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At least 343 records · Page 19
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NASA NTRS1991

Warm neutral halos around molecular clouds. II - H I and CO (J = 1-0) observations

Observational data are presented relating to the boundary regions between dense, molecular clouds and the more diffuse atomic gas. The data set consists of H I 21 cm and CO (J = 1-0) strip maps in 14 molecular clouds which traverse 62 known CO cloud boundaries. The angular lengths of the strips range from 0.5 deg to several degrees of arc, which is generally adequate to eliminate confusion with background (and foreground) H I. Most of the crossed boundaries (49 of 62) show clear evidence for the presence of H I emission maxima, or halos, lying outside the molecular clouds' gas. There is also general evidence for limb brightening in the CO emission.

Wannier, Peter G.↗
NASA NTRS1991

The development of the CO(+) coma of Comet P/Schwassmann-Wachmann 1

The development of the CO(+) coma of Comet P/Schwassmann-Wachmann 1 is studied in spectroscopic observations indicating that the maximum rise time of the CO(+) gas is 1.2 days. This result implies a maximum creation time-scale for the CO(+) gas of the order of 100,000 sec at 5.8 AU. Evidence is adduced that dust events and gas events observed in this comet are not necessarily connected.

Cochran, Anita L.↗
NASA NTRS1990

CO fundamental lines - Indicators for inhomogeneous atmospheres in cool stars

Carbon monoxide fundamental lines near 4.7 microns are employed to probe the thermal structure of the atmospheres of cool stars. A new non-LTE radiation transfer code is used to analyze high-resolution infrared CO line spectra and derive observation-based stellar atmosphere models. The main results are: (1) the CO-based models developed here deviate strongly from previously published models based on UV/visible observations; (2) varying degrees of agreement between the CO empirical models and predictions based on theoretical radiative-equilibrium atmosphere models are found; and (3) the parameter used to quantify this agreement is anticorrelated with the magnitude of chromospheric activity in the observed stars. These results suggest thermally bifurcated upper atmospheres as the standard case for cool stars.

Wiedemann, Guenter↗
NASA NTRS1991

Studies of proton irradiated H2O + CO2 and H2O + CO ices and analysis of synthesized molecules

Infrared spectra of H2O + CO2 and H2O + CO ices before and after proton irradiation showed that a major reaction in both mixtures was the interconversion of CO2 yields CO. Radiation synthesized organic compounds such as carbonic acid were identified in the H2O + CO2 ice. Different chemical pathways dominate in the H2O + CO ice in which formaldehyde, methanol, ethanol, and methane were identified. Sublimed material was also analyzed using a mass spectrometer. Implications of these results are discussed in reference to comets.

Moore, M. H.↗
NASA NTRS1992

A regional estimate of convective transport of CO from biomass burning

A regional-scale estimate of the fraction of biomass burning emissions that are transported to the free troposphere by deep convection is presented. The focus is on CO and the study region is a part of Brazil that underwent intensive deforestation in the 1980s. The method of calculation is stepwise, scaling up from a prototype convective event, the dynamics of which are well-characterized, to the vertical mass flux of carbon monoxide over the region. Given uncertainties in CO emissions from biomass burning and the representativeness of the prototype event, it is estimated that 10-40 percent of CO emissions from the burning region may be rapidly transported to the free troposphere over the burning region. These relatively fresh emissions will produce O3 efficiently in the free troposphere where O3 has a longer lifetime than in the boundary layer.

Pickering, Kenneth E.↗
NASA NTRS1991

A comparison of wet and dry season ozone and CO over Brazil using in situ and satellite measurements

A comparison conducted between direct measurements of Brazilian ozone and NO concentrations and space-based measurements has indicated a strong correlation between the two environmental sensing methods and indicated the seasonality of both ozone and CO concentrations in this region. Dry season increases appear to be due to both increased local biomass burning and the transport of CO and ozone from Africa. The coincident high values of both CO and ozone suggest photochemical sources, rather than a stratospheric source, for the African and South American ozone.

Watson, Catherine E.↗
NASA NTRS1991

Impact of biomass burning on tropospheric CO and OH - A two-dimensional study

Results are presented from a 2D model of the troposphere and stratosphere which allows the derivation of a budget for CO, as well as the assessment of contributions from different sources in maintaining observed CO concentrations. Attention is given to the results of a time-dependent calculation which evaluates the impact of present-day biomass burning on CO, OH, and CH4, as well as the time constants for the system to respond to changes in the biomass source.

Rodriguez, Jose M.↗
NASA NTRS1992

Theoretical study of Cr(+) and Co(+) bound to H2 and N2

Binding energies of Co(H2)n(+) (n = 1-3) and CrN2(+) computed using the modified coupled-pair functional approach agree well with measured values. The calculations show that both H2 and N2 bond much more strongly to Co(+) than to Cr(+). Theoretical studies also show that despite the similar polarizabilities of N2 and Ar, the CrN2(+) binding energy is twice as large as that of CrAr(+) due to the charge-quadrupole contribution. Finally, the bonding of H2 and N2 with Na(+) and Mg(+) is contrasted with that for Cr(+) and Co(+).

Bauschlicher, Charles W., Jr.↗
NASA NTRS1993

Observations of the CO J=6-5 transition in starburst galaxies

Over the past several years, short-submillimeter observations of carbon monoxide's (CO) mid-J rotational levels have revealed the presence of a large amount of excited molecular gas in luminous giant molecular clouds in our Galaxy. Submillimeter lines are specific probes of excited material: collisional excitation of the level energy of 116 K above ground, and 6-5 transition's critical density is approximately 10(exp 6) cm(exp -3) in optically thin gas. Radiative trapping effects reduce the excitation requirements to some extent, but detection of the CO J=6-5 line is nearly indisputable proof of the existence of gas that is both warm and dense. The excitation conditions also imply that cool (T less than 20 K) molecular clouds within the beam neither emit nor absorb in the short-submillimeter lines; in our Galaxy, clouds with active massive star formation emit the strongest short-submillimeter CO rotational lines. We used these properties to explore the distribution of excited molecular material and physical conditions within the star formation regions of several classical starburst nuclei: NGC253, M82, and IC342. We have used the 6-5 transition as a thermometer of warm molecular gas in starburst nuclei, unambiguously finding that the nuclear molecular gas in starburst galaxies is substantially warmer than in typical disk clouds.

Harris, A. I.↗
NASA NTRS1992

Fractionation of CO in the diffuse clouds toward Zeta Ophiuchi

An analysis of CO A-X bands in diffuse clouds toward Zeta Ophiuchi is presented. The results provide isotopic ratios that constitute the strongest observational evidence for highly localized isotopic fractionation of CO in diffuse portions of an interstellar cloud. The value of the fractionation implies that selective photodissociation is the controlling influence of the fractionation. The molecule's excitation temperature is discussed and a lower limit to the O-16/O-18 ratio is provided. The absence of CO lines from the gas that provides broad CH+ and CH lines commonly attributed to warm gas behind a shock front is addressed.

Sheffer, Yaron↗
NASA NTRS1993

CO(J = 1-0) line emission from giant molecular clouds

Numerical models of the (C-12)O (J = 1-0) line emission from giant molecular clouds (GMCs) have been constructed. Line profiles are presented for both microturbulent and macroturbulent clouds. The observed width of the CO (J = 1-0) line cannot be physically interpreted as a microturbulent gas velocity dispersion. Microturbulent models produce emission with a wide range of profile shapes and brightness temperatures at line center over a cloud mass range of 100 to 10 exp 6 solar masses. Macroturbulent models produce smooth, centrally peaked profiles. Clumpy GMC models can produce peak brightness temperatures over about 6 K provided that clump densities are larger than 1000/cu cm. If there are no significant velocity gradients, photoelectric heating dominates in the region where the CO line arises. The observed relation between cloud mass and CO luminosity can be constructed from theoretical models.

Wolfire, Mark G.↗
NASA NTRS1993

CO observations of candidates for carbon-rich asymptotic giant branch and post-asymptotic giant branch stars

Circumstellar CO emission has been detected in a number of featureless or weak SiC emission, low color temperature IRAS sources. The CO detections confirm the suggestion that these are either extreme carbon stars, carbon-rich proto-planetary nebulae (PPNs), or carbon-rich planetary nebulae (PNs). We find that the CO emission is relatively stronger for a given luminosity in post-AGB stars than AGB stars, suggesting a more efficient excitation mechanism is at work in the post-AGB phase. One probable post-AGB star was detected in HCN for the first time. The available HCN data suggest a rapid decline in HCN emission after the AGB. Molecular emission is shown to be a useful tracer of the evolution from asymptotic giant branch to the planetary nebula phase.

Volk, Kevin↗
NASA NTRS1993

Extended CO(7-6) emission from warm gas in Orion

Results of a search for extended CO(7-6) line emission in the Orion A molecular cloud using the University of Texas submillimeter laser heterodyne receiver are presented. The large-scale distribution of quiescent CO(7-6) emission is mapped along a cut across the Trapezium cluster extending more than 13 arcmin (nearly 2 pc) in R.A. The receiver, observing method, and calibration techniques are described, and the CO(7-6) spectra and maps are presented. The physical parameters and energetics of the molecular gas are discussed. The findings are compared with observations of other high-luminosity star-forming regions.

Howe, J. E.↗
NASA NTRS1994

Evidence for Ni-56 yields Co-56 yields Fe-56 decay in type Ia supernovae

In the prevailing picture of Type Ia supernovae (SN Ia), their explosive burning produces Ni-56, and the radioactive decay chain Ni-56 yields Co-56 yields Fe-56 powers the subsequent emission. We test a central feature of this theory by measuring the relative strengths of a (Co III) emission feature near 5900 A and a (Fe III) emission feature near 4700 A. We measure 38 spectra from 13 SN Ia ranging from 48 to 310 days after maximum light. When we compare the observations with a simple multilevel calculation, we find that the observed Fe/Co flux ratio evolves as expected when the Fe-56/Co-56 abundance ratio follows from Ni-56 yields Co-56 yields Fe-56 decay. From this agreement, we conclude that the cobalt and iron atoms we observe through SN Ia emission lines are produced by the radioactive decay of Ni-56, just as predicted by a wide range of models for SN Ia explosions.

Kuchner, Marc J.↗
NASA NTRS1994

Imaging spectroscopy of the solar CO lines at 4.67 microns

We analyze spatially and temporally resolved spectra of the fundamental vibration-rotation transitions of carbon monoxide (CO) in the solar spectrum at 4.67 micrometers. Our observations imply that, in the quiet Sun, spatial variations in CO intensity are largely dynamical in nature, reinforcing the suggestion that dynamical effects play a key role in the formation of the dark CO cores. Time sequences of resolved spectra exhibit mainly 3 minute power in line-core intensity but mainly a 5 minute period in Doppler shift. The weak 7-6 R68 line shows normal Evershed flow in the penumbra of a sunspot; we find evidence for the onset of inverse Evershed flow in the strong 3-2 R14 line. Spectra at the limb indicate that 3-2 R14 emission extends approximately 360 km beyond the continuum limb.

Uitenbroek, Han↗
NASA NTRS1993

Detection of the Carbon Monoxide Ion (CO+) in the Interstellar Medium and a Planetary Nebula

We report detection of the carbon monoxide ion (CO+) in the interstellar medium (Ml7SW) and a planetary nebula (NGC 7027). These detections are based on observations of three millimeter and submillimeter transitions in M17SW and one in NGC 7027. Chemical models suggest that CO+ should be most abundant where complex molecules are least likely to be present. In our search for CO+ we therefore minimized the chance of confusion while maximizing the probability of detection by observing regions whose chemistry is dominated by the effects of ultraviolet radiation.

Latter, William B.↗
NASA NTRS1997

Kinetics and Thermochemistry of ClCO Formation from the Cl + CO Association Reaction

Laser flash photolysis of Cl2/CO/M mixtures (M = N2, CO, Ar, CO2) has been employed in conjunction with Cl((sup 2)P(sub J)) detection by time-resolved resonance fluorescence spectroscopy to investigate equilibration kinetics in the reactions Cl((sup 2)P(sub J)) + CO ClCO as a function of temperature (185-260 K) and pressure (14-200 Torr). The association and dissociation reactions are found to be in the low-pressure limit over the range of experimental conditions investigated. In N2 and/or CO buffer gases, the temperature dependences of the ClCO formation and dissociation reaction rate constants are described by the Arrhenius expressions k(sub 1) = (1.05 +/- 0.36) x 10(exp -34) exp[(810 +/- 70)/T] cm(exp 6)/molecules(exp 2).s and k(sub -1) = (4.1 +/- 3.1) x 10(exp -10) exp[(-2960 +/- 60)/T]cu cm/(molecule.s) (errors are 2 sigma). Second- and third-law analyses of the temperature dependence of the equilbrium constant (k/k-1) lead to the following thermodynamic parameters for the association reaction: Delta-H(sub 298) = -7.7 +/- 0.6 kcal/mol, Delta-H(sub 0) = -6.9 +/- 0.7 kcal/mol, Delta-S(sub 298) = -23.8 +/- 2.0 cal/mole.K, Delta-H(sub f,298)(ClCO) = 5.2 +/- 0.6 kcal/mol (errors are 2 sigma). The results repported in this study significantly reduce the uncertainties in all reported kinetic and thermodynamic parameters.

Nicovich, J. M.↗
NASA NTRS1999

Polar Stratospheric Descent of NO(y) and CO and Arctic Denitrification During Winter 1992-1993

Observations inside the November 1994 Antarctic stratospheric vortex and inside the April 1993 remnant Arctic stratospheric vortex by the Atmospheric Trace Molecule Spectroscopy (ATMOS) Fourier transform spectrometer are reported. In both instances, elevated volume mixing ratios (VMRS) of carbon monoxide (CO) were measured. A peak Antarctic CO VMR of 60 ppbv (where 1 ppbv = 10(exp -9) per unit Volume) was measured at a potential temperature of 710 K (about 27 km), about 1 km below the altitude of a pocket of elevated NO(y) (total reactive nitrogen) at a deep minimum in N2O (<5 ppbv). The Arctic observations also show a region of elevated vortex CO with a peak VMR of 90 ppbv it 630-670 K (-25 km) but no corresponding enhancement in NO(sub y) perhaps because of stronger dynamical activity in the northern hemisphere polar winter and/or interannual variability in the production of mesospheric or lower thermospheric NO. By comparing vortex and extravortex observations of NO(y) obtained at the same N2O VMR, Arctic vortex denitrification of 5 +/- 2 ppbv at 470 K (at approximately 18 km) is inferred. We show that our conclusion of substantial Arctic winter 1992-1993 denitrification is robust by comparing our extravortex observations with previous polar measurements obtained over a wide range of winter conditions. Correlations of NO(y) with N2O measured at the same potential temperature by ATMOS in the Arctic vortex and at midlatitudes on board the ER-2 aircraft several weeks later lie along the same mixing line. The result demonstrates the consistency of the two data sets and confirms that the ER-2 sampled fragments of the denitrified Arctic vortex following its breakup. An analysis of the ATMOS Arctic measurements of total hydrogen shows no evidence for significant dehydration inside the vortex.

Rinsland, C. P.↗