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At least 343 records · Page 19

Use of MODIS Satellite Data to Evaluate Juniperus spp. Pollen Phenology to Support a Pollen Dispersal Model, PREAM, to Support Public Health Allergy Alerts

Juniperus spp. pollen is a significant aeroallergen that can be transported 200-600 km from the source. Local observations of Juniperus spp. phenology may not be consistent with the timing and source of pollen collected by pollen sampling instruments. Methods: The Dust REgional Atmospheric Model (DREAM)is a verified model for atmospheric dust transport modeling using MODIS data products to identify source regions and quantities of dust. We successfully modified the DREAM model to incorporate pollen transport (PREAM) and used MODIS satellite images to develop Juniperus ashei pollen input source masks. The Pollen Release Potential Source Map, also referred to as a source mask in model applications, may use different satellite platforms and sensors and a variety of data sets other than the USGS GAP data we used to map J. ashei cover type. MODIS derived percent tree cover is obtained from MODIS Vegetation Continuous Fields (VCF) product (collection 3 and 4, MOD44B, 500 and 250 m grid resolution). We use updated 2010 values to calculate pollen concentration at source (J. ashei ). The original MODIS derived values are converted from native approx. 250 m to 990m (approx. 1 km) for the calculation of a mask to fit the model (PREAM) resolution. Results: The simulation period is chosen following the information that in the last 2 weeks of December 2010. The PREAM modeled near-surface concentrations (Nm-3) shows the transport patterns of J. ashei pollen over a 5 day period (Fig. 2). Typical scales of the simulated transport process are regional.

Luvall, J. C.↗

Single-crystal X-ray diffraction study of Fe 2 SiO 4 fayalite up to 31 GPa

Olivine is widely believed to be the most abundant mineral in the Earth’s upper mantle. Here, we report structural refinement results for the Fe-end-member olivine, Fe 2 SiO 4 fayalite, up to 31 GPa in diamond-anvil cell, using single-crystal synchrotron X-ray diffraction. Unit-cell parameters a, b, c and V, average Si–O Fe–O bond lengths, as well as Si–O Fe–O polyhedral volumes continuously decrease with increasing pressure. The pressure derivative of isothermal bulk modulus K' T0 is determined to be 4.0 (2) using third-order Birch–Murnaghan equation of state with ambient isothermal bulk modulus fixed to 135 GPa on the basis of previous Brillouin measurements. The Si–O tetrahedron is stiffer than the Fe–O octahedra, and the compression mechanism is dominated by Fe–O bond and Fe–O octahedral compression. Densities of olivine along 1600 and 900 K adiabats are calculated based on this study. The existence of metastable olivine inside the cold subduction slab could cause large positive buoyancy force against subduction, slow down the subduction and possibly affect the slab geometry.

58 GEOSCIENCES↗

Study of the interaction of C60 fullerene with human serum albumin in aqueous solution

Concern about the toxicity of engineered nanoparticles, such as the prototypical nanomaterial C60 fullerene, continues to grow. While evidence continues to mount that C60 and its derivatives may pose health hazards, the specific molecular interactions of these particles with biological macromolecules require further investigation. To better understand the interaction of C60 with proteins, the protein human serum albumin (HSA) was studied in solution with C60 at C60:HSA molar ratios ranging from 1:2 to 4:1. HSA is the major protein component of blood plasma and plays a role in a variety of functions, such as the maintenance of blood pH and pressure. The C60-HSA interaction was probed by a combination of circular dichroism (CD) spectroscopy, small-angle neutron scattering (SANS) and atomistic molecular dynamics (MD) simulations to understand C60-driven changes in the structure of HSA in solution. The CD spectroscopy demonstrates that the secondary structure of the protein decreases in -helical content in response to the presence of C60. Similarly, C60 produces subtle changes in the solution conformation of HSA, as evidenced by the SANS data and MD. The data do not indicate that C60 is causing a change in the oligomerization state of the protein. Taken together results demonstrate that C60 interacts with HSA, but it does not strongly perturb the structure of the protein by unfolding it or inducing aggregation, suggesting a mechanism for transporting C60 throughout the body to accumulate in various tissues.

Li, Song↗

Novel symmetries in N=2 supersymmetric quantum mechanical models

We demonstrate the existence of a novel set of discrete symmetries in the context of the N=2 supersymmetric (SUSY) quantum mechanical model with a potential function f(x) that is a generalization of the potential of the 1D SUSY harmonic oscillator. We perform the same exercise for the motion of a charged particle in the X–Y plane under the influence of a magnetic field in the Z-direction. We derive the underlying algebra of the existing continuous symmetry transformations (and corresponding conserved charges) and establish its relevance to the algebraic structures of the de Rham cohomological operators of differential geometry. We show that the discrete symmetry transformations of our present general theories correspond to the Hodge duality operation. Ultimately, we conjecture that any arbitrary N=2 SUSY quantum mechanical system can be shown to be a tractable model for the Hodge theory. -- Highlights: •Discrete symmetries of two completely different kinds of N=2 supersymmetric quantum mechanical models have been discussed. •The discrete symmetries provide physical realizations of Hodge duality. •The continuous symmetries provide the physical realizations of de Rham cohomological operators. •Our work sheds a new light on the meaning of the above abstract operators.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Early development of multifilament polyacrylonitrile-derived structural hollow carbon fibers from a segmented arc spinneret

Carbon fiber is a highly desired material for structural applications requiring high strength and stiffness and low weight but has seen only incremental improvements in properties over the last few decades. Further increases in carbon fiber specific properties, including specific strength and specific modulus, would further propel its unique capabilities. One method to produce high specific property carbon fibers for structural applications is the development of hollow carbon fibers. In this work, we report on the early development of polyacrylonitrile-derived structural hollow carbon fibers. Here, multifilament, continuous tow, polyacrylonitrile-based precursor hollow fibers were successfully produced utilizing a segmented arc spinneret approach. When batch oxidized, the hollow precursor fibers demonstrated evidence of oxidation proceeding from both the interior and exterior of the filament. Further results suggested that reducing the precursor hollow fiber wall thickness would allow for complete, homogeneous oxidation, thereby avoiding the skin-core structure often observed in commercial carbon fiber. Here, hollow carbon fibers were as small as 35 µm outer diameter, 22 µm inner diameter (6.5 µm wall thickness). At these diameters, the hollow carbon effective fiber specific strength was 0.54 N/tex and the effective specific modulus was 120 N/tex, approaching the effective specific modulus of T700S at 136 N/tex.

36 MATERIALS SCIENCE↗

Preservation of physical properties of stochastic Maxwell equations with additive noise via stochastic multi-symplectic methods

Stochastic Maxwell equations with additive noise are a system of stochastic Hamiltonian partial differential equations intrinsically, possessing the stochastic multi-symplectic conservation law. It is shown that the averaged energy increases linearly with respect to the evolution of time and the flow of stochastic Maxwell equations with additive noise preserves the divergence in the sense of expectation. Moreover, we propose three novel stochastic multi-symplectic methods to discretize stochastic Maxwell equations in order to investigate the preservation of these properties numerically. We make theoretical discussions and comparisons on all of the three methods to observe that all of them preserve the corresponding discrete version of the averaged divergence. Meanwhile, we obtain the corresponding dissipative property of the discrete averaged energy satisfied by each method. Especially, the evolution rates of the averaged energies for all of the three methods are derived which are in accordance with the continuous case. Numerical experiments are performed to verify our theoretical results.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Dissecting Anvil Cloud Response to Sea Surface Warming

Abstract We derive an anvil cloud diagnostic from the continuity equation of cloud ice and apply it to the output of convection‐permitting Energy Exascale Earth System Model (E3SM) simulations run in radiative‐convective equilibrium mode. This diagnostic shows that anvil cloud fraction can be reliably diagnosed as a product of cloud detrainment and lifetime. Detrainment is found to be approximated well by a product of clear sky convergence and cloud ice mixing ratio, while cloud lifetime is dominated by sedimentation. Taken together, this diagnostic expresses anvil cloud fraction as a function of five physically measurable quantities. Of these, clear‐sky convergence changes drive the anvil cloud reduction with warming while an increase in cloud ice mixing ratio buffers the decrease. Accordingly, this study provides a theoretical foundation upon which the Stability‐Iris hypothesis can be tested.

54 ENVIRONMENTAL SCIENCES↗

Hayward Fault Creep From Coda Wave Interferometry

Understanding creep is essential for assessing seismic hazards along the creeping Hayward Fault, which threatens the San Francisco area. Current 1-D monitoring methods, like creepmeters and theodolites, provide limited measurements with low spatial resolution. InSAR offers higher 2-D spatial sampling but lower temporal resolution. We introduce a novel method using coda wave interferometry (CWI) to monitor creep in 2-D with high resolution. By calculating changes in ambient seismic noise travel times, we relate these measurements to creep offsets, bridging the gap between existing methods. Applied to seismic data from 2021 around the Hayward Fault, our CWI-derived offsets aligned with creepmeter measurements, revealing continuous and episodic creep. A 2-D regionalization identified a spatial boundary between these regimes, corroborating previous findings. This approach could enhance seismic monitoring and improve understanding of fault mechanics and earthquake risks.

Luckie, Thomas William [Sandia National Laboratori↗

Extracting band edge profiles at semiconductor heterostructures from hard-x-ray core-level photoelectron spectra

Hard-x-ray photoelectron spectroscopy (HAXPES) is a valuable source of information on band-edge profiles deep inside semiconductor thin films and heterojunctions. However, extracting this information requires robust and physically meaningful decomposition of spectra into contributions from individual atomic planes. We present an approach that utilizes the physical requirements of a monotonic dependence of the built-in electrostatic potential on depth and continuity of the potential function and its derivatives. These constraints enable efficient extraction of band-edge profiles and allow one to capture details of the electronic structure, including determination of the signs and magnitudes of the band bending as well as the valence band offsets. The utility of this approach to generate quantitative insight into the electronic structure of complex materials is illustrated for epitaxial SrTiO 3 on intrinsic Si(001).

97 MATHEMATICS AND COMPUTING↗

Properties of surface modes in one dimensional plasma photonic crystals

Properties of surface modes supported at the interface of air and a semi-infinite one dimensional plasma photonic crystal are analyzed. The surface mode equation is obtained by using transfer matrix method and applying continuity conditions of electric fields and its derivatives at the interface. It is observed that with increase in the width of cap layer, frequencies of surface modes are shifted towards lower frequency side, whereas increase in tangential component of wave-vector increases the mode frequency and total energy carried by the surface modes. With increase in plasma frequency, surface modes are found to shift towards higher frequency side. The group velocity along interface is found to control by cap layer thickness.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Pedothem carbonates reveal anomalous North American atmospheric circulation 70,000–55,000 years ago

Our understanding of climatic conditions, and therefore forcing factors, in North America during the past two glacial cycles is limited in part by the scarcity of long, well-dated, continuous paleoclimate records. Here, we present the first, to our knowledge, continuous, millennial-resolution paleoclimate proxy record derived from millimeter-thick pedogenic carbonate clast coatings (pedothems), which are widely distributed in semiarid to arid regions worldwide. Our new multiisotope pedothem record from the Wind River Basin in Wyoming confirms a previously hypothesized period of increased transport of Gulf of Mexico moisture northward into the continental interior from 70,000 to 55,000 years ago based on oxygen and carbon isotopes determined by ion microprobe and uranium isotopes and U-Th dating by laser ablation inductively coupled plasma mass spectrometry. This pronounced meridional moisture transport, which contrasts with the dominant zonal transport of Pacific moisture into the North American interior by westerly winds before and after 70,000–55,000 years ago, may have resulted from a persistent anticyclone developed above the North American ice sheet during Marine Isotope Stage 4. We conclude that pedothems, when analyzed using microanalytical techniques, can provide high-resolution paleoclimate records that may open new avenues into understanding past terrestrial climates in regions where paleoclimate records are not otherwise available. When pedothem paleoclimate records are combined with existing records they will add complimentary soil-based perspectives on paleoclimate conditions.

54 ENVIRONMENTAL SCIENCES↗

Cosmological backreaction in higher-derivative gravity expansions

We calculate a general effective stress-energy tensor induced by cosmological inhomogeneity in effective theories of gravity where the action is Taylor-expandable in the Riemann tensor and covariant derivatives of the Riemann tensor. This is of interest as an effective fluid that might provide an alternative to the cosmological constant, but it also applies to gravitational waves. We use an adaptation of Green and Wald's weak-averaging framework, which averages over perturbations in the field equation where the perturbation length scales are small compared to the averaging scale. In this adaptation, the length scale of the effective theory, 1/ M , is also taken to be small compared with the averaging scale. This ensures that the perturbation length scales remain in fixed proportion to the length scale of the effective theory as the cosmological averaging scale is taken to be large. We find that backreaction from higher-derivative terms in the effective action can continue to be important in the late universe, given a source of sufficiently high-frequency metric perturbations. This backreaction might also provide a window on exotic particle physics in the far ultraviolet.

79 ASTRONOMY AND ASTROPHYSICS↗

Fixed interval smoothing with discrete measurements.

Smoothing equations for a linear continuous dynamic system with linear discrete measurements, derived from the discrete results of Rauch, Tung, and Striebel (1965), (R-T-S), are used to extend, through recursive updating, the previously published results of Bryson and Frazier (1963), (B-F), and yield a modified Bryson and Frazier, (M-B-F), algorithm. A comparison of the (M-B-F) and (R-T-S) algorithms leads to the conclusion that the former is to be preferred because it entails less computation, less storage, and less instability. It is felt that the presented (M-B-F) smoothing algorithm is a practical mechanization and should be of value in smoothing discretely observed dynamic linear systems.

Bierman, G. J.↗

Energy cascade in large-eddy simulations of turbulent fluid flows

The derivation of smoothed or filtered momentum and continuity equations for large-scale, energy-containing eddies is considered. Questions regarding the energy loss of large-scale turbulence are discussed along with aspects of turbulent diffusion of a passive scalar. It is found that the large-scale fluctuations satisfy filtered or averaged momentum and continuity equations. An averaging of the nonlinear advection term yields two terms.

Leonard, A.↗

Application of NCOREL to aircraft configurations

The NCOREL computer program and methodology (Grossman, 1979) modified for computation of flows over complex geometries is described. The newly introduced features include a more flexible grid-generation package, capable of generating grids for realistic wing-body cross sections, and a more general numerical method, developed for the capture of highly three-dimensional embedded, oblique shocks. In addition, an inlet capability is included, by means of which the cross section is allowed to change discontinuously with the addition of the inlet geometry. The new cross section is regridded and the potentials and their derivatives are interpolated for the marching to continue. Hence, a discontinuity in the grid or mappings is taken into account at the inlet station. The results of the flow-field computation for a realistic fighter configuration are discussed.

Siclari, M. J.↗

Inversion of 2 wavelength Lidar data for cloud properties

The inversion of the lidar equation to derive quantitative properties of the atmosphere has continued to present considerable difficulty. The results of a study in which Klett's procedure was utilized for the analysis of cloud backscatter measurements made simulataneously at two ruby lidar wavelengths (694nm,347nmm) are presented. With one lidar system a cloud is probed at the two wavelength and the backscatter measured simulataneously by separate receivers. As a result two sigma profiles which should differ only because the wavlength dependence of the scattering. Experimental data presented to demonstrate the effects and the implications of the applications of the inversion method will be discussed.

Pal, S. R.↗

On model reduction

Three model reduction methods are described. These are the discrete balanced realizations of Mullis and Roberts (1976) where a characterization of the reduction error is given and a previously unknown L(infinity) norm bound on the reduction error, is obtained. Another method is a new model reduction technique for discrete time systems which has the advantage that the reduced order model is balanced and has an L(infinity) norm bound on the reduction error. The last method derived is a frequency weighting technique for continuous and discrete systems where it is possible to specify the approximation accuracy with frequency and also, for this method, an L(infinity) norm on the weighted reduction error is obtained.

Al-Saggaf, Ubaid M.↗

Electrostatic dry powder prepregging of carbon fiber

Ultrafine, 5-10 micron polymer-matrix resin powders are directly applied to carbon fiber tows by passing then in an air or nitrogen stream through an electrostatic potential; the particles thus charged will strongly adhere to grounded carbon fibers, and can be subsequently fused to the fiber in a continuously-fed radiant oven. This electrostatic technique derived significant end-use mechanical property advantages from the obviation of solvents, binders, and other adulterants. Additional matrix resins used to produce prepregs to date have been PMR-15, Torlon 40000, and LaRC TPI.

Throne, James L.↗