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At least 343 records · Page 19

Experimental Investigation of the System Nonmetallic Inclusion-Molten Steel-Refractory System at High Temperatures

In continuous casting, the buildup of particles in the flow control system is called clogging. Clogging may be caused by preexisting nonmetallic inclusions attached to the refractory wall, interrupting or disturbing the fluid flow conditions. The interfacial properties of the nonmetallic inclusion-molten steel-refractory system are believed to play a key role in the clogging tendency of selected steel grades in contact with ceramics. The combination of a high-temperature laser scanning confocal microscope (HT-LSCM), which is employed for in situ observation of inclusions’ behavior in the liquid steel or at the steel/ceramic interface, and a high-temperature drop shape analyzer (HT-DSA), which is utilized for contact angle measurements, enabled the investigation of reactions and interactions in the described system at experimental temperatures of approximately 1600 °C. The objective of this study was to develop a method to obtain qualitative information on the deposition of nonmetallic inclusions (NMIs) in the submerged entry nozzle (SEN) during casting. The behavior of solid NMIs from a calcium-treated steel at the interface between liquid steel and Al{sub 2}O{sub 3} or MgO was investigated by means of HT-LSCM. During the test evaluation, inclusions were found to separate at the steel/ceramic interface due to an attractive force. This force increased with the NMIs’ size as well as with the ceramic particle change. The HT-DSA provided contact angle data between molten steel and the ceramic used for implementation into the theoretical capillary force model. A clear correspondence between the estimated and calculated capillary forces was observed. The change in the wettability of the system, as induced by the change in the ceramic from MgO to Al{sub 2}O{sub 3}, showed a reduction of the attractive forces, indicating a weaker separation toward the SEN for the same inclusion type. This study confirmed the strong potential of wettability investigations to predict the clogging tendency of certain steel grades.

36 MATERIALS SCIENCE↗

Microstructures and Impact Wear Behavior of Al-Alloyed High-Mn Austenitic Cast Steel After Aging Treatment

The microstructural evolution and impact wear behavior of Al-alloyed ultra-high-Mn austenitic cast steel were investigated after different heat treatments, including quenching (Q) and quenching + aging (Q + A). Another ultra-high-Mn austenitic cast steel without Al was compared under the same experimental condition. After Q + A, Al addition contributed to the precipitation of κ-carbides which improves the yield strength and wear resistance of the austenite matrix. However, the mechanical properties and wear resistance of the Al-free steel were strongly deteriorated due to the precipitation of plate-like M{sub 3}C-type carbides, as well as the worn surface of the Al-free steel had the feature of micro-scratches. After Q + A (2 h), the Al-alloyed steel obtained optimal wear resistance and the main wear feature was strain fatigue. But, excessive aging time (4 h) would lead to a large fragile peeling from the worn surface and the wear resistance was decreased. Also, the worn subsurface microstructures with different heat treatments were observed by transmission electron microscopy (TEM). These results show that the deformation microstructures of the Al-free steel contained stacking faults, dislocation tangle and deformation twins. The deformation character of Al-alloyed steel is dominated by planar glide, and with increase in the aging time, planar dislocation substructures gradually evolved, relating to dislocation pileups, Taylor lattices and micro-bands.

36 MATERIALS SCIENCE↗

Electro-carburization of mild steel through two-step reaction in molten-salt electrolyte

The rapid carburization of mild steel is demonstrated via the electrochemical deposition of solid carbon, followed by thermochemical iron-carbon (Fe-C) reaction using a molten lithium-potassium carbonate (LiKCO 3 ) salt electrolyte and carbon dioxide as the carbon source. Depth-dependent microstructural and compositional changes in the steel are shown to be controlled by the applied cell voltage and reaction temperatures. Reaction temperatures above the Fe-C eutectoid temperature promote faster carburization due to carbon dissolution into austenite. The carbon deposition rate is regulated by the applied cell voltage: At - 2.4 V, carbon deposition occurs much faster than its diffusion into the steel, resulting in the accumulation of a carbon-rich layer exceeding 1 mm, which does not diffuse into the steel. In contrast, at - 1.8 V, all deposited carbon effectively diffuses into the steel, leaving a minimal external deposit. In both cases, carbon ingress forms a carbide-rich surface layer and precipitates additional carbides along the grain boundaries within the steel electrode. This method offers a potential approach to increase the carbon content of mild or low-carbon steel feedstocks, such as scrap or direct reduced iron, for industrial applications.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Inhibition mechanisms of steel slag on the early-age hydration of cement

Steel slag inhibits the early-age hydration of cement. However, its mechanism is still unclear. In this paper, the early-age hydration kinetics and the evolution of the solid phases, aqueous species and microstructures in a cement-steel slag composite binder are investigated to explore how steel slag inhibits the early-age hydration of cement. Two novel phenomena are found: (1) steel slag slows the depletion of gypsum and reduces the formation of ettringite, and (2) steel slag significantly inhibits the precipitation of CH and CSH. The results show that the addition of steel slag increases the Ca concentration in the pore solution, reduces the supersaturation of the pore solution with respect to CH and inhibits the nucleation and growth of CSH. Based on the above results, the retardation mechanisms of steel slag on the initial setting of cement paste are explained.

36 MATERIALS SCIENCE↗

Microstructural characterization of high-manganese austenitic steels with different stacking fault energies

Microstructures of tensile-deformed high-manganese austenitic steels exhibiting twinning-induced plasticity were analyzed by electron backscatter diffraction pattern observation and X-ray diffraction measurement to examine the influence of differences in their stacking fault energies on twinning activity during deformation. The steel specimen with the low stacking fault energy of 15 mJ/m{sup 2} had a microstructure with a high population of mechanical twins than the steel specimen with the high stacking fault energy (25 mJ/m{sup 2}). The <111> and <100> fibers developed along the tensile axis, and mechanical twinning occurred preferentially in the <111> fiber. The Schmid factors for slip and twinning deformations can explain the origin of higher twinning activity in the <111> fiber. However, the high stacking fault energy suppresses the twinning activity even in the <111> fiber. A line profile analysis based on the X-ray diffraction data revealed the relationship between the characteristics of the deformed microstructures and the stacking fault energies of the steel specimens. Although the variation in dislocation density with the tensile deformation is not affected by the stacking fault energies, the effect of the stacking fault energies on the crystallite size refinement becomes significant with a decrease in the stacking fault energies. Moreover, the stacking fault probability, which was estimated from a peak-shift analysis of the 111 and 200 diffractions, was high for the specimen with low stacking fault energy. Regardless of the difference in the stacking fault energies of the steel specimens, the refined crystallite size has a certain correlation with the stacking fault probability, indicating that whether the deformation-induced crystallite-size refinement occurs depends directly on the stacking fault probability rather than on the stacking fault energies in the present steel specimens. - Highlights: {yields} We studied effects of stacking fault energies on deformed microstructures of steels. {yields} Correlations between texture and occurrence of mechanical twinning are discussed. {yields} Evolutions of dislocations and crystallite are analyzed by line profile analysis.

36 MATERIALS SCIENCE↗

Effect of silicon on ultra-low temperature toughness of Nb–Ti microalloyed cryogenic pressure vessel steels

The effect of Si on the ultra-low temperature toughness of Nb–Ti microalloyed cryogenic pressure vessel steels was investigated by electron back-scattered diffraction and transmission electron microscope with energy dispersive spectroscopy. Equiaxed ferrite and bainite were obtained in the tempered steels with small Si additions. Nanosized Nb–Ti carbides (< 10 nm) were formed in the steel containing 0.05% Si, whereas much coarser carbides (> 30 nm) were found in the steel containing 0.47% Si. The ultra-low temperature toughness of the Nb–Ti microalloyed cryogenic pressure vessel steel was remarkably enhanced by the reduction in the Si content, which was attributed to the pre-existing iron carbide formation before the precipitation of nanosized Nb–Ti carbides during tempering. - Highlights: • Nanosized Nb-Ti carbides formed in the tempered steel with smaller Si addition. • Coarser Nb-Ti carbides formed in the tempered steel with more Si addition. • Pre-existing cememtites provide nucleation sites for Nb-Ti carbide precipitation. • Ultra-low temperature toughness was remarkably enhanced by Si content reduction.

36 MATERIALS SCIENCE↗

Improved the microstructures and properties of M3:2 high-speed steel by spray forming and niobium alloying

The microstructures and properties of spray formed (SF) high-speed steels (HSSs) with or without niobium (Nb) addition were studied. Particular emphasis was placed on the effect of Nb on the solidification microstructures, decomposition of M{sub 2}C carbides, thermal stability and mechanical properties. The results show that spray forming can refine the cell size of eutectic carbides due to the rapid cooling effect during atomization. With Nb addition, further refinement of the eutectic carbides and primary austenite grains are obtained. Moreover, the Nb addition can accelerate the decomposition of M{sub 2}C carbides and increase the thermal stability of high-speed steel, and also can improve the hardness and bending strength with slightly decrease the impact toughness. The high-speed steel made by spray forming and Nb alloying can give a better tool performance compared with powder metallurgy M3:2 and commercial AISI M2 high-speed steels. - Highlights: • Spray forming can effectively refine the microstructure of M3:2 steel. • Niobium accelerates the decomposition of M{sub 2}C carbides. • Niobium increases the hardness and bending strength of spray formed M3:2 steel. • Spray-formed niobium-containing M3:2 steel has the best tool performance.

36 MATERIALS SCIENCE↗

Solar energy protects steels against corrosion: Enhanced protection capability achieved by NiFeOx decorated BiVO4 photoanode

Highlights: • Steel corrosion is inhibited by coupling to irradiated photoanode. • NiFeO{sub x} promotes charge transfer from BiVO{sub 4} to connected steel. • BiVO{sub 4} composite photoanode decreases the self-corrosion potential of 316 steel by 256 mV. - Abstract: Coupling n-type semiconductor photoelectrode with steels provides protection from corrosion for the latter by pumping electrons produced by water oxidation reaction in a sustainable way. Although the concept of the photocathodic protection of steels has been proposed for about two decades, this technique is still far away from practical applications due to the limited protection capability. In this work, we reported that the BiVO{sub 4} photoanode significantly decreases the self-corrosion potential of 316 steel by 166 mV, and the decoration of NiFeO{sub x} films onto BiVO{sub 4} further shifts the self-corrosion potential by ∼90 mV negatively, which exhibits an excellent protection capability. The protection capability of the photoelectrode to steel is limited by the relative position of the Fermi level of the semiconducting material, and confined by the thermodynamics of the surface reactions on the semiconductor-electrolyte interface.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Effects of scan rate on the corrosion behavior SS 304 stainless steel in the nanofluid measured by Tafel polarization methods

The Effects of scan rate on the Tafel polarization curve that is obtained to determine corrosion rate are conducted. The tafel polarization curves are obtained at different scan rates for Stainless Steel 304 in nanofluids contain 0.01 gpl nano particle ZrO{sub 2}. The corrosion stainless steel in nanofluid contains adm+0.01 gpl ZrO{sub 2} nanoparticles at different scan rate was performed by Tafel polarization. The results show that according corrosion potential examination of the stainless steel in nanofluid media 0.01gpl ZrO{sub 2} nanoparticle was actively corroded. The value of cathodic Tafel slope stainless steel in nanofluid at different scan rate relatively unchanged after polarization testing. Mean while the value of anodic Tafel slope stainless steel in nanofluid increase at different scan rate. The results of Tafel polarization technique show that corrosion rate of stainless steel in nanofluid increase with increasing scan rate. X ray diffraction examination of stainless steel after Tafel polarization depict that γ Fe phase is major phase in the surface of alloy.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Effects of Thiocyanate on Anodic Dissolution of Iron, Chromium, Nickel and Type 304 Stainless Steel: I. Electrochemical Measurements and Surface Morphology

Recently published work investigated themechanism of the catalytic effect of thiocyanate on the active dissolution of ferritic stainless steel (Type 430 stainless steel). This work has been extended to Type 304 stainless steel. Potentiostatic and impedance measurements were performed on pure iron, pure chromium, pure nickel and Type 304 stainless steel in 1 M sulfate solutions at pH = 2.5 and pH= 0. As proposed for Type 430 stainless steel, the catalytic effect of thiocyanate on anodic dissolution of Type 304 stainless steel also appears to be primarily caused by the increased dissolution rate of chromium, counteracting the formation of the Cr-O-Cr passivating network at ledges. Nickel does contribute to the corrosion resistance of Type 304 stainless steel in the presence of thiocyanate, but its beneficial effect appears to be secondary to that of chromium.

36 MATERIALS SCIENCE↗

Corrosion of Steel During Long-Term Exposure to Evolving Cementitious Environments

SRS is proceeding with closure of the H-Area Tank Farm (HTF) and F-Area Tank Farm (FTF). Closure consists of removing the bulk waste, heel removal, and filling the tank with tailored grout formulations. The long-term performance of the concrete and steel materials of construction and the closure grout is an important consideration for Performance Assessment (PA) of closed tanks in FTF and HTF. Over PA timeframes of hundreds, thousands, to tens of thousands of years, the chemical and physical properties of the concrete and steel materials will slowly degrade due to environmental exposure and material aging. In the interim these materials will provide a barrier to the leaching of radionuclides into the soil. Savannah River Remediation (SRR) is updating relevant portions of these analysis inputs to support an imminent revision to the HTF PA and a future update to the FTF PA. This analysis provides an update to the previous PA inputs for steel corrosion. The Central Scenario for the PA analysis includes three postulated modeling cases: 1) Realistic Case, 2) Compliance Case, and 3) Pessimistic Case. This analysis also included a Fast Flow Path Case. This latter case considered the circumstance where the initial condition of the concrete was a completely degraded state and that grout shrinkage exposed the steel to the soil environment immediately. In effect, the steel was unprotected by the concrete and grout. The cases have various degrees of conservatism considered. Chemical, physical and tank configuration parameters were investigated to understand their effects on the predicted time to release of the contaminants. The assessment reviewed the initial tank and steel configuration, service life degradation of the steel, and potential corrosion mechanisms associated with degradation of the concrete materials.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Improved Processing Techniques for Inclusion-Free Steel for Bearing and Mechanical Component Applications

High hardness, high carbide powder metallurgy tools steels such as M62 enable the operation of ball bearings at extremely high load and stress levels. Operation under such conditions increases the potential for rolling contact fatigue failure attributed to ceramic particle inclusions. To address this challenge, industry has sought steel made from ever increasing levels of cleanliness but the results have been uneven owing to the random nature of the occurrence of material flaws. One common approach is to rely upon careful ingot inspections prior to bearing manufacture. By selecting the cleanest portion of an ingot, it is expected that bearings relatively free from material flaws will result. This approach is not always successful because detrimental flaws that exist deep within an ingot can pass inspection undetected potentially causing subsequent failure. Recent efforts to commercialize an intermetallic material, 60NiTi, for rolling element bearings demonstrates a pathway to produce bearing steel that is free from unwanted ceramic particle inclusions. In this paper, the process used to make bearing grade ceramic-free NiTi alloys is described and applied to steelmaking. At its core, the NiTi process differs from steel making in one key aspect. NiTi alloys are made from elementally pure starting materials that are melted, blended and processed in equipment absolutely free from exposure to oxygen and ceramics ensuring a ceramic particle-free product. In contrast, the predominant method to make bearing steel is to employ a successive series of purification steps to reduce contamination levels below required thresholds. This paper describes the processes developed and applied to high carbide tool steel, M62. The resulting material and microstructures are evaluated and compared to M62 prepared by conventional powder metallurgy techniques. It is hoped that the application of materials manufacturing techniques used for fracture sensitive ceramics and intermetallic materials like NiTi can provide a pathway to Ultra-Clean, Ceramic-Inclusion free steels for rolling element bearings and other failure critical applications.

Steel↗

Development of FeCrAl-ODS steels for ATF cladding

As an enhanced accident tolerant fuel (ATF) for LWR at severe accident condition, FeCrAl-ODS ferritic steels have been developed, and their applicability is being studied under the Japanese MEXT program. Alloying design of FeCrAl-ODS ferritic steels has been conducted, focusing on effect of mutual interaction of Cr-Al on oxidation resistance and α'-embrittlement. Effects of co-addition of Zr and excessive oxygen have also been studied to improve high-temperature strength. The ring tensile test of the manufactured claddings showed that tensile strength increases by Zr-addition and Zr-added FeCrAl-ODS steels have the highest strength among the existed steels at entire temperature range from room temperature up to 1000 Celsius degrees. Although Zr-addition sometimes leads to growth of alumina scale by rapid inward diffusion of oxygen through zirconia inside alumina, oxidation rate of Zr-added FeCrAl-ODS steels was successfully reduced to the level of Zr-free specimen by controlling oxygen content to form Y{sub 2}Zr{sub 2}O{sub 7} inside ODS steel matrix. This finding makes possible to improve not only high-temperature strength but also steam oxidation resistance in the Zr-added FeCrAl-ODS steels. (authors)

36 MATERIALS SCIENCE↗

Crickets{sup TM} and Curies: Lessons Learned from the Steel Industry - 18221

The global nuclear power industry, and to a lesser extent, the decommissioning and demolition of old nuclear weapons plants, obviously present challenges to those in the radioactive waste management field. Some if not many of these challenges have already been dealt with, and resolved, in the steel industry, including its recycling component. This paper presents proven state-of-the-art radiation detection systems used in steel and related recycling facilities, emphasizing current, reliable and flexible technologies for characterization, volume reduction, and remote handling of recyclable solid wastes contaminated and, just as important, not contaminated, with a wide range of radioactive isotopes. It will also cover features of remotely operated waste handling equipment effective in reducing or eliminating exposure of workers engaged in decontamination and demolition work on active and/or inactive nuclear installations. The industry group identified above has a long-standing policy regarding any radioactivity in potentially recyclable as well as waste materials it receives: if it is detected, it is rejected. The US Steel Manufacturers Association (SMA) put it this way in one of their Public Policy Statements: 'SMA members have not, and will not, accept scrap that is known to be radioactively contaminated' (emphasis included in the original) (1). This policy, adopted around the globe, obviously has major implications for decommissioning and demolition projects. To put it bluntly, if rad-contaminated metal, concrete, or other materials are sent to a facility for possible recycling, reuse or even disposal, they may well be rejected. If so, the materials will be returned to the generator--at the generator's cost-and a new solution will have to be found. This also results in additional costs for the generator. Facilities in the steel making and metal recycling industries have access to, and routinely count on, a wide range of proven detection technologies and techniques for monitoring incoming shipments and sorting the materials in them. The approaches range from using sensitive handheld instruments for pinpointing and isolating small devices such as isotope-containing gauges and radium dials all the way up to technologies effective for large volumes and weights of contaminated construction and demolition material. In this latter realm, the most suitable, robust, and field-proven system for decommissioning and demolition work is a radiation detection system fitted to a grappling and/or magnetic device, known as the Crickets{sup TM} technology, which automatically scans bulk material with no added effort or time in material handling operations. Highly versatile, a Crickets{sup TM} system can be put to work on any material-handling system, including grapples handling volumes ranging from 1 up to 18 cubic yards, while detecting radioactivity in real-time over a very wide dose range, from nSv to Sv levels. Other field-proven real-time measuring radiation detection devices can be fixed to conveyor belts with traverse speeds up 3 meters/second, also measuring in real time and over the same dose range, allowing both recyclable and waste materials with a pre-set level of radioactivity to be diverted off the belt. Finally, there are highly sensitive radiation portal installations for detecting radiation from materials being transported by vehicles, including those with roll-offs, dump trailers, and other containers, again in real-time and for the same dose ranges. For vehicles, the speed must be carefully controlled-the vehicles need to travel from 5 to 10 km/h through the scanning zone to ensure that maximum detection capability is maintained. When radiation detection systems at recycling and steel making facilities detect radioactive material in an incoming shipment, these facilities have a zero tolerance for accepting the cargo. Therefore, it is imperative that material from a demolition operation that is slated to be sent for recycling or other reuse be checked at the point of demolition at similar detection levels to avoid possible rejection later of a shipment because of its radioactivity. In addition to measuring overall radiation levels (for example, total gamma), when necessary, combinations of different radiation detection media can be used to detect the presence and intensities of specific isotopes such as U-235, Cs-137, Co-60, Am-241, etc., again in real-time and over a similar dose range. These detection technologies can be fixed or transportable. More important for the rad-waste management profession, this overall systems approach can be tailored and adapted during use on-site in any dismantling, demolition or remediation project, to allow materials to be thoroughly scanned before being released to the recycling stream for reuse, or to appropriate long-term storage and disposal facilities. Potentially recyclable materials with contamination such as steel beams and rebar will set off alarms at recycling facilities, resulting in unnecessary added expenses to the generator, primarily due to increased transportation costs, time delays and additional rad-waste handling and disposal charges. Additionally, there are situations where relatively lightly contaminated materials, once identified and appropriately characterized, can be reused in new construction applications, such as concrete from demolition being used in the base layer for roads or recycled steel used for repair or construction of bridges. In other cases, specific smaller volumes can be sent to specialized rad-waste disposal sites. These radiation detection systems can also be custom tailored to ensure proper handling and disposition of contaminated materials destined for reuse in specific applications where, for example, acceptable levels of radioactivity in NORM or TENORM can be reused or safely disposed of. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Characterization of TiN, TiC and Ti(C,N) in titanium-alloyed ferritic chromium steels focusing on the significance of different particle morphologies

Titanium-alloyed ferritic chromium steels are a competitive option to classical austenitic stainless steels owing to their similar corrosion resistance. The addition of titanium significantly influences their final steel cleanliness. The present contribution focuses on the detailed metallographic characterization of titanium nitrides, titanium carbides and titanium carbonitrides with regard to their size, morphology and composition. The methods used are manual and automated Scanning Electron Microscopy with Energy Dispersive X-ray Spectroscopy as well as optical microscopy. Additional thermodynamic calculations are performed to explain the precipitation procedure of the analyzed titanium nitrides. The analyses showed that homogeneous nucleation is decisive at an early process stage after the addition of titanium. Heterogeneous nucleation gets crucial with ongoing process time and essentially influences the final inclusion size of titanium nitrides. A detailed investigation of the nuclei for heterogeneous nucleation with automated Scanning Electron Microscopy proved to be difficult due to their small size. Manual Scanning Electron Microscopy and optical microscopy have to be applied. Furthermore, it was found that during solidification an additional layer around an existing titanium nitride can be formed which changes the final inclusion morphology significantly. These layers are also characterized in detail. Based on these different inclusion morphologies, in combination with thermodynamic results, tendencies regarding the formation and modification time of titanium containing inclusions in ferritic chromium steels are derived. - Graphical abstract: Display Omitted - Highlights: • The formation and modification of TiN in the steel 1.4520 was examined. • Heterogeneous nucleation essentially influences the final steel cleanliness. • In most cases heterogeneous nuclei in TiN inclusions are magnesium based. • Particle morphology provides important information on inclusion formation.

36 MATERIALS SCIENCE↗

Latest Results from DIII-D and Their Implications for Future Devices

The DIII-D Tokamak has become one of the major sources of physics and technology data for the design of future large machines such as ITER and CIT. In large part this is because of its extremely flexible design and the ability to run tests or add new diagnostic devices with a minimum of down-time and expense. Fundamental plasma physics studies are still the major focus of our experimental program, but increasingly, we are looking at new ways to answer the complex fusion technology questions emerging from the design studies for the next-generation devices. Recent results have demonstrated world record beta plasmas, long quiescent H-mode operation, partial noninductive current drive using both neutral beam and rf power injection, single- and double-null divertor operation, and divertor particle- and heat-load management. The recently installed Advanced Divertor hardware will allow critical transport experiments to be run with independent control of the density. It will also permit the concept of dc helicity injection current drive to be tested. This paper summarizes our most important recent findings and also outlines a few of the many interesting problems that are now under study to address fusion technology questions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Elastic Properties in Tension and Shear of High Strength Nonferrous Metals and Stainless Steel - Effect of Previous Deformation and Heat Treatment

A resume is given of an investigation of the influence of plastic deformation and of annealing temperature on the tensile and shear elastic properties of high strength nonferrous metals and stainless steels in the form of rods and tubes. The data were obtained from earlier technical reports and notes, and from unpublished work in this investigation. There are also included data obtained from published and unpublished work performed on an independent investigation. The rod materials, namely, nickel, monel, inconel, copper, 13:2 Cr-Ni steel, and 18:8 Cr-Ni steel, were tested in tension; 18:8 Cr-Ni steel tubes were tested in shear, and nickel, monel, aluminum-monel, and Inconel tubes were tested in both tension and shear. There are first described experiments on the relationship between hysteresis and creep, as obtained with repeated cyclic stressing of annealed stainless steel specimens over a constant load range. These tests, which preceded the measurements of elastic properties, assisted in devising the loading time schedule used in such measurements. From corrected stress-set curves are derived the five proof stresses used as indices of elastic or yield strength. From corrected stress-strain curves are derived the secant modulus and its variation with stress. The relationship between the forms of the stress-set and stress-strain curves and the values of the properties derived is discussed. Curves of variation of proof stress and modulus with prior extension, as obtained with single rod specimens, consist in wavelike basic curves with superposed oscillations due to differences of rest interval and extension spacing; the effects of these differences are studied. Oscillations of proof stress and modulus are generally opposite in manner. The use of a series of tubular specimens corresponding to different amounts of prior extension of cold reduction gave curves almost devoid of oscillation since the effects of variation of rest interval and extension spacing were removed. Comparison is also obtained between the variation of the several properties, as measured in tension and in shear. The rise of proof stress with extension is studied, and the work-hardening rates of the various metals evaluated. The ratio between the tensile and shear proof stresses for the various annealed and cold-worked tubular metals is likewise calculated. The influence of annealing or tempering temperature on the proof stresses and moduli for the cold-worked metals and for air-hardened 13:2 Cr-Ni steel is investigated. An improvement of elastic strength generally is obtained, without important loss of yield strength, by annealing at suitable temperature. The variation of the proof stress and modulus of elasticity with plastic deformation or annealing temperature is explained in terms of the relative dominance of three important factors: namely, (a) internal stress, (b) lattice-expansion or work-hardening, and (c) crystal reorientation. Effective values of Poisson's ratio were computed from tensile and shear moduli obtained on tubular specimens. The variation of Poisson's ratio with plastic deformation and annealing temperature is explained in terms of the degree of anisotropy produced by changes of (a) internal stress and (b) crystal orientation.

METALS - ELASTICITY↗

A Review of Medium-Mn, Low-Density Steels for Transportation Applications

Low-density steels constitute a broad and complex alloy space (Fe–Mn–Al–C) suitable for a variety of applications. In particular, there has been growing interest in duplex (ferrite + austenite) or multiphase (+ martensite, carbides) low-density steels as a lightweight, advanced high-strength steel (AHSS) for vehicle applications, spurred by extensive decarbonization efforts. Medium-Mn (med-Mn) (3 to 12 wt pct) steels with 3.5 to 10 wt pct Al additions have decreased densities, presenting an interesting opportunity for high-specific strength, intrusion-resistant, and energy-absorbing sheet components with reduced alloying contents compared to high-Mn grades like austenitic Fe–Mn–Al–C or twinning-induced plasticity steels. Compared to leaner med-Mn steels, the physical metallurgy of med-Mn, low-density steels (MMLS) is complex and distinguished by increased δ-ferrite fractions and austenite stacking fault energies, decreased martensite start temperatures, and modified phase transformation windows. Mechanical properties of MMLS are comparable to 3rd generation AHSS, attributable to the unique, multiphase microstructures, and the array of strengthening mechanisms that can be accessed. Despite this, challenges and unknowns remain with respect to their industrial implementation, and new processing routes may need to be developed. Here, this review aims to highlight the composition effects, processing methods, microstructural evolution, deformation behavior, and application properties geared toward manufacturing and performance, altogether assessing the potential of MMLS for transportation applications.

36 MATERIALS SCIENCE↗