Magnetic phase diagram of Cs3Cu2C17.2H20
Magnetic phase diagram of hydrated cesium-copper carbide at 1.625 Neel temperature in external magnetic fields, giving equation for spin flop field temperature dependence
Butterworth, G. J.↗
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Results for “Hydrate”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Carbon dioxide clathrate in the Martian ice cap
Carbon dioxide clathrate in Martian ice cap suggested from hydrate stability relative to solid phase and water ice as function of temperature
Miller, S. L.↗
Phase transitions and magnetostriction in CsMnCl3.2H2O
Magnetostriction in hydrated cesium manganese chloride, examining dimensional changes as function of magnetic field and temperature through antiferromagnetic, spin flopped and paramagnetic phases
Aron, P. R.↗
Exercise temperature regulation in man during hypohydration and hyperhydration
Human body temperature regulation under various hydration regimes during exercise, noting changes related to sweating
Castle, B. L.↗
Magnetostriction, thermal expansion, and phase transitions in CsMnCl3.2H2O
Magnetostriction in antiferromagnetic, spin flopped and paramagnetic phases of hydrated cesium manganese trichloride, studying volume changes and thermal expansion near phase transition
Aron, P. R.↗
Infrared and Raman spectroscopic studies of structural variations in minerals from Apollo 11, 12, 14 and 15 samples, volume 3
Infrared and Raman vibrational spectroscopic data, yielding direct information on molecular structure, were obtained for single grains ( 150 microns) of minerals, basalts, and glasses isolated from Apollo 11, 12, 14, and 15 rock and dust samples, and for grains in Apollo 14 polished butt samples. From the vibrational data, specification substitutions were determined for the predominant silicate minerals of plagioclase, pyroxene, and olivine. Unique spectral variations for grains of K-feldspar, orthopyroxene, pyroxenoid, and ilmenite were observed to exceed the ranges of terrestrial samples, and these variations may be correlatable with formation histories. Alpha-quartz was isolated as pure single grains, in granitic grains composited with sanidine, and in unique grains that were intimately mixed with varying amounts of glass. Accessory minerals of chromite and ulvospinel were isolated as pure grains and structurally characterized from their distinctive infrared spectra. Fundamental vibrations of the SiO4 tetrahedra in silicate minerals were used to classify bulk compositions in dust sieved fractions, basalt grains and glass particles, and to compare modal characteristics for maria, highland and rille samples. No hydrated minerals were found in any of the samples studied, indicating anhydrous formation conditions.
Estep, P. A.↗
Measurements of recombination of electrons with H3O(plus)-(H2O)n series ions
Recombination coefficients of electrons with ions of the hydrated hydronium ion series (H3O(+))(H2O)n, where n = 0, 1, 2, 3, 4, 5, 6, were determined with a microwave afterglow/mass spectrometer apparatus. Afterglow measurements of electron density decays in helium-water vapor mixtures are correlated with the decay of mass-identified ion currents to the wall of the microwave cavity. By varying the temperature of the gas and the partial pressure of the water vapor in the mixture, different groups of hydronium series ions are made to dominate the afterglow.
Leu, M. T.↗
Effect of surface moisture on dielectric behavior of ultrafine BaTiO3 particulates.
The effects of adsorbed H2O on the dielectric properties of ultrafine BaTiO3 particulates of varying particle size and environmental history were determined. The dielectric behavior depends strongly on surface hydration. No particle size dependence of dielectric constant was found for dehydroxylated surfaces in ultrafine particulate (unsintered) BaTiO3 materials. For equivalent particle sizes, the ac conductivity is sensitive to surface morphology. Reactions with H2O vapor appear to account for the variations in dielectric properties. Surface dehydration was effectively accomplished by washing as-received powders in isopropanol.
Mountvala, A. J.↗
The relationship of theory and experiment in the D-region.
To monitor the descriptive parameters of the lower ionosphere and construct a model which predicts their temporal and spatial variations is a particularly difficult task. In a given situation simultaneous measurements should be conducted of ionization sources, the altitude distribution of all neutral atmospheric constituents, the identification, number density, and altitude distribution of different species of positive and negative ions and electrons. These results are compared with theoretical predictions to serve as boundary conditions and guides to modification of the theory. It has not been possible to realize this goal in lower ionosphere research because of the large number of parameters and since certain parameters, such as positive ion species distribution and nitric oxide, can only be measured with the aid of sounding rockets. To illustrate the difficulty, recent positive ion composition measurements are compared with predictions utilizing clustering of ions and neutrals to form hydrated ions.
Aikin, A. C.↗
Rubber composition compatible with hydrazine
Formulation improves compatibility of butyl rubbers with hydrazine while reducing permeation to low levels necessary for prolonged storage in space. This is accomplished by replacing carbon-black filler with inert materials such as hydrated silica or clay. Pressure increases suggest that hydrazine is decomposed only slightly by new type of rubber.
Repar, J.↗
Nature and Origin of Cometary Heads
In cometary spectra the three major constituents seem to be OH, H, and O. Their common precursor is likely to be water, whose rates of evaporation and dissociation have so far not led to a major discrepancy with the observations. This type of explanation, however, has not led to a positive identification of other parent molecules. With the known solar intensities, all the molecules that have been suggested, as NH3, CH4, etc, would lead to lifetimes one-to-two orders of magnitude larger than needed by the coma observations. An alternate hypothesis is that the precursors are not molecules, but icy particles stripped from the nucleus by the evaporating gases. By evaporating within an icy halo, the grains would liberate either parent molecules with very short lifetimes or some of the radicals themselves. Recent laboratory work suggests that the grains could be made of clathrate hydrates of gases or of radicals. The observations appear to indicate the presence of icy grains within the inner coma.
Delsemme, A. H.↗
High altitude infrared spectroscopic evidence for bound water on Mars.
The reflectivity of the Martian surface has been measured between 2.0 and 4.0 microns. A broad absorption band is observed which has a minimum at 2.85 microns. The position and shape of the band is compared to features in numerous terrestrial minerals. Bound water in the Martian surface material is the most likely cause of the observed band. The strength of the observed band suggests a bound water content of approximately 1% by weight. The band is inconsistent with more than a few % limonite or hydrated polymeric carbon suboxide. A mean particle radius of about 100 microns is deduced. The quality of bound water derived has a range of geological, climatic, and exobiological implications.
Houck, J. R.↗
Batteries for storage of wind-generated energy
Cost effectiveness characteristics of conventional-, metal gas-, and high energy alkali metal-batteries for wind generated energy storage are considered. A lead-acid battery with a power density of 20 to 30 watt/hours per pound is good for about 1500 charge-discharge cycles at a cost of about $80 per kilowatt hour. A zinc-chlorine battery that stores chlorine as solid chlorine hydrate at temperatures below 10 C eliminates the need to handle gaseous chlorine; its raw material cost are low and inexpensive carbon can be used for the chlorine electrode. This system has the best chance to replace lead-acid. Exotic alkali metal batteries are deemed too costly at the present stage of development.
Schwartz, H. J.↗
An unusual meteor spectrum
An extraordinary spectrum of a meteor at a velocity of about 18.5 + or - 1.0 km/s was observed with an image orthicon camera. The radiant of the meteor was at an altitude of about 49 deg. It was first seen showing a yellow red continuous spectrum alone at a height of 137 + or - 8 km which is ascribed to the first positive group of nitrogen bands. After the meteor had descended to 116 + or - 6 km above sea level it brightened rapidly from its previous threshold brightness into a uniform continuum, the D-line of neutral sodium appeared, and at height 105 + or - 5 km all the other lines of the spectrum also appeared. The continuum remained dominant to the end. Water of hydration and entrained carbon flakes of characteristic dimension about 0.2 micron or less are proposed as constituents of the meteoroid to explain these phenomena.
Cook, A. F.↗
Interior and its implications for the atmosphere
The bulk composition and interior structure of Titan required to explain the presence of a substantial methane atmosphere are shown to imply the presence of solid CH4 - 7H2O in Titan's primitive material. Consideration of the possible composition and structure of the present atmosphere shows plausible grounds for considering models with total atmospheric pressures ranging from approximately 20 mb up to approximately 1 kb. Expectations regarding the physical state of the surface and its chemical composition are strongly conditioned by the mass of atmosphere believed to be present. A surface of solid CH4, liquid CH4 solid, CH4 hydrate, H2O ice, aqueous NH3 solution, or even a non-surface of supercritical H2O-NH3-CH4 fluid could be rationalized.
Lewis, J. S.↗
Investigations in space-related molecular biology
Improved instrumentation and preparation techniques for high resolution, high voltage cryo-electron microscopic and diffraction studies on terrestrial and extraterrestrial specimens are reported. Computer correlated ultrastructural and biochemical work on hydrated and dried cell membranes and related biological systems provided information on membrane organization, ice crystal formation and ordered water, RNA virus linked to cancer, lunar rock samples, and organometallic superconducting compounds. Apollo 11, 12, 14, and 15 specimens were analyzed
Fernandez-Moran, H.↗
Organic compounds in meteorites
The problem of whether organic compounds originated in meteorites as a primary condensate from a solar gas or whether they were introduced as a secondary product into the meteorite during its residence in a parent body is examined by initially attempting to reconstruct the physical conditions during condensation (temperature, pressure, time) from clues in the inorganic matrix of the meteorite. The condensation behavior of carbon under these conditions is then analyzed on the basis of thermodynamic calculations, and compounds synthesized in model experiments on the condensation of carbon are compared with those actually found in meteorites. Organic compounds in meteorites seem to have formed by catalytic reactions of carbon monoxide, hydrogen, and ammonia in the solar nebula at 360 to 400 K temperature and about 3 to 7.6 microtorr pressure. The onset of these reactions was triggered by the formation of suitable catalysts (magnetite, hydrated silicates) at these temperatures.
Anders, E.↗
Water and carbon in rusty lunar rock 66095
The reported study of the lunar rock 66095 included the determination of hydrogen, carbon, and oxygen isotope ratios. One group of experiments with rock 66095 and meteoritic rust involved the examination of the O-18 content of the oxygen in the ferric oxide found on the rock and the determination of the O-18 content in the oxygen of the adsorbed or hydration water. It is suggested that the enrichment of the rock 66095 in volatile materials is caused by volcanic or fumarolic activity. Water released by such activity may be juvenile lunar water.
Friedman, I.↗