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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2017

Removal of Dissolved Silica using Calcinated Hydrotalcite in Real-life Applications.

Water shortages are a growing global problem. Reclamation of industrial and municipal wastewater will be necessary in order to mitigate water scarcity. However, many operational challenges, such as silica scaling, prevent large scale water reuse. Previously, our team at Sandia has demonstrated the use of selective ion exchange materials, such as calcinated hydrotalcite (HTC, (Mg 6 Al 2 (OH) 16 (CO 3 )*4H 2 O)), for the low cost removal of silica from synthetic cooling tower water. However, it is not currently know if calcinated HTC has similar capabilities in realistic applications. The purpose of this study was to investigate the ability of calcinated HTC to remove silica from real cooling tower water. This was investigated under both batch and continuous conditions, and in the presence of competing ions. It was determined that calcinated HTC behaved similarly in real and synthetic cooling tower water; the HTC is highly selective for the silica even in the presence of competing cations. Therefore, the data concludes that calcinated HTC is a viable anti-scaling pretreatment for the reuse of industrial wastewaters.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2017

Enriched Boron-Doped Amorphous Selenium Based Position-Sensitive Solid-State Thermal Neutron Detector for MPACT Applications

High-efficiency thermal neutron detectors with compact size, low power-rating and high spatial, temporal and energy resolution are essential to execute non-proliferation and safeguard protocols. The demands of such detector are not fully covered by the current detection system such as gas proportional counters or scintillator-photomultiplier tube combinations, which are limited by their detection efficiency, stability of response, speed of operation, and physical size. Furthermore, world-wide shortage of 3 He gas, required for widely used gas detection method, has further prompted to design an alternative system. Therefore, a solid-state neutron detection system without the requirement of 3 He will be very desirable. To address the above technology gap, we had proposed to develop new room temperature solidstate thermal neutron detectors based on enriched boron ( 10 B) and enriched lithium ( 6 Li) doped amorphous Se (As- 0.52%, Cl 5 ppm) semiconductor for MPACT applications. The proposed alloy materials have been identified for its many favorable characteristics - a wide bandgap (~2.2 eV at 300 K) for room temperature operation, high glass transition temperature (t g ~ 85°C), a high thermal neutron cross-section (for boron ~ 3840 barns, for lithium ~ 940 barns, 1 barn = 10 -24 cm 2 ), low effective atomic number of Se for small gamma ray sensitivity, and high radiation tolerance due to its amorphous structure.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2013

Long-Term Instrumentation, Information, and Control Systems (II&C) Modernization Future Vision and Strategy

Life extension beyond 60 years for the U.S operating nuclear fleet requires that instrumentation and control (I&C) systems be upgraded to address aging and reliability concerns. It is impractical for the legacy systems based on 1970’s vintage technology operate over this extended time period. Indeed, utilities have successfully engaged in such replacements when dictated by these operational concerns. However, the replacements have been approached in a like-for-like manner, meaning that they do not take advantage of the inherent capabilities of digital technology to improve business functions. And so, the improvement in I&C system performance has not translated to bottom-line performance improvement for the fleet. Therefore, wide-scale modernization of the legacy I&C systems could prove to be cost-prohibitive unless the technology is implemented in a manner to enable significant business innovation as a means of off-setting the cost of upgrades. A Future Vision of a transformed nuclear plant operating model based on an integrated digital environment has been developed as part of the Advanced Instrumentation, Information, and Control (II&C) research pathway, under the Light Water Reactor (LWR) Sustainability Program. This is a research and development program sponsored by the U.S. Department of Energy (DOE), performed in close collaboration with the nuclear utility industry, to provide the technical foundations for licensing and managing the long-term, safe and economical operation of current nuclear power plants. DOE’s program focus is on longer-term and higher-risk/reward research that contributes to the national policy objectives of energy security and environmental security . The Advanced II&C research pathway is being conducted by the Idaho National Laboratory (INL). The Future Vision is based on a digital architecture that encompasses all aspects of plant operations and support, integrating plant systems, plant work processes, and plant workers in a seamless digital environment to enhance nuclear safety, increase productivity, and improve overall plant performance. The long-term goal is to transform the operating model of the nuclear power plants (NPP)s from one that is highly reliant on a large staff performing mostly manual activities to an operating model based on highly integrated technology with a smaller staff. This digital transformation is critical to addressing an array of issues facing the plants, including aging of legacy analog systems, potential shortage of technical workers, ever-increasing expectations for nuclear safety improvement, and relentless pressure to reduce cost. The Future Vision is based on research is being conducted in the following major areas of plant function: 1. Highly integrated control rooms 2. Highly automated plant 3. Integrated operations 4. Human performance improvement for field workers 5. Outage safety and efficiency. Pilot projects will be conducted in each of these areas as the means for industry to collectively integrate these new technologies into nuclear plant work activities. The pilot projects introduce new digital technologies into the nuclear plant operating environment at host operating plants to demonstrate and validate them for production usage. In turn, the pilot project technologies serve as the stepping stones to the eventual seamless digital environment as described in the Future Vision.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2018

Connecting LWRS Human Factor Engineering R&D to NUREG-0711 Elements and Modification Activities in Nuclear Power Plants

This Report documents the connection between DOE INL LWRS HFE R&D activities and the technical content of NUREG-0711 Results Summary Reports. Since the current and most recent LWRS HFE activities are associated with modernization and modification of nuclear power electric generating stations, this Report will limit its scope to these topics. NUREG-0711 Results Summary Reports content is shared with US nuclear generating stations by INL HFE staff through HFE Technical Reports to identify potential HEDs with planned upgrades. With such information, utilities have confidence that their upgraded HMIs, operating procedures, conduct of operations, and training with the upgraded systems will ensure their continued safe control of the nuclear plant. The utilities use the HFE Technical Reports as basis documents in their licensing processes used to modify the plant (LAR or 10CFR50.59). For plant modifications, LWRS HFE R&D activities commence as early as an agreement is reached between the utility and the LWRS Program staff. The multiple interfaces usually result in the two organizations meeting at INL, at the utility’s site, and at the vendor’s facility. Since there generally is a shortage of utility based HFE experience, INL HFE staff supports the HFE related utility modernization & modification (obsolescence) activities whenever requested.

10 CFR 50.59↗
DOE OSTI2018

Assessing the Wind Energy Potential in Bangladesh: Enabling Wind Energy Development with Data Products

USAID Bangladesh and the U.S. Department of Energy’s National Renewable Energy Laboratory partnered with the Government of Bangladesh to develop a national wind resource assessment. The assessment used sophisticated resource modeling that was validated by a ground measurement campaign. Results from the project included a long-term, correlated wind data set; validated high-resolution wind resource maps; and publicly available data accessible through the RE Data Explorer (https://www.re-explorer.org/). The Renewable Energy (RE) Data Explorer allows users to access and download the Bangladesh wind resource assessment data and related geographic information system (GIS) data sets and perform customized technical potential analyses. Figure ES-1 is an example wind resource map for Bangladesh that can be created with the RE Data Explorer. This project improved upon existing global data sets by using best-in-class modeling techniques and analysis. Global models are good first steps in predicting wind resources in various parts of the world, but they do not generate the accuracy needed to reduce project risk and stimulate renewable investment. This project improved the quality of modeled wind resource data for Bangladesh. In addition to the modeling effort, the project team used a multi-year, local data-collection campaign to validate the model and further improve the accuracy of the data sets. The measurement campaign consisted of nine meteorological sites representing all geographical regions of the country. Seven meteorological towers and one remote-sensing, sonic detection and ranging unit (deployed at two sites) collected the data. Site-selection criteria focused on geographic diversity and proximity to existing transmission lines. Figure ES-1 shows measurement locations. The measurement campaign spanned June 2014 through December 2017. The results of the Bangladesh wind resource assessment will help Bangladesh overcome significant energy challenges. Its energy sector suffers from power shortages, increasing demand, decreasing domestic natural gas reserves, and inadequate transmission infrastructure. As part of a comprehensive plan to overcome these challenges, Bangladesh has committed that 10% of the total generation capacity will be renewable energy by 2021 (Power Division 2016). High-quality renewable energy resource data and other GIS data, such as those developed in this assessment, are important if Bangladesh wishes to reach its 10% renewable energy capacity target. These data support informed decision making, ranging from policy and investment decisions to reliable power sector planning. Specifically, the Bangladesh wind resource assessment will help reduce technical risk and encourage private-sector interest in the nascent wind market in Bangladesh. In addition, the Government of Bangladesh may use the results of the wind resource assessment to develop well-designed policies that could encourage investment in wind energy. This report provides a comprehensive description of the Bangladesh wind resource assessment, including details on the modeling approach and methods, instrumentation, data quality-control techniques, and resulting data sets.

17 WIND ENERGY↗
DOE OSTI2018

Electrochemical Water Treatment for Cooling Towers

Cooling towers are an integral component of many refrigeration systems, providing comfort or process cooling across a broad range of applications. They are the point in the system where heat is dissipated to the atmosphere through the evaporative cooling process. Cooling towers are commonly found in industrial applications and are also commonly applied to water cooled chilled water plants in medium to large commercial buildings. Cooling towers used in medium to large commercial buildings are the focus of this paper. Cooling towers consume a large amount of water. Cooling tower related water consumption is one of largest potable water loads within buildings in the United States, with over 26% of water use associated with heating and cooling. Reducing water consumption is a priority for the General Services Administration (GSA) due to Executive Order 13514, Energy Policy Act of 1992, and regional water shortage concerns. These factors have brought about the investigation of cost effective opportunities to reduce water use, such as alternative water treatment (AWT) technologies for cooling towers. Traditional water treatment approaches rely on chemicals to extend the ability of the water to hold scaling minerals in suspension, minimize corrosion, and prevent biological growth. This treatment protects the chillers and cooling tower equipment, however even when chemicals are used regularly, a certain percentage of condenser water must be blown down and made up with fresh water to maintain system water quality parameters. In addition, the use of chemicals sometimes creates a waste issue and can cause building owners to incur additional fees such as disposal or sewer charges. The current state of water treatment in GSA buildings is to contract for a fixed fee with a company specializing in a conventional chemical maintenance. There are many vendors of AWT systems. This project assesses the effectiveness of one technology provided by Dynamic Water Technologies (DWT). This project assesses the effectiveness of DWT for lowering GSA operating costs while maintaining proper water treatment. The application of the DWT technology in place of traditional chemical water treatment has the anticipated benefits of: - Saving water and water/sewer costs by reducing the amount of blowdown required due to being able to remove scale causing minerals that allows the system to operate at a higher cycles of concentration - Eliminating the need for water treatment chemicals for scale, corrosion, and biological growth - Increasing chiller efficiency by preventing scaling and removing some of the existing scale, which improves heat transfer - Maintaining very low corrosion rates. The technology was installed at the Juliette Gordon Low Federal Building located in Savannah, Georgia. The building has two cooling towers utilizing traditional chemical water treatment for the cooling water circulating through the two chiller condensers. Measurement at the site includes the flow of makeup water to the cooling towers and the blowdown flow rate from the cooling tower basins. Additionally, energy measurements include the electrical energy from the chillers, chiller water pumps, condenser water pumps, cooling tower fans and the energy used by the DWT skid and slip stream pump.

15 GEOTHERMAL ENERGY↗
DOE OSTI2018

Am-241 Nuclear Safety and Environmental Interactions

NASA’s supply of radioisotopes for Radioisotope Heat Units (RHU) and Radioisotope Thermoelectric Generator (RTG) power sources is facing a crisis due to shortages of Pu-238 for future missions. Am-241 is a possible replacement for Pu-238 since its stockpile from the nuclear weapons program has remained relatively intact. The purpose of this project was to assess the safety of Am-241 and the risks associated with it as compared with PU-238. The project has resulted in a journal article, F. De-La-Torre-Aguilar, N. White, M. Prelas, R. V. Tompson, and S. K. Loyalka "Space nuclear power system accidents: Doses from Pu-238 and Am- 241 inhalation," Progress in Nuclear Energy vol.100C (2017), pp.171-182, which showed that the radiation dosage resulting from Am-241 inhalation are about 1/2.5 of the dosage resulting from Pu-238 inhalation per KW of Pu-238 power. Considerable progress was also made on the Direct Simulation Monte Carlo Method (DSMC) for simulation of aerosol evolution during accidents resulting in three publications: 1.I. Saldivar, F. De-La-Torre-Aguilar, M. Boraas, and S. K. Loyalka “Benchmark problems in aerosol evolution: Comparison of some exact and DSMC results” in Annals of Nuclear Energy vol.117 (2018), pp.213-222. 2. I. Saldivar and S. K. Loyalka, “Evolution of Aerosols Coupled to Environments: Verification of Direct Simulation Monte Carlo (DSMC)”, Nuclear Technology 204 (2018), pp.172-183. 3. M. Boraas and S. K. Loyalka, “Mesh Free Simulation of Spatially Inhomogeneous aerosols in Arbitrary Geometries” Nuclear Science and Engineering (2018). Further, we have computations on Am-241/Pu-238 vapor and aerosol interactions, and found that the vapor condensation rate is relatively insensitive to the mass effects, confirming some previous results. We have also completed computations of charge effects on evolution of different species aerosols and a manuscript is in preparation. Additionally, we have compared atmospheric dispersion and deposition of Pu-238 and Am-241 using the HYSPLIT code. We have also used a real lung model and the CFD program FLUENT to compute PuO2 and AmO2 deposition to explore improvements upon the ICPR-66 model. We have found that the deposition efficiencies of PuO2 and AmO2 are similar. These results (four manuscripts) will be submitted for publication in the post project period. We have made progress using framework of Mars 2020 mission nuclear risk assessment model to integrate all results, but our progress has been limited as the improved consequence modeling itself has been quite involved and challenging. We will integrate and complete the more extensive risk modeling computations and publish the results in the post-project period. In addition to the above, the project has resulted in research training of four PhD students

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2019

Off-Road Vehicles Research Workshop (Summary Report)

This report summarizes the off-road vehicles stakeholder workshop that was focused on research, technical challenges, and future direction related to off-road vehicles and held at Argonne National Laboratory in October 2018. The views expressed in this report are those of the workshop participants. Topics discussed and included in this report are engine efficiency and emissions; efficient fluid power; and system integration, control, and new technologies. The purposes of this workshop were to: 1) Discuss and exchange information on the current state of technology for off-road vehicles; 2) Work collectively to address the technical challenges; and 3) Help shape the future direction for off-road vehicles research and development (R&D). The report highlights some key points, takeaways, and technical challenges and ideas to inform DOE R&D programs for the off-road sector. The workshop objectives were to: • Identify the barriers to cost-effective, high-efficiency, off-road vehicles; • Identify pre-competitive research topics that could have the biggest impact in overcoming barriers; and • Identify metrics that should be applied to program progress and ambitious but realistic goals. Customer acceptance, reliability, and system durability are some of the market barriers to new technology that were discussed during the workshop. Participants agreed that a comprehensive strategy is required to explore ways to improve engine efficiency while lowering emissions (i.e., NO x , GHG, etc.) and at the same time, meet customer needs and expectations. A full system optimization was recommended for off-road vehicles. It was noted that off-road vehicles are very diverse with a wide range of engine size and vehicle applications. A need for R&D for transient operations and other operating conditions was identified, as off-road vehicles are currently optimized for steady state. Fuel type for these vehicles has an important role. Fuel cost and fuel delivery to the work-site are challenging for any new fuel. Increased vehicle electrification is one of the new technologies discussed during the workshop. Electric propulsion for off-road vehicles has limited applications in the near term, but hybridization seems more promising. Furthermore, electrification requires better batteries and, possibly, the use of higher-voltage systems. Developing more efficient component technologies, including pumps, motors, and valves, is important for more efficient fluid power systems. New work-circuit architectures that can decrease throttling losses and better integrate the work circuit and engine can offer significant efficiency gains. Autonomous vehicles for off-road sectors were also discussed. Autonomous vehicles for off-road space are very appealing for some markets due to shortage in skilled labor and its significant impact on productivity, vehicle weight, and therefore, energy use and emissions. Autonomous driving for mining and farming applications is more feasible because the routes are predefined, but for other applications, such as forestry and construction vehicles, autonomous driving would be very challenging.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2019

A Code to Code Benchmark for HTGR Fuel Element Depletion

The current lack of well-qualified experimental measurements for spent HGTR fuel elements limits the validation of advanced doubly heterogeneous depletion methods. Because of this shortage of data, a benchmark was developed as the first, simplest phase in a planned series of increasingly complex set of code-to-code benchmarks. The intent of this benchmark was to encourage submission of a wide range of computational results for depletion calculations in a set of basic fuel cell models. Comparison of results using independent methods and data should provide insight into potential limitations in various modeling approximations. The benchmark seeks to provide the simplest possible models, in order to minimize the effect of competing and potentially offsetting phenomena that might mask weaknesses in given methods. Twenty-one sets of results were submitted by twelve participants internationally. Various approaches were used for the treatment of microscopic grains dispersed in fuel elements in the second and third parts of the benchmark, including explicit treatment of grains distributed within a regular lattice, a randomized distribution of explicit grains, reactivity-equivalent physical transformation and a two-pass homogenization with disadvantage factors. The broad agreement appears to validate each of the double heterogeneity treatments.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2019

Energy Storage Policy Summaries for the Global Energy Storage Database

This report includes energy storage policy analysis from six states: Arizona, California, Massachusetts, Nevada, New Mexico, and New York. These summaries offer prototypes for summaries that will subsequently be prepared for all 50 states (and territories). There is presently a shortage of comprehensive energy storage policy analysis that public utility regulators can call upon to inform policymaking in their own jurisdictions. The state policy summaries that will be offered publicly on the Global Energy Storage Database (GESDB) will include analysis on the executive directives, legislation, regulations pertaining to energy storage that have been adopted by an individual state, along with perspective on the remaining policy issues pertaining to storage that a state will be likely to address in the future. It is anticipated that public utility regulators in particular will find the database to be a useful resource in benchmarking policy approaches critical to the continued development of an energy storage marketplace in the U.S., including policy approaches specific to storage and renewables procurement targets, interconnection standards, valuation of energy storage, rate reform and tariff design specific to energy storage, consideration of multiple uses for storage at the distribution level, and potential revisions to existing state net metering programs to accommodate an expected growth of energy storage technologies.

25 ENERGY STORAGE↗
DOE OSTI2019

Transforming the Uranium Fuel Cycle: Safe & Economical Conversion of DUF 6 to DUF 4 [Slides]

Project Outcomes: Designed and fabricated SS reaction vessels for executing reactions with UF 6 at SIGMA, followed by transport and analysis at TA-48; Established a new capability at SIGMA for performing small mass transfers of UF 6 ; Safety documentation approved for performing new UF 6 chemistry at SIGMA; Staff training and conversion opportunity established for LANL Seaborg post-doc; Neat reaction with HMDS (CH 3 ) 3 Si-Si(CH 3 ) 3 produced fluorosilanes; In reactions with solvents, fluorination observed. No DUF 4 observed yet. Observations: Only 4 reactions were completed – more clearly needed; Due to problems with procurement, we did not get the mass control flow (MFC) unit until late August; Due to staff and time shortages UF 4 was never delivered from SIGMA to TA-48 by SHIP-IT; Established ability for future collaboration between C and Sigma.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2019

Overview of Leak Detection Technologies A Summary of Capabilities and Costs

As droughts and changing climate patterns cause water shortages and potential water system disruptions, there is a growing need for water resilience, which is the ability to withstand, adapt to, and recover from disruption. The Environmental Protection Agency’s (EPA) report on Water Audits and Water Loss Control for Public Water Systems [EPA, Water Audits and Water Loss Control for Public Water Systems] states that average water loss in distribution systems is 16%, 75% of which is lost through leaks. Commercially available leak detection technologies were researched to identify current capabilities and average use costs, including operation and management (O&M) considerations, how to operate the devices, and current limitations. It was found that the cost-effectiveness of leak detection technologies is not ubiquitous across all systems. Factors that must be taken into account include the size of the water system, the amount of water use, and the currently known water losses in the system. A variety of technologies are summarized to give water managers a basic understanding of the tools available to them, and help enable them to make a more informed choice of how to reduce water losses in their water systems.

42 ENGINEERING↗
DOE OSTI2019

Next-Generation Optimization under Uncertainty: Structure-Oriented Algorithms

With the advent of the smart grid, renewable technologies, and carbon emission programs, a key concern is the coordination of national infrastructures such as the electricity, natural gas, and water supply network systems. Anticipating and mitigating uncertainty of weather, demands, and contingencies in a more integrated environment is necessary to maximize resource efficiency and prevent cascading failures that can ultimately lead to catastrophic shortages of supplies. This project developed scalable algorithms for stochastic optimization capable of addressing extreme-scale problems (motivated by challenges in the design and operation of national infrastructures). Specifically, the project developed a new family of algorithms to solve continuous stochastic problems to local and global optimality as well as algorithms to solve mixed-integer convex and nonconvex stochastic programs. We developed supporting local and global convergence theory for these algorithms and implemented the algorithms in open-source software packages that can leverage high-performance computing architectures.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2020

Electrical Safety Practices Developed for Automotive Lithium Ion Battery Dismantlement

ORNL is developing electrical safety practices for handling and disassembling automotive lithium ion batteries in a research environment. Online literature searches did not reveal any standard electrical safety practices for disassembling lithium ion battery stacks from automobiles. Until recently, there has been insufficient motivation to recycle or refurbish spent automotive lithium ion batteries due to limited volumes entering the secondary market. However, a growing volume of spent lithium ion batteries are beginning to collect in automobile salvage yards, recycling facilities, landfills, and other places due to a shortage of economically and environmentally viable end-of-life options. ORNL studied automotive battery pack, module, and cell dismantlement to understand the risks, hazards, and controls necessary to perform dismantlement safely and economically. Packs, modules, and cells were manually taken apart, while wearing appropriate personal protective equipment, with insulated hand tools. These dismantlement studies point out the hazards and risks associated with dismantling automotive lithium ion batteries and describe practices for controlling such hazards and risks while demonstrating the controls through a case study of a first-generation Chevrolet Volt battery pack.

25 ENERGY STORAGE↗
DOE OSTI2020

Evaluation of an Additively Manufactured Respirator for Personnel Protection from Particulates

Additively manufactured respirators (AMRs) made using rigid plastic can be fitted with repurposed filter media to yield a wearable mask capable of passing a quantitative fit test with criteria set for commercial, N95 health care particulate respirators. This has been verified through an evaluation study assessing AMR masks fabricated using open-source design files and a commercial fused-filament fabrication machine, using N95 filter cloth and a P100 respirator cartridge. A few examples of filter media not designed for human respiratory protection were also evaluated in an AMR mask but did not demonstrate filtering sufficient to pass the N95 test criteria. All attributes of an AMR mask system must be considered during design and when testing performance, including the mask frame, gasket, and the cord used to secure the mask to the face. AMR masks are not the same as commercially available respiratory masks. If AMR masks are used as personal protective equipment (PPE) during a crisis when there is a shortage of regular PPE it is important that wearers are fully informed of the differences, tradeoffs, and risks associated with their use. Quantitative fit testing and proper training on how to don and doff the AMR mask are important to help achieve the best possible outcome when they are used.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2020

Favipiravir Flow Synthesis

Researchers at Los Alamos have invented a novel flow/batch chemistry synthetic process to produce the small molecule anti-viral favipiravir more cheaply and rapidly to enable on-demand production for pandemic response. Current methods for synthesizing favipiravir are constrained by long reaction times and low yields. If ongoing clinical trials for favipiravir demonstrate its effectiveness as a COVID-19 antiviral, and as a broad spectrum anti-viral for treating future viral outbreaks, this synthesis would help alleviate potential drug shortages and supply chain issues for the manufacturing and availability of this small molecule anti-viral. This U.S.-based synthesis route would be capable of scale-up for making large (kilogram) amounts of favipiravir as needed to assist with clinical trial needs and demand for patient treatment, and can also produce isotopically labeled favipiravir. We are seeking a CRADA partner to finalize method development who has interest in licensing the method and employing it for domestic production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Continuous Monitoring and Partial Water Softening for Cooling Tower Water Treatment

Cooling towers are an integral component of many refrigeration systems, providing comfort or process cooling across a broad range of applications. They are the point in the system where heat is dissipated to the atmosphere through the evaporative cooling process. Cooling towers are commonly found in industrial applications and are also often used in water-cooled chilled water plants in medium to large commercial buildings. Continuous monitoring and partial water softening for cooling towers used in medium to large commercial buildings are the focus of this paper. Cooling towers consume large amounts of water. Cooling tower-related water consumption is one of largest potable water loads within buildings in the United States, with substantial building water use associated with heating and cooling. Regional water shortages have highlighted a need to reduce water consumption; the U.S. General Services Administration (GSA) and Executive Order 13834 place priority on reducing water consumption. This priority has fueled interest in the identification, investigation, and potential broad deployment of cost-effective opportunities to reduce water use, such as alternative water treatment (AWT) technologies for cooling towers. Traditional water treatment approaches use chemicals to extend the ability of the water to hold scaling minerals in suspension, minimize corrosion, and prevent biological growth. This treatment protects the chillers and cooling tower equipment; however, even when chemicals are used regularly, a certain percentage of condenser water must be drained and made up with fresh water to maintain system water quality parameters. In addition, the use of chemicals sometimes creates a waste disposal issue and can cause building owners to incur additional fees, such as disposal or wastewater charges. To manage cooling tower water treatment, GSA typically contracts with a company specializing in conventional chemical maintenance for a fixed fee. While there are many types and vendors of AWT systems, this project assesses the effectiveness of one technology provided by Aqualogix. This system is a chilled water plant monitoring and control system aimed at optimizing system performance by reducing the blowdown occurrences used to remove mineral build-up. The technology consists of two components – continuous programmable logic control (PLC) monitoring and side-stream filtration with partial water softening. PLC monitoring calculates cycles of concentration (CoC) and determines the optimum amount of blowdown water required to satisfy all water chemistry requirements. Side-stream filtration removes suspended matter and improves biocide efficacy while precisely dispensing softened water to achieve optimal makeup water hardness. Unlike other AWT systems evaluated by GSA to date, this system does not replace the legacy treatment system but is used in addition to chemical water treatment. The vendor claims their technology will reduce water consumption, water discharge, and maintenance costs. The AWT system evaluated in this demonstration is a commercialized technology. Given its commercialized state, the system evaluated in this report is at a Technology Readiness Level 9 according to National Aeronautics and Space Administration (NASA) definitions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Quantitative form and fit of N95 filtering facepiece respirators are retained after dry and humid heat treatments for coronavirus deactivation

Re-use of filtering facepiece respirators (FFRs, commonly referred to as N95s) normally meant for single use only is becoming common in healthcare facilities due to shortages caused by the COVID19 pandemic. Here we report that mouse hepatitis virus (MHV) initially seeded on FFR filter material is inactivated (6 log reduction as measured by 50% tissue culture infective dose (TCID50)) after dry heating at 75 °C for 30 minutes. We also find that the quantitative fit of FFRs after heat treatment at this temperature, under dry conditions or at 90% relative humidity, is not affected by single or ten heating cycles. Previous studies have reported that the filtration efficiency of FFR filters is not negatively impacted by these heating conditions. These results suggest that thermal inactivation of coronaviruses is a potentially rapid and widely deployable method to re-use N95 FFRs in emergency situations where reusing FFRs is a necessity and broad-spectrum sterilization is unavailable. However, we also found that a heat source that emits radiation (e.g., an exposed heating element) results in rapid qualitative degradation of the FFR. Finally, we discuss differences in the results reported here and other recent studies investing heat as a means to recycle FFRs and suggest that overall wear time and donning/doffing cycles are important factors that need to be considered.

36 MATERIALS SCIENCE↗