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At least 343 records · Page 19

Carbon-14 in lunar soil and in meteorites

C-14 was measured in grain-size fractions of lunar soil 10084 and in samples of the Bruderheim chondrite and of several meteorites recently found in Antarctica (Allan Hills no. 5, 6, and 8). Temperature-release patterns were investigated. It was found that C-14 is released at temperatures below melting from small soil grains (less than 74 microns), but not from meteorites or from large soil grains. Below-melting C-14 contents increase with decreasing grain size in a manner similar to solar-wind-implanted rare-gas isotope contents (Eberhardt et al., 1970), whereas the C-14 released above melting temperatures is independent of grain size, suggesting that below-melting C-14 is solar-wind-implanted and above-melting C-14 is the result of cosmic ray spallations. The activity of C-14 in lunar samples is half that measured in the Bruderheim meteorite, which fell on May 4, 1970. No C-14 activity was observed in the Allan Hills chondrites; the C-14 limits suggest that these meteorites fell more than 25,000 years ago.

Fireman, E. L.↗

I-Xe dating of silicate and troilite from IAB iron meteorites

Silicate and troilite inclusions from IAB iron meteorites were dated by the I-Xe technique. Silicate samples from inclusions in the Copiapo, Landes, Woodbine, Pitts and Mundrabilla meteorites and troilite samples from Pitts and Mundrabilla were subjected to neutron irradiation and the xenon isotope ratios produced were determined. Well-defined I-Xe ages were obtained for Woodbine, Copiapo, Landes and Mundrabilla and are found to be within 3.7 million years of the Bjurbole meteorite, suggesting a close relationship to the stone chondrites. The analysis of troilite from Pitts suggests an age of 17 million years older than Bjurbole, while Mundrabilla troilite is observed to predate Mundrabilla silicate. The abundances of Ga, Ge and Ni are found to be correlated with I-Xe ages, supporting the validity of the I-Xe dating method. The results are considered to favor a nebular model of meteorite formation.

Niemeyer, S.↗

Isotopically anomalous silver in the Santa Clara and Pinon iron meteorites

The isotopic composition and concentration of Ag and the concentration of Pd have been determined in the Santa Clara and Pinon iron meteorites. It is shown that these meteorites contain isotopically anomalous Ag with an excess of Ag-107 relative to normal Ag, confirming earlier findings. Using an improved procedure for cleaning the sample surface from terrestrial Ag, a new concentration of 1.4 x 10 to the 11th atoms of Ag-109/g meteorite is established which is an order of magnitude below the levels found earlier. As a result ratios of Ag-107/Ag-109 were found which are enriched in Ag-107 by 60 percent to 160 percent. The existence of an excess Ag-107 in these two meteorites, which have high Pd-108/Ag-109 ratios of about 7 x 10 to the 4th is established.

Kaiser, T.↗

The isotopic composition of uranium and lead in Allende inclusions and meteoritic phosphates

The isotopic compositions of uranium and lead in Ca-Al-rich inclusions from the Allende chondrite and in whitlockite from the St. Severin chondrite and the Angra dos Reis achondrite are reported. Isoptopic analysis of acid soluble fractions of the Allende inclusions and the meteoritic whitlockite, which show isotopic anomalies in other elements, reveals U-235/U-238 ratios from 1/137.6 to 1/138.3, within 20 per mil of normal terrestrial U abundances. The Pb isotopic compositions of five coarse-grained Allende inclusions give a mean Pb-207/Pb-206 model age of 4.559 + or - 0.015 AE, in agreement with the U results. Pb isotope ratios of two fine-grained inclusions and a coarse-grained inclusion with strong mass fractionation and some nonlinear isotopic anomalies indicate that the U-Pb systems of these inclusions have evolved differently from the rest of Allende. Th/U abundance ratios in the Allende inclusions and meteoritic phosphate are found to range from 3.8 to 96, presumably indicating an optimal case for Cm/U fractionation, although the normal U concentrations do not support claims of abundant live Cm-247 or Cm-247/U-238 fractionation at the time of meteorite formation, in contrast to previous results. A limiting Cm-247/U-235 ratio of 0.004 at the time of meteorite formation is calculated which implies that the last major r process contribution at the protosolar nebula was approximately 100 million years prior to Al-26 formation and injection.

Chen, J. H.↗

Antimony in iron meteorites

Sb concentrations determined by radiochemical neutron activation analysis in 60 iron meteorites range from 0.2 ng/g to 36 microg/g. The meteorites with the highest Sb concentrations are those of the nonmagmatic groups IAB and IIICD, while meteorites with the lowest Sb concentrations are found in groups IVA and IVB. In all groups Sb is positively correlated with Ni; slopes on log Sb vs log Ni plots decrease with increasing Ni. This decrease may reflect an increasing tendency to avoid schreibersite during the analysis of high-Ni meteorites because Sb partitions strongly into schreibersite. It is found that schreibersite from New Westville is enriched in Cr, Ni, Ge, As, Sb, and Au and depleted in Fe, Co, Ir; the Sb content in schreibersite is 540 times higher than the bulk metal value.

Willis, J.↗

The Allan Hills icefield and its relationship to meteorite concentration

The Allan Hills icefield is described by as a limited icefield that has large concentrations of meteorites. The meteorites appear to be concentrated on the lower limb of an ice monocline with other finds scattered throughout the field. In an attempt to understand the mechanisms of meteorite concentration, a triangulation chain was established across the icefield. This chain is composed of 20 stations, two of which are on bedrock, and extends westward from the Allan Hills a distance of 15 kilometers. The triangulation chain and its relationship to the meteorite concentrations is shown.

Annexstad, J. O.↗

Mineralogy, petrology, and trace element geochemistry of the Johnstown meteorite - A brecciated orthopyroxenite with siderophile and REE-rich components

The compositional and petrologic characteristics of the Johnstown meteorite show it to contain uncontaminated and unbrecciated orthopyroxenite clasts of cumulative origin that (1) must have undergone subsolidus recrystalization, (2) are parental to the brecciated matrix, and (3) show no evidence of a xenolithic, meteoritic contribution to the matrix except for contamination by the projectile which crushed it on impact. The trapped liquid was not introduced in the impact process. The variability of such trace elements as the light rare earth elements, and the presence of plagioclase and olivine in only one of the thin sections studied, demonstrates the heterogeneity of coarse-grained diogenites on a millimeter scale and the difficulty of obtaining representative samples of such meteorites. The data presented indicate that this meteorite is a monominct breccia.

Floran, R. J.↗

The concentration and isotopic composition of hydrogen, carbon and nitrogen in carbonaceous meteorites

Stepwise pyrolysis was used to extract H2, N2 and C from powdered meteorites and from meteorite residues resulting from partial dissolution in aqueous HF or from reaction with HF-HCl solutions. Concentrations and isotopic compositions were determined for the cases of the carbonaceous chondrites Orgueil, Murray, Murchison, Renazzo and Cold Bokkeveld. Acidification of the meteorites removed the organic sources of H2, so that H2 in the HF-HCl acid residues came mostly from the insoluble organic matter making up 70-80% of the total carbon in carbonaceous meteorites. Good correlation is found between delta-D and the concentration of H2 in the acid residues, but no correlation exists between the delta-D, delta-C-13 and delta-N-15 in them. A model is proposed for both the high delta-D values and the relationship between those values and the H2 concentration.

Robert, F.↗

Silver isotopic anomalies in iron meteorites - Cosmic-ray production and other possible sources

Sources of excess Ag-107 observed in iron meteorites are investigated with emphasis on reactions of cosmic-ray particles with palladium. Cross sections for the production of the silver isotopes from palladium by energetic cosmic-ray particles are estimated to calculate spallogenic production rates relative to that of Mn-53 from iron. The upper limits for the production rates of Ag-107 and Ag-109 by energetic galactic cosmic-ray particles are 690 and 270 atoms/min/kg(Pd), respectively, and the maximum rate for making excess Ag-107 by spallation reactions is 400 atoms/min/kg(Pd). The excess Ag-107 cannot be produced by a long exposure to cosmic-ray particles, and because it is harder to make the amount of Pd-107 observed in the iron meteorites by an early intense proton irradiation than it is to make the Al-26 observed in other meteorites, it is concluded that the excess Ag-107 is due to the decay of nucleosynthetic Pd-107 in the iron meteorites.

Reedy, R. C.↗

Brazilian stone meteorites

A survey of Brazilian meteorites is presented, along with basic premises of meteoritics, including classification, naming, and analytic procedures. Meteorites are noted to be of interest as representative samples of ancient rocks, perhaps half as old as the universe, as sometimes originating from outside the solar system, containing early solar material, and containing evidence of cosmic ray interactions or collisions. The characteristics which make up the achondrite and chondrite group are reviewed, and a listing of the primary characteristics of known Brazilian meteorites is provided.

Gomes, C. B.↗

Distribution and enantiomeric composition of amino acids in the Murchison meteorite

Studies of the amino acid contents and enantiomeric compositions of a single stone from the Murchison meteorite are reported. Water-extracted and 6M HCl-extracted samples from the meteorite interior of meteorite fragments were analyzed by gas chromatography and combined gas chromatography-chemical ionization mass spectrometry. Examination of the D/L ratios of glutamic acid, aspartic acid, proline, leucine and alanine reveals those amino acids extractable by water to be partially racemized, whereas the acid-extracted amino acids were less racemized. The amino acid composition of the stone is similar to those previously reported, including the absence of serine, threonine, tyrosine phenylalanine and methionine and the presence of unusual amino acids including such as isovaline, alpha-aminoisobutyric acid and pseudoleucine. It is concluded that the most likely mechanism accounting for the occurrence of nonracemic amino acid mixtures in the Murchison meteorite is by extraterrestrial stereoselective synthesis or decomposition reactions.

Engel, M. H.↗

Heterogeneous growth of meteorites and planets, especially the earth and moon

It is pointed out that enough information remains in meteorites to show that the solar nebula was chemically inhomogeneous, and that it did not develop under physical and chemical equilibrium. It is found that the earth is not in chemical equilibrium, and that it still retains vestiges of its heterogeneous growth in spite of prolonged convection and volcanism. The present investigation has the aim to unify simple ideas into a comprehensive, complex scheme for heterogeneous growth of the planets and parent bodies of meteorites. A scheme is considered for the conversion of dust and gas in the solar nebula into the present population of bodies. Attention is given to possible processes for the growth and development of planetesimals from dust via clouds, the major episodes in the development of the solar system, the relation of meteorites to a solar nebula with monotonic variation of temperature and oxidation state, the significance of meteorite properties, the composition of the inner planets, and the development of the earth.

Smith, J. V.↗

The 45th Annual Meteoritical Society Meeting

Impact craters and shock effects, chondrite formation and evolution, meteorites, chondrules, irons, nebular processes and meteorite parent bodies, regoliths and breccias, antarctic meteorite curation, isotopic studies of meteorites and lunar samples, organics and terrestrial weathering, refractory inclusions, cosmic dust, particle irradiations before and after compaction, and mineralogic studies and analytical techniques are discussed.

Jones, P.↗

Primordial retention of nitrogen by terrestrial planets and meteorites

Thermodynamic calculations of the amount of dissolved nitrogen in Fe-Ni alloy in a solar composition gas were done over a wide range of temperatures and pressures. The stabilities of the nitride minerals found in meteorites, a large number of other nitrides, and ammonium aluminosilicates were also calculated in a solar gas. This thorough study indicates that equilibrium mechanisms cannot account for the nitrogen contents of the terrestrial planets and meteorites. The best available data indicate that the observed nitrogen contents of planets and meteorites are several orders of magnitude greater than the predicted nitrogen contents of condensed material in a solar gas. It is suggested that the nitrogen in meteorites was originally retained as organic compounds produced by disequilibrium mechanisms. Nitrogen retention by the terrestrial planets could be due to homogeneous accretion or to accretion of a volatile-rich veneer. However, the actual mode of nitrogen accretion cannot yet be determined.

Fegley, B., Jr.↗

The role of S in the evolution of the parental cores of the iron meteorites

The S contents of iron meteorite parent bodies are estimated on the basis of cosmochemical relationships to undifferentiated meteorites, the results are compared to observations on the major magmatic iron meteorite groups, and evidence is presented that S/Ni ratios in their parent melts were much lower than those inferred for the parent body. Several alternative models to account for the discrepancy are offered, including volatilization of S from the IIAB parent body, liquid immiscibility, and metastable liquid layers produced by episodic melting. Finally, the fate of the S-rich meteoroidal material is discussed, as well as the question of why it seems to be missing from meteorite collections.

Kracher, A.↗

Asteroids and meteorites - Parent bodies and delivered samples

Asteroid physical strengths, which critically affect the quantity of ejecta that can be placed in orbits evolving so as to cross that of the earth, vary widely due to initial composition and size, and subsequent geophysical and collisional evolutions. The meteorite yield on earth additionally depends on meteorite strength, which affects longevity in space and survival through the atmosphere. It is presently shown that meteorites may be primarily derived by cratering rather than disruptive fragmentation, and from large, main-belt asteroids rather than from small, earth-approaching bodies. The model presented combines a variety of evidence from various disciplines to yield results that are consistent with meteorite statistics, although no claim is made for the uniqueness of the model and many of its elements remain uncertain.

Greenberg, R.↗

Cosmic ray exposure of SNC meteorites and constraints on their derivation from Mars

There is chemical, mineralogical, and isotopic evidence that several rare meteorites originated from the planet Mars. The eight specimens (4 sphergottites, 3 nakhlites, and 1 chassignite) possess a variety of characteristics that suggest a mutual relationship. It can be predicted with reasonable confidence that these SNC meteorites were exposed to cosmic rays at relatively shallow depths for three distinct periods of time during the past approximately 10 million years. Within the context of a Martian origin, this implies that either relatively large objects were ejected from Mars at a common time and underwent three disruptive events in space or that three ejection events occurred within the past approximately 10 million years on restricted segments of Martian terrain with 1300 million year-old rocks. If mechanisms can be identified which satisfy the geochemical properties of SNC meteorites, as well as their cosmic ray exposure, and dynamical problems associated with ejection out of a large gravity field, then the case for the SNC meteorites being samples of Mars can become stronger.

Bogard, D. D.↗

High-temperature inclusions in the Murchison meteorite

Inclusions found in type 3 carbonaceous chondrites such as the Allende meteorite are described and compared with those in the Murchison type 2 carbonaceous chondrite. Scanning electron microscope studies of the SH-6 (containing abundant hibonite) and the GR-1 (containing abundant hibonite and corundum) are discussed. Because corundum and hibonite are higher temperature condensates than the melilite and pyroxene found in the Allende meteorite, it is concluded that most refractory inclusions in the Murchison meteorite were isolated from the solar nebular gas at a higher temperature than their counterparts in the Allende meteorite. Whether the inclusion crystallized from a liquid or condensed directly from solar nebular gas is discussed.

Grossman, L.↗