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At least 343 records · Page 19

Aluminous mare basalts - New data from Apollo 14 coarse fines

Four aluminous mare basalt fragments selected from the Apollo 14 coarse fines collection are described: 14004,34 has an intergranular texture; 14160,103 and 14168,38 are granular; and 14256,10 is a fine-grained metabasalt. Pyroxene compositional trends vary among the fragments: in 14004,34 the trend is from ferroaugite to pyroxferrite; 14160,103 exhibits well-defined iron enrichment trends involving both pigeonite and augite; 14168,38 contains mostly pigeonite with minor augite; and pyroxene compositions in 14256,10 cluster in two distinct populations, high- and low-Ca. The igneous textures (except for 14256,10), the absence of discernible clasts, and low Ni compositions of metal grains lead to the conclusion that the fragments are pieces of pristine aluminous mare basalts. The marked differences in the REE patterns rule out a close genetic relation between any of the four basalts.

Warner, R. D.↗

Howardites - Samples of the regolith of the eucrite parent-body: Petrology of Frankfort, Pavlovka, Yurtuk, Malvern, and ALHA 77302

Modal petrographic methods have been applied to the meteorites Frankfort, Pavlovka, Yurtuk, Malvern, and ALHA 77302, to determine some of the characteristics of the regolith of the eucrite parent body. Lithic clasts in the meteorites fall into three major groups: pyroxene + plagioclase rocks, orthopyroxenites, and fused-soil clasts. Lithic clasts make up a small proportion of the soil; mineral clasts from orthopyroxenites dominate the coarse-grained fraction; and the fine-grained fraction contains minerals from both orthopyroxenites and plagioclase + pyroxene rocks. The eucrite regolith appears to have the following characteristics: the source rocks are friable, the soils are immature, comminution is the major soil-forming process, and the soil is well mixed.

Labotka, T. C.↗

Metamorphism in mesosiderites

Previous studies of mesosiderites have identified a metamorphic overprint in these meteorites. However, the effects and implications of this overprint have not yet been explored in detail. The present study documents several important textural and chemical features of the mesosiderites. The components of mesosiderites are examined, taking into account orthopyroxenites, olivine in clasts, mesosiderite mafic clasts, and metal. The characteristics of the silicate matrix of the mesosiderites is explored, and textural and chemical evidence of metamorphism is discussed, giving attention to coronas on olivine clasts, overgrowths on Mg-pyroxene clasts, rims on iron rich pyroxene grains, poikiloblasts of plagioclase, and resorption of clasts. Aspects of redox formation of merrillite are considered along with the causes and the implications of metamorphism. It is found that metamorphism has radically changed the texture of the silicate fraction of the mesosiderites.

Delaney, J. S.↗

Petrology of igneous lithic clasts from polymict eucrites ALHA76005 and ALHA77302

A total of seven lithic clasts from the polymict eucrites ALHA76005 and ALHA77302 have been studied petrographically and analyzed with the electron microprobe. All clasts are composed predominantly of pyroxene and plagioclase, + or - ilmenite, troilite, Fe-Ni metal, mesostasis, and silica. Pyroxene compositions in unequilibrated clasts and clast bulk compositions, calculated by modal recombination, indicate that the clasts originally crystallized under similar conditions and that they may be genetically related to each other by fractionation of pigeonite and plagioclase.

Simon, S. B.↗

Surface compositions in the Aristarchus Region: Implications for regional stratigraphy

Near infrared reflectance spectra for the Aristachus region, obtained using the 2.2m UH telescope at the Mauna Kea Observatory, were reduced and analyzed. The spectra obtained for the central peak, southern floor, southwestern wall, eastern wall, and northwestern wall of Aristachus crater exhibit shallow continuum slopes, relatively strong feldspar bands, pyroxene bands stronger than those typically seen in the spectra of fresh higland features, and pyroxene band centers near l micrometer suggesting the dominance of Ca rich clinopyroxene. The spectrum of the south rim of Aristachus is quite distinct from those of other crater units. The position of Aristrchus on the plateau/mare boundary raises questions concerning compositional variations in crater ejects deposits.

Hawke, H. R.↗

Stillwater anorthosites - A lunar analog?

Samples of anorthosite from Stillwater complex units AN-I and AN-II have been studied by instrumental neutron activation analysis for FeO, CaO, Na2O, REE, and other trace elements, and the results are discussed. No systematic variations of chemical composition with stratigraphic position were observed. The major and trace compositions of both units appear to be identical, with plagioclase compositions virtually constant throughout both. Thus, there is almost no evidence for evolution of parent magma composition during the genesis of these units. The bulk of the anorthosites appear to consist of cumulus-adcumulus plagioclase and pyroxene. Very little trapped liquid component was found. The chemical elements are not normally or lognormally distributed among samples taken from either anorthosite unit. The irregular distribution of pyroxene oikocrysts indicates that interstitial melt migrated substantially prior to final consolidation of the rock.

Salpas, P. A.↗

Chondrules and other components in C, O, and E chondrites Similarities in their properties and origins

Three types of chondrules are described that are common to H3, LL3, CM2, CO3, and CV3 chondrites. Low- and high-FeO, porphyritic olivine chondrules contain olivine with Fa0.3-8 and Fa5-50 respectively, and can easily be distinguished petrographically. Poikilitic pyroxene chondrules have 1-20 vol pct olivine (Fa0.2-8) enclosed by low-Ca pyroxene (Fs0.5-7), and also occur in E chondrites. These three types formed in separate nebular regions which had dimensions and spacings such that a few percent of the chondrules that collided to form compound chondrules were of different types. Sorting of chondrule precursor material and mixing of chondrule types probably account for most variations in bulk and mineral chemistry among chondrite groups. Metallic Fe,Ni grains containing 0.1-1 percent Cr, Si, and P are present in low-FeO olivine chondrules from all type 2 and least metamorphosed type 3 chondrites. Metal compositions reflect reduction during chondrule formation in the nebula, not nebular condensation. Opaque matrices in type 3 ordinary and carbonaceous chondrites are somewhat similar in composition and mineralogy, and probably have related origins. It is concluded that chondrules in all known chondrite groups share similar nebular origins.

Scott, E. R. D.↗

Relict and other anomalous grains in chondrules - Implications for chondrule formation

Relict olivine and pyroxene grains have been identified in chondrules from ordinary and carbonaceous chondrites that probably did not crystallize in situ. Some of these olivines are clear, but others contain fine-grained Fe, Ni ('dusty olivines') and resemble previously described occurrences in ordinary chondrites. There are also chondrules in which all olivine is dusty. It is concluded that: (1) not all relict olivines are dusty, (2) not all dusty olivines crystallized outside the chondrule in which they occur, and (3) some dusty olivines were produced during chondrule formation by a reduction process that affected the whole chondrule. The occurrence of dusty olivines and relict pyroxenes and olivines in chondrules from carbonaceous as well as ordinary chondrites supports the argument that chondrules from all chondrites had similar origins and histories. It is proposed that chondrules and mineral fragments were transported across f(O2) gradients in the solar nebula while they were hot, or were reheated in an environment different from the one in which they formed. Partially molten chondrules sometimes incorporated mineral grains or chondrules with different redox states, producing compound chondrules and chondrules containing anomalous grains. Dusty olivines may also have formed when hot chondrules were transported to regions of lower oxygen fugacity.

Kracher, A.↗

Equilibration temperatures of the ordinary chondrites - A new evaluation

The novel calibrations of the Ca-pyroxene thermometer accomplished by Kretz (1982) and Lindsley (1983) are presently applied to 24 analyzed pyroxenes from 24 H6, L6, and LL6 chondrites. Both thermometers indicate that the H group equilibrated to significantly lower temperature (820-830 C) than the L and LL groups, yielding values of 860 C (Lindsley) to 930 C (Kretz).

Olsen, E. J.↗

Major element chemical compositions of chondrules in unequilibrated chondrites

The chemical compositions (except for metals and sulfides in chondrules) of more than 500 chondrules from unequilibrated E, H, L, LL, and C chondrites were measured using a broad beam of an electron-probe microanalyzer. The compositions of chondrules can be represented by various mixtures of normative compositions of olivine, low-Ca pyroxene, plagioclase, and high-Ca pyroxene with minor amounts of spinel, feldspathoid, SiO2-minerals, etc., indicating that the chondrule precursor materials consisted of aggregates of these minerals. The Al, Na, and K contents of most chondrules reflect the compositions of the ternary feldspar (An-Ab-Kf) of the chondrule precursor materials, and chemical types of chondrules (KF, SP, IP, and CP) are defined on the basis of the atomic proportion of Al, Na, and K.

Ikeda, Y.↗

The Colony meteorite and the possible existence of a new chemical subgroup of CO3 chondrites

The Colony meteorite, found in Oklahoma around 1975, has an unrecrystallized texture and contains heterogeneous olivine and low Ca pyroxene, kamacite with low Ni and Co and high Cr, amoeboid inclusions with low FeO and MnO, and numerous small chondrules with clear pink glass. These characteristics are shared by members of the least metamorphosed subgroup of CO3 chondrites. Colony contains a fine grained matrix that has higher FeO and K2O and lower MgO and Na2O than normal CO3 matrices. Allan Hills A77307 is another unmetamorphosed meteorite that has many petrologic similarities to normal CO chondrites, including matrix abundance, mineral compositions and chondrule size. However, it differs from them in its abundance of magnetite and presence of iron carbides. The olivine and low Ca pyroxene compositional distributions of Colony and A77307 are very similar. The shapes of the thermoluminescence glow curves of Colony and A77307 are very similar, but differ significantly from those of normal CO chondrites. It is suggested that Colony and A77307 represent a distinct chemical subgroup of CO3 chondrites, characterized by low Ni, Co, S, Ca, Mg, Mn and, possibly, high Cd.

Rubin, A. E.↗

Solar cosmic ray produced neon in lunar soils and their implication for gas-rich meteorite studies

Characteristic neon isotopic ratios, produced due to solar cosmic ray spallation (SCR) in lunar soils, are useful in deciphering and estimating the relative contributions of SCR and GCR spallation. To delineate these features, etched mineral grains from mature and immature lunar soils (14148 and 61221 respectively) were analyzed using mass spectrometry. The SF-Ne composition deduced in this work agrees with that obtained from earlier etched lunar pyroxene studies. The data points for mature soil 14148 define a line which significantly deviates from the 61221 tie line. This deviation is attributed to the presence of SCR spallation component. In this context, neon isotopic compositions (step-wise heating) in Pantar and Leighton dark portions were studied and compared with that of Fayetteville. The meteorite data points deviate significantly from the tie line joining SF-Ne and GCR (pyroxene) end points. This deviation is attributed to SCR-spallation in gas-rich chondrites.

Nautiyal, C. M.↗

A solid-state framework for terrestrial upper mantles

A framework is proposed for understanding the upper mantle structure of the terrestrial planets which is based on solid state dislocation processes. It is proposed that the base of the lithosphere on any planet with a Mg-Fe silicate rich upper mantle is defined by the threshold temperatures of low energy dislocation glide systems in olivine and the pyroxenes. This threshold temperature is approximately 1100 to 1200 K and is directly tied to the mobility of olivine and pyroxene dislocations. Using this definition, all terrestrial planets of the Inner Solar System are expected to have mantle lithospheres. Second, the anomalous properties of the asthenosphere in the Earth are related to the rheological properties of an olivine rich differentiate approximately 220 km thick. All of these properties can be the result of the abundant low energy glide systems in olivine which are mobile at temperatures above approximately 1200 K. It is proposed that a true planetary asthenosphere must be both olivine rich and at temperatures above approximately 1200 K. This mode for the asthenosphere does not require partial melting and is therefore less sensitive to the constraints of volatile content in the upper mantle. The thickness of planetary lithospheres is estimated as is maximum thickness of the olivine rich differentiate on each planet. The cooling of the olivine rich layer on Mars (and hence disappearance of the asthenosphere) may coincide with the cessation of global tectonic activity approximately 1 Gyr ago.

Estey, L.↗

Mineralogical comparison and cooling history of lunar and chondritic vesicular melt breccias

Lunar sample 77135, an impact melt breccia full of vesicles, has been reinvestigated by electron microprobe and X-ray diffraction techniques and compared with a vesicular melt LL chondrite, Yamato 790964, in an attempt to understand their impact heating processes and subsequent cooling history. Notable similarities between the lunar and chondritic melt breccias include: abundant vesicles, similar pyroxene chemical zoning trends, the presence of variable amounts of clastic material, and similar chemical compositions except for K and Na contents of glass and mesostasis. Some constraints on the cooling history are estimated from Mg-Fe diffusion profiles in olivine and pyroxene. The burial depth of lunar sample 77135 during cooling was 0.2-100 m; the depth for the chondrite was probably smaller. Impact melts were probably produced and a layer of regolith retained on the parent body sufficiently thick to allow the olivines to homogenize during slow cooling.

Miyamoto, M.↗

Origin of howardites, diogenites and eucrites - A mass balance constraint

Two petrogenetic models for the noncumulate-basaltic parts of howardite meteorites are discussed. A mass balance constraint is developed which indicates that more than half of the basaltic components in howardites formed as residual liquids from fractional crystallization of melts that had earlier produced diogentelike pyroxene cumulate components. Other model constriants involving scandium trends, clustering near olivine-pyroxene-plagioclase peritectic, and MgO/(MgO + FeO) ratios are discussed.

Warren, P. H.↗

Near-infrared spectroscopy of probable impact melt from three large lunar highland craters

Near IR terrestrial telescope data are used to compare the composition of small areas in three large lunar highland craters, whose walls and central peaks yield spectra indicative of crystalline components encompassing olivine, two types of pyroxene, and occasionally Fe-bearing feldspar. Spectra from other crater wall and floor areas suspected of being impact melt deposits yield similar yet anomalous features which are interpreted as indications of pyroxene, Fe-bearing glass, and Fe-bearing feldspar.

Smrekar, S.↗

Chondrules in the Murray CM2 meteorite and compositional differences between CM-CO and ordinary chondrite chondrules

Thirteen of the least aqueously altered chondrules in Murray (CM2) were analyzed for bulk compositions, by means of a broad beam electron microprobe, to explore the compositional differences between the CM-CO, and the ordinary chondrite OC chondrules. The CO chondrules are richer in refractory lithophiles and poorer in Cr, Mn, and volatile lithophiles than the OC chondrules; much lower refractory lithophile abundances in CM chondrules resulted from aqueous alteration. Evidence is found for two important lithophile precursor components of CM-CO chondrite chondrules: (1) pyroxene- and refractory-rich, FeO-poor, and (2) olivine-rich, refractoryand FeO-poor. It is suggested that the pyroxene- and refractory-rich, FeO-poor lithophile precursor component has formed by an incomplete evaporation of presolar silicates that brought these materials into the enstatite stability field.

Rubin, A. E.↗

Clinopyroxene REE distribution coefficients for shergottites The REE content of the Shergotty melt

Rare-earth element (REE) distribution coefficients were measured between synthetic pyroxenes and melts similar in composition to the Shergotty intercumulus fluid. REE-doped synthetic glass samples were analyzed by means of an automated microbeam electron microprobe. The coefficients were found to exhibit a strong positive correlation with pyroxene wollastonite content. Using distribution coefficients measured for the natural phase compositions, REE abundances for the Shergotty intercumulus melt were computed.

Mckay, G.↗