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At least 343 records · Page 19

The Need for International Consensus and Acceptance of Free Released Material - 20177

World Nuclear Association (WNA) believes that the waste hierarchy is best implemented when a good compromise exists between disposal and reuse/recycling methods of valuable materials and waste generated by the nuclear industry. The rapid normalization of recycling in both domestic and industrial worlds strengthens WNA's position, as new facilities worldwide emerge providing treatment for clearance. As a foundation for reuse and recycling, the International Atomic Energy Agency (IAEA) provided international guidance on clearance (Safety Guide RSG 1.7) [1], defining associated threshold values approved by all member states. Nevertheless, despite this consensus, a lack of alignment of national regulations has occurred as countries have departed for this international guidance, leading to confusion, even between neighborhood countries. As a consequence, this discrepancy between national rules, despite industrial and technical international consensus based on radiological and environmental considerations appeared as a brake, weakening public acceptance as well as nuclear industry credibility. As a matter of fact, what is allowed in one side of a border may be forbidden on the other side. Conversely, an international consensus on clearance would promote: - Sustainability improvements, including preservation of natural and rare resources resulting from optimized recycling and reuse practices; - A broader acceptance of free released materials; - taking advantage of the available technologies worldwide in materials treatment aiming for clearance; - Increased sharing and use of methods, know-how and operators, leading to better efficiency, innovation, improvement as well as technical and financial mastery. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Feedback from International Decommissioning Planning Projects - 20269

Decommissioning of Nuclear Power Plants is an increasing reality in many countries with nuclear power. Already many years before final shutdown, planning of the decommissioning work is usually started in order to understand for example the costs, waste volume capacity and licensing work needed. In many countries it is required to have a final decommissioning plan before any decommissioning work is allowed to start. Westinghouse has been involved in international decommissioning planning for more than 30 years, where the first 20 years was mostly funding and preliminary plans due to that decommissioning was many years away. However, as many more plants are now moving into decommissioning, the focus has shifted to final decommissioning plans with budgets instead of funding plans, strategic decisions instead of choices, waste volume specifications instead of estimates and a defined approach instead of what ifs. Westinghouse has developed a methodology based on the planning and execution of many decommissioning projects in Europe, America and Asia. That international experience and understanding helps the customers to adopt a systematic planning process where strategy development is done with the end state in mind, where the goals are clearly outlined and the starting point described. The process and steps to reach the desired end state need to be clearly defined and all options/alternatives evaluated from a cost/benefit point of view. This is followed by a thorough and quantitative risk analysis in order to give solid recommendations and credible conclusions. One important feedback has been that real decommissioning experience from reference projects is invaluable for an efficient and timely progress in order not to spend unnecessary time and effort on understanding the barriers and links between different activities in decommissioning. Skilled project managers or engineers can drive the project forward, but without decommissioning experience previously gained, valuable lessons learned are not used and the same mistakes can be made again. Many utilities have invested in knowledge transfer from other decommissioning projects through site visits, exchange programs and supplier meetings, which is a valuable asset and way of implementing lessons learned from performed decommissioning projects into the planning process. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Importance of Inventory for Informing Waste Strategy - 20280

A waste inventory aims to present the best available information about the nature, quantity and location of radioactive wastes and materials at a facility, site or in a country. Quality inventory data is necessary for developing appropriate strategies and plans for managing radioactive wastes and materials, with high standards of protection for people and the environment. The inventory of wastes will change over time due to a wide range of technical, commercial or policy reasons, for example, if reactor lifetimes are extended, if decommissioning strategies change or if new technologies are introduced for managing waste. Inventory information can also improve as better waste characterisation data becomes available. At a facility or site level, good quality inventory data are needed to underpin decision making about the waste management options and to demonstrate compliance with the chosen treatment or disposal route. At a site and country level, knowledge of the inventory can drive the improvement to waste strategy; waste management asset and service planning; and implementation. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Resource Adequacy in Decarbonizing Power Systems

Decarbonization of the power sector is instrumental to reducing emissions worldwide. Following the 13th Clean Energy Ministerial conference (CEM13) in 2022, several governments signaled their intention to develop power sector decarbonization action plans. The 21st Century Power Partnership (21CPP), in coordination with all Clean Energy Ministerial power workstreams and collaborators, is providing technical support on critical focus areas as these countries prepare their action plans. Countries will present the action plans at the upcoming CEM14 in India. Brought to you by the Clean Energy Solutions Center and 21CPP, this webinar will focus on resource adequacy and grid flexibility, key themes in the CEM14 action plans and critical topics for integrating variable renewable energy into the grid while ensuring system reliability. Global energy experts will discuss how grid planners can ensure stable supply while rapidly decarbonizing the power system and how various policies can increase the power grid's flexibility.

emissions↗

Summary of the the 11th Symposium of the International Society of Root Research

11th Symposium of the International Society of Root Research (ISRR11) and the 9th International Symposium on Root Development (Rooting2021) - Root Biology Never Sleeps virtual meeting May 24 - 28. These meetings are generally held in separate years. However, because of travel restrictions imposed by the COVID-19 pandemic, the organizing committees of both symposia decided to host the two meetings as a fully-joint and virtual-only conference. Various time zones were considered when developing the schedule, as live interactions was an important focus. Scientific sessions were held from 3 a.m. to 10 p.m. US Central Daylight Time (CDT) to meet the international demand. More than 700 participants from 52 countries virtually attend both events which featured 74 talks in 16 sessions including: 10 plenary lectures, 16 keynote speakers and 48 selected talks. Additionally, nearly 300 posters were presented in nine poster sessions. The meeting also featured an Ambassador Program with 21 ambassadors from 10 countries. These ambassadors organized a half-day pre-symposium workshop and produced a review of the meeting for “New Phytologist”. The meeting also awarded a Lifetime Award to Dr. Wendy Silk (Prof. Emerita University of California, Davis). Committee Members: • Bob Sharp (Chair) – University of Missouri • Felix Fritschi (Chair, Int’l Program Committee) – University of Missouri • David Braun – University of Missouri • Vicki Bryan – University of Missouri • Rich Ferrieri – University of Missouri • Laura Greeley – University of Missouri (postdoctoral representative) • Ali Housh – University of Missouri (graduate student representative) • Allison Miller – Donald Danforth Plant Science Center and St Louis University • Mel Oliver – University of Missouri • Jonathan Stemmle – University of Missouri • Gus Thies – University of Missouri & Donald Danforth Plant Science Center (graduate student representative) • Chris Topp - Donald Danforth Plant Science Center

Root Biology↗

How to Design and Implement an Equitable Building Performance Standard: Lessons from the Building Performance Standards Technical Assistance Network

States and local governments seek to accomplish the intersecting goals of reducing greenhouse gas emissions, improving building operations, and bettering the daily lives of their communities. Building Performance Standards (BPS) have emerged as a critical policy lever to reach these intertwined climate and societal goals. These policies, if shaped and implemented well, have the chance to not only help reach our nation's climate, energy, and livability goals, but to do so with the active participation of those traditionally excluded from policy processes. This nascent policy movement provides jurisdictions across the country the opportunity to shape these policies from the outset to deliver comfort, health, and safety in our built environment for all. The US Department of Energy in partnership with our National Laboratories have been providing technical assistance for jurisdictions interested in, adopting, and implementing Building Performance Standards. Through this work, the BPS Technical Assistance Network (TA Network) has tracked and documented the innovative and equitable approaches to BPS across the country. The TA Network has crafted foundational technical analysis, such as building stock and emissions impacts, equity prioritization and peak load impacts, and aggregated cost benefit analysis. And by combining powerful technical analysis with dissemination of best practices resources to support equitable implementation, the TA Network provides jurisdictions with the tools and support necessary to embark on their ambitious policy goals.

building performance standards↗

Applicability of the Milestones Approach to Deployments of Transportable Nuclear Power Plants (TNPPs)

Transportable nuclear power plants (TNPPs) can provide potential benefits to countries embarking on nuclear programs, offering reduced infrastructure requirements, shorter timeframes for implementation, cost savings and greater deployment flexibility than larger conventional reactors. However, the deployment of a TNPP in a Host State comes with the obligation to establish sufficient regulatory, institutional, and technical infrastructure, which, among others, includes a legal and regulatory framework and a competent regulatory body to implement a State’s safeguards obligations. This paper considers how the unique technical and deployment features of TNPPs may affect the process of preparing for and implementing safeguards in nuclear newcomer countries. Evaluating this issue through the lens of the IAEA’s Milestones Approach, this paper discusses some potential implications arising from the shortening of some milestones phases due to reduced construction or licensing time for TNPPs, and the need for increased cooperation between Host States and Supplier States in preparing for and meeting certain safeguards obligations. These considerations are potentially relevant to various stakeholders: newcomer States considering TNPP deployment; the States and companies that supply such reactors; as well as organizations that support international safeguards capacity building.

Siserman-Gray, Ioana-Cristina↗

National Modeling of Geothermal District Energy Systems with Ambient-Temperature Loops Using dGeo: Preprint

Geothermal district energy systems (DES) with ambient-temperature loops, also known as thermal energy networks, are one option for decarbonizing space heating and cooling loads. Geothermal fifth-generation DES include an "ambient" temperature thermal loop that connects heat pumps at each building with thermal balancing sources such as geothermal borehole fields. Heating and cooling are provided via a water-source heat pump at each end-user. This project seeks to analyze the nationwide potential for ambient-temperature loop districts by creating a new module within the Distributed Geothermal Market Demand Model (dGeo). dGeo is an agent-based modeling tool for distributed geothermal resources; it can investigate potential on a nationwide or statewide scale using geospatial data for all 50 states and thermal demands for existing buildings. This process allows for high-level estimates of technical and economic potential for ambient-temperature loop districts across the United States. Using GHEDesigner, a lookup table was created to size borehole fields for different thermal loads and ground conditions experienced across the country. A cost and financing structure, along with incentives, were applied. Cost estimates include costs for the distribution network, borehole field installation and operation, and circulation pump operation, while savings are calculated based on agent energy bills. This newly developed module can be used for assessing which areas of the country have the highest potential for agent benefits from ambient-temperature loop installation and assess the impact of different costing and pricing future scenarios. While the code is still under development and nationwide simulations are ongoing, initial results for two states are provided. Future work includes expanding the module to consider mixed residential and commercial districts and considering multiple costing scenarios.

ambient temperature loop↗

National Modeling of Geothermal District Energy Systems with Ambient-Temperature Loops Using dGeo

Geothermal district energy systems (DES) with ambient-temperature loops, also known as thermal energy networks, are one option for decarbonizing space heating and cooling loads. Geothermal fifth-generation DES include an "ambient" temperature thermal loop that connects heat pumps at each building with thermal balancing sources such as geothermal borehole fields. Heating and cooling are provided via a water-source heat pump at each end-user. This project seeks to analyze the nationwide potential for ambient-temperature loop districts by creating a new module within the Distributed Geothermal Market Demand Model (dGeo). dGeo is an agent-based modeling tool for distributed geothermal resources; it can investigate potential on a nationwide or statewide scale using geospatial data for all 50 states and thermal demands for existing buildings. This process allows for high-level estimates of technical and economic potential for ambient-temperature loop districts across the United States. A lookup table was created using GHEDesigner to size borehole fields for different thermal loads and ground conditions experienced across the country. A cost and financing structure, along with incentives, were applied. Cost estimates include costs for the distribution network, borehole field installation and operation, and circulation pump operation, while savings are calculated based on energy bills for building owners (agents). This newly developed module can be used for assessing which areas of the country have the highest potential for agent benefits from ambient-temperature loop installation and assess the impact of future cost and price scenarios. Initial results for statewide analysis (for Vermont) and nationwide (for United States) are provided. Future work includes expanding the module to consider mixed residential and commercial districts as well as evaluating multiple cost scenarios.

ambient-temperature loop↗

Nuclear waste reduction: Exploring new pathways one step at a time

In my home country of Venezuela, nuclear energy is not a topic that attracts much attention. The government briefly oversaw some nuclear energy programs during the 1950s, but currently there are no active nuclear power facilities in the country. In fact, the Venezuelan government signed and ratified the treaty of the prohibition of nuclear weapons in 2021, which states that Venezuela has never owned, possessed or controlled nuclear weapons or programs of any kind. When I moved to the United States, however, nuclear energy became an extremely relevant topic. In the 1940s, the U.S. government established and oversaw the Manhattan Project to build atomic bombs for use in World War II. After the war, the government encouraged scientists to use this information on nuclear reactions to develop nuclear energy for peaceful civilian purposes instead.1 During these early days of nuclear research, there were no formal regulatory standards for nuclear waste management. Policies usually were self-regulated and often created based on existing policies of disposal for non-nuclear waste.2 As a result, there were instances of nuclear waste leaching into the environment and affecting local communities. So, much research has been conducted since then to characterize and store nuclear waste safely and securely.3 I first became interested in nuclear energy during my undergraduate studies when I worked on a project involving ligand synthesis to help extract actinides from nuclear waste. I then studied electrochemistry in molten salt systems for nuclear energy applications during my Ph.D. As I approached graduation, I started looking into national laboratories that have programs involving nuclear energy and waste management. At Idaho National Laboratory (INL), the focus is more on applied processes and how nuclear energy can be innovated to realize next-generation reactor design and technologies. This focus led me to apply for a Seaborg distinguished postdoctoral position at INL, for which I was chosen based on my proposal of a way to improve nuclear waste recycling. To understand my proposal, we must familiarize ourselves with the makeup of nuclear waste. After uranium dioxide is used as nuclear fuel in a reactor, the fuel matrix is then characterized by various fission products, including rare earth elements, alkali and alkaline earths, and actinides. Some of these fission products can potentially be recovered through pyroprocessing, 4 which involves the electrochemical dissolution of the used nuclear fuel in a molten chloride salt mixture at high temperatures. Though some of the fission products can be easily recovered—for example, uranium is reduced onto an inert cathode by applied potentials—numerous other fission products such as rare earth elements are difficult to recover due to their multivalent oxidation states and side reactions.5 To improve the recovery efficiency of rare earth elements specifically, I proposed investigating the fundamental interactions between rare earth elements in the molten chloride salt and their metallic form (Figure 1). The kinetic pathways and the chemical reactions of these elements, which will be elucidated through spectro-electrochemistry at high temperatures, will give insights on how the recovery efficiency can be improved. Although my research focuses on fundamental science, it will benefit the applied process by generating new scientific knowledge and closing the gap for efficient recycling of the waste: one step at a time.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Idaho National Laboratory’s Mobile Hot Cell Transportation: Engineering Solutions for Global Disused Sealed Radioactive Sources.

Title: Idaho National Laboratory’s Mobile Hot Cell Transportation: Engineering Solutions for Global Disused Sealed Radioactive Sources. Abstract: The Mobile Hot Cell (MHC), currently under development by Idaho National Laboratory (INL) for the Off-Site Source Recovery Project (OSRP), is designed to help international partners meet the unique challenges of end-of-life radioactive material management. The MHC will provide a critical resource for countries that require assistance securing and disposing of Disused Sealed Radioactive Sources (DSRS) and orphaned sources in challenging environments, allowing these sources to be secured against misuse and nefarious activities. The MHC is a rapidly deployable system for conditioning and preparing end-of-life radioactive sources for transportation or storage. It is designed to handle sources of up to 1,000 Ci Co-60 equivalent while maintaining full radiological and biological containment. It will be deployable within 48 hours of an alert, making it ideal for emergency situations. The MHC features an operational suite for control, support racks for electronics, pneumatics, and welding systems, and a modular robust steel structure providing radiological shielding and internal robotic support. This design allows configurations for multiple device types to be conditioned and the ability to safely manage routine issues such as leaking or damaged sources. The MHC has been designed with the transportation challenges of rapid deployment to difficult environments in mind. The system weighs approximately 150,000 pounds, with individual systems breaking down into pieces not exceeding 20,000 pounds. Components are to be transportable on standard 20ft ISO containers, with shielding shells on 20ft flat racks. It is estimated that a total of eight containers and flat racks will be required. The use of 20ft containers, as opposed to 40ft containers, minimizes the impact on less developed road infrastructures, enabling the MHC to be positioned in constrained environments such as hospital parking lots. The system’s modularity also allows for deployment using smaller equipment, such as a 10-ton boom truck or forklift, which is crucial given the potential logistical challenges in different countries. This transportation strategy, evaluated in collaboration with Utah State University, ensures the MHC can be deployed via ground, rail, sea, or air, addressing the primary concern of international transport logistics.

99 - GENERAL AND MISCELLANEOUS↗

Commercialization of the Transportation-Security, Tracking, and Reporting System (T-STAR)

The Transportation-Security, Tracking, and Reporting System (T-STAR) was developed by the National Nuclear Security Administration, NA-21, Office of Radiological Security (ORS) to provide a transportation security system for detection and tracking during transport of Category 1 and Category 2 radiological material. Few off-the-shelf systems for conveyance tracking offer detection of a cargo compartment breach or a removal of the cargo. Systems that do offer this capability often require permanent installation through modifying of the conveyance itself. This is not sustainable in many countries where ORS is building use, storage, and transport security capacity. The development of T-STAR has moved from fielding robust prototypes deployed in countries ranging from North America, Latin America and Central Asia to a commercially produced product that can now be deployed to provide enhanced security during transit. Each prototype deployment resulted in important lessons learned, which informed the requirements for the final commercial product. T-STAR uses both cellular and Iridium satellite modems to provide redundant communications to provide the configuration, status, and alerts to a server monitoring the shipment, which is accessible using a multilanguage browser-based user interface. A wireless security system employing using Z-wave sensors for intrusion detection located in the conveyance provide low cost but effective solution for a wide range of conveyance types. Additional capabilities include the ability to monitor a vehicles’ CANBUS (Controller Area Network) system, an ethernet port for high throughput sensor information such as video cameras, and the ability to power and use advanced external sensor payloads. These features make the T-STAR a capable and expandable security gateway that can be deployed on a variety of conveyances from box trucks to open trailers. The ability to provide tracking, monitoring, and detection provide a key component in overall best practices designed to protect shipments of radioactive material.

Schultze, Michael [ORNL] (ORCID:0000000283205671)↗

Reproductive Factors and Endometrial Cancer Risk Among Women

Despite evidence of an association between reproductive factors and endometrial cancer risk, prospective studies have been conducted mainly in non-Asian countries. To assess the association between reproductive factors, such as number of deliveries, age at menarche, or menopause, and endometrial cancer risk. This cohort study used pooled individual data from 13 prospective cohort studies conducted between 1963 and 2014 in the Asia Cohort Consortium. Participants were Asian women. Data analysis was conducted from September 2019 to April 2023. Reproductive factors were assessed using a questionnaire in each cohort. The main outcome was time to incidence of endometrial cancer. A Cox proportional hazards model was used to calculate hazard ratios (HRs) and 95% CIs.

60 APPLIED LIFE SCIENCES↗

Comparing Parallel Plastic‐to‐X Pathways and Their Role in a Circular Economy for PET Bottles

Abstract The United States generates the most plastic waste of any country and is a top contributor to global plastic pollution. Multiple end‐of‐life strategies must be implemented to minimize environmental impacts and retain valuable plastic material, but it is challenging to compare options that generate products with different lifetimes and utilities. Herein, they present a material flow model equipped with consequential life cycle assessment, cost analysis, and a plastic circularity indicator that considers product quality and lifetime. The model is used to estimate the greenhouse gas (GHG) emissions, circularity, and cost of polyethylene terephthalate (PET) bottle mechanical downcycling to lower‐quality resin, closed‐loop glycolysis to food‐grade PET, upcycling to glass fiber‐reinforced plastic, and conversion to non‐plastic products (electricity, oil) on a United States economy‐wide basis for the year 2020. A brute force algorithm suggests that a combination of 68% glycolysis, 11% mechanical recycling, 6% upcycling, 9% landfilling, and 5% incineration can minimize the cost and GHG emissions and maximize the circularity of the current PET economy. However, uncertainty around transportation distances, materials recovery facility efficiencies, and recycling yields can result in different “optimal” pathway mixes. This flexible framework enables informed decision‐making to move toward a cost‐ and environment‐conscious circular economy for plastic.

09 BIOMASS FUELS↗

Overcoming Fundamental Limitations in Adsorbent Design: Alkene Adsorption by Non‐porous Copper(I) Complexes

Abstract Purifying alkenes from alkanes requires cryogenic distillation. This consumes energy equivalent to countries of ca. 5 million people. Replacing distillation with adsorption processes would significantly increase energy efficiency. Trade‐offs between kinetics, selectivity, capacity, and heat of adsorption have prevented production of an optimal adsorbent. We report adsorbents that overcome these trade‐offs. [Cu‐Br] 3 and [Cu‐H] 3 are air‐stable trinuclear complexes that undergo reversible solid‐state inter‐molecular rearrangements to produce dinuclear [Cu‐Br⋅(alkene)] 2 and [Cu‐H⋅(alkene)] 2 . The reversible solid‐state rearrangement, confirmed in situ using powder X‐ray diffraction, allows adsorbent design trade‐offs to be overcome, coupling low heat of adsorption (−10 to −17 kJ mol −1 alkene ), high alkene:alkane selectivity (47; 29), and uptake capacity (>2.5 mol alkene mol −1 Cu3 ). Most remarkably, [Cu‐H] 3 displays fast uptake and regenerates capacity within 10 minutes.

Parasar, Devaborniny↗

Overcoming Fundamental Limitations in Adsorbent Design: Alkene Adsorption by Non-porous Copper(I) Complexes

Purifying alkenes from alkanes requires cryogenic distillation. This consumes energy equivalent to countries of ca. 5 million people. Replacing distillation with adsorption processes would significantly increase energy efficiency. Trade-offs between kinetics, selectivity, capacity, and heat of adsorption have prevented production of an optimal adsorbent. Here, we report adsorbents that overcome these trade-offs. [Cu-Br] 3 and [Cu-H] 3 are air-stable trinuclear complexes that undergo reversible solid-state inter-molecular rearrangements to produce dinuclear [Cu-Br∙(alkene)] 2 and [Cu-H∙(alkene)] 2 . The reversible solid-state rearrangement, confirmed in situ using powder X-ray diffraction, allows adsorbent design trade-offs to be overcome, coupling low heat of adsorption (-10 to -17 kJ mol -1 alkene ), high alkene:alkane selectivity (47; 29), and uptake capacity (>2.5 molalkene mol -1 Cu3 ). Most remarkably, [Cu-H] 3 displays fast uptake and regenerates capacity within 10 minutes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Say where you sample: Increasing site selection transparency in urban ecology

Urban ecological studies have the potential to extend our understanding of socio-ecological systems beyond that of an individual city or region. Cross-comparative empirical work and synthesis are imperative to develop a general urban ecological theory. This can be achieved only if studies are replicable and generalizable. Transparency in methods reporting facilitates generalizability and replicability by documenting the decisions scientists make during the various steps of research design; this is particularly true for sampling design and selection because of their impact on both internal and external validity and the potential to unintentionally introduce bias. Three interdependent aspects of sample design are study sample selection (e.g., specific organisms, soils, or water), sample specification (measurement of specific variable of interest), and site selection (locations sampled). Of these, documentation of site selection—the where component of sample design—is underrepresented in the urban ecology literature. Using a stratified random sample of 158 papers from 12 major urban ecology journals, we investigated how researchers selected study sites in urban ecosystems and evaluated whether their site selection methods were transparent. We extracted data from these papers using a 50-question, theory-based questionnaire and a multiple-reviewer approach. Our sample represented almost 45 years of urban ecology research across 40 different countries. We found that more than 80% of the papers read were not transparent in their site selection methodology. We do not believe site selection methods are replicable for 70% of the papers read. Key weaknesses include incomplete descriptions of populations and sampling frames, urban gradients, sample selection methods, and property access. Low transparency in reporting the where methodology limits urban ecologists’ ability to assess the internal and external validity of studies’ findings and to replicate published studies; it also limits the generalizability of existing studies. The challenges of low transparency are particularly relevant in urban ecology, a field where standard protocols for site selection and delineation are still being developed. These limitations interfere with the fields’ ability to build theory and inform policy. We conclude by offering a set of recommendations to increase transparency, replicability, and generalizability.

54 ENVIRONMENTAL SCIENCES↗