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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Hydraulic and Thermal Stimulation Program at Raft River Idaho, A DOE EGS

A Department of Energy Enhanced Geothermal System (EGS) stimulation program has injected over 254 million gallons of water into the well RRG-9 ST1 since the summer of 2013. Three major stimulations have been conducted during the program increasing injection flow rates from less than 20 gpm to 550 gpm. Geologic, water chemistry, microseismic activity, and borehole imaging data have been used to develop a conceptual model describing possible flow paths of this injected water. This model contains two major fracture zones one of which intersects the RRG-9 ST1 wellbore. Modified Hall and injectivity index plots constructed using injection flow rates, surface temperatures, and wellhead pressures show steady improvement in the injectivity of the well. Here, the injectivity index has risen from 0.15 gpm/psi to 2.0 gpm/ psi. A pressure falloff test conducted on April 28, 2015 indicates a reservoir permeability of 1,220 md and -5.38 skin factor. The well stimulation program was simulated numerically using an Idaho National Laboratory reservoir simulation code, FALCON. These simulations show a significant increase in the permeability of connecting fracture pathways after each stimulation event.

Enhanced geothermal system↗
NASA NTRS1989

Modeling of high speed chemically reacting flow-fields

The SPARK3D and SPARK3D-PNS computer programs were developed to model 3-D supersonic, chemically reacting flow-fields. The SPARK3D code is a full Navier-Stokes solver, and is suitable for use in scramjet combustors and other regions where recirculation may be present. The SPARK3D-PNS is a parabolized Navier-Stokes solver and provides an efficient means of calculating steady-state combustor far-fields and nozzles. Each code has a generalized chemistry package, making modeling of any chemically reacting flow possible. Research activities by the Langley group range from addressing fundamental theoretical issues to simulating problems of practical importance. Algorithmic development includes work on higher order and upwind spatial difference schemes. Direct numerical simulations employ these algorithms to address the fundamental issues of flow stability and transition, and the chemical reaction of supersonic mixing layers and jets. It is believed that this work will lend greater insight into phenomenological model development for simulating supersonic chemically reacting flows in practical combustors. Currently, the SPARK3D and SPARK3D-PNS codes are used to study problems of engineering interest, including various injector designs and 3-D combustor-nozzle configurations. Examples, which demonstrate the capabilities of each code are presented.

Drummond, J. P.↗
DOE OSTI2023

Intermetallic Single-Atom Alloy In–Pd Bimetallene for Neutral Electrosynthesis of Ammonia from Nitrate

Harvesting recyclable ammonia (NH 3 ) from the electrocatalytic reduction of nitrate (NO 3 RR) offers a sustainable strategy to close the ecological nitrogen cycle from nitration contamination in an energy-efficient and environmentally friendly manner. The emerging intermetallic single-atom alloys (ISAAs) are recognized to achieve the highest site density of single atoms by isolating contiguous metalatoms into single sites stabilized by another metal within the intermetallic structure, which holds promise to couple the catalytic benefits from intermetallic nanocrystals and single-atom catalysts for promoting NO 3 RR. Herein, ISAA In-Pd bimetallene, in which the Pd single atoms are isolated by surrounding In atoms, is reported to boost neutral NO 3 RR with a NH 3 Faradaic efficiency(FE) of 87.2%, a yield rate of 28.06 mg h -1 mg Pd -1 , and an exceptional electrocatalytic stability with increased activity/selectivity over 100 h and 20 cycles. The ISAA structure induces substantially diminished overlap of Pdd-orbitals and narrowed p-d hybridization of In-p and Pd-d states around the Fermi level, resulting in a stronger NO 3 - adsorption and a depressed energy barrier of the potential-determining step for NO 3 RR. Finally, further integrating the NO 3 RR catalyst into a Zn-NO 3 - flow battery as the cathode delivers a power density of 12.64 mW cm -2 and a FE of 93.4% for NH 3 production.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1991

A numerical study of shock wave/boundary layer interaction in nonequilibrium chemically reacting air - The effects of catalytic walls

This paper presents a numerical study that investigate the effects of nonequilibrium chemistry, and in particular, wall catalycity on the separated flow region generated by an oblique shock wave impinging upon a flat plate boundary layer. To obtain a solution to this problem, the full two dimensional Navier-Stokes equations were solved using MacCormack's predictor-corrector time dependent technique on a rectangular grid. Nonequilibrium chemistry was included by utilizing the 5 species, 17 reaction modified Dunn-Kang chemical kinetics model. Separate results were obtained for: calorically perfect, chemically reacting - noncatalytic wall, and chemically reacting - fully catalytic wall cases, for a given set of flow conditions. A direct comparison of all three cases revealed a slight decrease in the peak heat transfer for the noncatalytic wall case, as compared to the calorically perfect case. On the other hand, the fully catalytic wall case had a tremendous increase in the peak surface heat transfer. It is concluded that, for the particular conditons treated here (nearly frozen flow in the free stream), the effects of the nonequilibrium chemically reacting flow on the shock-wave/boundary-layer interaction depend critically on the catalycity of the wall, having virtually no effect for the case of a noncatalytic wall, and exerting a tremendous effect for a fully catalytic wall.

Grumet, Adam A.↗
NASA NTRS1987

Duct flow nonuniformities for Space Shuttle Main Engine (SSME)

A three-duct Space Shuttle Main Engine (SSME) Hot Gas Manifold geometry code was developed for use. The methodology of the program is described, recommendations on its implementation made, and an input guide, input deck listing, and a source code listing provided. The code listing is strewn with an abundance of comments to assist the user in following its development and logic. A working source deck will be provided. A thorough analysis was made of the proper boundary conditions and chemistry kinetics necessary for an accurate computational analysis of the flow environment in the SSME fuel side preburner chamber during the initial startup transient. Pertinent results were presented to facilitate incorporation of these findings into an appropriate CFD code. The computation must be a turbulent computation, since the flow field turbulent mixing will have a profound effect on the chemistry. Because of the additional equations demanded by the chemistry model it is recommended that for expediency a simple algebraic mixing length model be adopted. Performing this computation for all or selected time intervals of the startup time will require an abundance of computer CPU time regardless of the specific CFD code selected.

Source record↗
DOE OSTI2024

Concurrent measurement of strain and chemical reaction rates in a calcite grain pack undergoing pressure solution: Evidence for surface-reaction controlled dissolution

Pressure solution is inferred to be a significant contributor to sediment compaction and lithification, especially in carbonate sediments. For a sediment deforming primarily by pressure solution, the compaction rate should be directly related to the rate of calcite dissolution, transport along grain contacts, and calcite reprecipitation. Previous experimental work has shown that there is evidence that deformation in wet calcite grain packs is consistent with control by pressure solution, but considerable ambiguity remains regarding the rate limiting mechanism. We present the results of laboratory compaction experiments designed to directly measure calcite dissolution and precipitation rates (recrystallization rates) concurrently with strain rate to test whether measured rates are consistent with predicted rates both in absolute magnitude and time evolution. Recrystallization rates are measured using trace element chemistry (Sr/Ca, Mg/Ca) and isotopes (87Sr/86Sr) of fluids flowing slowly through a compacting grain pack as it is being triaxially compressed. Imaging techniques are used to characterize the grain contacts and strain effects in the post-experiment grain pack. Our data show that calcite recrystallization rates calculated from all three geochemical parameters are in approximate agreement and that the rates closely track strain rate. The geochemically inferred rates are close to predicted rates in absolute magnitude. Uncertainty in grain contact dimensions makes distinguishing between surface reaction control and diffusion control difficult. Measured reaction rates decrease faster than predicted from standard pressure solution creep flow laws. This inconsistency may indicate that calcite dissolution rates at grain contacts are more complex, and more time-dependent, than suggested by geometric models designed to predict grain contact stresses.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1986

Numerical study of hydrogen-air supersonic combustion by using elliptic and parabolized equations

The two-dimensional Navier-Stokes and species continuity equations are used to investigate supersonic chemically reacting flow problems which are related to scramjet-engine configurations. A global two-step finite-rate chemistry model is employed to represent the hydrogen-air combustion in the flow. An algebraic turbulent model is adopted for turbulent flow calculations. The explicit unsplit MacCormack finite-difference algorithm is used to develop a computer program suitable for a vector processing computer. The computer program developed is then used to integrate the system of the governing equations in time until convergence is attained. The chemistry source terms in the species continuity equations are evaluated implicitly to alleviate stiffness associated with fast chemical reactions. The problems solved by the elliptic code are re-investigated by using a set of two-dimensional parabolized Navier-Stokes and species equations. A linearized fully-coupled fully-implicit finite difference algorithm is used to develop a second computer code which solves the governing equations by marching in spce rather than time, resulting in a considerable saving in computer resources. Results obtained by using the parabolized formulation are compared with the results obtained by using the fully-elliptic equations. The comparisons indicate fairly good agreement of the results of the two formulations.

Chitsomboon, T.↗
NASA NTRS2022

A preliminary assessment of olivine phenocrysts from the monogenetic basalt of the McCartys Flow, Zuni-Bandera Volcanic Field, New Mexico

Monogenetic small-volume basaltic volcanoes are the most abundant subaerial volcanic landforms on Earth but are some of the most poorly understood systems. Their short durations, small volumes, and lack of recurrence make monitoring and hazard assessment difficult. The Zuni-Bandera volcanic field in western New Mexico contains small-volume basaltic centers erupting tholeiitic to alkalic basalts. Evidence shows no correlation of magma composition with eruption age, location, or volumetric output, prompting questions about the influence of magma ascent rates, magma storage conditions, and mantle source characteristics on lava compositions. Here, we present olivine major and minor element mineral chemistry from the 3200-year-old McCartys Flow, the youngest tholeiite basalt in the volcanic field. Olivine displays four phenocryst types with unique textures and major and minor element compositions. Multiple olivine types co-exist at the thin section scale. Major and minor element diffusion at frozen melt–phenocryst interfaces was modeled, revealing magma residence times ranging from 3–9 months. Type 3 olivine phenocrysts require step function initial conditions and record diffusion re-equilibration followed by magma mixing. These profiles indicate the magma resided in the reservoir for 10–15 years and accumulated from multiple batches of mixed magmas less than 10 days before the eruption. Our results show that primitive magmas in small-volume monogenetic volcanoes have complex lithospheric magmatic histories and stored in magma bodies influenced by an open system to develop different local chemical environments.

Gary S. Michelfelder↗
NASA NTRS1999

The Effects of Buoyancy and Dilution on the Structure and Lift-off of Coflow Laminar Diffusion Flames

The ability to predict the coupled effects of complex transport phenomena with detailed chemical kinetics in diffusion flames is critical in the modeling of turbulent reacting flows and in understanding the processes by which soot formation and radiative transfer take place. In addition, an understanding of the factors that affect flame extinction in diffusion flames is critical in the suppression of fires and in improving engine efficiency. The goal of our characterizations of coflow laminar diffusion flames is to bring to microgravity the multidimensional diagnostic tools available in normal gravity, and in so doing provide a broader understanding of the successes and limitations of current combustion models. This will lead to a more detailed understanding of the interaction of convection, diffusion and chemistry in both buoyant and nonbuoyant environments. As a sensitive marker of changes in the flame shape, the number densities of excited-state CH (A(exp 2)delta, denoted CH*), and excited-state OH (A(exp 2)Sigma, denoted OH*) are measured in mu-g and normal gravity. Two-dimensional CH* and OH* number densities are deconvoluted from line-of-sight chemiluminescence measurements made on the NASA KC-135 reduced-gravity aircraft. Measured signal levels are calibrated, post-flight, with Rayleigh scattering. Although CH* and OH* kinetics are not well understood, the CH*, OH*, and ground-state CH distributions are spatially coincident in the flame anchoring region. Therefore, the ground-state CH distribution, which is easily computed, and the readily measured CH*/OH* distributions can be used to provide a consistent and convenient way of measuring lift-off height and flame shape in the diffusion flame under investigation. Given that the fuel composition affects flame chemistry and that buoyancy influences the velocity profile of the flow, we have the opportunity to computationally and experimentally study the roles of fluids and chemistry. In performing this microgravity study, improvements to the computational model have been made and new calculations performed for a range of gravity and flow conditions. Furthermore, modifications to the experimental approach were required as a consequence of the constraints imposed by existing microgravity facilities. Results from the computations and experiments are presented in the following sections.

Walsh, Kevin T.↗
NASA NTRS1992

Effect of finite-rate chemistry and unequal Schmidt numbers on turbulent non-premixed flames modeled with single-step chemistry

The interaction between a quasi-laminar flame and a turbulent flowfield is investigated through direct numerical simulations (DNS) of reacting flow in two- and three-dimensional domains. Effects due to finite-rate chemistry are studied using a single step global reaction A (fuel) + B (oxidizer) yields P (product), and by varying a global Damkoehler number, as a result of which the turbulence-chemistry interaction in the flame is found to generate a wide variety of conditions, ranging from near-equilibrium to near-extinction. Differential diffusion effects are studied by changing the Schmidt number of one reactive species to one-half. It is observed that laminar flamelet response is followed within the turbulent flowfield, except in regions where transient effects seem to dominate.

Chen, J. H.↗
NASA NTRS1989

Aerodynamic stability and heating analyses for the aeroassist flight experiment vehicle

Since ground based flow simulations are presently unable to model flight conditions expected for AOTVs (Aeroassist Orbital Transfer Vehicle) and other hypersonic space vehicles, computer codes are being developed to provide design parameters necessary for structure, guidance, and control aspects. Over the past four years, VRFLO (Viscous Reactive Flow) has been written to model finite-rate chemistry and viscous effects for a variety of aerobrake bodies. VRFLO includes a number of unique features that are summarized as follows: (1) Grid generation is an integral part of the code for several aerobrake configurations which includes the wake flow region; (2) The formulation is valid for three air chemical models; (3) An ADI central difference technique is used to solve the Navier-Stokes and species continuity equations in split groups; and (4) Grid density and numerical damping are minimized by shock-fitting and conformal mapping of body points.

Mcgary, J.↗
NASA NTRS1990

CFD propels NASP propulsion progress

The most complex aerothermodynamics encountered in the National Aerospace Plane (NASP) propulsion system are associated with the fuel-mixing and combustion-reaction flows of its combustor section; adequate CFD tools must be developed to model shock-wave systems, turbulent hydrogen/air mixing, flow separation, and combustion. Improvements to existing CFD codes have involved extension from two dimensions to three, as well as the addition of finite-rate hydrogen-air chemistry. A novel CFD code for the treatment of reacting flows throughout the NASP, designated GASP, uses the most advanced upwind-differencing technology.

Povinelli, Louis A.↗
DOE OSTI2023

Effect of the ..beta..-Hydroxy Group on Ester Reactivity: Combustion Kinetics of Methyl Hexanoate and Methyl 3-Hydroxyhexanoate

One of the major biofuels used today is biodiesel, composed of fatty acid methyl esters. The fats and oils feedstocks used to make biodiesel are in relatively short supply. To meet increasing global demand, engineered microorganisms have been developed to catalyze conversion of sugar to fatty acid esters that contain unique ..beta..-hydroxy-esters. This study investigated the effect of a hydroxyl group on the combustion characteristics of methyl esters by comparing the chemical behavior of methyl hexanoate (MHx) and methyl 3-hydroxyhexanoate (M3OHHx) - used as surrogates for diesel-boiling-range esters with longer fatty acid chains. The oxidation of these esters was studied experimentally in a flow reactor at 0.84 and 10 bar, 600 to 1,100 K, and stoichiometric conditions; and in a constant volume combustion chamber at 5 and 10 bar, 600 to 900 K, and equivalence ratios of 0.3 and 0.6. MHx was more reactive in the constant volume chamber at temperatures below 800 K at 10 bar and equivalence ratio of 0.6. MHx also exhibited a higher indicated cetane number (16.4) than M3OHHx (8.1). We investigated this reactivity trend using an updated MHx kinetic model and M3OHHx model developed as part of this work. The kinetic models predicted that radicals formed from MHx were consumed by low-temperature chemistry reactions, whereas the M3OHHx reactivity was significantly governed by the ..beta..-radical (on the same carbon as the OH group) chemistry which mainly terminated via the less reactive chain propagation pathway to methyl-3-oxohexanoate + HO2. This study extends our understanding of structural effects on ester reactivity, which will allow for accurate surrogate formulation and performance simulations.

AFIDA↗
NASA NTRS2013

Time-Filtered Navier-Stokes Approach and Emulation of Turbulence-Chemistry Interaction

This paper describes the time-filtered Navier-Stokes approach capable of capturing unsteady flow structures important for turbulent mixing and an accompanying subgrid model directly accounting for the major processes in turbulence-chemistry interaction. They have been applied to the computation of two-phase turbulent combustion occurring in a single-element lean-direct-injection combustor. Some of the preliminary results from this computational effort are presented in this paper.

Liu, Nan-Suey↗
NASA NTRS1980

Computational models for the viscous/inviscid analysis of jet aircraft exhaust plumes

Computational models which analyze viscous/inviscid flow processes in jet aircraft exhaust plumes are discussed. These models are component parts of an NASA-LaRC method for the prediction of nozzle afterbody drag. Inviscid/shock processes are analyzed by the SCIPAC code which is a compact version of a generalized shock capturing, inviscid plume code (SCIPPY). The SCIPAC code analyzes underexpanded jet exhaust gas mixtures with a self-contained thermodynamic package for hydrocarbon exhaust products and air. A detailed and automated treatment of the embedded subsonic zones behind Mach discs is provided in this analysis. Mixing processes along the plume interface are analyzed by two upgraded versions of an overlaid, turbulent mixing code (BOAT) developed previously for calculating nearfield jet entrainment. The BOATAC program is a frozen chemistry version of BOAT containing the aircraft thermodynamic package as SCIPAC; BOATAB is an afterburning version with a self-contained aircraft (hydrocarbon/air) finite-rate chemistry package. The coupling of viscous and inviscid flow processes is achieved by an overlaid procedure with interactive effects accounted for by a displacement thickness type correction to the inviscid plume interface.

Dash, S. M.↗
NASA NTRS1995

Effects of Chemistry on Blunt-Body Wake Structure

Results of a numerical study are presented for hypersonic low-density flow about a 70-deg blunt cone using direct simulation Monte Carlo (DSMC) and Navier-Stokes calculations. Particular emphasis is given to the effects of chemistry on the near-wake structure and on the surface quantities and the comparison of the DSMC results with the Navier-Stokes calculations. The flow conditions simulated are those experienced by a space vehicle at an altitude of 85 km and a velocity of 7 km/s during Earth entry. A steady vortex forms in the near wake for these freestream conditions for both chemically reactive and nonreactive air gas models. The size (axial length) of the vortex for the reactive air calculations is 25% larger than that of the nonreactive air calculations. The forebody surface quantities are less sensitive to the chemistry than the base surface quantities. The presence of the afterbody has no effect on the forebody flow structure or the surface quantities. The comparisons of DSMC and Navier-Stokes calculations show good agreement for the wake structure and the forebody surface quantities.

Dogra, Virendra K.↗
NASA NTRS1991

Intrusive and nonintrusive measurements of flow properties in arc jets

While numerous diagnostic techniques are available for determining the flow properties of arc jets, these have to be used complementarily in order to cover all the requisite information. Although intrusive techniques disturb the flow, they yield much information. The determination of total enthalpy remains a major challenge, and accurate heat-flux measurements entail knowledge of atom recombination and chemical energy recombination coefficients. Such state-specific methods as the spectroscopic and laser techniques are useful in understanding the chemistry and nonequilibrium reaction and excitation rates of the flow.

Scott, Carl D.↗
DOE OSTI2024

A miniature jet pump for slurries

Here, this work reports on the design and performance of a jet pump system to pump slurries. The jet pump uses a high-velocity water jet to entrain and pump the slurry. This pumping action requires no valves and does not use moving solid parts. Hence, the system can be readily sealed, and the pumping action creates no observable mechanical damage to slurry particles. We tested carbon black beads suspended in water at concentrations of 0.0, 0.2, and 2.0 wt% at primary jet flow rates of 50 and 100 mL/min. Our measurements show an approximately linear decrease in entrainment ratio (slurry-to-jet flow rate) and absolute slurry flow rate with increasing adverse (load) pressure difference. The entrainment ratio is a strong function of the absolute jet flow rate. Pump performance was insensitive to slurry composition. Micron-resolution particle image velocimetry (micro-PIV) revealed qualitative changes in the pump’s internal flow due to changes in absolute jet flow rate, including evidence of the suppression of a vortex at higher flow rates. These findings establish key operational parameters for the jet pump and highlight its potential in a variety of slurry flow pumping applications. The pump is particularly suited for flow electrode slurries (e.g. as used for energy storage and water treatment) as it maintains particle integrity and can be used with standard tubing, tube fittings, and sealing methods.

42 ENGINEERING↗