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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Synthesizing Lithium Sorbents Using Acid Mine Drainage Solids

In this study, we prepared HMO from coal mine drainage (CMD) solids and examined the practicability of recovering Li from oil and gas produced waters and geothermal brines. We aim to innovate high-value added products from the existing extract REEs and CMs processing chain of legacy byproducts associated with coal production. CMD solids, which are precipitates collected from exhausted limestone gravels of passive CMD treatment beds, are enriched in rare earth elements (REEs) and other critical minerals (CMs), and therefore, considered as a viable alternative source for REEs/CMs to supply the Nation’s demands. A patented extraction process developed by NETL (TREE) has been demonstrated as a cost-effective and efficient approach to recover REEs/CMs from CMD solids. Here, we selected residuals of CMD solids from the TREE process that are enriched in manganese (Mn) (>20% w/w) and successfully prepared LMO using a solid-state method modified from Yoshizuka et al. (2002).

Cheng, Chin-Min↗
DOE OSTI2024

Rare Earth Elements (REE) and Critical Minerals (CM) in Middle Pennsylvanian-Age Coals and Associated Sediments in the Central Appalachian Basin, Eastern U.S.A.

The Central Appalachian Basin (CAB) of Kentucky, Tennessee, West Virginia and Virginia has a long history of coal mining and oil and gas extraction that has empowered the regional and national economies, the development of infrastructure, and a highly trained energy resources work force. As our societal demands for advanced technologies have rapidly increased in recent years, coal-related materials are viewed as an important new unconventional domestic source of critical minerals (CM) that are required for telecommunications, aerospace and transportation industries, electronics, the transition to low-carbon emissions energy production, and many consumer products. Coal-related materials encompass coal, associated sediments, coal mining waste materials, produced waters, and ash residues from coal-fired power plants. An important objective of the Evolve Central Appalachia Project (Evolve CAPP), sponsored by the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to assess the quantity and distribution of CM resources in the CAB region. The rare earth elements (REE) are considered highest priority, although other important CM such as niobium, gallium, and zirconium are known to occur in the Middle Pennsylvanian-age coals and sediments. Working with coal industry partners who provided access to drill cores, coal-related sediments and waste materials, over 600 samples have been collected for laboratory analysis, and over 730 materials have been scanned using portable x-ray fluorescence (pXRF) equipment. The application of pXRF provides the means for real-time semiquantitative analysis of CM content at very close spacings (typically 2-3 inch intervals) along drill core and in-situ channel samples that span the roof, coal seam, and floor rock. The comparison of pXRF geochemical data with laboratory results, geologic data, and downhole spectral gamma logs can provide high resolution input to lithologic and depositional models for future CM resource evaluations. The preliminary findings show that pXRF is capable of accurately measuring low concentrations of many of the CM with a high level of confidence (Ba, Cr, Ga, K, Nb, Rb, Sr, Th, Y), whereas for others (La, Ce, Co, Mn, Nd, Ni, Sc, Ti, V) the detection limits are very high or spectral interferences increase the uncertainty. Notably, the mean abundances of Y (34 ppm), La (86 ppm), Ga (40 ppm), and V (146 ppm) in coal underclays in the CAB region are up to 7X enriched compared with the overlying coal. These values also exceed the reported concentrations in published reference materials for upper continental crustal rocks (Rudnick and Gao, 2003), North American Shale Composite (Gromet et al., 1984), and North American coal (Finkelman, 1993). The pXRF data are in part verified by laboratory results that indicate the mean Y abundance (36 ppm) is highly correlated (R2 = 0.807) with total REE (ΣREE). The correlation is even higher (R2 = 0.957) with heavy REE (ΣHREE). Applying these correlations to the pXRF data for the coal underclays, the mean estimated values for ΣREE+Y and ΣHREE+Y are 270 ppm and 58 ppm, respectively. Although these average values are not considered high, the range of Y measured by pXRF in the coal underclays extended as high as 114 ppm, which would suggest ΣREE+Y equal to 847 ppm. The mean abundances of Zr (192 ppm) and Th (21 ppm) in coal underclays are also enriched compared with the overlying coal and these results likely reflect the presence of resistant detrital heavy minerals such as monazite, xenotime, and zircon in the underclay matrix. Several of the profiled coal seams and associated wall rocks contained thin volcanic ash layers up to 4-5 inches in thickness. The extent to which these ash fall layers provided a source for CM under the paleoenvironmental conditions that resulted in coal deposits in the CAB remains to be fully studied. Continuing investigations in the Evolve CAPP study area will include laboratory determinations of mineralogic and clay compositions, and evaluations of CM geochemical mobility in the coal and coal underclays.

Lassetter, Billy↗
DOE OSTI2024

Application of Ion Sieve Sorbent Prepared from Mineral Stream Associated with Critical Minerals in Direct Lithium Extraction

In this presentation, the speaker discusses the research that has been carried out at NETL regarding direct lithium extraction. The three main discussing points are as follows: developing high-capacity lithium-ion sieve sorbent using mineral streams associated with critical minerals; demonstrating the sorbent ability to recover lithium from oil/gas produced waters and geothermal brines; and assessing the feasibility of large-scale implementation through technoeconomic analysis.

Cheng, Chin-Min [NETL Site Support Contractor, Nat↗
DOE OSTI2025

Methane Mitigator – Development of a Scalable Vent Mitigation Strategy to Simultaneously Reduce Methane Emissions and Fuel Consumption from the Compression Industry (Final Technical Report)

Researchers at West Virginia University completed a multi-year project under DE-FE0031865 entitled “Methane Mitigator – Development of a Scalable Vent Mitigation Strategy to Simultaneously Reduce Methane Emissions and Fuel Consumption from the Compression Industry”. An assessment of natural gas production site emission sources was completed to quantify the potential for emissions reductions and reductions in fuel consumption. The main sources of fugitive methane emissions at gas productions sites include condensate tanks, produced water tanks, gas compressor packing vents, pneumatic controller vents, and natural gas engine crankcase vents.

03 NATURAL GAS↗
DOE OSTI2025

Phase II Field Demonstration at Lansing Smith Generating Plant, Southport, Florida (Final Report)

The Final Technical Report: Field Test Design and Pressure Management Strategies for Phase II Field Demonstration of Optimal Pressure Control, Plume Management, and Produced Water Strategies presents the culmination of multi-year efforts under the U.S. Department of Energy’s Brine Extraction and Storage Test (BEST) program, led by EPRI in partnership with Gulf Power at the Plant Smith site near Panama City, Florida. The project was designed to evaluate and demonstrate the technical feasibility of managing subsurface pressures and fluid movement associated with large-scale CO₂ injection, using low-salinity water as a proxy fluid. Through a combination of field injection testing, reservoir modeling, and optimization studies, the research team developed and refined active and passive brine extraction strategies aimed at controlling injection-induced pressure buildup, mitigating risks of fault activation, and managing plume migration. The field demonstration incorporated a new injection well (TIW-2), a new monitoring/extraction well (TEMW-A), and an existing well (TIW-1) repurposed for passive pressure relief. Complementary geophysical monitoring was designed to track plume development and evaluate the effectiveness of pressure management strategies. The report details the integrated workflow encompassing wellfield development, regulatory permitting, model calibration, and survey design. It includes a comprehensive electromagnetic (EM) modeling and inversion study used to develop a cost-effective, time-lapse geophysical monitoring plan capable of imaging the evolving low-salinity plume within the highly saline Lower Tuscaloosa formation. Reservoir simulation results guided the design of the 17-month injection program and the timing of active extraction to maintain formation pressures below a hypothetical fault reactivation threshold. Supporting analyses evaluated potential injectivity risks related to clay fines migration and geochemical incompatibility, identifying practical mitigation measures such as salinity and pH control. The final design recommends a series of crosswell EM surveys—conducted before, during, and after injection—as the most effective and economical approach for plume imaging, supplemented by continuous downhole pressure and flow monitoring. Collectively, the study provides a field-ready framework for cost-effective pressure management and monitoring in support of future CO₂ storage projects.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2025

"Mining" for Critical Minerals: Critical Minerals from Fossil Energy Waste Byproducts

NETL researcher Mengling Stuckman is an invited speaker for the panel discussion session of "Mining for Critical Minerals" at the Marcellus Shale Coalition event, "Shale 2.0: Learn the Facts about Upstream, Midstream and Downstream". Recent studies from DOE have shown that produced water and drill cuttings from the development of unconventional shale in Appalachia has a significant source of valuable critical minerals and will support bolstering America's supply chain security, putting Pennsylvania in a unique position to capitalize. The panel discussion facilitates obtaining an overview of pipeline capacity needs, downstream users for natural gas and effectively educating and engaging the public relevant to the Marcellus Shale community. The event also offers opportunities for local oil and gas industries, water and waste management companies to work with NETL and participate in FECM’s Critical Mineral program. Industrial feedbacks and participation as outcomes of this invited talk will accelerate the technology and knowledge transfer for the DOE’s Critical Mineral program and for DOE’s mission to unleash American Energy and lead in energy innovation.

critical minerals↗
DOE OSTI2021

Effects of Carbonate Minerals on Shale-Hydraulic Fracturing Fluid Interactions in the Marcellus Shale

Natural gas extracted from tight shale formations, such as the Marcellus Shale, represents a significant and developing front in energy exploration. By fracturing these formations using pressurized fracturing fluid, previously unobtainable hydrocarbon reserves may be tapped. While pursuing this resource, hydraulic fracturing operations leave chemically complex fluids in the shale formation for at least two weeks. This provides a substantial opportunity for the hydraulic fracturing fluid (HFF) to react with the shale formation at reservoir temperature and pressure. In this study, we investigated the effects of the carbonates on shale-HFF reactions with a focus on the Marcellus Shale. We performed autoclave experiments at high temperature and pressure reservoir conditions using a carbonate-rich and a decarbonated or carbonate-free version of the same shale sample. We observed that carbonate minerals buffer the pH of the solution, which in turn prevents clay dissolution. Carbonate and bicarbonate ions also scavenge reactive oxidizing species (ROS), which prevents oxidation of shale organic matter and volatile organic compounds (VOCs). Carbonate-free samples also show higher pyrite dissolution compared to the carbonate-rich sample due to chelation reactions. This study demonstrates how carbonate minerals (keeping all other variables constant) affect shale-HFF reactions that can potentially impact porosity, microfracture integrity, and the release of heavy metals and volatile organic contaminants in the produced water.

58 GEOSCIENCES↗
DOE OSTI2021

Effect of Humidity on the Reactive Uptake of Ammonia and Dimethylamine by Nitrogen-Containing Secondary Organic Aerosol

This study investigated the uptake of ammonia (NH3) by secondary organic aerosol (SOA) particles generated via limonene photooxidation or ozonolysis as well as the uptake of dimethylamine (DMA) by limonene ozonolysis, α-cedrene photooxidation, or toluene photooxidation SOA in an environmental chamber between 0–50% relative humidity. In addition to the acid-base equilibrium uptake, NH3 and DMA can react with SOA carbonyl compounds converting them into nitrogen-containing organic compounds (NOCs). The effective reactive uptake coefficients for the formation of NOCs from ammonia were measured on the order of 10−5. The observed DMA reactive uptake coefficients ranged from 10−5 to 10−4. Typically, the reactive uptake coefficient decreased with increasing relative humidity. This is consistent with NOC formation by a condensation reaction between NH3 or DMA with SOA, which produces water as a product. Ammonia is more abundant in the atmosphere than amines. However, the larger observed reactive uptake coefficient suggests that amine uptake may also be a potential source of organic nitrogen in particulate matter.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Salt Transport in Crosslinked Hydrogel Membranes Containing Zwitterionic Sulfobetaine Methacrylate and Hydrophobic Phenyl Acrylate

Produced water is a by-product of industrial operations, such as hydraulic fracturing for increased oil recovery, that causes environmental issues since it includes different metal ions (e.g., Li+, K+, Ni2+, Mg2+, etc.) that need to be extracted or collected before disposal. To remove these substances using either selective transport behavior or absorption-swing processes employing membrane-bound ligands, membrane separation procedures are promising unit operations. This study investigates the transport of a series of salts in crosslinked polymer membranes synthesized using a hydrophobic monomer (phenyl acrylate, PA), a zwitterionic hydrophilic monomer (sulfobetaine methacrylate, SBMA), and a crosslinker (methylenebisacrylamide, MBAA). Membranes are characterized according to their thermomechanical properties, where an increased SBMA content leads to decreased water uptake due to structural differences within the films and to more ionic interactions between the ammonium and sulfonate moieties, resulting in a decreased water volume fraction, and Young’s modulus increases with increasing MBAA or PA content. Permeabilities, solubilities, and diffusivities of membranes to LiCl, NaCl, KCl, CaCl2, MgCl2, and NiCl2 are determined by diffusion cell experiments, sorption-desorption experiments, and the solution-diffusion relationship, respectively. Permeability to these metal ions generally decreases with an increasing SBMA content or MBAA content due to the corresponding decreasing water volume fraction, and the permeabilities are in the order of K+ > Na+ > Li+ > Ni2+ > Ca2+ > Mg2+ presumably due to the differences in the hydration diameter.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1971

Ultrasonic metal etching for metallographic analysis

Ultrasonic etching delineates microstructural features not discernible in specimens prepared for metallographic analysis by standard chemical etching procedures. Cavitation bubbles in ultrasonically excited water produce preferential damage /etching/ of metallurgical phases or grain boundaries, depending on hardness of metal specimens.

Young, S. G.↗
NASA NTRS1971

Improved high-temperature metal-sheathed cables

Process prevents moist air degradation of cables insulated with magnesium oxide. Electrical-grade silicone oil is polymerized by heat application to produce water repellant surface coating. Insulation treated with this oil repels moisture.

Fox, H. A., Jr.↗
NASA NTRS1972

Bosch CO2 reduction unit research and development.

Development of Bosch CO2 reduction units for manned spacecraft application has been in progress for a decade. The Bosch process catalytically reacts CO2 with H2 to produce water and carbon. The water may then be electrolyzed to close the biological oxygen and process hydrogen loops. A critical problem has been to confine the reaction so that carbon does not block flow and stop the process. Reaction isolation within a replaceable catalyst cartridge has been successfully demonstrated. Objectives of the current development program are a 25% reduction in operating power, an 80% reduction in expendable weight, and minimized resupply volume.

Holmes, R. F.↗
NASA NTRS1975

Design and the parametric testing of the space station prototype integrated vapor compression distillation water recovery module

Potable water for the Space Station Prototype life support system is generated by the vapor compression technique of vacuum distillation. A description of a complete three-man modular vapor compression water renovation loop that was built and tested is presented; included are all of the pumps, tankage, chemical post-treatment, instrumentation, and controls necessary to make the loop representative of an automatic, self-monitoring, null gravity system. The design rationale is given and the evolved configuration is described. Presented next are the results of an extensive parametric test during which distilled water was generated from urine and urinal flush water with concentration of solids in the evaporating liquid increasing progressively to 60 percent. Water quality, quantity and production rate are shown together with measured energy consumption rate in terms of watt-hours per kilogram of distilled water produced.

Reveley, W. F.↗
NASA NTRS1978

Multi-wire slurry wafering demonstrations

Ten slicing demonstrations on a multi-wire slurry saw, made to evaluate the silicon ingot wafering capabilities, reveal that the present sawing capabilities can provide usable wafer area from an ingot 1.05m/kg (e.g. kerf width 0.135 mm and wafer thickness 0.265 mm). Satisfactory surface qualities and excellent yield of silicon wafers were found. One drawback is that the add-on cost of producing water from this saw, as presently used, is considerably higher than other systems being developed for the low-cost silicon solar array project (LSSA), primarily because the saw uses a large quantity of wire. The add-on cost can be significantly reduced by extending the wire life and/or by rescue of properly plated wire to restore the diameter.

Chen, C. P.↗
NASA NTRS1980

Solar domestic hot water system installed at Texas City, Texas

This is the final technical report of the solar energy system located at LaQuinta Motor Inn, Texas City, Texas. The system was designed to supply 63 percent of the total hot water load for a new 98 unit motor inn. The solar energy system consists of a 2100 square feet Raypack liquid flat plate collector subsystem and a 2500 gallon storage subsystem circulating hot water producing 3.67 x 10 to the 8th power Btu/year. Abstracts from the site files, specification references, drawings, installation, operation, and maintenance instructions are included.

Source record↗
NASA NTRS1981

Chesapeake Bay plume dynamics from LANDSAT

LANDSAT images with enhancement and density slicing show that the Chesapeake Bay plume usually frequents the Virginia coast south of the Bay mouth. Southwestern (compared to northern) winds spread the plume easterly over a large area. Ebb tide images (compared to flood tide images) show a more dispersed plume. Flooding waters produce high turbidity levels over the shallow northern portion of the Bay mouth.

Munday, J. C., Jr.↗
NASA NTRS1981

Alkaline regenerative fuel cell systems for energy storage

A description is presented of the results of a preliminary design study of a regenerative fuel cell energy storage system for application to future low-earth orbit space missions. The high energy density storage system is based on state-of-the-art alkaline electrolyte cell technology and incorporates dedicated fuel cell and electrolysis cell modules. In addition to providing energy storage, the system can provide hydrogen and oxygen for attitude control of the satellite and for life support. During the daylight portion of the orbit the electrolysis module uses power provided by the solar array to generate H2 and O2 from the product water produced by the fuel cell module. The fuel cell module supplies electrical power during the dark period of the orbit.

Schubert, F. H.↗
NASA NTRS1986

Formation and characterization of simulated small droplet icing clouds

Two pneumatic two-fluid atomizers operating at high liquid and gas pressures produced water sprays that simulated small droplet clouds for use in studying icing effects on aircraft performance. To measure median volume diameter, MVD or D sub v.5, of small droplet water sprays, a scattered-light scanning instrument was developed. Drop size data agreed fairly well with calculated values at water and nitrogen pressures of 60 and 20 psig, respectively, and at water and nitrogen pressures of 250 and 100 psig, respectively, but not very well at intermediate values of water and nitrogen pressure. MVD data were correlated with D sub 0, W sub N, and W sub w, i.e., orifice diameter, nitrogen, and water flowrate, respectively, to give the expression for MVD in microns.

Ingebo, R. D.↗