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At least 343 records · Page 19

Effect of pore pressure buildup on slowness of rupture propagation

Pore fluid pressure is known to play an important role in brittle fracture initiation and propagation, yet the underlying mechanisms remain unclear. We conducted triaxial experiments on saturated porous sandstones to investigate effects of pore pressure buildup on the slowness of shear rupture propagation at different confining pressures. At low to intermediate confinements, rocks fail by brittle faulting, and pore pressure buildup causes a reduction in rock’s shear strength but does not induce measurable differences in slip behavior. When the confinement is high enough to prohibit dynamic faulting, rocks fail in the brittle-ductile transitional regime. In the transitional regime, pore pressure buildup promotes slip instability on an otherwise stably sliding fracture. Compared to those observed in the brittle regime, the slip rate, stress drop, and energy dissipated during rupture propagation with concurrent pore pressure buildup in the transitional regime are distinctively different. When decreasing confining pressure instead, the slip behavior resembles the ones of the brittle regime, emphasizing h ow the observed slowness is related to excess pore pressure beyond the effective pressure phenomenon. Analysis of the mechanical data using existing theoretical models confirms these observations. Quantitative microstructural analyses reveal that increasing pore pressure lessens the dilatancy hardening during failure, thus enhances slip along the localized zone in the transitional regime. Lastly, our experimental results suggest that pore pressure buildup induces slow slip in the transitional regime, and slip rates along a shear fracture may vary considerably depending on effective stress states.

58 GEOSCIENCES↗

Statistical Models of Fracture Relevant to Nuclear-Grade Graphite: Review and Recommendations

The nuclear-grade (low-impurity) graphite needed for the fuel element and moderator material for next-generation (Gen IV) reactors displays large scatter in strength and a nonlinear stress-strain response from damage accumulation. This response can be characterized as quasi-brittle. In this expanded review, relevant statistical failure models for various brittle and quasi-brittle material systems are discussed with regard to strength distribution, size effect, multiaxial strength, and damage accumulation. This includes descriptions of the Weibull, Batdorf, and Burchell models as well as models that describe the strength response of composite materials, which involves distributed damage. Results from lattice simulations are included for a physics-based description of material breakdown. Consideration is given to the predicted transition between brittle and quasi-brittle damage behavior versus the density of damage (level of disorder) within the material system. The literature indicates that weakest-link-based failure modeling approaches appear to be reasonably robust in that they can be applied to materials that display distributed damage, provided that the level of disorder in the material is not too large. The Weibull distribution is argued to be the most appropriate statistical distribution to model the stochastic-strength response of graphite.

Nemeth, Noel N.↗

The Effect of Prestrain Temperature on Kinetics of Static Recrystallization, Microstructure Evolution, and Mechanical Properties of Low Carbon Steel

In this research, the samples of a low carbon steel sheet were rolled up to a thickness prestrain of 67% at three different temperatures consisted of room, blue brittleness, and subzero temperature. Microhardness, SEM, and tensile tests were carried out to evaluate the static recrystallization kinetics defined by the Avrami equation, microstructural evolution, and mechanical properties. It was found that the Avrami exponent is altered with change in prestrain temperature and it achieves the value of 1 to 1. 5. Moreover, it was indicated that prestraining at subzero temperature followed by annealing at 600 °C leads to considerable enhancement in tensile properties and kinetics of static recrystallization compared to room and blue brittleness temperatures. The prestraining at blue brittleness temperature followed by annealing treatment caused, however, a higher strength and faster kinetics compared with that at room temperature. It was concluded that although from the steel ductility point of view, the blue brittleness temperature is called an unsuitable temperature, but it can be used as prestraining temperature to develop noticeable combination of strength and ductility in low carbon steel.

36 MATERIALS SCIENCE↗

Microstructure and Mechanical Property Improvement in Laser-Welded TC4 Titanium Alloy and 301L Stainless Steel Joints Without Filler Metal

Pulsed laser welding of Ti alloy to stainless steel (SS) has been applied without filler metal. When the laser beam was focused on the Ti alloy–SS interface, large volumes of Ti-Fe intermetallics were formed in the joint. These Ti-Fe intermetallics were highly brittle, causing the joint to crack spontaneously after welding. The brittle coarse Ti-Fe intermetallics seriously deteriorates the joint strength of Ti alloy and SS; therefore, it is necessary to control the quantities and distributions of brittle Ti-Fe intermetallics in the joint. The amount of melted base materials was controlled by changing laser offset to control the melted proportion and thus control the quantity and distribution of brittle Ti-Fe intermetallics in weld. When laser beam was on the SS side, melting amount of Ti alloy in weld was decreased. When laser beam was on the Ti alloy side, melting amount of SS in weld was decreased. When the laser offset was 0.35 mm away from SS side, the sample realizes the effective connection between Ti alloy and SS. A compound layer was formed at the SS side with the main microstructure of β-Ti and TiFe{sub 2}. The joint fractured at the compound layer with the maximum tensile strength of 182 MPa. Microstructures and mechanical properties of joints were improved by changing laser offset.

36 MATERIALS SCIENCE↗

Texture evolution and microcracking mechanisms in as-extruded and cross-rolled conditions of a 14YWT nanostructured ferritic alloy

Cr-stabilized nanostructured ferritic alloys (NFAs), dispersion strengthened by an ultra-high density of nanooxides, are attractive candidates for many nuclear energy applications due to their high-temperature strength, in-service stability and remarkable irradiation tolerance. However, typical NFA deformation processing paths lead to crystallographic texturing, formation of brittle microstructures and low toughness orientations, making fabricating components very difficult. In this paper, we characterize the dislocation-mediated deformation mechanisms that lead to the brittle texture component. The as-extruded bar is less brittle than the cross-rolled plate, which contains a large population of pre-existing cleavage microcracks. More generally, deformed ODS/NFAs are most often textured and have anisotropic low toughness orientations, even absent microcracks. However, cross-rolling produces a very high volume fraction of a plate normal {001}<110>-texture component, which constitutes the brittle cleavage system in iron. Finally, microcracks propagate along {001} low angle deformation induced subgrain boundaries in <110> directions after nucleating by the Cottrell mechanism.

36 MATERIALS SCIENCE↗

Faulting of natural serpentinite: Implications for intermediate-depth seismicity

The seismic potential of serpentinites at high pressure was investigated via deformation experiments on cored natural serpentinite samples, during which micro-seismicity was monitored by recording Acoustic Emissions (AEs). Deformation was performed at pressures of 3–5 GPa, using a Deformation-DIA device, and over a wide range of temperatures, both within and outside antigorite's stability field. Below 400 °C, serpentinite deformation involves “silent” semi-brittle mechanisms, even in cases where strain localization is observed. At high temperature (i.e., above 600 °C), despite conditions propitious to dehydration embrittlement (i.e., fast strain rates and reaction kinetics), joint deformation and dehydration lead to ductile shear, without generation of AEs. Brittle behavior was observed in a narrow temperature window ca. 500 °C. In this latter case, AEs are consistently observed upon faulting and extremely sharp strain localization is observed in recovered samples. The resulting microstructures are consistent with the inverse ductile-to-brittle transition proposed by Proctor and Hirth (2016) in antigorite. This may therefore be a source of seismicity in subducting slabs at mantle pressures and temperatures from 500 to 600 °C. However, the acoustic signal observed here is orders of magnitude weaker than what is obtained at low PT conditions with brittle failure, consistently with low radiation efficiency of serpentinite faulting (Prieto et al., 2013) and suggests that other mechanisms are responsible for large intermediate-depth earthquakes. In fact, the present results are in line with a recent study (Ferrand et al., 2017), that suggests that intermediate earthquakes are likely induced by mechanical instabilities due to dehydration in partly hydrated peridotites.

58 GEOSCIENCES↗

Irradiation dose and temperature dependence of fracture toughness in high dose HT9 steel from the fuel duct of FFTF

To expand the knowledge base for fast reactor core materials, fracture toughness has been evaluated for high dose HT9 steel using miniature disk compact tension (DCT) specimens. The HT9 steel DCT specimens were machined from the ACO-3 fuel duct of the Fast Flux Test Facility (FFTF), which achieved high doses in the range of 3–148 dpa at 378–504 C. The static fracture resistance (J-R) tests have been performed in a servohydraulic testing machine in vacuum at selected temperatures including room temperature, 200 C, and each irradiation temperature. Brittle fracture with a low toughness less than 50 MPa pm occurred in room temperature tests when irradiation temperature was below 400 C, while ductile fracture with stable crack growth was observed when irradiation temperature was higher. No fracture toughness less than 100 MPa pm was measured when the irradiation temperature was above 430 C. It was shown that the influence of irradiation temperature was dominant in fracture toughness while the irradiation dose has only limited influence over the wide dose range 3–148 dpa. A slow decrease of fracture toughness with test temperature above room temperature was observed for the nonirradiated and high temperature (>430 *C) irradiation cases, which indicates that the ductile–brittle transition temperatures (DBTTs) in those conditions are lower than room temperature. A comparison with the collection of existing data confirmed the dominance of irradiation temperature in the fracture toughness of HT9 steels.

Byun, Thak Sang↗

A multiscale microstructural approach to ductile-phase toughened tungsten for plasma-facing materials

Increasing fracture toughness and decreasing the ductile-brittle transition temperature of a tungsten-alloy has been shown to be feasible by ductile-phase toughening of tungsten. In this method, a ductile phase is included in a brittle tungsten matrix to prevent fracture propagation by crack bridging or crack deflection. This paper models the deformation behavior of ductile phase toughened tungsten materials such as tungsten-copper composites using a multiscale modeling approach that involves a microstructural dual-phase (copper-tungsten) region of interest where the constituent phases are finely discretized and are described by a continuum damage mechanics model. Large deformation, damage and fracture are allowed to occur and are modeled in this region that is connected to the adjacent homogenized elastic regions to form a macroscopic structure such as a test specimen. This paper illustrates such a multiscale modeling approach to analyze un-notched and single-edge notched (SENB) tungsten-copper composite specimens subjected to three-point bending. The predicted load-displacement responses and crack propagation patterns are compared to the corresponding experimental results to validate the model.

Nguyen, Ba Nghiep↗

Investigation of the temperature-dependent failure processes in PVD Cr-coated ZIRLO nuclear fuel cladding using in situ X-ray micro-tomography imaging

In this work, an accident tolerant fuel cladding system with Cr coating deposited using physical vapour deposition (PVD) method onto commercial Optimized ZIRLO™ was studied. The cladding tubes were machined into C-rings and loaded to failure under compression with real-time synchrotron micro-X-ray computed tomography (XCT) imaging at room temperature (RT), 345 °C, 650 °C and 950 °C in argon (Ar) atmosphere. The mechanical behaviour and failure processes were found strongly temperature-dependent where the Cr coating showed brittle fracture at RT and 345 °C, ductile fracture at 650 °C and a reversion to brittle fracture at 950 °C. Nanoindentation measurements and scanning electron microscopy (SEM) imaging were conducted on the materials after high temperature testing. It was found that recrystallisation of the Cr coating occurred at elevated temperatures, which significantly affected its local properties hence the failure behaviour at different temperatures. This work represents the first in situ 3D XCT observation of progressive failure processes in PVD Cr-coated ZIRLO claddings up to 950 °C providing critical insights into its brittle-to-ductile transition (BDTT) behaviour and subsequent ductile-to-brittle reversion with the increase in temperature. Moreover, results are compared with other PVD Cr-coated Zircaloy materials from open literature; the influences of the coating microstructure and local properties on the failure stress/strain and fracture processes are discussed.

Yuan, Guanjie↗

Development and deployment of constitutive softening routines in Eulerian hydrocodes.

The state of the art in failure modeling enables assessment of crack nucleation, propagation, and progression to fragmentation due to high velocity impact. Vulnerability assessments suggest a need to track material behavior through failure, to the point of fragmentation and beyond. This eld of research is particularly challenging for structures made of porous quasi-brittle materials, such as ceramics used in modern armor systems, due to the complex material response when loading exceeds the quasi-brittle material's elastic limit. Further complications arise when incorporating the quasi-brittle material response in multi-material Eulerian hydrocode simulations. In this report, recent e orts in coupling a ceramic materials response in the post-failure regime with an Eulerian hydro code are described. Material behavior is modeled by the Kayenta material model [2] and Alegra as the host nite element code [14]. Kayenta, a three invariant phenomenological plasticity model originally developed for modeling the stress response of geologic materials, has in recent years been used with some success in the modeling of ceramic and other quasi-brittle materials to high velocity impact. Due to the granular nature of ceramic materials, Kayenta allows for signi cant pressures to develop due to dilatant plastic ow, even in shear dominated loading where traditional equations of state predict little or no pressure response. When a material's ability to carry further load is compromised, Kayenta allows the material's strength and sti ness to progressively degrade through the evolution of damage to the point of material failure. As material dilatation and damage progress, accommodations are made within Alegra to treat in a consistent manner the evolving state.

Fuller, Timothy Jesse↗

Real-Time Observation of Nanoscale Kink Band Mediated Plasticity in Ion-Irradiated Graphite: An In Situ TEM Study

Graphite IG-110 is a synthetic polycrystalline material used as a neutron moderator in reactors. Graphite is inherently brittle and is known to exhibit a further increase in brittleness due to radiation damage at room temperature. To understand the irradiation effects on pre-existing defects and their overall influence on external load, micropillar compression tests were performed using in situ nanoindentation in the Transmission Electron Microscopy (TEM) for both pristine and ion-irradiated samples. While pristine specimens showed brittle and subsequent catastrophic failure, the 2.8 MeV Au2+ ion (fluence of 4.378 × 1014 cm−2) irradiated specimens sustained extensive plasticity at room temperature without failure. In situ TEM characterization showed nucleation of nanoscale kink band structures at numerous sites, where the localized plasticity appeared to close the defects and cracks while allowing large average strain. We propose that compressive mechanical stress due to dimensional change during ion irradiation transforms buckled basal layers in graphite into kink bands. The externally applied load during the micropillar tests proliferates the nucleation and motion of kink bands to accommodate the large plastic strain. The inherent non-uniformity of graphite microstructure promotes such strain localization, making kink bands the predominant mechanism behind unprecedented toughness in an otherwise brittle material.

36 MATERIALS SCIENCE↗

Directionally solidified composite systems under evaluation

The directionally solidified eutectic in-situ composites being evaluated for use as turbine materials range from ductile-ductile systems, where both matrix and reinforcement are ductile, to brittle-brittle systems, where both phases are brittle. The alloys most likely to be used in gas turbine engines in the near term are the lamellar ductile-semiductile alloys gamma prime-delta, Ni3Al-Ni3Nb and gamma/gamma prime-delta Ni,Cr,Cb,Al/Ni3Al-Ni3Nb and the fibrous ductile-brittle alloys M-MC CoTaC or NiTaC and M-M7C3(Co,Cr,Al)-(Cr,Co)7C3. Gamma-prime strengthened NiTaC alloys and a (Co,Cr,Al)-(Co,Cr)7C3 have greater tensile strength than the strongest superalloys at temperatures up to about 600 C. The gamma prime-delta and gamma/gamma prime-delta alloys in the Ni,Al,Nb(Cr) systems have greater tensile strength than the superalloys at temperatures greater than 800 C. At low stresses fibrous carbide reinforced eutectic alloys have longer lives at high temperatures than the strongest superalloys. Lamellar delta, Ni3Nb reinforced eutectic alloys have longer lives at high temperatures than the strongest superalloys at all stresses.

Ashbrook, R. L.↗

On the differences in continental rifting at the Earth, Mars and Venus

During the process of continental rifting on Earth, the lower ductile crust stretches, forming a neck, while the upper brittle crust is broken in blocks by faults, and the blocks sink down the thinned lower crust; if the stretching continues, the neck may break and a newly originated oceanic crust is formed at this place. The rift system structure depends on the depth of the boundary surface between the brittle crust and the ductile crust, the litospheric thickness, the tension value, etc.. The rigid brittle rifting when narrow necks form in the lower crust is characteristic of the contemporary Earth; on Mars the brittle rifting with large subsidence was characteristic of the Tharsis upland formation epoch. The ductile rifting is typical of the Venus. The differences in rheologic features of the lithospheres of different planets causes the variation in types of rifting.

Nikishin, A. M.↗

Early thermal profiles and lithospheric strength of Ganymede from extensional tectonic features

The early thermal profiles and the lithospheric stability and strength of Ganymede are quantitatively determined on the basis of brittle lithosphere thickness estimates derived from the width and spacing of extensional tectonic features, together with lithospheric strength envelopes for ice. Plots of the brittle and ductile yield stress vs. depth for the icy lithosphere of Ganymede exhibit a linear increase in brittle strength with depth to a maximum at the brittle-ductile transition that is followed by an exponential decrease in ductile yield stress with depth. The results obtained imply that the thermal gradient and lithospheric strength have varied laterally by factor as great as 5, and that Ganymede underwent cooling in a highly inhomogeneous fashion with lateral thermal anomalies. The present analysis furnishes reasons for the stability of large cratered terrain remnants.

Golombek, Matthew P.↗

Effects of Internal and External Hydrogen on Inconel 718

Internal hydrogen embrittlement (IHE) and hydrogen environment embrittlement (HEE) tensile and bend crack growth tests were performed on Inconel 718. For the IHE tests, the specimens were precharged to approximately 90 ppm hydrogen by exposure to 34.5 MPa H2 at 650 C. The HEE tests were performed in 34.5 MPa H2. Parameters evaluated were test temperature, strain rate for smooth and notch specimen geometries. The strain rate effect was very significant at ambient temperature for both IHE and HEE and decreased with increasing temperatures. For IHE, the strain rate effect was neglible at 260'C, and for HEE the strain rate effect was neglible at 400 C. At low temperatures, IHE was more severe than HEE, and at high temperatures HEE was more severe than IHE with a cross over temperature about 350 C. At 350 C, the equilibrium hydrogen concentration in Inconel 718 is about 50% lower than the hydrogen content of the precharged IHE specimens. Dislocation hydrogen sweeping of surface absorbed hydrogen was the likely transport mechanism for increasing the hydrogen concentration in the HEE tests sufficiently to produce the same degree of embrittlement as that of the more highly hydrogen charged IHE specimens. The main IHE fracture characteristic was formation of large, brittle flat facets, which decreased with increasing test temperature. The IHE fracture matrix surrounding the large facets ranged between brittle fine faceted to microvoid ductility depending upon strain rate, specimen geometry as well as temperature. The HEE fractures were characteristically fine featured, transgranular and brittle with a significant portion forming a "saw tooth" crystallographic pattern. Both IHE and HEE fractures were predominantly along the {1 1 1) slip and twin boundaries. With respect to embrittlement mechanism, it was postulated that dislocation hydrogen sweeping and hydrogen enhanced localized plasticity were active in HEE and IHE for concentrating hydrogen along (1 1 1) slip and twin planes. Final brittle failure occurred by hydrogen induced planer decohesion.

Walter, R. J.↗

Intelligent Pilot Aids for Flight Re-Planning in Emergencies

Experimental studies were conducted with pilots to investigate the attributes of automation that would be appropriate for aiding pilots in emergencies. The specific focus of this year was on methods of mitigating automation brittleness. Brittleness occurs when the automatic system is used in circumstances it was not designed for, causing it to choose an incorrect action or make an inaccurate decision for the situation. Brittleness is impossible to avoid since it is impossible to predict every potential situation the automatic system will be exposed to over its life. However, operators are always ultimately responsible for the actions and decisions of the automation they are monitoring or using, which means they must evaluate the automation's decisions and actions for accuracy. As has been pointed out, this is a difficult thing for human operators to do. There have been various suggestions as to how to aid operators with this evaluation. In the study described in this report we studied how presentation of contextual information about an automatic system's decision might impact the ability of the human operators to evaluate that decision. This study focused on the planning of emergency descents. Fortunately, emergencies (e.g., mechanical or electrical malfunction, on-board fire, and medical emergency) happen quite rarely. However, they can be catastrophic when they do. For all predictable or conceivable emergencies, pilots have emergency procedures that they are trained on, but those procedures often end with 'determine suitable airport and land as quickly as possible.' Planning an emergency descent to an unplanned airport is a difficult task, particularly under the time pressures of an emergency. Automatic decision aids could be very efficient at the task of determining an appropriate airport and calculating an optimal trajectory to that airport. This information could be conveyed to the pilot through an emergency descent procedure listing all of the actions necessary to safely land the plane. However, there is still the potential problem of brittleness. This study examined the impact of contextual information in presentations of emergency descent procedures to see if they might impact the pilot's evaluation of the feasibility of the presented procedure. The study and its results are described in detail.

Pritchett, Amy R.↗

Polyurea-Based Aerogel Monoliths and Composites

aerogel insulation material was developed that will provide superior thermal insulation and inherent radiation protection for government and commercial applications. The rubbery polyureabased aerogel exhibits little dustiness, good flexibility and toughness, and durability typical of the parent polyurea polymer, yet with the low density and superior insulation properties associated with aerogels. The thermal conductivity values of polyurea-based aerogels at lower temperature under vacuum pressures are very low and better than that of silica aerogels. Flexible, rubbery polyurea-based aerogels are able to overcome the weak and brittle nature of conventional inorganic and organic aerogels, including polyisocyanurate aerogels, which are generally prepared with the one similar component to polyurethane rubber aerogels. Additionally, with higher content of hydrogen in their structures, the polyurea rubber-based aerogels will also provide inherently better radiation protection than those of inorganic and carbon aerogels. The aerogel materials also demonstrate good hydrophobicity due to their hydrocarbon molecular structure. There are several strategies to overcoming the drawbacks associated with the weakness and brittleness of silica aerogels. Development of the flexible fiber-reinforced silica aerogel composite blanket has proven to be one promising approach, providing a conveniently fielded form factor that is relatively robust in industrial environments compared to silica aerogel monoliths. However, the flexible, silica aerogel composites still have a brittle, dusty character that may be undesirable, or even intolerable, in certain application environments. Although the cross - linked organic aerogels, such as resorcinol- formaldehyde (RF), polyisocyanurate, and cellulose aerogels, show very high impact strength, they are also very brittle with little elongation (i.e., less rubbery). Also, silica and carbon aerogels are less efficient radiation shielding materials due to their lower content of hydrogen element. The invention involves mixing at least one isocyanate resin in solvent along with a specific amount of at least one polyamine hardener. The hardener is selected from a group of polyoxyalkyleneamines, amine-based polyols, or a mixture thereof. Mixing is performed in the presence of a catalyst and reinforcing inorganic and/or organic materials, and the system is then subjected to gelation, aging, and supercritical drying. The aerogels will offer exceptional flexibility, excellent thermal and physical properties, and good hydrophobicity. The rubbery polyurea-based aerogels are very flexible with no dust and hydrophobic organics that demonstrated the following ranges of typical properties: densities of 0.08 to 0.293 g/cu cm, shrinkage factor (raerogel/rtarget) = 1.6 to 2.84, and thermal conductivity values of 15.2 to 20.3 mW/m K.

Lee, Je Kyun↗

Polyolefin-Based Aerogels

An organic polybutadiene (PB) rubberbased aerogel insulation material was developed that will provide superior thermal insulation and inherent radiation protection, exhibiting the flexibility, resiliency, toughness, and durability typical of the parent polymer, yet with the low density and superior insulation properties associated with the aerogels. The rubbery behaviors of the PB rubber-based aerogels are able to overcome the weak and brittle nature of conventional inorganic and organic aerogel insulation materials. Additionally, with higher content of hydrogen in their structure, the PB rubber aerogels will also provide inherently better radiation protection than those of inorganic and carbon aerogels. Since PB rubber aerogels also exhibit good hydrophobicity due to their hydrocarbon molecular structure, they will provide better performance reliability and durability as well as simpler, more economic, and environmentally friendly production over the conventional silica or other inorganic-based aerogels, which require chemical treatment to make them hydrophobic. Inorganic aerogels such as silica aerogels demonstrate many unusual and useful properties. There are several strategies to overcoming the drawbacks associated with the weakness and brittleness of silica aerogels. Development of the flexible fiber-reinforced silica aerogel composite blanket has proven one promising approach, providing a conveniently fielded form factor that is relatively robust toward handling in industrial environments compared to silica aerogel monoliths. However, the flexible silica aerogel composites still have a brittle, dusty character that may be undesirable, or even intolerable, in certain applications. Although the cross-linked organic aerogels such as resorcinol-formaldehyde (RF), polyisocyanurate, and cellulose aerogels show very high impact strength, they are also very brittle with little elongation (i.e., less rubbery). Also, silica and carbon aerogels are less efficient radiation shielding materials due to their lower content of hydrogen element. The present invention relates to maleinized polybutadiene (or polybutadiene adducted with maleic anhydride)- based aerogel monoliths and composites, and the methods for preparation. Hereafter, they are collectively referred to as polybutadiene aerogels. Specifically, the polybutadiene aerogels of the present invention are prepared by mixing a maleinized polybutadiene resin, a hardener containing a maleic anhydride reactive group, and a catalyst in a suitable solvent, and maintaining the mixture in a quiescent state for a sufficient period of time to form a polymeric gel. After aging at elevated temperatures for a period of time to provide uniformly stronger wet gels, the micro porous maleinized polybutadiene- based aerogel is then obtained by removing interstitial solvent by supercritical drying. The mesoporous maleinized polybutadiene-based aerogels contain an open-pore structure, which provides inherently hydrophobic, flexible, nearly unbreakable, less dusty aerogels with excellent thermal and physical properties. The materials can be used as thermal and acoustic insulation, radiation shielding, and vibration-damping materials. The organic PB-based rubber aerogels are very flexible, no-dust, and hydrophobic organics that demonstrated the following ranges of typical properties: densities of 0.08 to 0.255 grams per cubic centimeters, shrinkage factor (raerogel/rtarget) = 1.2 to 2.84, and thermal conductivity values of 20.0 to 35.0 mW/m-K.

Lee, Je Kyun↗