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At least 343 records · Page 19

Zirconium, hafnium, and rare earth element partition coefficients for ilmenite and other minerals in high-Ti lunar mare basalts - An experimental study

Partition coefficients were determined for Gd, Lu, Hf and Zr among ilmenite, armalcolite, and synthetic high-Ti mare basaltic melts at temperatures from 1122 deg to 1150 deg, and at oxygen fugacities of IW x 10 exp 0.5, by in situ analysis with an electron microprobe, using samples doped to present concentration levels. Coefficients for Zr were also measured for samples containing 600-1600 ppm Zr using this microprobe. In addition, coefficients were determined for Hf and Zr between chromian ulvospinel and melt, for Hf between pigeonite and melt, and for Lu between olivine and melt by microprobe analysis of samples doped to present levels. Values measured using the microprobe were in agreement with the values measured by analyzing mineral separates from the same run products by isotope dilution. Coefficient values for ilmenite are less than 0.01 for the LREE, are around 0.1 for the HREE, and are several times greater than this for Zr and Hf.

Mckay, G.↗

Sharply curved turn around duct flow predictions using spectral partitioning of the turbulent kinetic energy and a pressure modified wall law

Computational predictions of turbulent flow in sharply curved 180 degree turn around ducts are presented. The CNS2D computer code is used to solve the equations of motion for two-dimensional incompressible flows transformed to a nonorthogonal body-fitted coordinate system. This procedure incorporates the pressure velocity correction algorithm SIMPLE-C to iteratively solve a discretized form of the transformed equations. A multiple scale turbulence model based on simplified spectral partitioning is employed to obtain closure. Flow field predictions utilizing the multiple scale model are compared to features predicted by the traditional single scale k-epsilon model. Tuning parameter sensitivities of the multiple scale model applied to turn around duct flows are also determined. In addition, a wall function approach based on a wall law suitable for incompressible turbulent boundary layers under strong adverse pressure gradients is tested. Turn around duct flow characteristics utilizing this modified wall law are presented and compared to results based on a standard wall treatment.

Santi, L. Michael↗

Phase partitioning, crystal growth, electrodeposition and cosmic ray experiments in microgravity

Five experiments are contained in one Get Away Special Canister (5 cu ft). The first utilizes microgravity to separate biological cells and to study the mechanism of phase partitioning in 12 separate cuvettes. Two experiments are designed to grow organic crystals by physical vapor transport. One experiment consists of eight electroplating cells with various chemicals to produce surfaces electroplated in microgravity. Some of the surfaces have micron sized particles of hard materials co-deposited during electrodeposition. The fifth experiment intercepts cosmic ray particles and records their paths on photographic emulsions. The first four experiments are controlled by an on-board C-MOS controller. The fifth experiment is totally passive. These are the first in Space. Their purpose is to create new commercial products with microgravity processing.

Wessling, Francis C.↗

Mathematical model partitioning and packing for parallel computer calculation

This paper deals with the development of multiprocessor simulations from a serial set of ordinary differential equations describing a physical system. The identification of computational parallelism within the model equations is discussed. A technique is presented for identifying this parallelism and for partitioning the equations for parallel solution on a multiprocessor. Next, an algorithm which packs the equations into a minimum number of processors is described. The results of applying the packing algorithm to a turboshaft engine model are presented.

Arpasi, Dale J.↗

Life prediction of thermomechanical fatigue using total strain version of strainrange partitioning (SRP): A proposal

A method is proposed (without experimental verification) for extending the total strain version of Strainrange Partitioning (TS-SRP) to predict the lives of thermomechanical fatigue (TMF) cycles. The principal feature of TS SRP is the determination of the time-temperature-waveshape dependent elastic strainrange versus life lines that are added subsequently to the classical inelastic strainrange versus life lines to form the total strainrange versus life relations. The procedure is based on a derived relation between failure and flow behavior. Failure behavior is represented by conventional SRP inelastic strainrange versus cyclic life relations, while flow behavior is captured in terms of the cyclic stress-strain response characteristics. Stress-strain response is calculated from simple equations developed from approximations to more complex cyclic constitutive models. For applications to TMF life prediction, a new testing technique, bithermal cycling, is proposed as a means for generating the inelastic strainrange versus life relations. Flow relations for use in predicting TMF lives would normally be obtained from approximations to complex thermomechanical constitutive models. Bithermal flow testing is also proposed as an alternative to thermomechanical flow testing at low strainranges where the hysteresis loop is difficult to analyze.

Saltsman, James F.↗

Partitioning of rare earth elements between hibonite and melt and implications for nebular condensation of the rare earth elements

The effect of oxygen fugacity on the partitioning of REEs between hibonite and silicate melt is investigated in hibonite-growth experiments at 1470 C. The experimental procedures and apparatus are described, and the results are presented in extensive tables and graphs and characterized in detail. The absolute activity coefficients in hibonite are estimated as 330 for La, 1200 for Eu(3+), and 24,000 for Yb. It is inferred that ideal solution behavior cannot be assumed when calculating REE condensation temperatures for (Ca, Al)-rich inclusions in carbonaceous chondrites.

Drake, Michael J.↗

Partitioning strategy for efficient nonlinear finite element dynamic analysis on multiprocessor computers

A computational procedure is presented for the nonlinear dynamic analysis of unsymmetric structures on vector multiprocessor systems. The procedure is based on a novel hierarchical partitioning strategy in which the response of the unsymmetric and antisymmetric response vectors (modes), each obtained by using only a fraction of the degrees of freedom of the original finite element model. The three key elements of the procedure which result in high degree of concurrency throughout the solution process are: (1) mixed (or primitive variable) formulation with independent shape functions for the different fields; (2) operator splitting or restructuring of the discrete equations at each time step to delineate the symmetric and antisymmetric vectors constituting the response; and (3) two level iterative process for generating the response of the structure. An assessment is made of the effectiveness of the procedure on the CRAY X-MP/4 computers.

Noor, Ahmed K.↗

Total strain version of strainrange partitioning for thermomechanical fatigue at low strains

A new method is proposed for characterizing and predicting the thermal fatigue behavior of materials. The method is based on three innovations in characterizing high temperature material behavior: (1) the bithermal concept of fatigue testing; (2) advanced, nonlinear, cyclic constitutive models; and (3) the total strain version of traditional strainrange partitioning.

Halford, G. R.↗

Procedures for characterizing an alloy and predicting cyclic life with the total strain version of Strainrange Partitioning

Procedures are presented for characterizing an alloy and predicting cyclic life for isothermal and thermomechanical fatigue conditions by using the total strain version of strainrange partitioning (TS-SRP). Numerical examples are given. Two independent alloy characteristics are deemed important: failure behavior, as reflected by the inelastic strainrange versus cyclic life relations; and flow behavior, as indicated by the cyclic stress-strain-time response (i.e., the constitutive behavior). Failure behavior is characterized by conducting creep-fatigue tests in the strain regime, wherein the testing times are reasonably short and the inelastic strains are large enough to be determined accurately. At large strainranges, stress-hold, strain-limited tests are preferred because a high rate of creep damage per cycle is inherent in this type of test. At small strainranges, strain-hold cycles are more appropriate. Flow behavior is characterized by conducting tests wherein the specimen is usually cycled far short of failure and the wave shape is appropriate for the duty cycle of interest. In characterizing an alloy pure fatigue, or PP, failure tests are conducted first. Then depending on the needs of the analyst a series of creep-fatigue tests are conducted. As many of the three generic SRP cycles are featured as are required to characterize the influence of creep on fatigue life (i.e., CP, PC, and CC cycles, respectively, for tensile creep only, compressive creep only, and both tensile and compressive creep). Any mean stress effects on life also must be determined and accounted for when determining the SRP inelastic strainrange versus life relations for cycles featuring creep. This is particularly true for small strainranges. The life relations thus are established for a theoretical zero mean stress condition.

Saltsman, James F.↗

Phase partitioning in space and on earth

The influence of gravity on the efficiency and quality of the impressive separations achievable by bioparticle partitioning is investigated by demixing polymer phase systems in microgravity. The study involves the neutral polymers dextran and polyethylene glycol, which form a two-phase system in aqueous solution at low concentrations. It is found that demixing in low-gravity occurs primarily by coalescence, whereas on earth the demixing occurs because of density differences between the phases.

Van Alstine, James M.↗

A partitioning strategy for efficient nonlinear finite element dynamic analysis on multiprocessor computer

A computational procedure is presented for the nonlinear dynamic analysis of unsymmetric structures on vector multiprocessor systems. The procedure is based on a novel hierarchical partitioning strategy in which the response of the unsymmetric and antisymmetric response vectors (modes), each obtained by using only a fraction of the degrees of freedom of the original finite element model. The three key elements of the procedure which result in high degree of concurrency throughout the solution process are: (1) mixed (or primitive variable) formulation with independent shape functions for the different fields; (2) operator splitting or restructuring of the discrete equations at each time step to delineate the symmetric and antisymmetric vectors constituting the response; and (3) two level iterative process for generating the response of the structure. An assessment is made of the effectiveness of the procedure on the CRAY X-MP/4 computers.

Noor, Ahmed K.↗

A nonlinear high temperature fracture mechanics basis for strainrange partitioning

A direct link was established between Strainrange Partitioning (SRP) and high temperature fracture mechanics by deriving the general SRP inelastic strain range versus cyclic life relationships from high temperature, nonlinear, fracture mechanics considerations. The derived SRP life relationships are in reasonable agreement based on the experience of the SRP behavior of many high temperature alloys. In addition, fracture mechanics has served as a basis for derivation of the Ductility-Normalized SRP life equations, as well as for examination of SRP relations that are applicable to thermal fatigue life prediction. Areas of additional links between nonlinear fracture mechanics and SRP were identified for future exploration. These include effects of multiaxiality as well as low strain, nominally elastic, long life creep fatigue interaction.

Kitamura, Takayuki↗

Binary space partitioning trees and their uses

Binary Space Partitioning (BSP) trees have some qualities that make them useful in solving many graphics related problems. The purpose is to describe what a BSP tree is, and how it can be used to solve the problem of hidden surface removal, and constructive solid geometry. The BSP tree is based on the idea that a plane acting as a divider subdivides space into two parts with one being on the positive side and the other on the negative. A polygonal solid is then represented as the volume defined by the collective interior half spaces of the solid's bounding surfaces. The nature of how the tree is organized lends itself well for sorting polygons relative to an arbitrary point in 3 space. The speed at which the tree can be traversed for depth sorting is fast enough to provide hidden surface removal at interactive speeds. The fact that a BSP tree actually represents a polygonal solid as a bounded volume also makes it quite useful in performing the boolean operations used in constructive solid geometry. Due to the nature of the BSP tree, polygons can be classified as they are subdivided. The ability to classify polygons as they are subdivided can enhance the simplicity of implementing constructive solid geometry.

Bell, Bradley N.↗

Application of partition technology to particle electrophoresis

The effects of polymer-ligand concentration on particle electrophoretic mobility and partition in aqueous polymer two-phase systems are investigated. Polymer coating chemistry and affinity ligand synthesis, purification, and analysis are conducted. It is observed that poly (ethylene glycol)-ligands are effective for controlling particle electrophoretic mobility.

Van Alstine, James M.↗

Cell separation in immunoaffinity partition in aqueous polymer two-phase systems

Two methods for immunoaffinity partitioning are described. One technique involves the covalent coupling of poly (ethylene glycol) (PEG) to immunoglobulin G antibody preparations. In the second method PEG-modified Protein A is used to complex with cells and unmodified antibody. The effects of PEG molecular weight, the degree of modification, and varying phase system composition on antibody activity and its affinity for the upper phase are studied. It is observed that both methods resulted in effective cell separation.

Karr, Laurel J.↗

A new partitioning strategy for efficient re-analysis of large structural systems

A computational procedure is presented for the reanalysis of large unsymmetric structural systems. The procedure is based on a novel partitioning strategy in which the responses of both the original and modified structures are approximated by symmetric and antisymmetric response vectors, each obtained by using only a fraction of the degrees of freedom of the discrete model of the structure. The procedure is applied to linear static analysis of framed structures. Design modifications consisted of removing members, resulting in topologically unsymmetric structures. The efficient application of the procedure on sequential computers as well as on multiprocessor computers is discussed, and its effectiveness is demonstrated by means of two numerical examples.

Noor, Ahmed K.↗

Solubility and partitioning of Ar in anorthite, diopside, forsterite, spinel, and synthetic basaltic liquids

The solubility and partitioning of Ar in natural anorthite, diopside, forsterite, spinel, and synthetic iron-free basaltic melts was investigated using a new technique that obviates the postquenching phase separation. It was found that the solubility of Ar in the minerals was surprisingly high. Moreover, the solubility of Ar in different samples of a particular mineral run in the same experiment varied more than the solubility in the same sample run in different experiments, suggesting that noble gases are held in lattice vacancy defects. Moreover, the results of TEM imaging revealed no anomalous microstructures, while EXAFS studies of some samples showed that Kr has no preferred site in the lattices, supporting the defect siting conclusion.

Broadhurst, C. Leigh↗

Partition coefficients for calcic plagioclase - Implications for Archean anorthosites

In most Archean cratons, cumulates of equant plagioclase megacrysts form anorthositic complexes, including those at Bad Vermilion Lake (Ontario). In this paper, partition coefficients (Ds) of REEs between natural high-Ca plagioclase megacrysts and their basaltic matrices were determined, using a multiple aliquot techique, and megacrystic plagioclases occurring in anorthosites were analyzed for the same components which, in conjunction with their Ds, were applied to calculations of melts in equilibrium with anorthosites. The REE's Ds were found to agree well with experimentally determined values and to predict equilibrium melts for Archean anorthosites that agree well with coeval basaltic flows and dikes. The Ds also appear to be valid for both the tholeiitic and alkali basalts over a wide range of mg numbers and REE concentrations. It is suggested that the moderately Fe-rich tholeiites that are hosts to plagioclase megacrysts in greenstone belts form the parental melts for megacrysts which make up the Bad Vermilion Lake Archean anorthositic complex.

Phinney, W. C.↗