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At least 343 records · Page 19

Application of remote sensing technology to land evaluation, planning utilization of land resources, and assessment of westland habitat in eastern South Dakota, parts 1 and 2

The author has identified the following significant results. LANDSAT fulfilled the requirements for general soils and land use information. RB-57 imagery was required to provide the information and detail needed for mapping soils for land evaluation. Soils maps for land evaluation were provided on clear mylar at the scale of the county highway map to aid users in locating mapping units. Resulting mapped data were computer processed to provided a series of interpretive maps (land value, limitations to development, etc.) and area summaries for the users.

Myers, V. I.↗

Inferences about magma sources and mantle structure from variations of Nd-143/Nd-144

Continental flood basalts and mid-ocean ridge (MOR) tholeiitic basalts have distinctly different Nd-143/Nd-144 which may permit a priori distinction between continental and oceanic igneous rocks. Initial Nd-143/Nd-144 of continental igneous rocks through time fall on a Sm/Nd evolution curve with chondritic REE abundance ratio. These observations indicate that many continental igneous rocks are derived from a reservoir with chondritic REE pattern which may represent primary material remaining since the formation of the earth. Oceanic igneous rocks are derived from a different ancient reservoir which has Sm/Nd higher than chondritic. Initial Nd-143/Nd-144 and Sr-87/Sr-86 in young basalts from both oceans and continents show a strong correlation suggesting that Sm-Nd and Rb-Sr fractionation events in the mantle may be correlative and caused by the same process. From this correlation Rb/Sr for the earth is inferred to be 0.029.

Depaolo, D. J.↗

On the age of Rhodesian greenstone belts

Isochron ages and initial Sr-87/Sr-86 ratios are derived from Rb-Sr isotopic analyses on metavolcanic rocks from some greenstone belts of the Rhodesian Archean craton. Three mineral isochron ages (about 2.4 billion years) are tentatively suggested to represent the time of an important low-grade metamorphic event.

Jahn, B.-M.↗

A new 1.3 Aeon-Young achondrite

The Ar-40/Ar-39 age of Governador Valadares, a Nakhlite achondrite, has been determined to be 1.32 plus or minus 0.04 billion yrs. The K-Ar age and cosmic-ray exposure age of Governador Valadares are essentially identical to analogous ages for the two other known Nakhlite achondrites and to Rb-Sr ages determined for Nakhla. These data suggest that all three known meteorites of this class were derived from the same parent body by a common event, and confirm that Governador Valadares is a member of this class. The most probable heat source for producing such meteorites may be collisional melting of a portion of the parent body. Nakhlites may represent a rare phenomenon and may not be at all representative of the surface of their parent body.

Bogard, D. D.↗

Outline of a lunar chronology

An outline is presented of lunar chronology and evolution based on analyses of the isotopic parent-daughter systems Rb-87-Sr-87, U-Th-Pb-206-Pb-207-Pb-208, and K-40-Ar-40. The samples which were investigated represent mare basalts (returned by Apollo 11, 12, 15, and 17 and by Luna 16) and terra rocks which include non-mare basalts, anorthosites, troctolites, and norites, but are predominantly comprised of complex breccias (returned by Apollo 12, 14, 16, and 17 and Luna 20)

Wasserburg, G. J.↗

Volatile element depletion and K-39/K-41 fractionation in lunar soils

Evidence for selective loss and isotopic fractionation (in the case of K) of volatile elements during formation of agglutinates by micrometeoritic bombardment of lunar soils is presented. Concentrations and isotopic compositions of volatile elements (K, Rb, Pb) and nonvolatile elements (U, Th, Ba, Sr, rare earths) in separates taken from soils 14163, 14259, 15041, 68501, and 71500 are examined. Rayleigh fractionation calculations applied to K-39/K-41 isotopic data indicate ten-fold recycling of bulk soil, to account for observed isotopic anomalies. The lunar soil fines fraction seems to be a site of deposition for volatile or labile Pb produced during agglutination. Local fines (below 75 microns) are viewed as representative of the parent material for agglutinates formed in situ by micrometeoritic impact. Magnetic separation of agglutinates from soil 68501 revealed a bimodal population, with one class comprising welded blocky magnetic glasses.

Church, S. E.↗

Sr isotopic constraints on the petrogenesis of Apollo 17 mare basalts

Sr-isotopic results are obtained for three basalt samples from Station 4, and it is shown that these basalts have Rb-Sr crystallization ages and initial Sr-87/Sr-86 ratios which are nearly identical to those of other Apollo 17 basalts. However, their Rb/Sr ratios have been increased two-to-four fold more at the time of their genesis than were those of the majority of Apollo 17 basalts. It is argued that this observation is consistent with their production by small degrees of partial melting of a source containing clinopyroxene as a residual phase.

Nyquist, L. E.↗

Composition of the projectiles that bombarded the lunar highlands

Twenty highland samples from Apollo 14, 15, and 17 and the eucrites Juvinas and Morre County were analyzed by radiochemical neutron activation for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Pd, Rb, Re, Sb, Se, Te, Tl, U, and Zn. The meteoritic components of 82 highland rocks were recalculated with the new corrections for the indigenous contribution and were classified by discriminant and cluster analysis as well as ternary diagrams, using Ir, Re, Au and Ni as diagnostic elements. To characterize these groups more fully, average abundances of meteoritic volatiles (Sb, Ge, Ag, Se, Te, and Bi) were calculated from regressions against Ir.

Gros, J.↗

'Mysterite' - A late condensate from the solar nebula

An attempt is made to clarify the nature of 'mysterite', a material that had been postulated to explain the overabundance of Tl, Bi, and Ag in certain chondrites. Four dark clasts and a vein sample from the H6 chondrite Supuhee were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Rb, Re, Sb, Se, Te, Tl, and Zn. One of the clasts is enriched in all volatile elements, while the other four samples are enriched only in the siderophile volatiles Ag, Bi, and Tl. The enrichments range up to 100 times typical H6 chondrite abundances. The proportions of Ag, Bi, and Tl suggest the presence of at least two, Tl-rich and Tl-poor, varieties of mysterite. The former seems to dominate in Supuhee and Krymka, and the latter in Mezo-Madaras. Apparently mysterite is a late condensate from the solar nebula that collected volatiles left behind by earlier generations of chondrites. It was incorporated in Supuhee and perhaps in other chondrites (mainly of low petrologic types) during brecciation events.

Higuchi, H.↗

Differentiation of the matter of the moon

The following facts were uncovered in comparing the basaltic surface rocks of the moon with terrestrial tholeiitic basalts and ordinary chondrites: (1) there is an excess of the so-called refractory chemical elements, including the group of truly refractory elements, the rare earths, U, and Th, in comparison with their content in primitive terrestrial basalts and chondrites; (2) the so-called siderophilic elements have lower contents in the lunar surface rocks than in terrestrial rocks; (3) the low alkali content (Na, K, Rb) in lunar rocks is established; (4) there is a low content of H2O and the ordinary gases CO2, halides, etc.; (5) the low content of metals with high vapor pressure, (In, Tl, etc.) has been established. It is proposed that U and Th were carried from the internal areas to the peripheral rocks of the moon during magmatic activity, i.e., up to 3 billion years ago. This redistribution of U and Th lead to their concentration in surface layers of the moon, and the heat which they generated was lost into surrounding space. The conclusion is then reached that in order to understand processes on the moon, the chondritic model cannot be used.

Vinogradov, A. P.↗

Geochemical zoning and early differentiation in the moon

The volatile elements (e.g., Rb, Pb, Tl, Bi, Cs) seem to have been depleted at the time of lunar accretion. Accordingly, it may be assumed that the moon initially accreted from refractory material. The good correlation between volatile/involatile element ratios (e.g., Cs/U, K/La, K/Zr) in both highland and maria samples means that element distribution in lunar crustal rocks is not governed by volatility differences. This and other evidence encourages the view that the moon was accreted homogeneously. A consequence of homogeneous accretion theories is that very efficient large-scale element fractionation is required to account both for the high near-surface concentrations of refractory elements (e.g., Th, U, REE, Zr, Ba, etc.) and for the Ca-Al-rich crust.

Taylor, S. R.↗

New data for the lunar 20 core and a survey of published chemical data

Lunar core samples were analyzed using a spark source mass spectrometer. The analytical results for the four zones of the Lunar 20 core suggest that the core is nonuniform with depth. The higher concentrations of Ce, Sc, Sc, Ba, La, Co, Sr, and Zr in zone 2001 may be connected with the presence in this zone of a basaltic rock type seldom seen in the other zones. That is, about half of the basaltic fragments in the large size fractions in zone 2001 are of a specific porphyritic breccia-like type. Anorthositic fragments containing a notable amount of metallic iron are basically limited to zone 2004 and probably explain the lower concentrations of Ce, Rb, Ba, La, and perhaps Co in this zone. The high concentrations of Ag and Ce found previously are confirmed. Although Ag is at nearly the same concentration in all four zones of the core, Cd in the core is the result of local enrichment. In particular, in zone 2004 the concentration of Cd may be as high as 10 ppm in a sample size of 0.01 mg.

Hubbard, N. J.↗

Formation and composition of the moon

Many of the properties of the Moon, including the enrichment in Ca, Al, Ti, U, Th, Ba, Sr, and the REE and the depletion in Fe, Rb, K, Na, and other volatiles can be understood if the Moon represents a high-temperature condensate from the solar nebula. Thermodynamic calculations show that Ca-, Al-, and Ti-rich compounds condense first in a cooling nebula. The initial high temperature mineralogy is gehlenite, spinel, perovskite, Ca-Al-rich pyroxenes, and anorthite. Inclusions in carbonaceous chondrites such as the Allende meteorite are composed primarily of these minerals and, in addition, are highly enriched in refractories such as REE relative to carbonaceous chondrites. These inclusions can yield basalt and anorthosite in the proportions required to eliminate the europium anomaly, leaving a residual spinel-melilite interior. A deep interior high in Ca-Al does not imply an unacceptable mean density or moment of inertia for the Moon. The inferred high-U content of the lunar interior, both from the Allende analog and the high heat flow, indicates a high-temperature interior. The model is consistent with extensive early melting, with shallow melting at 3 AE, and with presently high deep internal temperatures. It is predicted that the outer 250 km is rich in plagioclase and FeO. The low iron content of the interior in this model raises the interior temperatures estimated from electrical conductivity by some 800 C.

Anderson, D. L.↗

Physics and chemistry of MoS2 intercalation compounds

An investigation is made of the physics and chemistry of MoS2 intercalation compounds. These compounds may be separated into two groups according to their stoichiometry, structure and superconducting properties. The first group consists of Na, Ca, and Sr intercalates, and the second group consists of K, Rb, and Cs intercalates. Particular attention is given to the structure of the electronic energy band and to the normal state and superconducting properties of these compounds.

Woollam, J. A.↗

Evolution of mare basalts - The complexity of the U-Th-Pb system

An attempt has been made to gain more insight into mare-basalt evolution by performing a very detailed leaching and mineral-separation U-Th-Pb systematics study on mare basalt 15085. It is found that about 20-50% of the U, Th, and Pb reside on the grain boundaries or in the mesostasis and that the Pb-207/Pb-206 ratios of the grain boundaries and crystal interiors are distinctly different. These distinct trends appear to represent either continuous or episodic postcrystallizational disturbances to the U-Th-Pb system of this rock. Using U and Pb partition coefficients, it is concluded that existing two- and three-stage U-Pb evolution models do not accurately describe mare-basalt genesis. An alternative two-stage + KREEP mixing model is proposed as a simple approximation to U-Pb evolution in lunar rocks. Most Rb-Sr and Sm-Nd data are compatible with this model.

Unruh, D. M.↗

Chemical compositions and possible immiscibility of two silicate melts in 12013

The lunar sample 12013, a complex mixture of gray breccia and black breccia, is described. The gray breccia consists of mostly basaltic and gabbroic lithic clasts as well as plagioclase and pyroxene mineral clasts set in a matrix of smaller clasts and a felsite of granitic composition, while the black breccia is comprised of mostly mineral clasts, some lithic clasts, and felsite blebs enclosed in an aphanitic groundmass of basaltic composition. Textural relationships indicate that the felsite and the black breccia groundmass crystallized from melts which coexisted prior to the final lithification of 12013 but failed to mix. Both the felsite and the black breccia groundmass have extreme enrichments of incompatible elements. The critical feature of their compositions is a 'splitting up' of incompatible element associations so that the highest REE and P concentrations are in the black breccia groundmass, and the highest K, Ba, and Rb concentrations are in the felsite.

Quick, J. E.↗

Dunite 72417 - A chemical study and interpretation

The rock selected for the study is one of the rare ultrabasic rocks, which seems to have survived early lunar differentiation. The Rb-Sr internal isochron for this dunite gave an age of about 4.55 AE. The dunite was sampled at Apollo 17, Station 2 from a single 10x20-cm clast incorporated into a KREEP-rich blue-gray breccia 72435, Boulder 3. Nine dunite samples were analyzed with the aid of instrumental and radiochemical neutron activation analysis procedures. Data for 27 elements are shown in a table. Attention is given to trapped liquid (magma), a garnet hypothesis, models for the dunite genesis, and magma compositions from which 15415 and 72417 crystallized.

Laul, J. C.↗

Metamorphism, argon depletion, heat flow and stress on the Alpine fault

The Alpine fault of New Zealand is a major continental transform fault which was uplifted on its southeast side 4 to 11 km within the last 5 m.y. This uplift has exposed the Haast schists, which were metamorphosed from the adjacent Torlesse graywackes. The Haast schists increase in metamorphic grade from prehnite-pumpellyite facies 9-12 km from the fault through the chlorite and biotite zones of the greenschist facies to the garnet-oligoclase zone amphibolite facies within 4 km of the fault. These metamorphic zone boundaries are subparallel to the fault for 350 km along the strike. The K-Ar and Rb-Sr ages of the schists increase with distance from the fault: from 4 m.y. within 3 km of the fault to approximately 110 m.y. 20 km from the fault. Field relations show that the source of heat that produced the argon depletion aureole was the fault itself.

Scholz, C. H.↗