protection Agency (EPA), Food and Drug Administration (FDA), or local Protective Action Guidelines (PAGs). • Characterization of overall radiological conditions. Once a declaration to respond to a radiological emergency has been made, the National Nuclear Security Administration (NNSA) Headquarters will coordinate the response in consultation with the cognizant NNSA Regional Coordinating Office (RCO). Each of the eight RCOs maintain a 24-hour response capability for radiological emergencies that may occur in states served by its region. When a FRMAC is established, it operates under the parameters of the Incident Command System (ICS), as defined in the National Incident Management Systems (NIMS) construct. The Consequence Management Home Team (CMHT) will be activated immediately during normal business hours (Pacific Time Zone), and within two hours otherwise. The Consequence Management Response Team (CMRT) is prepared for deployment within six hours after activation. Along with the assets, FRMAC provides an operational framework for coordinating of all federal off-site radiological monitoring and assessment activities during a response to a radiological emergency to support the coordinating agency and SLTT governments. Potential radiological emergencies that fall within FRMAC vary widely in terms of the area affected, the nature of the contamination, and the scope of the government’s response. Detonation of a nuclear device, accidental release of radiation from a nuclear power plant, and a terrorist threat are just a few of the many possible scenarios FRMAC must be prepared to address. Through all this, supporting the state, local, and tribal organizations in the protection of the public remains the primary goal of the federal response.

54 ENVIRONMENTAL SCIENCES↗

A substituent-dependent deep-blue pyrene-based chemosensor for trace nitroaniline sensing

Nitroaniline (NA) is a kind of high toxicity and pathogenic amine derivative, and the trace monitoring of nitroaniline has become an urgent problem in terms of both the environment and security. Herein, two K-region multiple substituted pyrene-based luminogens with reasonable photoluminescence efficiency and blue emission (408–430 nm) have been synthesized and characterized. Their photophysical properties were carefully investigated in solution and in the solid state by experimental and density functional theory (DFT) methods. It is worth mentioning that both of these π-electron rich and extended π-conjugated materials were used for the detection of electron deficient nitroaromatics (NACs) based on a photo-induced electron transfer (PET) mechanism, and a sensitive response towards NA, especially for p-NA with a limit of detection (LOD) as low as 8.58 × 10 -9 M, was observed, with a fluorescence quenching efficiency up to 99.5%. In conclusion, these research results provided a low-cost and simple strategy for trace nitroaniline sensing.

36 MATERIALS SCIENCE↗

Assessing the Accuracy of a Borehole-Controlled Velocity Model of Yucca Flat, Nevada, Using Large-N Seismic Data

The Source Physics Experiment (SPE) aims to improve nuclear test monitoring capabilities through a series of chemical explosions in Yucca Flat within the Nevada National Security Site (NNSS) (Snelson et al., 2013). With geologic data from over 950 boreholes, Yucca Flat has excellent borehole control on stratigraphy. These data were used to create a Geologic Framework Model (GFM) of the basin to aid in the study of seismic wave propagation through the Earth. However, the seismic velocities of the geologic units in the GFM are less well-defined. With the acquisition of five new active source Large-N datasets, we can now quantitatively assess the accuracy of the seismic model previously controlled by borehole data alone.

58 GEOSCIENCES↗