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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2018

Passivation of Stainless Steel for Tritium Service

The goal of this project was to develop a method to passivate stainless steel components using electropolishing techniques and heat treatment methods. The process is intended to limit the in growth and isotope exchange of hydrogen with tritium and deuterium as well as other undesired contaminants of standard gas mixtures. This process has been named Q-Passivation, to set is apart from standard industrial passivation methods and a patent application has been submitted and publish on the process. The basis used for the development of this process was taken from the surface analytical data collected from decommissioned commercial tritium containment vessels that are used to hold standard gas mixtures. The information gained from the surface analysis along with the methods to eliminate residual hydrogen contamination will provide a reasonable method for passivation. Barriers in fabricating test vessels for tritium have delayed production for tritium exposure trials. Some of these barriers include base metal composition that may meet compositional specifications but does not meet a quality inspection as it contains inclusions, additional phases, and other metallurgical anomalies. A number of issues and challenges were encountered during this project that should be resolved. These challenges include base material specification, a non-destructive quality assurance technique, the use of other materials aside from 304L stainless steel, and reuse of expired standard gas containers.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2020

Guidance for Monitoring Passive Groundwater Remedies Over Extended Time Scales

Passive remediation can be appropriate where natural processes and actions such as institutional controls mitigate exposure to contaminated groundwater, achieving remedial action objectives and protectiveness of human health and the environment. Monitored natural attenuation (MNA) is a prevalent passive remediation strategy supported by a regulatory framework and monitoring design guidance. MNA can also be used after active remediation has been completed (e.g., pump-and-treat) as a polishing step to reach ultimate remedial action objectives. However, MNA and existing monitoring guidance primarily target situations where the remedial action objectives are met within a few decades. When timescales for passive remediation extend to many decades, a corresponding change in monitoring strategy is needed to adapt to the extended time scale. This document provides guidance for implementing an extended-scale monitoring (ESM) approach appropriate for long-duration passive remediation. Extended-scale is defined in this document with respect to time (i.e., a long duration of remediation) and a large enough physical scale such that receptors will not be impacted within the remediation timeframe.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Ammonia Generation and Utilization in a Passive SCR (TWC+SCR) System on Lean Gasoline Engine

Lean gasoline engines offer greater fuel economy than the common stoichiometric gasoline engine, but the current three way catalyst (TWC) on stoichiometric engines is unable to control nitrogen oxide (NOX) emissions in oxidizing exhaust. For these lean gasoline engines, lean NOX emission control is required to meet existing Tier 2 and upcoming Tier 3 emission regulations set by the U.S. Environmental Protection Agency (EPA). While urea-based selective catalytic reduction (SCR) has proven effective in controlling NOX from diesel engines, the urea storage and delivery components can add significant size and cost. As such, onboard NH 3 production via a passive SCR approach is of interest. In a passive SCR system, NH 3 is generated over a close-coupled TWC during periodic slightly rich engine operation and subsequently stored on an underfloor SCR catalyst. Upon switching to lean operation, NOX passes through the TWC and is reduced by the stored NH 3 on the SCR catalyst. In this work, a passive SCR system was evaluated on a 2.0-liter BMW lean burn gasoline direct injection engine to assess NH 3 generation over a Pd-only TWC and utilization over a Cu-based SCR catalyst. System NOX reduction efficiency and fuel efficiency improvement compared to stoichiometric engine operation were measured. A feedback control strategy based on cumulative NH 3 produced by the TWC during rich operation and NOX emissions during lean operation was implemented on the engine to control lean/rich cycle timing. At an SCR average inlet temperature of 350 °C, an NH 3 :NOX ratio of 1.15:1 (achieved through longer rich cycle timing) resulted in 99.7 % NOX conversion. Increasing NH 3 generation further resulted in even higher NOX conversion; however, tailpipe NH 3 emissions resulted. At higher underfloor temperatures, NH 3 oxidation over the SCR limited NH 3 availability for NOX reduction. At the engine conditions studied, greater than 99 % NOX conversion was achieved with passive SCR while delivering fuel efficiency benefits ranging between 6-11 % compared with stoichiometric operation.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2024

Metal-Complex Inks for Lower Cost and Improved Passivation for Silicon Photovoltaic Metallization

This contribution introduces the silicon PV community to screen-printable metal-complex inks that potentially will reduce Ag usage in Si PV metallization to one-quarter and costs to one-third that of traditional particle-based pastes while also improving passivation. Metal-complex inks are formulated using a Tollen’s reaction to produce inks with a high percentage of diamminesilver (I) cations (22 wt %) in a solution of acetate and formate anions. When printed and dried, labile ammonia ligands evaporate, leaving behind silver cations which, when reduced by formate anions and acetic acid, plate out silver and silver acetate. When annealed to just 300 °C a dense metallic silver film forms with excellent conductivity, and adhesion to silicon. When compared to traditional particle-based screen-printing pastes, the metal-complex inks are much denser, have higher conductivity, use less Ag, and are a fraction of the cost. Importantly, the inks anneal from 90 – 450 °C allowing for improved passivation schemes compared with fired SiNx. This contribution highlights first experiments on the improved passivation of metallized poly-Si/SiO2 passivated contacts using metal-complex Ag inks.

Young, David L. (ORCID:0000000340970493)↗
NASA NTRS1974

Maximum power transfer in n ports with passive loads

The problem of drawing maximum power from an n port by suitably terminating it with another passive n port is studied. Methods are derived for determining sets of passive impedance matrices which are 'optimal' in the sense that they draw maximum power from a given n port. It is shown that, in all nontrivial cases, if there exists any (passive or otherwise) optimum-load impedance matrix, then there exist, in fact, infinitely many passive optimum-load impedance matrices.

Vidyasagar, M.↗
NASA NTRS1979

Optokinetic motion sickness - Attenuation of visually-induced apparent self-rotation by passive head movements

An experimental study was conducted on seven normal subjects to evaluate the effectiveness of passive head movements in suppressing the optokinetically-induced illusory self-rotation. Visual simulation was provided by a servo-controlled optokinetic drum. Each subject participated in two experimental sessions. In one condition, the subject's head remained stationary while he gazed passively at a moving stripe pattern. In the other, he gazed passively and relaxed his neck muscles while his head was rotated from side to side. It appears that suppression of optokinetically-induced illusory self-rotation with passive head movements results from the operation of a spatial constancy mechanism interrelating visual, vestibular, and kinesthetic information on ongoing body orientation. The results support the view that optokinetic 'motion sickness' is related, at least in part, to an oculomotor disturbance rather than a visually triggered disturbance of specifically vestibular etiology.

Teixeira, R. A.↗
NASA NTRS1984

Advanced passive radiator for spaceborne cryogenic cooling

A novel design to improve the cooling capability of spaceborne cryogenic passive radiators is described. The design is based on the use of lightweight angled radiation shields, low-conductance structural supports, and a separate detachable launch-support system to reduce the parasitic heat leaks from the warm spacecraft to the cold radiator. The effectiveness of this design is demonstrated by thermal-vacuum-chamber experiments which indicate that the angled-radiation-shield assembly has an effective emittance that is an order of magnitude lower than that of the best multilayer insulation used in flight. Performance predictions based on the experiments and analytical model indicate that an advanced passive-radiator design based on this technology would be between 10 and 57% of the size and 10 and 36% of the mass of the best state-of-the-art passive radiators and would make lower temperatures (< 60 K) and larger heat loads practical. The cooling requirements of many new spaceborne instruments could be accommodated by application of this new passive-radiator design.

Steven Bard↗
NASA NTRS1986

Active-passive airborne ocean color measurement. I - Instrumentation

The instrumentation used in a multichannel lidar fluorosensor spectrometer functioning concurrently as a passive spectroradiometer for measuring upwelling ocean color radiance is discussed. The instrument calibration techniques are addressed, including the absolute passive calibration technique, the importance of relative channel-to-channel calibration for accurate ocean color measurement, and active mode calibration techniques using passive calibration transfer methods. Ground and flight test results from the dual-mode active-passive ocean color sensor are discussed.

Hoge, F. E.↗
NASA NTRS1987

Optimum mix of passive and active control of space structures

The objective of this research was to test vibration suppression (settling time and jitter) of a large space structure (LSS) characterized by low frequency high global vibration modes. Five percent passive damping in a large truss was analyzed, tested and correlated. A representative system article re-target analysis shows that modest levels of passive damping dramatically reduce the control energy required. LSS must incorporate passive damping from the outset. The LSS system performance will not be met by either active or passive damping alone.

Rogers, Lynn↗
NASA NTRS1990

Computational study for passive control of supersonic asymmetric vortical flows around cones

The unsteady, compressible, double and single thin-layer Navier-Stokes equations are used to numerically study for the passive control of steady and unsteady, supersonic asymmetric flows around circular and noncircular cones. The main computational scheme of the present study is the implicit upwind, flux-difference splitting, finite-volume scheme. Passive control of flow asymmetry is studied by using a vertical fin in the leeward plane of geometric symmetry and side strakes with and without thickness at different orientations. The study is focused on circular-section cones since they are the most potential section-shapes for strong flow asymmetry. Side-strakes passive control has been shown to be more efficient and practical than the vertical-fin passive control.

Liu, C. H.↗
NASA NTRS1991

Passivation Of High-Temperature Superconductors

Surfaces of high-temperature superconductors passivated with native iodides, sulfides, or sulfates formed by chemical treatments after superconductors grown. Passivating compounds nearly insoluble in and unreactive with water and protect underlying superconductors from effects of moisture. Layers of cuprous iodide and of barium sulfate grown. Other candidate passivating surface films: iodides and sulfides of bismuth, strontium, and thallium. Other proposed techniques for formation of passivating layers include deposition and gas-phase reaction.

Vasquez, Richard P.↗
NASA NTRS1991

Active and passive vibration suppression for space structures

The relative benefits of passive and active vibration suppression for large space structures (LSS) are discussed. The intent is to sketch the true ranges of applicability of these approaches using previously published technical results. It was found that the distinction between active and passive vibration suppression approaches is not as sharp as might be thought at first. The relative simplicity, reliability, and cost effectiveness touted for passive measures are vitiated by 'hidden costs' bound up with detailed engineering implementation issues and inherent performance limitations. At the same time, reliability and robustness issues are often cited against active control. It is argued that a continuum of vibration suppression measures offering mutually supporting capabilities is needed. The challenge is to properly orchestrate a spectrum of methods to reap the synergistic benefits of combined advanced materials, passive damping, and active control.

Hyland, David C.↗
NASA NTRS1992

Passive control of supersonic asymmetric vortical flows around cones

The unsteady, compressible, thin-layer Navier-Stokes equations are used to numerically study the passive control of steady and unsteady supersonic asymmetric flows around circular and noncircular cones. The main computational scheme of the present study is an implicit upwind, flux-difference splitting, finite-volume scheme. Passive control of flow asymmetry is studied by using a vertical fin in the leeward plane of geometric symmetry and side strakes with and without thickness at different orientations. The study focuses on circular-section cones since they are the most likely section-shapes for strong flow asymmetry. Side-strake passive control is shown to be more efficient and practical than vertical-fin passive control.

Liu, C. H.↗
NASA NTRS1993

Passive recirculation in the National Launch System's fuel feedlines

This report contains the passive recirculation tests on the fuel feedline of the National Launch System (NLS). The majority of testing was performed in February 1992, at the National Institute of Standards and Technology in Boulder, CO. The primary objective was to characterize passive recirculation in the NLS fuel feedline. The objective was met by observing the passive recirculation in a one-fifth scale model of the feedline with clear glass sections. The testing was recorded on video tape and with photographs. A description of the testing apparatus and support equipment is included. The experiment indicates that passive recirculation was occurring; higher angles from the horizontal transfer more heat.

Wilson, W. R.↗
NASA NTRS1993

Liquid hydrogen and liquid oxygen feedline passive recirculation analysis

The primary goal of the National Launch System (NLS) program was to design an operationally efficient, highly reliable vehicle with minimal recurring launch costs. To achieve this goal, trade studies of key main propulsion subsystems were performed to specify vehicle design requirements. These requirements include the use of passive recirculation to thermally condition the liquid hydrogen (LH2) and liquid oxygen (LO2) propellant feed systems and Space Transportation Main Engine (STME) fuel pumps. Rockwell International (RI) proposed a joint independent research and development (JIRAD) program with Marshall Space Flight Center (MSFC) to study the LH2 feed system passive recirculation concept. The testing was started in July 1992 and completed in November 1992. Vertical and sloped feedline designs were used. An engine simulator was attached at the bottom of the feedline. This simulator had strip heaters that were set to equal the corresponding heat input from different engines. A computer program is currently being used to analyze the passive recirculation concept in the LH2 vertical feedline tests. Four tests, where the heater setting is the independent variable, were chosen. While the JIRAD with RI was underway, General Dynamics Space Systems (GDSS) proposed a JIRAD with MSFC to explore passive recirculation in the LO2 feed system. Liquid nitrogen (LN2) is being used instead of LO2 for safety and economic concerns. To date, three sets of calibration tests have been completed on the sloped LN2 test article. The environmental heat was calculated from the calibration tests in which the strip heaters were turned off. During the LH2 testing, the environmental heat was assumed to be constant. Therefore, the total heat was equal to the environmental heat flux plus the heater input. However, the first two sets of LN2 calibration tests have shown that the environmental heat flux varies with heater input. A Systems Improved Numerical Differencing Analyzer and Fluid Integrator (SINDA/FLUINT) model is currently being built to determine if this variation in environmental heat is due to a change in the wall temperature. During the third set of calibration tests, a faulty reference junction was found. Based on this anomaly with the reference junction, the heat flux calculations from the first two calibration sets are now considered questionable.

Holt, Kimberly Ann↗
NASA NTRS1993

Synergism of active and passive microwave data for estimating bare surface soil moisture

Active and passive microwave sensors were applied effectively to the problem of estimating the surface soil moisture in a variety of environmental conditions. Research to date has shown that both types of sensors are also sensitive to the surface roughness and the vegetation cover. In estimating the soil moisture, the effect of the vegetation and roughness are often corrected either by acquiring multi-configuration (frequency and polarization) data or by adjusting the surface parameters in order to match the model predictions to the measured data. Due to the limitations on multi-configuration spaceborne data and the lack of a priori knowledge of the surface characteristics for parameter adjustments, it was suggested that the synergistic use of the sensors may improve the estimation of the soil moisture over the extreme range of naturally occurring soil and vegetation conditions. To investigate this problem, the backscattering and emission from a bare soil surface using the classical rough surface scattering theory were modeled. The model combines the small perturbation and the Kirchhoff approximations in conjunction with the Peak formulation to cover a wide range of surface roughness parameters with respect to frequency for both active and passive measurements. In this approach, the same analytical method was used to calculate the backscattering and emissivity. Therefore, the active and passive simulations can be combined at various polarizations and frequencies in order to estimate the soil moisture more actively. As a result, it is shown that (1) the emissivity is less dependent on the surface correlation length, (2) the ratio of the backscattering coefficient (HH) over the surface reflectivity (H) is almost independent of the soil moisture for a wide range of surface roughness, and (3) this ratio can be approximated as a linear function of the surface rms height. The results were compared with the data obtained by a multi-frequency radiometer-scatterometer system working at frequencies between 3.0 GHz to 11.0 GHz. The data were acquired over bare soil surfaces with moisture variations due to freezing and thawing and roughness changes due to rain and erosion. The model predictions are shown to be in reasonable agreement with the data. In addition, it was shown that the same ratio when calculated from the data shows almost no dependence on the soil moisture. Finally, a simple technique which combines the backscattering coefficient at HH polarization (active sensing) with the emissivity at H polarization (passive sensing) is suggested for retrieving the soil moisture from bare soil surfaces.

Saatchi, Sasan S.↗
NASA NTRS1993

Analysis of passive acoustic ranging of helicopters from the joint acoustic propagation experiment

For more than twenty years, personnel of the U.S.A.E. Waterways Experiment Station (WES) have been performing research dealing with the application of sensors for detection of military targets. The WES research has included the use of seismic, acoustic, magnetic, and other sensors to detect, track, and classify military ground targets. Most of the WES research has been oriented toward the employment of such sensors in a passive mode. Techniques for passive detection are of particular interest in the Army because of the advantages over active detection. Passive detection methods are not susceptible to interception, detection, jamming, or location of the source by the threat. A decided advantage for using acoustic and seismic sensors for detection in tactical situations is the non-line-of-sight capability; i.e., detection of low flying helicopters at long distances without visual contact. This study was conducted to analyze the passive acoustic ranging (PAR) concept using a more extensive data set from the Joint Acoustic Propagation Experiment (JAPE).

Carnes, Benny L.↗
NASA NTRS1994

Late Cenozoic flexural deformation of the middle U.S. Atlantic passive margin

Despite the century-long recognition of regional epeirogeny along the middle Atlantic passive margin, relatively few studies have focused on understanding postrift uplift mechanisms. Here, we demonstrate that epeirogenic uplift of the central Appalachian Piedmont and subsidence of the Salisbury Embayment represent first-order, flexural isostatic processes driven by continental denudation and offshore deposition. Our results show that regional epeirogenic processes, present on all Atlantic-type passive margins, are best resolved by specific stratigraphic and geomorphic relationships, rather than topography. A simple one-dimensional geodynamic model, constrained by well-dated Baltimore Canyon trough, Coastal Plain, and lower Susquehanna River (piedmont) stratigraphy, simulates flexural deforamtion of the U.S. Atlantic margin. The model represents the passive margin lithosphree as a uniformly thick elastic plate, without horizontal compressive stresses, that deforms flexurally under the stress of strike-averaged, vertically applied line loads. Model results illustrate a complex interaction among margin stratigraphy and geomorphology, the isostatic repsonse to denudational and depositional processes, and the modulating influence of exogenic forces such as eustasy. The current elevation, with respect to modern sea level, of fluvial terraces and correlateive Coastal Plain deposits or unconformities is successfully predicted through the synthesis of paleotopography, eustatic change, and margin flexure. Results suggest that the middle U.S. Atlantic margin landward of East Coast Magnetic Anomaly is underlain by lithoshpere with an average elastic thickness of 40 km (flexural rigidity, D = 4 X 10(exp 23) N m), the margin experience an average, long-term denudation rate of approximately 10m/m.y., and the Piedmont has been flexurally upwaped between 35 and 130 meters in the last 15 m.y. Long term isostatic continental uplift resulting rom denudation and basin subsidence resulting rom sediment loading are accomodated primately by a convex-up flexural hinge, physiographically represented by the Fall Zone. Our results elucidate an inherent danger in using topography alone to constrain late-stage passive margin deformation mechanisms. Only through careful synthesis of field stratigraphic and geomorphic elements such as fluvial terraces, Coastal Plain deposits, and offshore stratigraphy can age control be extended from the offshore depositional setting to the erosionally dominated continent. This sudy demonstrates that despite a relatively subdued topography, the middle U.S. Atlantic margin experiences progressive flexural isostatic deformation similar to that proposed for high-relief margins characterized by great escarpments. Thus margin topographic diversity remains a function of other factors, such as lithospheric composition and/or structure, supracrustal stratigraphy and structure, degree of drainage integration, drainage divide migration and climate.

Pazzaglia, Frank J.↗