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At least 343 records · Page 19

COMPLEX ORGANIC AND INORGANIC COMPOUNDS IN SHELLS OF LITHIUM-RICH K GIANT STARS

Hydrocarbon organic material, as found in the interstellar medium, exists in complex mixtures of aromatic and aliphatic forms. It is considered to originate from carbon-enriched giant stars during their final stages of evolution, when very strong mass loss occurs in a few thousand years on their way to becoming planetary nebulae. We show here that the same organic compounds appear to be formed in previous stages of the evolution of giant stars, more specifically, during the first-ascending giant branch K-type stars. According to our model, this happens only when these stars are being abruptly enriched with lithium, together with the formation of a circumstellar shell with a strong mass loss during just a few thousand years. This sudden mass loss is, on average, a thousand times larger than that of normal Li-poor K giant stars. This shell would later be detached, especially when the star stops its Li enrichment and a rapid photospheric Li depletion occurs. In order to gain extra carbon-based material to form the organic hydrocarbons, as well as to explain the presence of complex inorganic compounds in these stars, we propose an interaction of these strong winds with the remaining asteroidal/cometary disks that already existed around these stars since they were dwarf A-type stars. The mechanism of interaction presented here is successful in explaining the presence of inorganic compounds; however, it is unable to produce new carbon-free atoms to form the organic hydrocarbon compounds. Finally, we discuss some suggestions and speculations that can eventually help solve the long-standing puzzle of Li-rich giants.

79 ASTRONOMY AND ASTROPHYSICS↗

Laboratory simulation of organic grain mantles

Laboratory simulations have been conducted of interstellar space conditions conducive to grain mantle evolution, including the photoproduction of a material which resembles the organic refractory mantle on interstellar grains. Upon analysis by various methods these organic refractory samples are noted to consist of a complex mixture of long, cross-linked chains, with a high probability of being aromatic carbon molecules.

Mendoza-Gomez, Celia X.↗

Wetting of a Hydrophobic Surface: Far-IR Action Spectroscopy and Dynamics of Microhydrated Naphthalene

The interaction of water and polycyclic aromatic hydrocarbons is of fundamental importance in areas as diverse as materials science and atmospheric and interstellar chemistry. The interplay between hydrogen bonding and dipole–π interactions results in subtle dynamics that are challenging to describe from first principles. Here, we employ far-IR action vibrational spectroscopy with the infrared free-electron laser FELIX to investigate naphthalene with one to three water molecules. We observe diffuse bands associated with intermolecular vibrational modes that serve as direct probes of the loose binding of water to the naphthalene surface. These signatures are poorly reproduced by static DFT or Møller–Plesset computations. Instead, a rationalization is achieved through Born–Oppenheimer Molecular Dynamics simulations, revealing the active mobility of water over the surface, even at low temperatures. Therefore, our work provides direct insights into the wetting interactions associated with shallow potential energy surfaces while simultaneously demonstrating a solid experimental–computational framework for their investigation.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Far-UV spectroscopy of the planet-hosting star WASP-13: High-energy irradiance, distance, age, planetary mass-loss rate, and circumstellar environment

Several transiting hot Jupiters orbit relatively inactive main-sequence stars. For some of those, the logR{sub HK}{sup ′} activity parameter lies below the basal level (−5.1). Two explanations have been proposed so far: (i) the planet affects the stellar dynamo, (ii) the logR{sub HK}{sup ′} measurements are biased by extrinsic absorption, either by the interstellar medium (ISM) or by material local to the system. We present here Hubble Space Telescope/COS far-UV spectra of WASP-13, which hosts an inflated hot Jupiter and has a measured logR{sub HK}{sup ′} value (−5.26), well below the basal level. From the star’s spectral energy distribution we obtain an extinction E(B − V) = 0.045 ± 0.025 mag and a distance d = 232 ± 8 pc. We detect at ≳4σ lines belonging to three different ionization states of carbon (C i, C ii, and C iv) and the Si iv doublet at ∼3σ. Using far-UV spectra of nearby early G-type stars of known age, we derive a C iv/C i flux ratio–age relation, from which we estimate WASP-13's age to be 5.1 ± 2.0 Gyr. We rescale the solar irradiance reference spectrum to match the flux of the C iv 1548 doublet. By integrating the rescaled solar spectrum, we obtain an XUV flux at 1 AU of 5.4 erg s{sup −1} cm{sup −2}. We use a detailed model of the planet’s upper atmosphere, deriving a mass-loss rate of 1.5 × 10{sup 11} g s{sup −1}. Despite the low logR{sub HK}{sup ′} value, the star shows a far-UV spectrum typical of middle-aged solar-type stars, pointing toward the presence of significant extrinsic absorption. The analysis of a high-resolution spectrum of the Ca ii H and K lines indicates that the ISM absorption could be the origin of the low logR{sub HK}{sup ′} value. Nevertheless, the large uncertainty in the Ca ii ISM abundance does not allow us to firmly exclude the presence of circumstellar gas.

79 ASTRONOMY AND ASTROPHYSICS↗

ABSORBING GAS AROUND THE WASP-12 PLANETARY SYSTEM

Near-UV observations of the planet host star WASP-12 uncovered the apparent absence of the normally conspicuous core emission of the Mg II h and k resonance lines. This anomaly could be due either to (1) a lack of stellar activity, which would be unprecedented for a solar-like star of the imputed age of WASP-12 or (2) extrinsic absorption, from the intervening interstellar medium (ISM) or from material within the WASP-12 system itself, presumably ablated from the extreme hot Jupiter WASP-12 b. HIRES archival spectra of the Ca II H and K lines of WASP-12 show broad depressions in the line cores, deeper than those of other inactive and similarly distant stars and similar to WASP-12's Mg II h and k line profiles. We took high-resolution ESPaDOnS and FIES spectra of three early-type stars within 20' of WASP-12 and at similar distances, which show the ISM column is insufficient to produce the broad Ca II depression observed in WASP-12. The EBHIS H I column density map supports and strengthens this conclusion. Extrinsic absorption by material local to the WASP-12 system is therefore the most likely cause of the line core anomalies. Gas escaping from the heavily irradiated planet could form a stable and thick circumstellar disk/cloud. The anomalously low stellar activity index ( log R{sup '}{sub HK}) of WASP-12 is evidently a direct consequence of the extra core absorption, so similar HK index deficiencies might signal the presence of translucent circumstellar gas around other stars hosting evaporating planets.

79 ASTRONOMY AND ASTROPHYSICS↗

Supernovae, young remnants, and nucleosynthesis

Chemical abundance data from extragalactic supernovae and from supernova remnants (SNR) less than 1000 yrs old are employed to show that nuclear burning beyond helium synthesis actually occurs. Supernova (SN) are classified into types I or II, having no hydrogen lines or featuring hydrogen lines, respectively. The SN I's have been observed as having a preponderance of Fe lines, and emitting from a source at around 12,000 K with a center continuum of approximately 10 AU. Decay chains which could account for detected luminosities and spectra are presented, noting a good fit of Fe II spectrum with observed SN spectra. SNR pass through younger and older stages, going from the outpouring of material to diffusion in the interstellar medium. Expanding flocculi from young SNR show oxygen abundances as well as lines from sulfur, calcium, and argon, with a corresponding necessity of an explosive source of 15 solar masses.

Kirshner, R. P.↗

The chemical composition of comets and possible contribution to planet composition and evolution

The theory of cold aggregation of interstellar dust into comets is shown to support the ideas that comets provided not only a substantial part of the earth's water but also of its complex organic surface material. Comparison of the density of interstellar dust with meteor densities leads to the conclusion that comets are very fluffy bodies whose solid matter occupies no more than 2/5 of the total volume and possibly substantially less. This implies an extremely low comet albedo of about 0.05 in the visual even for slightly absorbing individual components.

Greenberg, J. Mayo↗

The origin of the galactic emission in IRAS data

Using the high resolution IRAS data and the radial distribution of gaseous material and those of the interstellar radiation field (ISRF), a model of the Galactic infrared emission was built. The first step consisted of a separation of the diffuse emission in IRAS data from that of the well-defined strong Galactic sources. A well accepted idea is that IR emission comes from dust heated either by the ISRF and/or by internal cloud heating sources. Thus the IR galactic emission was modelled from radial distributions of gas and ISRF and the following three main hypothesis: (1) the dust-to-gas ration is the same in the whole Galaxy; (2) IR emission is proportional to local dust density; and (3) IR emission is also proportional to the local ISRF. The IR emission as modelled was integrated over each line of sight and compared with observed IRAS data. The results show that the IR diffuse component comes from dust associated with H1 and heated by the general ISRF. For the dust embedded in cold H2 component, the heating source is also the general ISRF while the warm component is explained by dust embedded in molecular clouds and heated by high-mass stars born in the close vicinity of the clouds and by disc population ISRF.

Caux, Emanuel↗

Chemically anomalous, pre-accretionally irradiated grains in interplanetary dust -- interstellar grains?

Ultrafine-grained matrix is a unique and fundamental building block of chondritic porous (CP) interplanetary dust particles. Most IDPs so far determined to be of cometary origin belong to the CP class. The matrix in CP IDPs is not homogeneous but rather a loose mixture of discrete single crystals (e.g., olivine, pyroxene, Fe sulfides) and polyphase grains. The petrographic diversity observed among the polyphase grains suggest that they were formed under variable physiochemical conditions. One particular class of polyphase grains are a dominant component in cometary IDPs. Although their occurrence is well documented, the terminology used to describe them is confused. They have been called many names. Here they are simply called GEMS (Glass with Embedded Metal and Sulfides). The bulk compositions of GEMS are within a factor of 3 chondritic (solar) for all major elements except C. Quantitative thin-film X-ray (EDS) analyses have shown that GEMS are systematically depleted in Mg and Si, enriched in S, Fe, and Ni, and stoichiometrically enriched in O. Electron energy-loss spectroscopy (EELS) suggests that the excess O is present as hydroxyl (-OH) groups. These same chemical 'anomalies' were observed in solar-wind-irradiated amorphous rims on the surfaces of IDPs, suggesting that the compositions of GEMS reflect prior exposure to ionizing radiation. In order to test this hypothesis, a sample of Allende (CV3) matrix was exposed to proton flux. Radiation-damaged amorphous rims on olivine and pyroxene crystals in the Allende sample were found to be depleted in Mg and Ca, enriched in S, Fe, and Ni, and stoichiometrically enriched in O. Thus, the compositions of GEMS are indeed consistent with exposure to ionizing radiation. This study suggests that chemical as well as isotopic anomalies may be used to identify presolar interstellar grains in primitive meteoritic materials.

Bradley, J. P.↗

Light-Hydrocarbon Bearing Solids on Planetesimal 5145 Pholus

Object 5145 Pholus (=1992 AD) is a planetesimal in an orbit that crosses those of Saturn, Uranus, and Neptune (period 92.7 years). It is particularly notable because of its extreme red color, corroborated by several observing teams. A spectrum of Pholus obtained in 1992 shows a strong absorption band with a characteristic shape at 2.27 micrometers, plus a weaker band at 1.7 micrometers. A better spectrum of the 2.0-2.5 micrometer region in 1993 confirms the position and shape of the 2.27-micrometer band. The color and spectral bands are identified with the aliphatic-rich and high H/C organic solid called asphaltite, which in a terrestrial setting originates from thermal processing of products of biological activity. In Pholus, this material is attributed to formation from radiation processing of ices on grains in the interstellar medium. Laboratory spectra of asphaltite and related materials have been published by Moroz et al., while Cloutis showed similar bands in comparable materials and identified them as the overtone and combination bands of C-H stretching and bending modes in CH2 and CH3 groups. Asphaltites, kerites, and anthraxolites are solid non-graphite members of a sequence ranging from oil to graphite; diffuse reflectance spectra of suites of these intermediate materials show color characteristics similar to those of the low-albedo asteroids (C,P,D), although specific identifications have not been made because of the lack of distinct absorption bands in the spectra of most low-albedo solar system bodies. In the case of Pholus, however, the primary band is strong; its wavelength and its shape, plus the match of the extremely red color, leads us to the identification of aliphatic-rich, asphaltite-like organic solid. The C, P, and D-type asteroids vary in degree of "redness", but are all less red than Pholus. Pholus and the Ctype asteroids are the end members of a sequence that represents the radiation processing of hydrocarbons, with Pholus being the least processed. Solar irradiation processes and heating reduce the H/C and aliphatic content of hydrocarbons preserved from the interstellar medium, and in the end produce opaque solids of neutral reflectance, including the kerogens (similar to anthraxolites) found in profusion in the carbonaceous meteorites.

Cruikshank, Dale P.↗

Light-Hydrocarbon Bearing Solids on Planetesimal 5145 Pholus

Object 5145 Pholus (=1992 AD) is a planetesimal in an orbit that crosses those of Saturn, Uranus, and Neptune (period 92.7 years). It is particularly notable because of its extreme red color, corroborated by several observing teams. A spectrum of Pholus obtained in 1992 shows a strong absorption band with a characteristic shape at 2.27 micron, plus a weaker band at 1.7 microns. A better spectrum of the 2.0-2.5 micron region in 1993 confirms the position and shape of the 2.27 micron band. The color and spectral bands are identified with the aliphatic-rich and high H/C organic solid called asphaltite, which in a terrestrial setting originates from thermal processing of products of biological activity. In Pholus, this material is attributed to formation from radiation processing of ices on grains in the interstellar medium. Laboratory spectra of asphaltite and related materials have been published by Moroz et al., while Cloutis showed similar bands in comparable materials and identified them as the overtone and combination bands of C-H stretching and bending modes in CH2 and CH3 groups. Asphaltites, kerites, and anthraxolites are solid non-graphite members of a sequence ranging from oil to graphite; diffuse reflectance spectra of suites of these intermediate materials show color characteristics similar to those of the low-albedo asteroids (C,P,D), although specific identifications have not been made because of the lack of distinct absorption bands in the spectra of most low-albedo solar system bodies. In the case of Pholus, however, the primary band is strong; its wavelength and its shape, plus the match of the extremely red color, leads us to the identification of aliphatic-rich, asphaltite-like organic solid. The C, P, and D-type asteroids vary in degree of 'redness', but are all less red than Pholus. Pholus and the C-type asteroids are the end members of a sequence that represents the radiation processing of hydrocarbons, with Pholus being the least processed. Solar irradiation processes and heating reduce the H/C and aliphatic content of hydrocarbons preserved from the interstellar medium, and in the end produce opaque solids of neutral reflectance, including the kerogens (similar to anthraxolites) found in profusion in the carbonaceous meteorites.

Cruikshank, Dale P.↗

Website for the Astrochemistry Laboratory, Astrophysics Branch, Space Sciences Division

The Astrochemistry Laboratory in the Astrophysics Branch (SSA) of the Space Sciences Division at NASA's Ames Research Center specializes in the study of extraterrestrial materials and their analogs. The staff has pioneered laboratory studies of space environments including interstellar, cometary, and planetary ices, simulations of the so-called 'Unidentified' Infrared Emission Bands and Diffuse Interstellar Bands using PAHs (Polycyclic Aromatic Hydrocarbons) and PAH-related materials, and has extensive experience with low-temperature spectroscopy and astronomical observation. Important discoveries made by the Astrochemistry Group include: (1) The recognition that polycyclic aromatic hydrocarbons and their ions are common in space; (2) The identification of a major fraction of the known molecular species frozen in interstellar/pre-cometary ices; (3) The recognition that a significant fraction of the carbon in the interstellar medium is carried by both microdiamonds and organic materials; (4) The expansion of the types of molecules expected to be synthesized in interstellar/pre-cometary ices. These could be delivered to the early Earth (or other body) and influence the origin or early evolution of life.

Sandford, Scott↗

A speckle hologram of the interstellar plasma

Observations of a speckle hologram of scattering material along the line of sight to the Vela pulsar indicate that this material is concentrated in the Vela supernova remnant, deep within the Gum Nebula. The speckle hologram is observed through the amplitude and phase variations of the interferometric cross-power spectrum with time and frequency. These variations describe the density fluctuations of the interstellar plasma, in a holographic fashion. The decorrelation due to the phase variations of the speckles yields the angular size of the scattering disk; comparison with the bandwidth of their amplitude variations yields a characteristic distance from earth to the scattering material of 0.81 +/- 0.03 of the distance from earth to the pulsar. This result is consistent with theories of irregularities associated with particle acceleration in shocks in supernova remnants.

Desai, K. M.↗

The Origin, Composition and History of Comets from Spectroscopic Studies

A wealth of information essential to understanding the composition and physical structure of cometary ice and hence gain deep insight into the comet's origin and history, can be gleaned by carrying out a full range of spectroscopic studies on the returned sample. These studies ought to be among the first performed as they are generally non-destructive and will provide a broad data bank which will be crucial in planning subsequent analysis. Examples of the spectroscopic techniques along with relative sensitivities and transitions probed, are discussed. Different kind of "spectroscopy" is summarized, with emphasis placed on the kind of information each provides. Infrared spectroscopy should be the premier method of analysis as the mid-IR absorption spectrum of a substance contains more global information about the identity and structure of that material than any other property. In fact, the greatest strides in our understanding of the composition of interstellar ices (thought by many to be the primordial material from which comets have formed) have been taken during the past ten years or so because this was when high quality infrared spectra of the interstellar medium (ISM) first became available. The interpretation of the infrared spectra of mixtures, such as expected in comets, is often (not always) ambiguous. Consequently, a full range of other non-destructive, complementary spectroscopic measurements are required to fully characterize the material, to probe for substances for which the IR is not well suited and to lay the groundwork for future analysis. Given the likelihood that the icy component (including some of the organic and mineral phases) of the returned sample will be exceedingly complex, these techniques must be intensely developed over the next decade and then made ready to apply flawlessly to what will certainly be one of the most precious, and most challenging, samples ever analyzed.

Allamandola, L. J.↗

Investigating the Geological History of Asteroid 101955 Bennu Through Remote Sensing and Returned Sample Analyses

The NASA New Frontiers Mission OSRIS-REx will return surface regolith samples from near-Earth asteroid 101955 Bennu in September 2023. This target is classified as a B-type asteroid and is spectrally similar to CI and CM chondrite meteorites [1]. The returned samples are thus expected to contain primitive ancient Solar System materials that formed in planetary, nebular, interstellar, and circumstellar environments. Laboratory studies of primitive astromaterials have yielded detailed constraints on the origins, properties, and evolutionary histories of a wide range of Solar System bodies. Yet, the parent bodies of meteorites and cosmic dust are generally unknown, genetic and evolutionary relationships among asteroids and comets are unsettled, and links between laboratory and remote observations remain tenuous. The OSIRIS-REx mission will offer the opportunity to coordinate detailed laboratory analyses of asteroidal materials with known and well characterized geological context from which the samples originated. A primary goal of the OSIRIS-REx mission will be to provide detailed constraints on the origin and geological and dynamical history of Bennu through coordinated analytical studies of the returned samples. These microanalytical studies will be placed in geological context through an extensive orbital remote sensing campaign that will characterize the global geological features and chemical diversity of Bennu. The first views of the asteroid surface and of the returned samples will undoubtedly bring remarkable surprises. However, a wealth of laboratory studies of meteorites and spacecraft encounters with primitive bodies provides a useful framework to formulate priority scientific questions and effective analytical approaches well before the samples are returned. Here we summarize our approach to unraveling the geological history of Bennu through returned sample analyses.

Messenger, S.↗

Meteoritic silicon carbide - Pristine material from carbon stars

All five gases in interstellar silicon carbide grains have grossly nonsolar isotopic and elemental abundances that vary with grain size but are strikingly similar to calculated values for the helium-burning shell of low-mass carbon stars. Apparently these grains formed in carbon-star envelopes, and were impregnated with noble gas ions from a stellar wind. Meteoritic SiC provides a detailed record of nuclear and chemical processes in carbon stars.

Lewis, Roy S.↗

Interstellar grain chemistry and organic molecules

The detection of prominant infrared absorption bands at 3250, 2170, 2138, 1670 and 1470 cm(-1) (3.08, 4.61, 4.677, 5.99 and 6.80 micron m) associated with molecular clouds show that mixed molecular (icy) grain mantles are an important component of the interstellar dust in the dense interstellar medium. These ices, which contain many organic molecules, may also be the production site of the more complex organic grain mantles detected in the diffuse interstellar medium. Theoretical calculations employing gas phase as well as grain surface reactions predict that the ices should be dominated only by the simple molecules H2O, H2CO, N2, CO, O2, NH3, CH4, possibly CH3OH, and their deuterated counterparts. However, spectroscopic observations in the 2500 to 1250 cm(-1)(4 to 8 micron m) range show substantial variation from source reactions alone. By comparing these astronomical spectra with the spectra of laboratory-produced analogs of interstellar ices, one can determine the composition and abundance of the materials frozen on the grains in dense clouds. Experiments are described in which the chemical evolution of an interstellar ice analog is determined during irradiation and subsequent warm-up. Particular attention is paid to the types of moderately complex organic materials produced during these experiments which are likely to be present in interstellar grains and cometary ices.

Allamandola, L. J.↗

Interstellar Precursors of Meteoritic Organics

The organic inventory initially available to protostellar disks is the first step on the long chemical path to the development of Life. The early earth may have obtained most its volatile material from the arrival of meteorites and comets at its surface. Determining the most likely distribution of meteoritic and cometary organic molecules that could seed primitive planets is a major goal since it sets the initial conditions for, at least part of, the phase of prebiotic chemical evolution. Observations and measurements of the chemical composition of primitive Solar System organics, and of dense molecular clouds, should allow the construction of coherent theoretical picture of the development of organic complexity from interstellar biogenic material to the beginning of prebiotic evolution.

Charnley, S. B.↗