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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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NASA NTRS1978

Energy and remote sensing applications

The nature of the U.S. energy problem is examined. Based upon the best available estimates, it appears that demand for OPEC oil will exceed OPEC productive capacity in the early to mid-eighties. The upward pressure on world oil prices resulting from this supply/demand gap could have serious international consequences, both financial and in terms of foreign policy implementation. National Energy Plan objectives in response to this situation are discussed. Major strategies for achieving these objectives include a conversion of industry and utilities from oil and gas to coal and other abundant fuels. Remote sensing from aircraft and spacecraft could make significant contributions to the solution of energy problems in a number of ways, related to exploration of energy-related resources, the efficiency and safety of exploitation procedures, power plant siting, environmental monitoring and assessment, and the transportation infrastructure.

Summers, R. A.↗

NASA NTRS1989

A rocket engine design expert system

The overall structure and capabilities of an expert system designed to evaluate rocket engine performance are described. The expert system incorporates a JANNAF standard reference computer code to determine rocket engine performance and a state-of-the-art finite element computer code to calculate the interactions between propellant injection, energy release in the combustion chamber, and regenerative cooling heat transfer. Rule-of-thumb heuristics were incorporated for the hydrogen-oxygen coaxial injector design, including a minimum gap size constraint on the total number of injector elements. One-dimensional equilibrium chemistry was employed in the energy release analysis of the combustion chamber and three-dimensional finite-difference analysis of the regenerative cooling channels was used to calculate the pressure drop along the channels and the coolant temperature as it exits the coolant circuit. Inputting values to describe the geometry and state properties of the entire system is done directly from the computer keyboard. Graphical display of all output results from the computer code analyses is facilitated by menu selection of up to five dependent variables per plot.

Davidian, Kenneth J.↗

NASA NTRS1980

Hydrogen production by photoelectrolytic decomposition of H2O using solar energy

Photoelectrochemical systems for the efficient decomposition of water are discussed. Semiconducting d band oxides which would yield the combination of stability, low electron affinity, and moderate band gap essential for an efficient photoanode are sought. The materials PdO and Fe-xRhxO3 appear most likely. Oxygen evolution yields may also be improved by mediation of high energy oxidizing agents, such as CO3(-). Examination of several p type semiconductors as photocathodes revealed remarkable stability for p-GaAs, and also indicated p-CdTe as a stable H2 photoelectrode. Several potentially economical schemes for photoelectrochemical decomposition of water were examined, including photoelectrochemical diodes and two stage, four photon processes.

Rauh, R. D.↗

NASA NTRS1993

Effect of disorder on the optical properties of short period superlattices

The optical properties of disordered short period superlattices are studied using a one-dimensional tight-binding model. A difference vector and disorder structure factor are proposed to characterize the disordered superlattice. The density of states, participation number, and optical absorption coefficients for both ordered and disordered superlattices are calculated as a function of energy. The results show that introduction of disorder into an indirect band gap material enhances the optical transition near the indirect band edge.

Strozier, J. A.↗

NASA NTRSDate not supplied

The LHS 1678 System: Two Small Planets and a Likely Brown Dwarf Orbiting a Nearby M Dwarf in Unconventional Circumstances

We present the LHS 1678 (TOI-696) exoplanet system: two nearly Earth-sized transiting planets detected by TESS and a likely brown dwarf orbiting a bright M2 dwarf at 19.9 pc. The ultra-short-period LHS 1678 b (0.70 Earth radii, 0.9-day orbit) is a captivating target for emission spectroscopy observations with the JWST. LHS 1678 c (0.98 Earth radii, 3.7- day orbit) is in the Venus-zone and may be Venus density: a promising target for greenhouse effect studies. Both planets are favorable targets for EPRV mass measurements and for JWST transmission spectroscopy observations to study their atmospheres. The substellar companion, detected via CTIO/SMARTS 0.9m astrometry, is on a decades-long orbit and may someday eclipse the host star, revealing a rare system architecture in which more and less massive objects orbit in the same plane. There is also a candidate third planet detected in TESS multi-cycle data in near 4:3 resonance with LHS 1678 c. The host star is associated with an observed gap in the HR diagram tied to a change in M dwarf energy transport mechanisms. The effect of the associated stellar astrophysics on exoplanet evolution is currently unknown. In aggregate, LHS 1678 an exciting playground for comparative exoplanet science and understanding the formation and evolution of small, short-period exoplanets orbiting low-mass stars.

Michele L Silverstein↗

NASA NTRSDate not supplied

An Analysis of Exploration Capability Gaps for Future Habitation Systems to Inform Risk Assessment and Development Priorities

Within NASA, exploration capability gaps are defined as the difference between the current state-of-the-art in capabilities and the anticipated needs of future human spaceflight architectures. As NASA and its partners’ capabilities for human exploration of deep space continue to mature, it is necessary to understand the capability gaps that require closure to support future habitation systems, such as the Lunar Surface Habitat (SH) and Mars Transit Habitat (TH) currently in concept development. This paper will identify high-priority capability gaps for exploration habitation and show potential options for gap closure through investment in technology, development, and testing. High-priority capability gaps are divided into the following general taxonomy areas: human health/life support/habitation systems, flight computing and avionics, power and energy storage, communications and navigation, thermal management systems, human exploration destination systems, autonomous systems, sensors and instruments, GNC (guidance, navigation, and control), robotic systems, ground and uncrewed surface systems, and materials/structures/mechanical systems/manufacturing. In the gap identification process, teams of discipline experts from across NASA reviewed the latest habitation architecture needs against current capabilities to understand where gaps may exist. The results of the assessment established a basis for the current state-of-the-art within each gap and identified the capability needs of the proposed exploration missions the gap links to. An assessment of how each test platform (e.g., Ground, International Space Station (ISS), Commercial Low Earth Orbit (LEO) Destinations, Gateway) may be leveraged to mature capabilities and potentially provide a route to gap closure will be discussed. The notional timeline for gap closure to support reference missions and impacts to overall schedule are also assessed where appropriate. Based on the capability gap analysis described above, the paper summarizes important technology maturation considerations for human exploration architectures, with a focus on the Mars TH. The previously published NASA habitation ground rules and assumptions document is used as the basis to classify gaps as enabling, enhancing, or “push” opportunities for a particular architecture. Stepwise technology maturation plans/considerations are presented for some selected critical gaps. Overall, the analysis in this paper is intended to help influence development priorities for habitation systems, where high-priority, critical gaps are those currently assessed as having a low probability of closure by the anticipated need date. Capability gap analysis also informs the risk register for exploration habitation systems and mitigation strategies to ensure readiness of key technologies to support future mission timelines. Linkage between capability gaps for Moon and Mars is noted, as closure of a gap at a Lunar destination may subsequently enable or enhance Mars TH architectures.

technology development↗

NASA NTRSDate not supplied

An Analysis of Exploration Capability Gaps for Future Habitation Systems to Inform Risk Assessment and Development Priorities

technology development↗

NASA NTRS1991

GaP betavoltaic cells as a power source

Maximum power output for the GaP cells of this study was found to be on the order of 1 microW. This resulted from exposure to 200 and 40 KeV electrons at a flux of 2 x 10(exp 9) electrons/sq cm/s, equivalent to a 54 mCurie source. The efficiencies of the cells ranged from 5 to 9 percent for 200 and 40 KeV electrons respectively. The lower efficiency at higher energy is due to a substantial fraction of energy deposition in the substrate, further than a diffusion length from the depletion region of the cell. Radiation damage was clearly observed in GaP after exposure to 200 KeV electrons at a fluence of 2 x 10(exp 12) electrons/sq cm. No discernable damage was observed after exposure to 40 KeV electrons at the same fluence. Analysis indicates that a GaP betavoltaic system would not be practical if limited to low energy beta sources. The power available would be too low even in the ideal case. By utilizing high activity beta sources, such as Sr-90/Y-90, it may be possible to achieve performance that could be suitable for some space power applications. However, to utilize such a source the problem of radiation damage in the beta cell material must be overcome.

Pool, F. S.↗

NASA NTRS1987

Soft x ray window encapsulant for HgI2 detectors

HgI2 is an excellent semiconductor material for a low energy, room temperature x-ray spectrometer. The high values of the atomic numbers for its constituent elements gives high x-ray and gamma ray stopping power. The band gap of HgI2 is significantly higher than other commonly used semiconductors. Owing to the large value band gap, the leakage current for HgI2 devices is smaller, thus allowing low noise performance. Devices fabricated from HgI2 crystals have demonstrated energy resolution sufficient to distinguish the x-ray emission from the neighboring elements on the periodic table. Also the power requirements of HgI2 are very low. These characteristics make a HgI2 spectrometer an ideal component in a satellite based detection system. Unfortunately, HgI2 crystals tend to deteriorate with time, even if protected by standard semiconductor encapsulants. This degradation ruins the performance of the device in terms of its energy resolution and pulse amplitude. The degrading mechanism is believed to be material loss occurring from below the electrodes, due to high vapor pressure of HgI2 at room temperature. To address this major obstacle to rapid expansion of HgI2 technology, a research program aimed at improving device stability by encapsulation with inert polymeric materials was carried out. The program focused specifically on optimizing the encapsulant materials and their deposition techniques. The principal objectives for this program were device encapsulation, device testing, and accelerated testing to ensure very long term stability of these high resolution sensors. A variety of encapsulants were investigated with the selection criteria based on their chemical diffusion barrier properties, mechanical stability, reactivity, and morphology of encapsulant films. The investigation covered different classes of encapsulants including solvent based encapsulants, vapor deposited encapsulants, and plasma polymerized encapsulants. A variety of characterization techniques were employed to examine their effectiveness in stabilizing HgI2 devices; these included permeability evaluation, vacuum and heat testing, scanning electron microscopy (SEM) as well as studying the detector performance of coated detectors. The plasma polymerized films appear to have entirely solved the HgI2 degradation problem. Another achievement of this program was the development of an accelerated testing technique which correlates extremely well with long term tesing.

Entine, G.↗

NASA NTRS1951

Spark Ignition of Flowing Gases. 2: Effect of Electrode Parameters on Energy Required to Ignite a Propane-Air Mixture

Research was conducted to determine the effect of the electrode parameters of spacing, configuration, and material' on the energy required for ignition of a flowing propane-air mixture. In addition, the data were used to indicate the energy distribution along the spark length and to confirm previous observations concerning the effect of spark duration on ignition energy requirements. The data were obtained with a mixture at a fuel-air ratio of 0.0835 (by weight), a pressure of 3 inches of mercury absolute, a temperature of 80 F, and a mixture velocity of 5 feet per second. Results showed that the energy required for ignition decreased as the electrode spacing was increased; a minimum energy occurred at. a spacing of 0.65 inch for large electrodes. For small electrodes, the spacing for minimum energy was not sharply defined. Small-diameter electrodes required less energy than large-diameter electrodes if the spacing was less than the optimum distance of 0.65 inch; at a spacing equal to the optimum distance, no difference was noted. Significant effects of electrode material on ignition energy were ascribed to differences in the type of spark discharges produced; glow discharges required higher energy than the arc-glow discharges. With pure glow discharges, the ignition energy was substantially constant for lead, cadmium, brass, aluminum, and tungsten electrodes. A method is described for determining the energy distribution along a glow discharge. It was found that one-third to one-half of the energy in the spark was concentrated in a small region near the cathode electrode, and the remainder was uniformly distributed across the spark gap. It was impossible to ascertain the dependence of ignition on. this distribution. It was also observed that long-duration (600 microsec) sparks required much less energy for ignition than did short-duration (1 microsec) sparks.

Swett, Clyde. C., Jr.↗

NASA NTRS2022

Ab initio Screening of Refractory Nitrides and Carbides for High Temperature Hydrogen Permeation Barriers

Density functional theory was used to screen eleven refractory materials – two pure metals, six nitrides, and three carbides–as high-temperature hydrogen permeation barriers to prevent hydrogen embrittlement. Activation energies were calculated for atomic hydrogen (H) diffusion into the first subsurface layer from the lowest energy surface of the high-temperature phase of each candidate material. The candidate barrier materials with the highest activation energies are h-BN, c-BN, HfN, and ZrN with predicted barriers of 3.25 eV, 3.23 eV, 3.14 eV, and 2.76 eV, respectively. Strain energies, Bader charges, and density of states were calculated for the diffusing H at the relaxed initial state and the transition state to provide insight into contributing factors to high energy barriers. The diffusing H atom in materials with the highest predicted barriers are protic. In addition, interstitial H atoms induce mid-gap states in the density of states of both BN polymorphs. The nitrogen retention of each nitride material at high temperatures was predicted using nitrogen vacancy formation energies with respect to gaseous nitrogen. Experimental evaluation of nitrogen retention in h-BN, ZrN, and TiN confirmed their resistance to nitrogen loss at 1773 K. However, of these nitrides, TiN is predicted to be the least stable. This work identifies multiple promising materials that are predicted to be effective hydrogen barriers at high temperatures and that are stable at temperatures above 2700 K, with BN predicted to perform best.

Density Functional Theory (DFT)↗

NASA NTRS1975

Citizen's actions

The various ways in which energy may be conserved by individual citizens as consumers were explored. The following barriers against citizens implementing an effective conservation program were described: credibility gap between producers and consumers, consumptive lifestyles, inverted rate structure, low fuel costs, and initial costs compared to life cycle costs. The following indices for saving energy were identified: time to develop alternatives, scarcity of fuels, reduction of dependence on imports, and decreasing environmental pollution. The various approaches to encourage energy conservation by individuals were described, followed by specific conclusions and recommendations.

Source record↗

NASA NTRS2022

Spectral Power-law Formation by Sequential Particle Acceleration in Multiple Flare Magnetic Islands

We present a first-principles model of pitch-angle and energy distribution function evolution as particles are sequentially accelerated by multiple flare magnetic islands. Data from magnetohydrodynamic (MHD) simulations of an eruptive flare/coronal mass ejection provide ambient conditions for the evolving particle distributions. Magnetic islands, which are created by sporadic reconnection at the self-consistently formed flare current sheet, contract and accelerate the particles. The particle distributions are evolved using rules derived in our previous work. In this investigation, we assume that a prescribed fraction of particles sequentially "hops" to another accelerator and receives an additional boost in energy and anisotropy. This sequential process generates particle number spectra that obey an approximate power law at mid-range energies and presents low- and high-energy breaks. We analyze these spectral regions as functions of the model parameters. We also present a fully analytic method for forming and interpreting such spectra, independent of the sequential acceleration model. The method requires only a few constrained physical parameters, such as the percentage of particles transferred between accelerators, the energy gain in each accelerator, and the number of accelerators visited. Our investigation seeks to bridge the gap between MHD and kinetic regimes by combining global simulations and analytic kinetic theory. The model reproduces and explains key characteristics of observed flare hard X-ray spectra as well as the underlying properties of the accelerated particles. Our analytic model provides tools to interpret high-energy observations for missions and telescopes, such as RHESSI, FOXSI, NuSTAR, Solar Orbiter, EOVSA, and future high-energy missions.

magnetic reconnection↗

NASA NTRS2001

Band Anticrossing in Highly Mismatched Compound Semiconductor Alloys

Compound semiconductor alloys in which metallic anions are partially replaced with more electronegative isoelectronic atoms have recently attracted significant attention. Group IIIN(x)V(1-x), alloys with a small amount of the electronegative N substituting more metallic column V elements has been the most extensively studied class of such Highly Mismatched Alloys (HMAs). We have shown that many of the unusual properties of the IIIN(x),V(1-x) alloys can be well explained by the Band Anticrossing (BAC) model that describes the electronic structure in terms of an interaction between highly localized levels of substitutional N and the extended states of the host semiconductor matrix. Most recently the BAC model has been also used to explain similar modifications of the electronic band structure observed in Te-rich ZnS(x)Te(l-x) and ZnSe(Y)Te(1-y) alloys. To date studies of HMAs have been limited to materials with relatively small concentrations of highly electronegative atoms. Here we report investigations of the electronic structure of ZnSe(y)Te(1-y) alloys in the entire composition range, 0 less than or equal to y less than or equal to 1. The samples used in this study are bulk ZnSe(y)Te(1-y) crystals grown by either a modified Bridgman method or by physical vapor transport. Photomodulated reflection (PR) spectroscopy was used to measure the composition dependence of optical transitions from the valence band edge and from the spin-orbit split off band to the conduction band. The pressure dependence of the band gap was measured using optical absorption in a diamond anvil cell. We find that the energy of the spin-orbit split off valence band edge does not depend on composition and is located at about 3 eV below the conduction band edge of ZnSe. On the Te-rich side the pressure and the composition dependence of the optical transitions are well explained by the BAC model which describes the downward shift of the conduction band edge in terms of the interaction between localized Se states and the conduction band. On the other hand we show that the large band gap reduction observed on the Se-rich side of the alloy system is a result of an interaction between the localized Te level and the valence bands. This interaction leads to the formation of a Te-like valence band edge that strongly interacts with the light hole valence band. Calculations based on a modified k p model account for the reduction of the band gap and the large increase of the spin-orbit splitting observed in Se-rich ZnSe(y)Te(l-y) alloys. We will also discuss the importance of these new results for understanding of the electronic structure and band offsets in other highly mismatched alloy systems.

Yu, Kin Man↗

NASA NTRS2001

Band Anticrossing in Highly Mismatched Compound Semiconductor Alloys

Compound semiconductor alloys in which metallic anions are partially replaced with more electronegative isoelectronic atoms have recently attracted significant attention. Group IIIN(sub x)V(sub 1-x) alloys with a small amount of the electronegative N substituting more metallic column V elements has been the most extensively studied class of such Highly Mismatched Alloys (HMAs). We have shown that many of the unusual properties of the IIIN(sub x)V(sub 1-x) alloys can be well explained by the Band Anticrossing (BAC) model that describes the electronic structure in terms of an interaction between highly localized levels of substitutional N and the extended states of the host semiconductor matrix. Most recently the BAC model has been also used to explain similar modifications of the electronic band structure observed in Te-rich ZnS(sub x)Te(sub 1-x) and ZnSe(sub y)Te(sub 1-y) alloys. To date studies of HMAs have been limited to materials with relatively small concentrations of highly electronegative atoms. Here we report investigations of the electronic structure of ZnSe(sub y)Te(sub 1-y) alloys in the entire composition range, y between 0 and 1. The samples used in this study are bulk ZnSe(sub y)Te(sub 1-y) crystals grown by either a modified Bridgman method or by physical vapor transport. Photomodulated reflection (PR) spectroscopy was used to measure the composition dependence of optical transitions from the valence band edge and from the spin-orbit split off band to the conduction band. The pressure dependence of the band gap was measured using optical absorption in a diamond anvil cell. We find that the energy of the spin-orbit split off valence band edge does not depend on composition and is located at about 3 eV below the conduction band edge of ZnSe. On the Te-rich side the pressure and the composition dependence of the optical transitions are well explained by the BAC model which describes the downward shift of the conduction band edge in terms of the interaction between localized Se states and the conduction band. On the other hand we show that the large band gap reduction observed on the Se-rich side of the alloy system is a result of an interaction between the localized Te level and the valence bands. This interaction leads to the formation of a Te-like valence band edge that strongly interacts with the light hole valence band. Calculations based on a modified k(sup dot)p model account for the reduction of the band gap and the large increase of the spin-orbit splitting observed in Se-rich ZnSe(sub y)Te(sub 1-y) alloys. We will also discuss the importance of these new results for understanding of the electronic structure and band offsets in other highly mismatched alloy systems.

Yu, Kin Man↗

NASA NTRS1975

Laser-to-electricity energy converter for short wavelengths

Short-wavelength energy converter can be made using Schottky barrier structure. It has wider band gap than p-n junction silicon semiconductors, and thus it has improved response at wavelengths down to and including ultraviolet region.

Stirn, R. J.↗

NASA NTRS1951

Preliminary results of turbojet-engine altitude-starting investigation

A spark energy of 2.13 joules per spark at 1 spark per second produced ignition to an altitude of 50,000 feet at a flight Mach number of 0.6. The minimum power requirements for ignition were obtained from a combination of low spark repetition rates and high spark energy. The altitude-ignition limit was also increased by increasing spark-gap immersion, fuel temperature, inlet-air temperature, and fuel volatility, and by decreasing flight Mach number. The maximum altitude at which flame propagation was accomplished from combusters with spark plugs to combusters without spark plugs to combustors without spark plugs was increased about 5000 feet by increasing fuel volatility.

COMBUSTION - IGNITION OF GASES↗

NASA NTRS1998

The Nightside Auroral Gap: Implications for Magnetosphere-Ionosphere Coupling in the Midnight Auroral Zone

We present observations of a new synoptic scale feature of the nightside aurora identified by the Polar Ultraviolet Imager (UVI) in which a well defined segment of the pre-midnight auroral oval exhibits significantly reduced auroral luminosity in the atomic oxygen and Lyman-Birge-Hopfield (LBH) emission bands in comparison to adjacent auroral activity. This gap in the nightside aurora is typically observed in the 2200-2400 MLT sector and spans 1.0-1.5 hours in local time (710-1100 km). The energy flux ($\rm erg$ $\rm cm'{-2}$ $\rm s'{-1}$) is shown to be lower by as much as a factor of four in the nightside gap region in comparison to the adjacent auroral activity. The appearance of the nightside gap does not depend on substorm phase. However, substorm intensifications are often observed on either side of the nightside gap which remains relatively inactive. Moreover, auroral breakups sometimes develop within the nightside gap, indicating that this feature may have dynamical implications for substorm onset location.

Chua, D. H.↗