Formation and composition of the moon
Many of the properties of the Moon, including the enrichment in Ca, Al, Ti, U, Th, Ba, Sr, and the REE and the depletion in Fe, Rb, K, Na, and other volatiles can be understood if the Moon represents a high-temperature condensate from the solar nebula. Thermodynamic calculations show that Ca-, Al-, and Ti-rich compounds condense first in a cooling nebula. The initial high temperature mineralogy is gehlenite, spinel, perovskite, Ca-Al-rich pyroxenes, and anorthite. Inclusions in carbonaceous chondrites such as the Allende meteorite are composed primarily of these minerals and, in addition, are highly enriched in refractories such as REE relative to carbonaceous chondrites. These inclusions can yield basalt and anorthosite in the proportions required to eliminate the europium anomaly, leaving a residual spinel-melilite interior. A deep interior high in Ca-Al does not imply an unacceptable mean density or moment of inertia for the Moon. The inferred high-U content of the lunar interior, both from the Allende analog and the high heat flow, indicates a high-temperature interior. The model is consistent with extensive early melting, with shallow melting at 3 AE, and with presently high deep internal temperatures. It is predicted that the outer 250 km is rich in plagioclase and FeO. The low iron content of the interior in this model raises the interior temperatures estimated from electrical conductivity by some 800 C.