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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2013

Pressure-induced densification in GeO{sub 2} glass: A transmission x-ray microscopy study

Nanoscale transmission x-ray microscopy measurements have been performed to determine the effect of pressure (P) on the volume (V) change in GeO{sub 2} glass up to 38.5 GPa. The P-V data show a continuous increase upon compression, indicating that the density-driven structural transformation is a gradual process. Over the pressure range studied, a transition is observed at approximately 10–13 GPa, where the material displays distinct compression behaviors. The pressure-induced densification that involves the coordination number change has been discussed. Using this newly developed high-pressure imaging technique with tens of nanometer resolution, we have provided a direct and unequivocal way for measuring density of amorphous materials to much higher pressures with accuracy rivaling x-ray diffraction of crystalline solids.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2018

Effects of non-hydrostaticity and grain size on the pressure-induced phase transition of the CoCrFeMnNi high-entropy alloy

Recently, an irreversible polymorphic transition from face-centered cubic to hexagonal close-packing was surprisingly observed under high pressure in the prototype CoCrFeMnNi high-entropy alloys (HEAs) by various research groups. This unexpected phase transition brings new insights into the stability of HEAs, and its irreversibility stimulates exploration for new HEAs via high-pressure compression synthesis. However, the onset pressure for the phase transition was reported to fluctuate over a vast range from ~7 to above 49 GPa in the reported experiments. The reason for this inconsistency remains unclear and puzzles the HEA community. To address this problem, this work systematically investigates the effects of non-hydrostaticity and grain size. Our results demonstrate that larger deviatoric stress induced by the non-hydrostaticity of the pressure medium and larger grain size of the initial sample can both promote a phase transition and, therefore, considerably depress the onset pressure.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Infrared spectroscopy study of the nodal-line semimetal candidate ZrSiTe under pressure: Hints for pressure-induced phase transitions

We studied the effect of external pressure on the optical response of the nodal-line semimetal candidate ZrSiTe by reflectivity measurements. At pressures of a few GPa, the reflectivity, optical conductivity, and loss function are strongly affected in the whole measured frequency range (200–16 500 cm –1 ), indicating drastic changes in the electronic band structure. The pressure-induced shift of the electronic bands affects both the intraband and interband transitions. Here, we find anomalies in the pressure dependence of several optical parameters at the pressures P c1 ≈ 4.1GPa and P c2 ≈ 6.5GPa, suggesting the occurrence of two phase transitions of either structural or electronic type.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2022

Quantum-cascade-laser-absorption-spectroscopy diagnostic for temperature, pressure, and NO X 2 Π 1/2 at 500 kHz in shock-heated air at elevated pressures

The design, validation, and application of a quantum-cascade-laser-absorption-spectroscopy diagnostic for measuring gas temperature, pressure, and nitric oxide (NO) in high-temperature air are presented. A distributed-feedback quantum-cascade laser (QCL) centered near 1976 c m − <#comment/> 1 was used to scan across two transitions of NO in its ground electronic state ( X 2 Π <#comment/> 1 / 2 ). A measurement rate of 500 kHz was achieved using a single QCL by: (1) performing current modulation through a bias-tee, and (2) targeting closely spaced transitions with a large difference in lower-state energy. The diagnostic was validated in a mixture of 95% argon and 5% NO, which was shock-heated to ≈ <#comment/> 2000 to 3700 K. The average mean percent differences between laser-absorption-spectroscopy (LAS) measurements and predictions from shock-jump relations for temperature, pressure, and NO mole fraction were 3.1%, 4.1%, and 6.5%, respectively. The diagnostic was then applied to characterize shock-heated air at high temperatures (up to ≈ <#comment/> 5500 K ) and high pressures (up to 12 atm) behind either incident or reflected shocks. The LAS measurements were compared to theoretical predictions from shock-jump relations, pressure sensors mounted in the wall of the shock tube, and equilibrium values of the NO mole fraction. The average mean percent differences between LAS measurements and their aforementioned reference values were 3.2%, 10.8%, and 10.4% for temperature, pressure, and NO mole fraction, respectively. Last, a comparison between a measured NO mole fraction time history and a time-stepped homogeneous reactor simulation performed using two different chemical kinetics mechanisms is presented.

Gilvey, Jonathan J. (ORCID:0000000317664383)↗
DOE OSTI2017

Uranyl peroxide nanoclusters at high-pressure

Here, U 60 ([UO 2 (O 2 )(OH)] 60 60– in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U 60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U 60 -bearing material: Li 68 K 12 (OH) 20 [UO 2 (O 2 )(OH)] 60 (H 2 O) 310 ( Fm 3¯; a = 37.884 Å) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li 68 K 12 (OH) 20 [UO 2 (O 2 )(OH)] 60 (H 2 O) 310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U 60 -bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U 60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U 60 clusters at high pressure may have been enhanced by the interaction between U 60 nanoclusters and the alcohol pressure medium. Once formed, U 60 nanoclusters persist regardless of their associated long-range ordering—in crystals, amorphous solids, or solutions.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Simulation and Analysis on Reactor Pressure Vessel (RPV) subjected to Pressurized Thermal Shock (PTS) under SBLOCA scenario by using Cardinal to support the fracture mechanics analyses

The structural components that comprise nuclear reactors and their supporting structures are subjected to harsh operating environments that can challenge their integrity, especially after exposure for extended durations or under accident condition. As one of the most significant components of a Reactor, the Reactor Pressure Vessel (RPV) is exposed to an aggressive environment during the operation time (e.g. more than 40 years). Ageing degradation mechanisms (e.g. thermos-fatigue) could grow initial defects up to a critical size, increasing the susceptibility to failure in the RPV. The conventional methods are mostly based on simple crack and structure geometries. Very limited studies consider the real conditions of the RPV subjected to a thermal shock due to a Loss of Coolant Accident (LOCA). During a LOCA event, the most severe conditions take place when the emergency core cooling (ECC) water is injected inside the cold legs filled initially with hotter water and/or steam. The rapid cooling of the down-comer and the internal RPV surface followed probably by re-pressurization of the RPV causes large temperature gradients and variation of pressure which induces thermal-mechanical stresses. In order to develop the model for integrity assessment of a reactor pressure vessel (RPV) subjected to pressurized thermal shock (PTS), a multi-physics simulation, which includes the thermo-hydraulic, thermo-mechanical and fracture mechanics analyses is necessary. The multi-physics simulations are performed using Cardinal, a wrapping of the GPU-oriented spectral element Computational Fluid Dynamics (CFD) code NekRS and other multi-physics sub-modules within the MOOSE framework. Cardinal now fully supports MOOSE stochastic perturbations of NekRS models with varying boundary conditions, initial conditions, material properties, and any other quantity which is defined by a kernel (such as coefficients in a momentum source model). The implementation is designed in a flexible manner so that scalar values are sent from MOOSE into a user scratch space in NekRS, which can then be applied for any purpose within the NekRS case files (both on the host and device). When modeling PTS, several factors can impact the results significantly. In this report, the impacts of the geometry of the model, Reynolds number and buoyancy effect are investigated. Two geometry, i.e., a simplified model and a realistic RPV model, with both laminar and turbulent flow condition are adopted for the PTS simulation with and without buoyancy effect. The purpose of the investigation is to understand the impact of these factors on the prediction of temperature history of RPV. The accurate prediction on the temperature evolution, which will be exported to Grizzly code for further analyses on the progression of aging mechanisms and their effects on the integrity of RPV structures, is very crucial. Based on the understanding of these factors, a more sophisticated model is built to analysis the PTS under SBLOCA scenario. A literature survey is conducted to pick the SBLOCA scenario for the multi-physics simulation. The analysis helps to explain the form and the transformation of the cold plum when the ECC is activated under SBLOCA. This model can be can be applied to study the PTS effect for different RPV configurations. The results can help to assess structural component degradation for advanced reactors.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2022

Multi physics simulation on Reactor Pressure Vessel (RPV) subjected to Pressurized Thermal Shock (PTS) by using Cardinal

The structural components that comprise nuclear reactors and their supporting structures are subjected to harsh operating environments that can challenge their integrity, especially after exposure for extended durations or under accident condition. As one of the most significant components of a Reactor, the Reactor Pressure Vessel (RPV) is exposed to an aggressive environment during the operation time (e.g. more than 40 years). Ageing degradation mechanisms (e.g. thermo-fatigue) could grow initial defects up to a critical size, increasing the susceptibility to failure in the RPV. The conventional methods are mostly based on simple crack and structure geometries. Very limited studies consider the real conditions of the RPV subjected to a thermal shock due to a Loss of Coolant Accident (LOCA). During a LOCA event, the most severe conditions take place when the emergency core cooling (ECC) water is injected inside the cold legs filled initially with hotter water and/or steam. The rapid cooling of the down-comer and the internal RPV surface followed probably by re-pressurization of the RPV causes large temperature gradients and variation of pressure which induces thermal-mechanical stresses. In order to develop the model for integrity assessment of a reactor pressure vessel (RPV) subjected to pressurized thermal shock (PTS), a multi-physics simulation, which includes the thermo-hydraulic, thermo-mechanical and fracture mechanics analyses is necessary.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
NASA NTRS1971

Miniature pressure valve for on-board calibration of pressure transducers.

This paper describes the development and testing of a miniature one-pole, three-position pressure valve and actuation mechanism. This valve was designed primarily for installation with a pressure transducer directly in a wind-tunnel model, thereby reducing lag time effects resulting from long connecting tubes to the transducer. This valve provides for the in-situ calibration of the transducer during testing by providing one position for transducer zero, a second position for a known calibrate pressure, and a third position for measurement of the unknown test pressure. The valve is driven from the spring loaded test pressure position to the zero and calibrate positions by a pneumatically operated dual-piston yoke assembly. Large numbers of transducers can be simultaneously calibrated from a remote location in a matter of seconds.

Rollins, G. N.↗
NASA NTRS1973

High-pressure combustor exhaust emissions with improved air-atomizing and conventional pressure-atomizing fuel nozzles

A high-pressure combustor segment 0.456 meter (18 in.) long with a maximum cross section of 0.153 by 0.305 meter (6 by 12 in.) was tested with specially designed air-atomizing and conventional pressure-atomizing fuel nozzles at inlet-air temperatures of 340 to 755 k (610 deg to 1360 R), reference velocities of 12.4 to 26.1 meters per second (41 to 86 ft/sec), and fuel-air ratios of 0.008 to 0.020. Increasing inlet-air pressure from 4 to 20 atmospheres generally increased smoke number and nitric oxide, but decreased carbon monoxide and unburned hydrocarbon concentrations with air-atomizing and pressure-atomizing nozzles. Emission indexes for carbon monoxide and unburned hydrocarbons were lower at 4, 10, and 20 atmospheres, and nitric oxide emission indexes were lower at 10 and 20 atmospheres with air-atomizing than with pressure-atomizing nozzles.

Ingebo, R. D.↗
NASA NTRS1976

A dynamic pressure source for the calibration of pressure transducers

A dynamic pressure source is described for producing sinusoidally varying pressures of up to 34 kPa zero to peak, over the frequency range of approximately 50 Hz to 2 kHz. The source is intended for the dynamic calibration of pressure transducers. The transducer to be calibrated is mounted near the base of the thick walled aluminum tube forming the vessel so that the pressure sensitive element is in contact with the liquid in the tube. A section of the tube is filled with small steel balls to damp the motion of the 10-St dimethyl siloxane working fluid in order to extend the useful frquency range to higher frequencies than would be provided by an undamped system. The dynamic response of six transducers provided by the sponsor was evaluated using the pressure sources; the results of these calibrations are given.

Vezzetti, C. F.↗
NASA NTRS1987

Some features of surface pressure fluctuations in turbulent boundary layers with zero and favorable pressure gradients

Measurements of surface pressure fluctuation spectra, coherence and convective wave speeds from zero and favorable pressure gradient turbulent boundary layers are reported for momentum Reynolds numbers from 3000 to 18,800. The acceleration parameter K is near 2 x 10 to the -7 power for the favorable pressure gradient flow. The outer variables, U sub e, tau sub w and delta sub 1 non-dimensionalize and collapse the spectra for the low to middle range of frequencies for most test cases. The grouping using the inner variable, U sub tau and gamma, collapse the spectra for the middle to high range of frequencies for all test cases. The value of p'/tau sub w was near 3.8 and 2.8 for the smallest values of d+ in the zero and favorable pressure gradient flows, respectively. The coherence exhibits a decay that is not exponential in some cases, but the Corcos similarity parameters omega Delta x/U sub c and omega Delta z/U sub c collapse the data for all test cases. The ratio of U sub c/U sub e increases with omega delta sub 1/U sub e up to omega delta sub 1/U sub e on the order of unity, where U sub c/U sub e becomes nearly constant. This was observed in the present results for both streamwise pressure gradient flows. The experimental results presented show good agreement with previous research.

Mcgrath, B. E.↗
NASA NTRS1987

Mechanical characteristics of filament-wound pressure vessel (burst pressure)

The finite element method is used to analyze the mechanical characteristics of a pressurized filament-wound (FW) pressure vessel, and to predict its burst pressure. The analysis takes into account the bending moment, the stretch-bend coupling effect, nonlinear stress-strain relations, and finite deflection. The analysis is based on two initial failure criteria for laminae, and two ultimate fracture criteria for laminated structures. The numerical results, obtained by applying the load incremental method to the isotensoid CFRP pressure vessel used in the launching of the Zikiken satellite, are in good agreement with the experimental burst pressure and fracture behaviors.

Iida, H.↗
NASA NTRS1990

Aerodynamic pressure and heating-rate distributions in tile gaps around chine regions with pressure gradients at a Mach number of 6.6

Surface and gap pressures and heating-rate distributions were obtained for simulated Thermal Protection System (TPS) tile arrays on the curved surface test apparatus of the Langley 8-Foot High Temperature Tunnel at Mach 6.6. The results indicated that the chine gap pressures varied inversely with gap width because larger gap widths allowed greater venting from the gap to the lower model side pressures. Lower gap pressures caused greater flow ingress from the surface and increased gap heating. Generally, gap heating was greater in the longitudinal gaps than in the circumferential gaps. Gap heating decreased with increasing gap depth. Circumferential gap heating at the mid-depth was generally less than about 10 percent of the external surface value. Gap heating was most severe at local T-gap junctions and tile-to-tile forward-facing steps that caused the greatest heating from flow impingement. The use of flow stoppers at discrete locations reduced heating from flow impingement. The use of flow stoppers at discrete locations reduced heating in most gaps but increased heating in others. Limited use of flow stoppers or gap filler in longitudinal gaps could reduce gap heating in open circumferential gaps in regions of high surface pressure gradients.

Hunt, L. Roane↗
NASA NTRS1990

Determination of the Pressure Drag of Airfoils by Integration of Surface Pressures

A study was conducted of the causes of pressure drag of subsonic airfoils. In a previous paper by the author, the pressure drag is obtained by calculating the total drag from the momentum defect in the boundary layer at the trailing edge and subtracting the friction drag obtained from integration of surface friction along the chord. Herein, the pressure drag is obtained by integrating the streamwise components of surface pressure around the airfoil. Studies were made to verify the accuracy of the integration procedure. The values of pressure drag were much smaller than those obtained by the previous method. This lack of agreement is attributed to the difficulty of calculating boundary layer conditions in the vicinity of the trailing edge and to the extreme sensitivity of the circulation and lift to the trailing edge conditions. The results of these studies are compared with those of previous investigations.

Phillips, William H.↗