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Results for “Infrared techniques”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Photocatalytic Ammonia Synthesis using Fe-Based MOFs: The Role of Ligand Functionalization

Photocatalytic ammonia (NH 3 ) synthesis offers a carbon-neutral alternative to the Haber−Bosch process, which generates 42 million metric tons of CO 2 equivalent emissions annually. However, solar-to-ammonia conversion with contemporary photocatalysts remains far from practical requirements, and understanding the limiting factors in systems with well-defined active sites is crucial. Here, we show how the μ 3 -oxo-centered trinuclear Fe cluster in MIL-101(Fe) functions as the catalytic motif for N 2 -to-NH 3 conversion through combined experimental and computational investigations. Comparative studies with a molecular analogue demonstrate that the cluster is stabilized within the MOF framework, sustaining redox cycling and maintaining high catalytic activity. We systematically functionalized the dicarboxylate ligands of MIL-101(Fe) with −NH 2 , −Br, −NO 2 , −F, and −CF 3 to probe how ligand chemistry modulates Fe electron density, N 2 adsorption capacity, and proton availability, correlating these properties with catalytic performance using spectroscopic and surface characterization techniques alongside timeresolved infrared to assess excited-state lifetimes. F-functionalization optimally balances N 2 activation, proton availability at Fe active sites, and excited-state lifetimes, boosting NH 3 production by ∼ 60% relative to unmodified MIL-101(Fe). This study of ligandfunctionalized MIL-101(Fe) MOFs uncovers the underlying structure-activity relationships and advances design principles for solardriven NH 3 synthesis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Longitudinal position dependence of dark line defect growth rate in high-power diode lasers at 790 nm

Using a nondestructive, in situ near-infrared defect imaging technique, we obtained time-resolved images of dark line defect (DLD) growth in the cavities of several high-power 790-nm diode lasers and calculated individual DLD growth rates. A clear longitudinal spatial dependence in the DLD growth rate was observed, in which the DLD growth rate was faster near the anti-reflective (AR) facet. Longitudinal spatial hole burning simulation results indicate that the total photon density increases toward the AR facet, while the carrier density decreases toward the AR facet. Here, these results suggest that photon absorption plays a key role in enhancing DLD growth beyond the contribution of the traditional carrier capture mechanism. Asymmetric DLD growth that was preferentially directed toward the high-reflectivity facet was also observed, providing further support for the role of photon absorption in the growth process. To account for these findings, we propose a photon-accelerated mechanism for the enhancement of DLD growth in which the slower carrier capture process in the traditional recombination-enhanced dislocation glide mechanism is replaced by a faster photon absorption process.

Engineering - Electronic and electrical engineerin↗
DOE OSTI2020

Criegee intermediates: production, detection and reactivity

In the context of tropospheric chemistry, Criegee intermediates denote carbonyl oxides with biradical/zwitterionic character (R 1 R 2 COO) that form during the ozonolysis of alkenes. First discovered almost 70 years ago, stabilised versions of Criegee intermediates formed via collisional removal of excess energy have interesting kinetic and mechanistic properties. The direct production and detection of these intermediates were not reported in the literature until 2008. However, recent advances in their generation through the ultraviolet irradiation of the corresponding diiodoalkanes in excess O 2 and detection by various spectroscopic techniques (photoionisation, ultraviolet, infrared, microwave and mass spectrometry) have shown that these species can react rapidly with closed-shell molecules, in many cases at or exceeding the classical gas-kinetic limit, via multiple reaction pathways. These reactions can be complex, and laboratory measurements of products and the temperature and pressure dependence of the reaction kinetics have also revealed unusual behaviour. The possible role of these intermediates in atmospheric chemistry is significant, altering models of the oxidising capacity of the Earth's atmosphere and the rate of generation of secondary organic aerosol.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Measurements of time and spatial resolution of AC-LGADs with different designs

AC-LGAD sensors are prime candidates for fast and precise measurement of charged particles in a variety of applications. In a fine-pitched pixel or strip AC-LGAD sensor, the signal generated by the passage of a particle is not localized in a limited volume in the sensor, but is shared among multiple electrodes. This signal sharing characteristic allows us to improve the spatial resolution of AC-LGAD sensors beyond the capabilities of common silicon trackers. Since the magnitude of the shared signal depends on the distance between the pixels or strips and the point of passage of the particle, signal sharing is strongly influenced by the geometry of the sensor. The electrode pitch and gap size as well as the shape can be fine tuned to maximize the space resolution, while keeping the detector granularity and the number of channels to be read out under control. Prototypes of AC-LGAD sensors produced at the Brookhaven National Laboratory covering a variety of possible geometries have been studied via Transient Current Technique using an infrared laser, and the signal sharing, spatial resolution, and time resolution of the different topologies have been measured. These results have been compared with measurements performed in test-beams with 120 GeV protons at the Fermilab Test Beam Facility. A time resolution of ~30 ps can be achieved using AC-LGAD sensors with a thickness of 50 μm, compatible to that of standard DC-coupled LGADs, while presenting a far superior spatial resolution. Finally, this combination of high precision, fast timing capabilities, and low material budget makes AC-LGADs an ideal choice for a truly 4D detector.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
DOE OSTI2022

Landfill Emissions of Methane Inferred from Unmanned Aerial Vehicle and Mobile Ground Measurements

Municipal solid waste landfills are significant sources of atmospheric methane, the second most important greenhouse gas after carbon dioxide. Large emissions of methane from landfills contribute not only to global climate change, but also to local ozone formation due to the enhancement of radical chain lengths in atmospheric reactions of volatile organic compounds and nitrogen oxides. Several advanced techniques were deployed to measure methane emissions from two landfills in the Southeast Michigan ozone nonattainment area during the Michigan–Ontario Ozone Source Experiment (MOOSE). These techniques included mobile infrared cavity ringdown spectrometry, drone-mounted meteorological sensors and tunable diode laser spectrometry, estimation of total landfill emissions of methane based on flux plane measurements, and Gaussian plume inverse modeling of distributed methane emissions in the presence of complex landfill terrain. The total methane emissions measured at the two landfills were of the order of 500 kg/h, with an uncertainty of around 50%. The results indicate that both landfill active faces and leaking gas collection systems are important sources of methane emissions.

Olaguer, Eduardo P.↗
NASA NTRS1972

Effect of a magnetic field on the diffusion of an electron-hole plasma in germanium.

Study in germanium of an optically injected electron-hole plasma, parallel and perpendicular to an applied magnetic field. The density gradient within the crystal was measured directly by an infrared-beam-absorption technique. Diffusion measurements made parallel to the magnetic field are adequately explained by the theory.

Gurnee, M. N.↗
NASA NTRS1972

Infrared response measurements on radiation-damaged Si/Li/ detectors.

The improved infrared response (IRR) technique has been used to qualitatively compare radiation effects on Si(Li) detectors with energy levels reported for silicon in the literature. Measurements have been made on five commercial silicon detectors and one fabricated in-house, both before and after irradiation with fast neutrons, 1.9-MeV protons, and 1.6-MeV electrons. Effects dependent upon the extent of radiation damage have been observed. It seems likely that the photo-EMF, or photo-voltage, effect is the basic mechanism for the observation of IRR in p-i-n diodes with a wide i-region. Experimental characteristics of the IRR measurement are in agreement with those of the photovoltage effect.

Sher, A. H.↗
NASA NTRS1973

3 nu sub 3 band of C-12H4 at 1.1 micron.

The 3 nu sub 3 absorption band of C-12H4 has been measured using a high-resolution vacuum infrared spectrometer. A technique is described which allows an extension of the use of the absorption standards available at 4.7 microns to the photomultiplier region of the spectrum. The new measurements indicate a shift of about 0.18 per cm from the most recently published measurements of this band.

Pugh, L. A.↗
NASA NTRS1973

Investigations of lubricant rheology as applied to elastohydrodynamic lubrication

The pressure viscometer was modified to permit the measurement of viscosity at elevated pressures and shear stresses up to 5 x 10 to the 6th power N/sq m (720 psi). This shear stress is within a factor of three of the shear stress occurring in a sliding ehd point contact such as occurs in the ehd simulator. Viscosity data were taken on five lubricant samples, and it was found that viscous heating effects on the viscosity were predominant and not non-Newtonian behavior at the high shear stresses. The development of the infrared temperature measuring technique for the ehd simulator was completed, and temperature data for a set of operating conditions and one lubricant are reported. The numerical analysis of the behavior of nonlinear lubricants in the lubrication of rollers is reported.

Carlson, S.↗
NASA NTRS1973

Temperature measurements in sliding elastohydrodynamic point contacts

Techniques using the infrared radiation emitted by a sliding elastohydrodynamic (EHD) point contact to measure oil film and surface temperature are discussed. Temperature distributions in the EHD contact are presented for a naphthenic mineral oil at 1.04 GN/sq m (150,000 psi) Hertz pressure and several sliding velocities. Film temperatures as high as 360 C are reported at locations near the points of minimum film thickness in the contact side lobes.

Turchina, V.↗
NASA NTRS1975

Conclusions from the discussions on observational results of heterodyne spectroscopy in astronomy

Experimental results in astronomy obtained with the aid of infrared heterodyne detection techniques are considered, taking into account the detection of thermal emission with no dispersion at the intermediate frequency and observations involving molecular line detection. The tuning range of a heterodyne spectrometer and of a Fourier transform spectrometer is considered and attention is given to the selection of the appropriate technique for a specific investigative problem.-

Mumma, M.↗
NASA NTRS1977

Applied Remote Sensing Program (ARSP)

Descriptions of projects engaged by the Applied Remote Sensors Program in the state of Arizona are contained in an annual report for the fiscal year 1976-1977. Remote sensing techniques included thermal infrared imagery in analog and digital form and conversion of data into thermograms. Delineation of geologic areas, surveys of vegetation and inventory of resources were also presented.

Mouat, D. A.↗
NASA NTRS1977

Proceedings of the Eleventh International Symposium on Remote Sensing of Environment, volume 2

Application and processing of remotely sensed data are discussed. Areas of application include: pollution monitoring, water quality, land use, marine resources, ocean surface properties, and agriculture. Image processing and scene analysis are described along with automated photointerpretation and classification techniques. Data from infrared and multispectral band scanners onboard LANDSAT satellites are emphasized.

Source record↗
NASA NTRS1979

Post-shock temperatures in minerals

An experimental technique was developed for measuring post-shock temperatures in a wide variety of materials, including those of geophysical interest such as silicates. The technique uses an infrared radiation detector to determine the brightness temperature of samples shocked to pressures in the range 5 to approximately 30 GPa; in these experiments measurements were made in two wavelength ranges (4.5 to 5.75 microns and 7 to 14 microns). Reproducible results, with the temperatures in the two wavelength bands generally in excellent agreement, were obtained for aluminum-2024 (10.5 to 33 GPa, 125 to 260 C), stainless steel-304 (11.5 to 50 GPa, 80 to 350 C), crystalline quartz (5.0 to 21.5 GPa, 80 to 250 C), forsterite (7.5 to 28.0 GPa, approximately 30 to 160 C) and Bamble bronzite (6.0 to 26.0 GPa, approximately 30 to 225 C). It is concluded that release adiabat data should be used, wherever available, for calculations of residual temperature, and that adequate descriptions of the shock and release processes in minerals are more complex than generally assumed.

Raikes, S. A.↗
NASA NTRS1981

Ceramic and coating applications in the hostile environment of a high temperature hypersonic wind tunnel

A Mach 7, blowdown wind tunnel was used to investigate aerothermal structural phenomena on large to full scale high speed vehicle components. The high energy test medium, which provided a true temperature simulation of hypersonic flow at 24 to 40 km altitude, was generated by the combustion of methane with air at high pressures. Since the wind tunnel, as well as the models, must be protected from thermally induced damage, ceramics and coatings were used extensively. Coatings were used both to protect various wind tunnel components and to improve the quality of the test stream. Planned modifications for the wind tunnel included more extensive use of ceramics in order to minimize the number of active cooling systems and thus minimize the inherent operational unreliability and cost that accompanies such systems. Use of nonintrusive data acquisition techniques, such as infrared radiometry, allowed more widespread use of ceramics for models to be tested in high energy wind tunnels.

Puster, R. L.↗
NASA NTRS1980

Kinetics of the ClO + NO2 + M reaction

The ClO + NO2 + M reaction has been studied with two techniques: Fourier transform infrared spectroscopy of the products, and flash photolysis-ultraviolet absorption to monitor the decay of ClO in excess NO2. The measured third-order rate constant is 1.5 x 10 to the -31st cm to the 6th/molecule-squared per sec at 298 K with M = N2, in good agreement with previous literature values, but the rate constant appears to decrease by up to a factor of three in the presence of increasing amounts of OClO. For the infrared studies a stoichiometric mixture of ClO and NO2 was prepared in a flow system by mixing NO with OClO; at least as much NO2 as ClONO2 was produced under a variety of experimental conditions. These two sets of results are incompatible with the assumption made in previous kinetic studies that ClONO2 is the only recombination product; other isomers such as OClONO or ClOONO are likely to be formed three to four times faster. These results imply that potential stratospheric ozone depletion due to chlorofluoromethanes may be even larger than previously thought.

Molina, M. J.↗