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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 343 records · Page 19

Five-Segment Solid Rocket Motor Development Status

In support of the National Aeronautics and Space Administration (NASA), Marshall Space Flight Center (MSFC) is developing a new, more powerful solid rocket motor for space launch applications. To minimize technical risks and development costs, NASA chose to use the Space Shuttle s solid rocket boosters as a starting point in the design and development. The new, five segment motor provides a greater total impulse with improved, more environmentally friendly materials. To meet the mass and trajectory requirements, the motor incorporates substantial design and system upgrades, including new propellant grain geometry with an additional segment, new internal insulation system, and a state-of-the art avionics system. Significant progress has been made in the design, development and testing of the propulsion, and avionics systems. To date, three development motors (one each in 2009, 2010, and 2011) have been successfully static tested by NASA and ATK s Launch Systems Group in Promontory, UT. These development motor tests have validated much of the engineering with substantial data collected, analyzed, and utilized to improve the design. This paper provides an overview of the development progress on the first stage propulsion system.

Priskos, Alex S.↗

Space Environmental Effects on Additively Manufactured Materials

Space simulations including thermal vacuum, atomic oxygen, and ultraviolet radiation were performed to study the durability of various additively manufactured materials. In addition to ground simulations, additively manufactured materials were selected for a one-year flight on the Materials on International Space Station Experiment (MISSE) Flight Facility. The space environment is composed of atomic oxygen, ultraviolet radiation, protons, electrons, meteoroid/space debris impacts, thermal cycling, and hard vacuum. An improved UV sensor is also discussed.

Finckenor, M. M.↗

Technology Advancement and Insertion into Operating Nuclear Facilities

Key challenges in the NNSA modernization effort are centered around the selection of new processing / production technologies to deploy in existing, operating, and oftentimes, aging nuclear facilities. New uranium processing technologies may offer significant improvements in worker and environmental safety, material control and accountability, and production efficiencies, but adaptation of these technologies into existing facilities presents unique (and usually, difficult) engineering solutions for each new technology. This presentation discusses approaches utilized at Y-12 to mature and demonstrate new processing and production technologies for deployment into nuclear facilities. The technology advancement lifecycle (from concept to deployment) of uranium electrorefining technologies will be reviewed, as a prototypical example, to describe steps and approaches utilized at Y-12 (and NNSA Sites) to (i) mature technologies and manufacturing strategies, (ii) establish testbed capabilities for full-scale process demonstrations, and (iii) reduce risks associated with operational disruptions when commissioning new uranium processing technologies.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Technology Advancement and Insertion into Operating Nuclear Facilities

Key challenges in the NNSA modernization effort are centered around the selection of new processing / production technologies to deploy in existing, operating, and oftentimes, aging nuclear facilities. New uranium processing technologies may offer significant improvements in worker and environmental safety, material control and accountability, and production efficiencies, but adaptation of these technologies into existing facilities presents unique (and usually, difficult) engineering solutions for each new technology. This presentation discusses approaches utilized at Y-12 to mature and demonstrate new processing and production technologies for deployment into aging nuclear facilities. The technology advancement lifecycle (from concept to deployment) of uranium electrorefining technologies will be reviewed, as a prototypical example, to describe steps and approaches utilized at Y-12 (and NNSA Sites) to (i) mature technologies and manufacturing strategies, (ii) establish testbed capabilities for full-scale process demonstrations, and (iii) reduce risks associated with operational disruptions when commissioning new uranium processing technologies.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Mercury Speciation via Diffusive Gradients Thin-Films Technology

Objectives: Develop and test various diffusive gradient in thin films (DGT) samplers for mercury - SRNL is developing reactive DGTS (rDGTs). Test chemistry to differentiate methylmercury from total and/or inorganic mercury in environmental samples. Fabricate and test rDGT samplers for deployment. Deploy the rDGTs in variable settings. Mercury is a persistent-bioaccumulative-toxic environmental pollutant. Mercury exists in different species such as elemental, inorganic, and methyl. Mercury speciation determine mercury behavior and toxicity. For example, methylmercury strongly accumulates in biota such as fish resulting in potential human health impacts. DGTs are innovative samplers to measure water concentration by diffusion and capture. Types of Hg DGTs used: Total Hg, Inorganic Hg, and Methyl Hg. Deployment Sites: Upper Three Runs, Lower Three Runs, Steele Creek, East Fork Poplar Creek (SRNL Sites), Horizons Creek, NOA Creek, Bruners Creek (ORNL Sites). DGT concentration estimates closely matched alternative measurements for soluble mercury at each Oak Ridge site - DGTs did not respond to particulate mercury. DGTs provide a representative measure for biota uptake since they are left out longer which allows for an average exposure concentration. DMA-80 provided an efficient and quick analysis. Variability in site location made a difference in Hg species. DGT preparations and sampling wasn't as quick and simple as microcolumn technology. Copper reagent degraded agarose gel - more work and cleaner data are needed to assess speciation in rDGTs. Future Work: Use cross-linked polyacrylamide for the collection layer for a stronger plastic. Make a copper diffusion layer without agarose. Test copper separation in lab using realistic stream conditions such as high organic carbon.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Space Environmental Effects on Candidate Solar Sail Materials

The National Aeronautics and Space Administration's (NASA) Marshall Space Flight Center (MSFC) continues research into the utilization of photonic materials for spacecraft propulsion. Spacecraft propulsion, using photonic materials, will be achieved using a solar sail. A solar sail operates on the principle that photons, originating from the sun, impart pressure to the sail and therefore provide a source for spacecraft propulsion. The pressure imparted ot a solar sail can be increased, up to a factor of two, if the sun-facing surface is perfectly reflective. Therefore, these solar sails are generally composed of a highly reflective metallic sun-facing layer, a thin polymeric substrate and occasionally a highly emissive back surface. Near term solar sail propelled science missions are targeting the Lagrange point 1 (L1) as well as locations sunward of L1 as destinations. These near term missions include the Solar Polar Imager and the L1 Diamond. The Environmental Effects Group at NASA's Marshall Space Flight Center (MSFC) continues to actively characterize solar sail material in preparation for these near term solar sail missions. Previous investigations indicated that space environmental effects on sail material thermo-optical properties were minimal and would not significantly affect the propulsion efficiency of the sail. These investigations also indicated that the sail material mechanical stability degrades with increasing radiation exposure. This paper will further quantify the effect of space environmental exposure on the mechanical properties of candidate sail materials. Candidate sail materials for these missions include Aluminum coated Mylar, Teonex, and CP1 (Colorless Polyimide). These materials were subjected to uniform radiation doses of electrons and protons in individual exposures sequences. Dose values ranged from 100 Mrads to over 5 Grads. The engineering performance property responses of thermo-optical and mechanical properties were characterized. The contribution of Near Ultraviolet (NUV) radiation combined with electron and proton radiation was also investigated.

Edwards, David L.↗

A Proxy Method to Bridge LCA Data Gaps Using Automated Material Classification and Probabilistic Under-Specification

Life cycle assessments (LCAs) are essential for understanding the environmental impacts of material production. However, gaps in life cycle inventory (LCI) data for material and chemical inputs present a key challenge for LCA practitioners, especially in the early design stages. Strategies for filling in these gaps require additional time and expertise, which can hinder the LCA’s completion. This study combined automatic material classification and probabilistic under-specification to create a time-efficient method to fill material LCI data gaps. To illustrate the proposed method, proxy environmental impact distributions were generated using publicly available material LCI data classified into the ChemOnt chemical taxonomy using the open-source chemical classification software ClassyFire. Input materials with data gaps were then classified into the same taxonomy, where proxy environmental impact values could be selected from the available distributions to quickly fill in any data gaps. Although these methods were applied to classify material production processes available in the Federal LCA Commons and Ecoinvent databases, they can be applied to any LCA database. This study shows that classifying materials by their chemical structure produces taxonomies with increased granularity relative to industrial classification, improving the ability of under-specified proxy data to be used for differentiating the environmental impacts of competing designs.

biological databases↗

Corrosion fatigue of high strength fastener materials in seawater

Environmental effects which significantly reduce the fatigue life of metals are discussed. Corrosion fatigue is a major concern in the engineering application of high strength fasteners in marine environments. The corrosion fatigue failure of an AISI 41L4O high strength steel blade to hub attachment bolt at the MOD-OA 200 kW wind turbine generator was investigated. The reduction of fatigue strength of AISI 41L4O in marine environments and to obtain similar corrosion fatigue data for candidate replacement materials was studied. The AISI 4140, PH 13-8Mo stainless steel, alloy 718 and alloy MP-35N were tested in axial fatigue at a frequency of 20 Hz in dry air and natural seawater. The fatigue data are fitted by regression equations to allow determination of fatigue strength for a given number of cycles to failure.

Tipton, D. G.↗

What LDEF means for development and testing of materials

The Long Duration Exposure Facility (LDEF) served as the ultimate laboratory to provide combined space environmental effects on materials. The LDEF structure and its 57 experiments contained an estimated 12,000 to 14,000 specimens of materials and materials processes. It not only provided information about the resistance of these materials to the space environment but gives us direction into future needs for spacecraft materials development and testing. This paper provides an overview of the materials effects observed on the satellite and suggests recommendations for the future work in space-qualified materials development and space environmental simulation.

Whitaker, Ann F.↗

Environmental Barrier Coatings (EBC) for Ceramic Matrix Composite (CMC) Materials

The upper use temperature of current Environmental Barrier Coatings (EBC's) based on mullite and BSAS (EPM EBC's) is limited to -255 F due to silica volatility, chemical reactions, and high thermal conductivity. Therefore, new EBC s having low CTE, good chemical compatibility, and high melting point (greater than 2700 F ) are being investigated. Sinter-resistant, low thermal conductivity EBC s are strongly desired to achieve the UEET EBC goal of 270 F EBC surface temperature and 30 F AT over long exposures (greater than 1000 hr). Key areas affecting the upper temperature limit of current EBC s as well as the ongoing efforts to develop next generation EBC s in the UEET Program will be discussed.

Lee,Kang↗

Highly silanized cellulose biocomposites for sustainable insulation materials

Microfibrillated lignocellulose networks, derived from agricultural byproducts, represent an environmentally friendly biogenic material production due to their abundant availability to circular bioeconomy and inherent carbon sink in life cycle analysis. Yet, its vulnerability to moisture and flammability, coupled with challenges in creating highly reinforced insulation materials, poses challenges for the carbon-zero green building sector. Here we address these challenges with a new concept of in-situ grafting polymerization of nanoporous silica in pre-formed lignocellulosic fiber networks. The seamlessly integrating nanoporous silica with cellulose through hydrogen bonding networks enabled us to prepare highly reinforced biogenic composites for green building insulations. A high reinforcement biocomposite with hierarchal arrangements of nanoporous silica within the cellulose network exhibits remarkable attributes. It boasts a thermal conductivity of 24.2 mW·m –1 ·K –1 , a flexural modulus of 942 MPa, and soundproofing with a 20.8 % noise reduction, as well as the fire resistance characterized by an extended time to ignition and a reduced peak heat release rate of 144 kW·m –2 at 35 kW·m –2 of incident radiant heat flux. Furthermore, it demonstrates a reduced water absorption capacity, dropping from 5.12 g·g –1 to 0.75 g·g –1 . Altogether, this study opens the new pathways towards sustainable carbon-zero building materials in the context of circular bioeconomy.

36 MATERIALS SCIENCE↗

Addressing Critical Problems in Materials Science Through Multiscale and Multimode Characterization (Project 1); Characterization and Optimization of Novel Triple-Conducting Oxide Materials for Energy Applications (Project 2) (CRADA Final Report)

PROJECT 1: Address critical problems in materials science and simultaneously advance the state-of-the-art in multiscale and multimode characterization using the combined advanced analytical capabilities and expertise of Colorado School of Mines (CSM) and the National Renewable Energy Laboratory (NREL). The primary effort of the Phase I of this CRADA is to establish the International Center for Multiscale Characterization using shared resources at both NREL and CSM. Phase II will focus on capability development and marketing, choosing candidate materials science issues in the areas of structure imaging, chemical composition mapping, and correlating properties and performance of materials for impact in energy-related, environmental and critical materials areas. The CRADA will be modified to include specific topics of concern in materials science to industry member partners. Advanced analytical capabilities and expertise at CSM and NREL will be used to advance materials understanding and performance through characterization of multiscale phenomena including structural imaging, chemical composition mapping, and other techniques correlating properties and performance of materials. PROJECT 2: As part of the International Center for Materials Characterization, work under Modification #1 will be led by Colorado School of Mines (CSM), working in collaboration with NREL staff to mentor and advise CSM postdoctoral researchers on set up of diffusion annealing experiments. The purpose of the modification is to provide for NREL staff to mentor and advise CSM postdoctoral researchers on set up of diffusion annealing experiments, including mentoring and advising the CSM-NREL team on proper Secondary Ion Mass Spectrometry (SIMS) data analysis as needed. SIMS measurements of 10-20 samples will be performed at NREL during the project duration.

08 HYDROGEN↗