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At least 343 records · Page 19

Stratospheric Tracers of Atmospheric Transport (STRAT) Campaign: ER-2 Participation

The NASA Stratospheric Tracers of Atmospheric Transport (STRAT) mission was initiated to advance knowledge of the major transport mechanisms of the upper troposphere-lower stratosphere. This is the region of the atmosphere within which exchange processes take place that critically determine the response of the climate system and ozone distribution to changing conditions triggered by the release of chemicals at the surface. The mission series that extended from October 1995 to November 1997 was extremely successful. The scientific advances that emerged from that mission include analyses of: (1)troposphere-to-stratosphere transport in the lowermost stratosphere from measurements of H2O, CO2, N2O, and O3; (2) the effects of tropical cirrus clouds on the abundance of lower stratospheric ozone; and (3) the role of HO(x) in super- and subsonic aircraft exhaust plumes; and dehydration and denitrification in the arctic polar vortex during the 1995-96 winter.

Anderson, James G.↗

Hydrogen Radicals, Nitrogen Radicals, and the Production of O3 in the Upper Troposphere

The concentrations of the hydrogen radicals OH and HO2 in the middle and upper troposphere were measured simultaneously with those of NO, O3, CO, H2O, CH4, non-methane hydrocarbons, and with the ultraviolet and visible radiation field. The data allow a direct examination of the processes that produce O3 in this region of the atmosphere. Comparison of the measured concentrations of OH and HO2 with calculations based on their production from water vapor, ozone, and methane demonstrate that these sources are insufficient to explain the observed radical concentrations in the upper troposphere. The photolysis of carbonyl and peroxide compounds transported to this region from the lower troposphere may provide the source of HO, required to sustain the measured abundances of these radical species. The mechanism by which NO affects the production Of O3 is also illustrated by the measurements. In the upper tropospheric air masses sampled, the production rate for ozone (determined from the measured concentrations of HO2 and NO) is calculated to be about I part per billion by volume each day. This production rate is faster than previously thought and implies that anthropogenic activities that add NO to the upper troposphere, such as biomass burning and aviation, will lead to production of more 03 than expected.

Wennberg, P. O.↗

Stratospheric Tracers of Atmospheric Transport (STRAT) Campaign: ER-2 Participation

The NASA Stratospheric Tracers of Atmospheric Transport (STRAT) mission was initiated to advance knowledge of the major transport mechanisms of the upper troposphere-lower stratosphere. This is the region of the atmosphere within which exchange processes take place that critically determine the response of the climate system and ozone distribution to changing conditions triggered by the release of chemicals at the surface. The mission series that extended from October 1995 to November 1997 was extremely successful. The scientific advances that emerged from that mission include analyses of: (1) troposphere-to-stratosphere transport in the lowermost stratosphere from measurements of H2O, CO2, N2O, and O3; (2) the effects of tropical cirrus clouds on the abundance of lower stratospheric ozone; (3) the role of HO(sub x) in super- and subsonic aircraft exhaust plumes; and (4) dehydration and denitrification in the arctic polar vortex during the 1995-96 winter. The abstracts from published papers are included.

Anderson, James G.↗

Hydrogen Radicals, Nitrogen Radicals, and the Production of O3 in the Upper Troposphere

The concentrations of the hydrogen radicals OH and HO2 in the middle and upper troposphere were measured simultaneously with those of NO, O3, CO, H2O, CH4, non-methane hydrocarbons, and with the ultraviolet and visible radiation field. The data allow a direct examination of the processes that produce O3 in this region of the atmosphere. Comparison of the measured concentrations of OH and HO2 with calculations based on their production from water vapor, ozone, and methane demonstrate that these sources are insufficient to explain the observed radical concentrations in the upper troposphere. The photolysis of carbonyl and peroxide compounds transported to this region from the lower troposphere may provide the source of HO(sub x) required to sustain the measured abundances of these radical species. The mechanism by which NO affects the production of O3 is also illustrated by the measurements. In the upper tropospheric air masses sampled, the production rate for ozone (determined from the measured concentrations of HO2 and NO) is calculated to be about 1 part per billion by volume each day. This production rate is faster than previously thought and implies that anthropogenic activities that add NO to the upper troposphere, such as biomass burning and aviation, will lead to production of more O3 than expected.

Wennberg, P. O.↗

Hydrogen Radicals, Nitrogen Radicals, and the Production of O3 in the Upper Troposphere

The concentrations of the hydrogen radicals OH and HO2 in the middle and upper troposphere were measured simultaneously with those of NO, O3, CO, H2O, CH4, non-methane hydrocarbons, and with the ultraviolet and visible radiation field. The data allow a direct examination of the processes that produce O3, in this region of the atmosphere. Comparison of the measured concentrations of OH and HO2 with calculations based on their production from water vapor, ozone, and methane demonstrate that these sources are insufficient to explain the observed radical concentrations in the upper troposphere. The photolysis of carbonyl and peroxide compounds transported to this region from the lower troposphere may provide the source of HO(x) required to sustain the measured abundances of these radical species. The mechanism by which NO affects the production of 03 is also illustrated by the measurements. In the upper tropospheric air masses sampled, the production rate for ozone (determined from the measured concentrations of HO2 and NO) is calculated to be about 1 part per billion by volume each day.This production rate is faster than previously thought and implies that anthropogenic activities that add NO to the upper troposphere, such as biomass burning and aviation, will lead to production of more 03 than expected.

Wennberg, P. O.↗

Interferometric Images of the Sunyaev - Zel'dovich Effect in Galaxy Clusters from z = 0.15 to z = 0.83

We describe the current results of a sensitive interferometric imaging survey of the Sunyaev-Zel'dovich effect towards distant galaxy clusters. Images of the Sunyaev-Zel'dovich effect -- a minute distortion imprinted on the cosmic microwave background radiation by scattering within the hot gaseous envelopes of galaxy clusters -- are obtained using 30 GHz receivers at the OVRO and BIMA millimeter interferometers; with these highly sensitive receivers and the interferometric method's natural suppression of many systematic errors, we have obtained high quality images of 18 clusters with redshifts ranging from Z = 0.l5 to 0.83, with a sensitivity of 25 microkelvin. When combined with x-ray imaging and spectroscopic data, analysis of these S-Z images provides an independent measurement of the cosmic distance scale Results from a joint analysis of the X-ray and S-Z data will be presented, and we will describe the constraints that S-Z effect measurements can ultimately place on Ho and Omega.

Joy, Marshall K.↗

Stratospheric Tracers of Atmospheric Transport (STRAT) Campaign: ER-2 Participation

The NASA Stratospheric Tracers of Atmospheric Transport (STRAT) mission was initiated to advance knowledge of the major transport mechanisms of the upper troposphere-lower stratosphere. This is the region of the atmosphere within which exchange processes take place that critically determine the response of the climate system and ozone distribution to changing conditions triggered by the release of chemicals at the surface. The mission series that extended from October 1995 to November 1997 was extremely successful. The scientific advances that emerged from that mission include analyses of- troposphere-to-stratosphere transport in the lowermost stratosphere from measurements of H2O, CO2, N2O, and O3; the effects of tropical cirrus clouds on the abundance of lower stratospheric ozone; the role of HO, in super- and subsonic aircraft exhaust plumes; and dehydration and denitrification in the arctic polar vortex during the 1995-96 winter.

Anderson, James G.↗

SONEX Airborne Mission and Coordinated POLINAT-2 Activity: Overview and Accomplishments

The SASS (Subsonic Assessment) Ozone and NO(x) Experiment (SONEX) was an airborne field campaign conducted in October-November 1997 in the vicinity of the North Atlantic Flight Corridor Lo study the impact of aircraft emissions on NOx and ozone (03). A fully instrumented NASA DC-8 aircraft was used as the primary SONEX platform. SONEX activities were closely coordinated with the European POLINAT-2 (Pollution from Aircraft Emissions in the North Atlantic Flight Corridor) program, which used a Falcon-20 aircraft and an instrumented in-service Swissair B-747. Both campaigns focused on the upper troposphere/"lowermost" stratosphere (UT/LS) as the region of greatest interest. Specific sampling goals were achieved with the aid of a state-of-the art modeling and meteorological support system, which allowed targeted sampling of air parcels with desired characteristics. A substantial impact of aircraft emissions on NO(x) and O3 in the UT/LS of the study region is shown to be present. It is further shown that the NO(x)- HO(x)-O3 relationships are highly nonlinear and must be accurately simulated to make meaningful future predictions with global models. SONEXIPOLINAT-2 results are being published in Special Sections of GRL and JGR. Here we provide a brief overview of SONEX design, implementation, and expected results to provide a context within which these publications can be understood.

Singh, Hanwant B.↗

The Influence of Extremely Large Solar Proton Events in a Changing Stratosphere. Stratospheric Influence of Solar Proton Events

Two periods of extremely large solar proton events (SPEs) occurred in the past thirty years, which forced significant long-term polar stratospheric changes. The August 2-10, 1972 and October 19-27, 1989 SPEs happened in stratospheres that were quite different chemically. The stratospheric chlorine levels were relatively small in 1972 (approximately 1.2 ppbv) and were fairly substantial in 1989 at about (approximately 3 ppbv). Although these SPEs produced both HO(x) and NO(y) constituents in the mesosphere and stratosphere, only the NO(y) constituents had lifetimes long enough to affect ozone for several months to years past the events. Our recently improved two-dimensional chemistry and transport atmospheric model was used to compute the effects of these gigantic SPEs in a changing stratosphere. Significant upper stratospheric ozone depletions > 10% are computed to last for a few months past these SPEs. The long-lived SPE-produced NO(y) constituents were transported to lower levels during winter after these huge SPEs and caused impacts in the middle and lower stratosphere. During periods of high halogen loading these impacts resulted in interference with the chlorine and bromine loss cycles for ozone destruction. The chemical state of the atmosphere, including the stratospheric sulfate aerosol density, substantially affected the predicted stratospheric influence of these extremely large SPEs.

Jackman, Charles H.↗

End of Project Report

Nonmethane hydrocarbons (NMHCs) and halocarbons were measured in the troposphere over the northwestern Pacific as part of the airborne component of NASA's Pacific Exploratory Mission-West Phase B (PEM-West B). This study took place in late winter of 1994, a period characterized by maximum outflow from the Asian continent. The results are compared to those from Pacific Exploratory Mission-West Phase A (PEM-West A), which was flown in the same region during late summer of 1991, when flow from the subtropical western Pacific dominated the lower troposphere. Mixing ratios of NMHCS, tetrachloroethene (C2Cl4), and methyl bromide (CH3Br) were significantly higher during PEM-West B than during PEM-West A, particularly at latitudes north of 25 N and altitudes lower than 6 km. The primary reasons for these higher ambient concentrations were the seasonal increase in the atmospheric lifetimes of trace gases controlled by HO radical reactions, and the more frequent input of continental air masses. During PEM-West B, air masses of continental origin observed north of 25 N latitude were augmented with urban signature gases such as C2Cl4. By contrast, more southerly continental outflow had characteristics associated with combustion sources such as biomass burning, including wood fuel burning. During the summer PEM-West A period, the spatial distribution of methyl iodide (CH3I) was consistent with effective oceanic sources at all latitudes, being especially strong in tropical and subtropical regions. At low latitudes, PEM-West B CH3I mixing ratios in the lower troposphere were similar to PEM-West A, but at latitudes greater than about 25 N PEM-West B concentrations were significantly reduced. Equatorial regions exhibited enhanced CH3I mixing ratios extending into the upper tropical troposphere, consistent with fast vertical transport of air from the tropical marine boundary layer.

Blake, Donald R.↗

Cepheid Calibration of the Peak Brightness of SNe Ia.: SN 1989B in NGC 3627 - 9

Repeated imaging observations have been made of NGC 3627 with the Hubble Space Telescope in 1997/98, over an interval of 58 days. Images were obtained on 12 epochs in the F555W band and on five epochs in the F8141,V band. The galaxy hosted the prototypical, "Branch normal", type la supernova SN 1989B. A total of 83 variables have been found, of which 68 are definite Cepheid variables with periods ranging from 75 days to 3.85 days. The de-reddened distance modulus is determined to be (m - M)(sub 0) = 30.22 +/- 0.12 (internal uncertainty) using a subset of the Cepheid data whose reddening and error parameters are secure. The photometric data of Wells et al. (1994), combined with the Cepheid data for NGC 3627 give MB(max) = -19.36 +/- 0.18 and M(sub V)(max) = -19.34 +/- 0.16 for SN 1989B. Combined with the previous six calibrations in this program, plus two additional calibrations determined by others gives the mean absolute magnitudes at maximum of (M(sub B)) = -19.48 +/- 0.07 for "Brunch normal" SNe Ia at this interim stage in the calibration program. Using the argument by Wells et al. (1994) that SN 1989B here is virtually identical in decay rate and colors at maximum with SN 198ON in NGC 1316 in the Fornax cluster, and that such identity means nearly identical absolute magnitude, it follows that the difference in the distance modulus of NGC 3627 and NGC 1316 is 1.62 +/- 0.03 mag. Thus the NGC 3627 modulus implies that (m - M)(sub 0) = 31.84 for NGC 1316. The second parameter correlations of M(max) of blue SNe la with decay rate, color at maximum, and Hubble type are re-investigated. The dependence of (M(max)) on decay rate is non-linear, showing a minimum for decay rates between 1.0 less than ADelta(sub m)15 less than 1.6. Magnitudes corrected for decay rate show no dependence on Hubble type, but a dependence on color remains. Correcting both the fiducial sample of 34 SNe la with decay-rate data and the current eight calibrating SNe la for the correlation with decay rate as well as color gives H(sub 0) = 60 +/- 2 (internal) km/s Mpc, in both B and V. The same value to within 4% is obtained if only the SNe la in spirals (without second parameter corrections) are considered. The correlation of SNe la color at maximum with M(max) cannot be due to internal absorption because the slope coefficients in B, V, and I with the change in magnitude are far from or even opposite to the canonical reddening values. The color effect must be intrinsic to the supernova physics. "Absorption" corrections of distant blue SNe la will lead to incorrect values of H(sub 0). The Cepheid distances used in this series are insensitive to metallicity differences. The zeropoint of the P-L relation is based on an assumed LMC modulus of (m - M)(sub 0) = 18.50. As this may have to be increased by 0(sup m).06 to 0(sup m).08, all distances in this paper will follow and Ho will decrease by 3 - 4%.

Saha, A.↗

Review of Recent Thermophotovoltaic (TPV) Research at Lewis Research Center

Thermophotovoltaic (TPV) research at NASA Lewis Research Center that began in the late 1980's is reviewed. This work has been concentrated on low bandgap indium gallium arsenide (InGaAs) PV calls and rare earth - yttrium aluminum garnet (YAG) thin film selective emitters, as well as, TPV system studies. An emittance theory has been developed for the thin film emitters. Experimental spectral emittance results for erbium Er-YAG and holmium Ho-YAG show excellent emittance (greater than or equal to 0.7) within the emission bands. The 0.75 eV InGaAs PV cells fabricated at Lewis have excellent quantum efficiency. An efficiency of 130% has been measured for this cell coupled to an Er-YAG selective emitter and a short pass IR filter.

Chubb, Donald L.↗

Dominant Presence of Oxygenated Organic Species in the Remote Southern Hemisphere Troposphere

Oxygenated organic species are intimately involved with the fate of nitrogen oxides (NO(sub x)) and hydrogen oxides (HO(sub x)), which are necessary for tropospheric ozone formation. A recent airborne experiment (March-April, 1999) focused over the southern hemisphere (SH) Pacific Ocean (PEM-tropics-B) provided a first opportunity for a detailed characterization of the oxygenated organic composition of the remote southern hemisphere troposphere. Three co-located multi-channel airborne instruments measured a dozen key oxygenated species (carbonyls, alcohols, organic nitrates, organic pernitrates, peroxides) along with a comprehensive suite of C2-C8 Nonmethane hydrocarbons (NMHC). These measurements reveal that in the tropical SH (0-30 deg south), oxygenated chemical abundances are extremely large and collectively are nearly five times those of NMHC. Even in the NH remote atmospheres their burden is equal to or greater than that of NMHC. The relatively uniform global distribution oxygenates (EPSILON Ox-org) is indicative of the presence of large natural and distributed sources. A global 3-D model, reflecting the present state of science, is unable to correctly simulate the atmospheric distribution and variability of several of these species.

Singh, H.↗

Development of Unsteady Aerodynamic State-Space Models from CFD-Based Pulse Responses

A method for computing discrete-time state-space models of linearized unsteady aerodynamic behavior directly from aeroelastic CFD codes is presented. The method involves the treatment of CFD-based pulse responses as Markov parameters for use in a system identification /realization algorithm. Results are presented for the AGARD 445.6 Aeroelastic Wing with four aeroelastic modes at a Mach number of 0.96 using the EZNSS Euler/Navier-Stokes flow solver with aeroelastic capability. The System/Observer/Controller Identification Toolbox (SOCIT) algorithm, based on the Ho-Kalman realization algorithm, is used to generate 15th- and 32nd-order discrete-time state-space models of the unsteady aerodynamic response of the wing over the entire frequency range of interest.

Silva, Walter A.↗

On The Choice of a Zeroth-Order Hamiltonian for Second-Order Perturbation Theory with A CASSCF Reference Function

A new approach to perturbation theory based on a CASSCF reference function has been developed. The key to the approach is the definition of the zeroth order Hamiltonian, H(sub 0), which includes the full CI Hamiltonian for the active space. In the the inactive and secondary spaces, operators may be chosen which reduce to the usual Moller-Plesset or Epstein-Nesbet forms in the limit of a null active space. These operators are diagonal in the orbital indices and permit the block-diagonalization of H(sub 0). The reference is an eigenfunction of Ho without N-particle projection. H(sub 0) automatically incorporates denominator shifts in the style of those appearing in recent open-shell perturbation theories. Comparative results are presented for a few test cases.

Dyall, Kenneth G.↗

Resonances in Positronium Hydride

Recently, Ho and his colleagues have calculated the positions and widths of a series of resonances in the Ps+H scattering system, using the complex -rotation method and have compared them with estimates that I made many years ago using a quite different technique. I assumed that the resonance mechanism was the existence in the rearrangement channel [e+ + H-] of an infinite series of perturbed Coulomb bound states. Although these must be broadened and shifted by coupling with the open scattering channel, I expected them to lie very close to the actual resonance positions. To verify this, I did a model calculation for S-waves, including the coupling, and found that the first two resonances were not shifted very far from their unperturbed position. The new, detailed calculation agrees with this result, but when the P-wave was examined it was found, surprisingly, that the lowest resonance indeed moved up in energy by a large amount. With the help of Joseph DiRienzi of the College of Notre Dame of Maryland I am now extending the old calculation to P- and D-waves, in an attempt to understand this unexpected energy shift. Results will be presented at the Workshop.

Drachman, Richard J.↗

Sources, Sinks, and the Distribution of OH in the Lower Stratosphere

Extensive measurement campaigns by the NASA ER-2 research aircraft have obtained a nearly pole-to-pole database of the species that control HOx (OH + HO2) chemistry. The wide dynamic range of these in situ measurements provides an opportunity to demonstrate empirically the mechanisms that control the HOx system. Measurements in the lower stratosphere show a remarkably tight correlation of OH concentration with the solar zenith angle (SZA). This correlation is nearly invariant over latitudes ranging from 70 S to 90 N and all seasons. An analysis of the production and loss of HOx in terms of the rate determining steps of reaction sequences developed by Johnston and Podolske and Johnston and Kinnison is used to clarify the behavior of the system and to directly test our understanding of the system with observations. Calculations using in situ measurements show that the production rate of HOx is proportional to O3 and ultraviolet radiation flux. The loss rate is proportional to the concentration and the partitioning of NOy (reactive nitrogen) and the concentration of HO2. In the absence of heterogeneous reactions, the partitioning of NOy is controlled by O3 and NOx and the concentration of HO2 is controlled by NOy and O3, so that the removal rate of OH is buffered against changes in the correlation of O3 and NOy. The heterogeneous conversion of NO2 to HNO3 is not an important net source of HO, because production and removal sequences are nearly balanced. Changes in NOy partitioning resulting from heterogeneous chemistry have a large effect on the loss rates of HOx, but little or no impact on the measured abundance of OH. The enhanced loss rates at high NO2/HNO3 are offset in the data set examined here by enhanced production rates resulting from increased photolysis rates resulting from the decreased O3 column above the ER-2.

Hanisco, T. F.↗

Singlet Excited States of Cl and Br Molecules: New Theories Applied to the -XO and -XO2 (X=C1 and Br) Chromophores

Electronic excitation energies are determined using single-reference based theories derived from response equations involving perturbation theory and coupled-cluster theory. These methods are applied to the singlet manifold of excited electronic states of the HClO, HBrO, HOClO, HOBrO, HClO2, and HBrO2 molecules. The reliability of the various perturbation theory approaches is assessed by comparison to the linear-response singles and doubles coupled-cluster (LRCCSD) method. The excitation energies for the Y-XO compounds are compared and contrasted for Y=H and HO, and X=Cl and Br. A similar comparison is performed for the H-XO2 compounds.

Lee, Timothy J.↗