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At least 343 records · Page 19

Radiative Structures of Lycopodium-Air Flames in Low Gravity

Initially uniform clouds of fuel particulates in air sustain processes which may lead to particle cloud nonuniformities. In low gravity, flame-induced Kundt's Tube phenomena are observed to form regular patterns of nonuniform particle concentrations. Irregular patterns of particle concentrations also are observed to result from selected nonuniform mixing processes. Low gravity flame propagation for each of these classes of particle cloud flames has been found to depend importantly on the flame-generated infrared radiative fields. The spatial structures of these radiative fields are described. Application is made for the observed clases of lycopodium-air flames.

Berlad, A. L.↗

Non-thermal processes in large solar flares

The paper examines the significance of particle acceleration processes in large solar flares, and the importance of accelerated particles in the generation of other flare phenomena. Comprehensive observations of the August 1972 series of large flares were used to obtain quantitative estimates of the energetic particle populations, the electromagnetic emissions, and the mass ejections. The fluxes of energetic electrons and protons were derived from observed X-ray and gamma-ray emissions, respectively. The energy input into the solar atmosphere from the collisional losses of these energetic particles is computed as a function of overlying column density, under the assumption that particles are accelerated at a point high in the solar atmosphere and then precipitate down to denser layers. The flash phase radiation, soft X-ray flare plasma, and the interplanetary shock wave can be consistently and quantitatively explained as a result of the interaction of nonrelativistic electrons with the solar atmosphere.

Lin, R. P.↗

Arrested-motility states in populations of shape-anisotropic active Janus particles

The emergence of large-scale collective phenomena from simple interactions between individual units is a hallmark of active matter systems. Active colloids with alignment-dominated interparticle interactions tend to develop orientational order and form motile coherent states, such as flocks and swarms. Alternatively, a combination of self-propulsion and excluded-volume interactions results in self-trapping and active phase separation into dense clusters. Here, we reveal unconventional arrested-motility states in ensembles of active discoidal particles powered by induced-charge electrophoresis. Combining experiments and computational modeling, we demonstrate that the shape asymmetry of the particles promotes the hydrodynamically assisted formation of active particles’ bound states in a certain range of excitation parameters, ultimately leading to a spontaneous collective state with arrested motility. Unlike the jammed clusters obtained through self-trapping, the arrested-motility phase remains sparse, dynamic, and reconfigurable. The demonstrated mechanism of phase separation seeded by bound state formation in ensembles of oblate active particles is generic and should be applicable to other active colloidal systems.

42 ENGINEERING↗

First Observations of a Foreshock Bubble at Earth: Implications for Magnetospheric Activity and Energetic Particle Acceleration

Earth?s foreshock, which is the quasi-parallel region upstream of the bow shock, is a unique plasma region capable of generating several kinds of large-scale phenomena, each of which can impact the magnetosphere resulting in global effects. Interestingly, such phenomena have also been observed at planetary foreshocks throughout our solar system. Recently, a new type of foreshock phenomena has been predicted: foreshock bubbles, which are large-scale disruptions of both the foreshock and incident solar wind plasmas that can result in global magnetospheric disturbances. Here we present unprecedented, multi-point observations of foreshock bubbles at Earth using a combination of spacecraft and ground observations primarily from the Time History of Events and Macroscale Interactions during Substorms (THEMIS) mission, and we include detailed analysis of the events? global effects on the magnetosphere and the energetic ions and electrons accelerated by them, potentially by a combination of first and second order Fermi and shock drift acceleration processes. This new phenomena should play a role in energetic particle acceleration at collisionless, quasi-parallel shocks throughout the Universe.

Turner, D. L.↗

A simplified integrated framework for predicting the economic impacts of feedstock variations in a catalytic fast pyrolysis conversion process

Feedstock attributes of lignocellulosic biomass, such as particle size, compositional makeup, and moisture content, can vary substantially even within pre-processed materials and have a significant effect on conversion in fast pyrolysis-based processes. However, the economic impacts of these attributes are not well understood. To address this, biomass deconstruction phenomena captured with a versatile particle-scale simulation were linked to techno-economic impacts via reduced-order models. Parametric analysis of the particle-scale model, which was validated using literature data, was used in combination with multiple linear regression models to develop correlations between feedstock attributes and yields of pyrolysis oil, gas, and char. Yields were then correlated with the minimum fuel selling price (MFSP) using a techno-economic model, bridging the gap between physics-based biomass conversion simulations and predictions of MFSP for a catalytic fast-pyrolysis process. Empirical correlations derived from the literature regarding the impact of mineral matter (ash) on oil yield were also considered. The model correlations deployed in the integrated framework capture the impacts of variation in feedstock attributes on the MFSP. Variations in ash were shown to have the biggest impact, varying MFSP by -13%/+22% due to catalytic effects and lower relative amounts of convertible lignocellulosic material. It was also found that, if ash can be controlled to low levels, the increased extractives in forest residues can help compensate for some yield losses associated with increased ash. As a result, other inputs considered (particle size, moisture content, and reactor temperature) had relatively negligible effects on process economics within the ranges analyzed considering particle-scale effects alone.

BIOMASS FUELS↗

Physics of auroral arc formation; Proceedings of the Chapman Conference on Formation of Auroral Arcs, Fairbanks, AK, July 21-25, 1980

The results of satellite, balloon-borne, and ground-based observations of auroral phenomena are discussed in terms of the morphology of auroral arcs and the behavior and characteristics of auroral electrons and ions. Further attention is given to auroral electric fields and field aligned currents, and to the development of models of auroral potential structures and energization of auroral particles. A simulation of space plasma phenomena is presented, along with numerical simulations of auroral potential structures and related phenomena, including the V-potential double layers and auroral arc deformations, and a simulation of auroral arcs. Plasma waves observed on auroral field lines and in laboratory conditions are reported, and theoretical studies of waves and turbulence in auroral plasmas are described.

Akasofu, S.-I.↗

Packing and flow particle simulations

Granular material is present across natural and industrial processes on Earth and other planets. Granular particles show up in space exploration (lunar regolith), avalanches (boulders), food (coffee), construction (concrete powder) and manufacturing (additive manufacturing powder, battery slurries). Important phenomena emerge from large collections of granular particles. The size scales of the particles in granular material, 10 μm diameter or larger, makes particle-based simulations a tractable computational method. This seminar will present the packing and flow of granular matter using particle-based discrete element modeling simulations. Particles modeled with rotational friction only require as few as 2.6 contacts for mechanical stability, as opposed to 6 contacts for frictionless particles. Optimal parameters for in-space manufacturing particulate material are identified. Specifically, the maximum density and contacts occurs for a large-to-small particle volume ratio of 0.265. Stress and contact fabric fluctuations of flowing dry granular matter have power-law scaling with strain rate, and a kink. The pressure-dependent slope change kink could identify the transition between slower, quasistatic and faster, inertial flows.

granular↗

Packing and flow particle simulations

Granular material is present across natural and industrial processes on Earth and other planets. Granular particles show up in space exploration (lunar regolith), avalanches (boulders), food (coffee), construction (concrete powder) and manufacturing (additive manufacturing powder, battery slurries). Important phenomena emerge from large collections of granular particles. The size scales of the particles in granular material, 10 μm diameter or larger, makes particle-based simulations a tractable computational method. This seminar will present the packing and flow of granular matter using particle-based discrete element modeling simulations. Particles modeled with rotational friction only require as few as 2.6 contacts for mechanical stability, as opposed to 6 contacts for frictionless particles. Optimal parameters for in-space manufacturing particulate material are identified. Specifically, the maximum density and contacts occurs for a large-to-small particle volume ratio of 0.265. Stress and contact fabric fluctuations of flowing dry granular matter have power-law scaling with strain rate, and a kink. The pressure-dependent slope change kink could identify the transition between slower, quasistatic and faster, inertial flows.

granular↗

Complex motion of steerable vesicular robots filled with active colloidal rods

Abstract While the collective motion of active particles has been studied extensively, effective strategies to navigate particle swarms without external guidance remain elusive. We introduce a method to control the trajectories of two-dimensional swarms of active rod-like particles by confining the particles to rigid bounding membranes (vesicles) with non-uniform curvature. We show that the propelling agents spontaneously form clusters at the membrane wall and collectively propel the vesicle, turning it into an active superstructure. To further guide the motion of the superstructure, we add discontinuous features to the rigid membrane boundary in the form of a kinked tip, which acts as a steering component to direct the motion of the vesicle. We report that the system’s geometrical and material properties, such as the aspect ratio and Péclet number of the active rods as well as the kink angle and flexibility of the membrane, determine the stacking of active particles close to the kinked confinement and induce a diverse set of dynamical behaviors of the superstructure, including linear and circular motion both in the direction of, and opposite to, the kink. From a systematic study of these various behaviors, we design vesicles with switchable and reversible locomotions by tuning the confinement parameters. The observed phenomena suggest a promising mechanism for particle transportation and could be used as a basic element to navigate active matter through complex and tortuous environments.

42 ENGINEERING↗

Experimental Determination of Infrared Extinction Coefficients of Interplanetary Dust Particles

This technique is based on irradiating a single isolated charged dust particle suspended in balance by an electric field, and measuring the scattered radiation as a function of angle. The observed scattered intensity profile at a specific wavelength obtained for a dust particle of known composition is compared with Mie theory calculations, and the variable parameters relating to the particle size and complex refractive index are adjusted for a best fit between the two profiles. This leads to a simultaneous determination of the particle radius, the complex refractive index, and the scattering and extinction coefficients. The results of these experiments can be utilized to examine the IRAS and DIRBE (Diffuse Infrared Background Experiment) infrared data sets in order to determine the dust particle physical characteristics and distributions by using infrared models and inversion techniques. This technique may also be employed for investigation of the rotational bursting phenomena whereby large size cosmic and interplanetary particles are believed to fragment into smaller dust particles.

Spann, J. F., Jr.↗

Dynamical Change of Valence States and Structure in NiCu 3 Nanoparticles during Redox Cycling

Alloyed materials are promising candidates to improve catalytic processes. Ni–Cu nanoparticles are used for various reactions, including processes with biomass-derived components. However, dynamical restructuring effects alter the catalytic properties and can deactivate the sample. To understand these structural modifications, a multimodal investigation of NiCu 3 /C was performed to determine compositional and morphological changes during a redox cycle to simulate reduction and oxidation of the catalyst during reaction. We exploit a novel correlative, multimodal approach that combines in situ X-ray absorption spectroscopy (XAS) and in situ scanning transmission electron microscopy and electron energy-loss spectroscopy (STEM-EELS) to describe changes that occur in the sample in realistic conditions. In the fresh sample, there are two morphologies present: core–shell and hollow. Segregation of Cu was observed in both types of particles after synthesis, with Cu being more oxidized in the hollow structures. Upon reduction for 2 h under H 2 at 400 °C, the Cu was reduced, although segregation of Cu and Ni was still observed. Subsequent exposure to O 2 at 400 °C led to a strong reoxidation of Cu with the formation of hollow particles with compositional heterogeneities. The oxidation of metals and segregation phenomena can be related to known catalytic properties of NiCu 3 /C particles, especially regarding the hydrodeoxygenation of 5-hydroxymethylfurfural to 2,5-dimethylfuran.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Discrete electromagnetic emissions in planetary magnetospheres

The present state of knowledge and observations of discrete electromagnetic emissions detected in the magnetospheres of earth and the outer planets are reviewed. The history of ground observations and satellite observations is included. Active experiments studying wave propagation, wave-wave and wave-particle interactions, and the generation and triggering of discrete emissions are addressed. The various theories proposed to explain the phenomena are examined, and computer simulations of wave-particle interactions and the generation and triggering of discrete emissions are reviewed. Related phenomena observed at frequencies above both the electron cyclotron frequency and the plasma frequency are considered. Areas of future investigation are discussed.

Anderson, Roger R.↗

Trajectories of solid particles spalled from a carbonaceous heat shield

Trajectories are calculated of solid carbon particles that spall from a carbonaceous heat shield and travel through a given flow field. The mathematical model takes into account mass, momentum, and energy conservation during evaporation of the particles in an effort to understand spallation phenomena and their consequences in a physical way. The solution technique is applied to available Galileo Probe flow field solutions. Plots of trajectories and other particle parameters are presented for a range of initial particle sizes and velocities. It is shown that a significant amount of gaseous carbon is deposited in the inviscid region and ahead of the bow shock as well as in the ablation layer.

Davies, C. B.↗

Microgravity particle research on the Space Station - The gas-grain simulation facility

In the gravitational field on earth, the large settling rate of micron-sized particles and the effects of gravity-induced convection prohibit many interesting studies of phenomena such as coagulation, collisions, and mutual interactions of droplets, dust grains and other particles. Examples of exobiology experiments involving these phenomena are the simulation of organic aerosol formation in Titan's atmosphere, studies of the role of comets in prebiotic chemical evolution, and simulations of carbon grain interactions in various astrophysical environments. The Gas-Grain Simulation Facility (GGSF) is a proposed earth-orbital laboratory that will allow present ground-based experimental programs which study processes involving small particles and weak interactions to be extended to a new domain. Physics issues that scientists wishing to propose GGSF experiments must consider are reviewed in this paper. Specifically, coagulation, motion in gases and vacua, and wall deposition of particles in a microgravity environment are discussed.

Fogleman, G.↗

Solar flare emissions and geophysical disturbances

Various geophysical phenomena are produced by both wave and particle emissions from solar flares. Using the observed data for these emissions, a review is given on the nature of solar flares and their development. Geophysical phenomena are discussed by referring to the results for solar flare phenomena.

Sakurai, K.↗

Studies of the ionization states of solar and galactic cosmic ray heavy nuclei

Enhancement of abundances of heavy nuclei (e.g., Mg, Si, and Fe) at low energies relative to solar photospheric abundances and anomalously high abundances of iron relative to oxygen nuclei at low energies were recently discovered in solar energetic particles studied at low energy. These phenomena are not understood at present. The proposed experiment is designed to study the recently discovered anomalous component of low energy galactic cosmic ray ions of C, N, O, Ne, and Ca to Fe of energy 5- to 10-million electron volts per atomic mass unit in regard to their ionization states, composition, and intensity, and to study the ionization states of heavy elements from oxygen to iron in energetic solar particles emitted during flare events. The same detector system will serve for both studies, with the second objective being given priority if there are any solar particle events during the mission.

Biswas, S.↗

Dynamical Evolution of Simulated Particles Ejected from Asteroid Bennu

In early 2019, the OSIRIS-REx spacecraft discovered small particles being ejected from the surface of the near-Earth asteroid Bennu. Although they were seen to be ejected at slow speeds, on the order of tens of cm/s, a number of particles were surprisingly seen to orbit for multiple revolutions and days, which requires a dynamical mechanism to quickly and substantially modify the orbit to prevent re-impact upon their first periapse passage. This paper demonstrates that, based on simulations constrained by the conditions of the observed events, the combined effects of gravity, solar radiation pressure, and thermal radiation pressure from Bennu can produce many sustained orbits for ejected particles. Furthermore, the simulated populations exhibit two interesting phenomena that could play an important role in the geophysical evolution of bodies such as Bennu. First, small particles (< 1 cm radius) are preferentially removed from the system, which could lead to a deficit of such particles on the surface. Second, re-impacting particles preferentially land near or on the equatorial bulge of Bennu. Over time, this can lead to crater in-filling and growth of the equatorial radius without requiring landslides.

Jay W. McMahon↗

Connecting Hindered Transport in Porous Media across Length Scales: From Single-Pore to Macroscopic

Hindered mass transport is widely observed in various porous media, including filtration membranes and porous rocks. However, there is no universal model capable of predicting transport in porous media due to the heterogeneity of porous structures and the complexity of the underlying microscopic mechanisms, including electrostatic and hydrodynamic effects. Here, we used a highly ordered porous medium (i.e. a silica inverse opal film) as a model system to directly explore the effects of geometric parameters (i.e. pore size, pore throat size and tracer particle size) and microscopic interaction parameters (e.g. controlled by ionic strength) on nanoparticle transport in porous environments using three-dimensional single-particle tracking. We found a linear scaling relation between the macroscopic diffusion coefficient and microscopic diffusion behaviors and a combination of parameters associated with microscopic features and phenomena, including both geometric effects and particle-level interactions. The proportionality coefficient relating micro and macro behaviors was complex and related to the connectivity of the matrix and pore-size variation, which could lead to tortuous diffusion pathways, hindering macroscopic transport. Furthermore, these findings provide important insights into nanoparticles and macromolecules transport in various porous media.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗