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At least 325 records · Page 18

Machine Learning Reduced Order Model for Cost and Emission Assessment of a Pyrolysis System

Biomass pyrolysis is a promising approach for producing economic and environmentally-friendly fuels and bioproducts. Biomass pyrolysis experiments show that feedstock properties have a significant impact on product yields and composition. Scientists are developing detailed chemical reaction mechanisms to capture the relationships between biomass composition and pyrolysis yields. These mechanisms can be computationally intensive. In this study, we investigate the use of a machine learning reduced order model (ROM) for assessing the costs and emissions of a pyrolysis biorefinery. Here, we developed a Kriging-based ROM to predict pyrolysis yields of 314 feedstock samples based on the results of a detailed chemical kinetic pyrolysis mechanism. The ROM is integrated into a chemical process model for calculating mass and energy yields in a commercial-scale (2000 tonne/day) biorefinery. The ROM estimated biofuel yields of 65 to 130 gallons per ton of dry biomass. This results in biofuel minimum fuel-selling prices of $2.62 to $5.43 per gallon and emissions of -13.62 to 145 kg of CO 2 per MJ. The ROM achieved an average mean square error of 1.8e-20 and a mean absolute error of 0.53%. These results suggest that ROMs can facilitate rapid feedstock screening for biorefinery systems.

09 BIOMASS FUELS↗

The Global Land-Ocean Temperature Index in Relation to Sunspot Number, the Atlantic Multidecadal Oscillation Index, the Mauna Loa Atmospheric Concentration of CO2, and Anthropogenic Carbon Emissions

Global warming/climate change has been a subject of scientific interest since the early 19th century. In particular, increases in the atmospheric concentration of carbon dioxide (CO2) have long been thought to account for Earth's increased warming, although the lack of a dependable set of observational data was apparent as late as the mid 1950s. However, beginning in the late 1950s, being associated with the International Geophysical Year, the opportunity arose to begin accurate continuous monitoring of the Earth's atmospheric concentration of CO2. Consequently, it is now well established that the atmospheric concentration of CO2, while varying seasonally within any particular year, has steadily increased over time. Associated with this rising trend in the atmospheric concentration of CO2 is a rising trend in the surface-air and sea-surface temperatures (SSTs). This Technical Publication (TP) examines the statistical relationships between 10-year moving averages (10-yma) of the Global Land-Ocean Temperature Index (GLOTI), sunspot number (SSN), the Atlantic Multidecadal Oscillation (AMO) index, and the Mauna Loa CO2 (MLCO2) index for the common interval 1964-2006, where the 10-yma values are used to indicate trends in the data. Scatter plots using the 10-yma values between GLOTI and each of the other parameters are determined, both as single-variate and multivariate fits. Scatter plots are also determined for MLCO2 using single-variate and bivariate (BV) fits, based on the GLOTI alone and the GLOTI in combination with the AMO index. On the basis of the inferred preferential fits for MLCO2, estimates for MLCO2 are determined for the interval 1885-1964, thereby yielding an estimate of the preindustrial level of atmospheric concentration of CO2. Lastly, 10-yma values of MLCO2 are compared against 10-yma estimates of the total carbon emissions (TCE) to determine the likelihood that manmade sources of carbon emissions are indeed responsible for the recent warming now being experienced. (Parametric values used in this TP are those available prior to the end of 2012.)

Wilson, Robert M.↗

Future Climate Change Impacts on U.S. Agricultural Yields, Production, and Market

This study provides estimates of climate change impacts on U.S. agricultural yields and the agricultural economy through the end of the 21st century, utilizing multiple climate scenarios. Results from a process-based crop model project future increases in wheat, grassland, and soybean yield due to climate change and atmospheric CO2 change; corn and sorghum show more muted responses. Results using yields from econometric models show less positive results. Both the econometric and process-based models tend to show more positive yields by the end of the century than several other similar studies. Using the process-based model to provide future yield estimates to an integrated agricultural sector model, the welfare gain is roughly $16B/year (2019 USD) for domestic producers and $6.2B/year for international trade, but domestic consumers lose $10.6B/year, resulting in a total welfare gain of $11.7B/year. When yield projections for major crops are drawn instead from econometric models, total welfare losses of more than $28B/year arise. Simulations using the process-based model as input to the agricultural sector model show large future production increases for soybean, wheat, and sorghum and large price reductions for corn and wheat. The most important factors are those about economic growth, flooding, international trade, and the type of yield model used. Somewhat less, but not insignificant factors include adaptation, livestock productivity, and damages from surface ozone, waterlogging, and pests and diseases.

Agricultural sector↗

Empirical estimation of weather-driven yield shocks using biophysical characteristics for U.S. rainfed and irrigated maize, soybeans, and winter wheat

Agricultural yields are highly susceptible to changes in weather system patterns, including both annual and sub-annual changes in temperature and precipitation. Understanding the impacts of future changes in meteorological variables on crop yields have been widely studied in both empirical and process-based models. This work presents a structural econometric approach that combines historical weather data with information about the biophysical growth cycles of maize, winter wheat, and soy to predict the year-to-year yield responses for rainfed crops. Modeled soil moisture and temperature are taken as key predictors, which allows testing the fitted rainfed model’s ability to predict irrigated yields by assuming irrigation produces the numerically optimal level of soil moisture. This approach is grounded in known biophysical processes, which improves confidence in the model predictions. It produces estimates of interannual variability in yields, which enable study of the effects of extreme events on agricultural productivity. Finally, it enables prediction of the potential impacts of changing weather patterns on irrigated crops in areas that are currently primarily rainfed. We present the results of the empirical model, fitted with rainfed data; out-of-sample validation on irrigated crops; and projections of yield shocks under multiple future climate scenarios. Under a bias-corrected GFDL RCP8.5 scenario, this approach predicts average yield change, relative to 2006-2020 average yields, across U.S. counties in the 2040-2060 period of -16.9% and -13.4% for rainfed and irrigated maize, of -19.1% and -18.4% for rainfed and irrigated soy, and of -4.0% and -2.0% for rainfed and irrigated winter wheat. And in the 2070-2090 period of -30.3% and -28.8 % for rainfed and irrigated maize, of -33.1% and -32.8% for rainfed and irrigated soy, and of -6.5% and -5.2%for rainfed and irrigated winter wheat.

54 ENVIRONMENTAL SCIENCES↗

An alternative approach to estimating rainfall rate by radar using propagation differential phase shift

In this work it is shown that for frequencies from 3 to 13 GHz, the ratio of the specific propagation differential phase shift phi(sub DP) to the rainfall rate can be specified essentially independently of the form of the drop size distribution by a function only of the mass-weighted mean drop size D(sub m). This significantly reduces one source of substantial bias errors common to most other techniques for measuring rain by radar. For frequencies 9 GHz and greater, the coefficient can be well estimated from the ratio of the specific differential attenuation to phi(sub DP), while at nonattenuating frequencies such as 3 GHz, the coefficient can be well estimated using the differential reflectivity. In practice it appears that this approach yields better estimates of the rainfall rate than any other current technique. The best results are most likely at 13.80 GHz, followed by those at 2.80 GHz. An optimum radar system for measuring rain should probably include components at a both frequencies so that when signals at 13.8 GHz are lost because of attenuation, good measurements are still possible at the lower frequency.

Jameson, A. R.↗

REQUEST: A Recursive QUEST Algorithm for Sequential Attitude Determination

In order to find the attitude of a spacecraft with respect to a reference coordinate system, vector measurements are taken. The vectors are pairs of measurements of the same generalized vector, taken in the spacecraft body coordinates, as well as in the reference coordinate system. We are interested in finding the best estimate of the transformation between these coordinate system.s The algorithm called QUEST yields that estimate where attitude is expressed by a quarternion. Quest is an efficient algorithm which provides a least squares fit of the quaternion of rotation to the vector measurements. Quest however, is a single time point (single frame) batch algorithm, thus measurements that were taken at previous time points are discarded. The algorithm presented in this work provides a recursive routine which considers all past measurements. The algorithm is based on on the fact that the, so called, K matrix, one of whose eigenvectors is the sought quaternion, is linerly related to the measured pairs, and on the ability to propagate K. The extraction of the appropriate eigenvector is done according to the classical QUEST algorithm. This stage, however, can be eliminated, and the computation simplified, if a standard eigenvalue-eigenvector solver algorithm is used. The development of the recursive algorithm is presented and illustrated via a numerical example.

Bar-Itzhack, Itzhack Y.↗

Polarimetric, Two-Color, Photon-Counting Laser Altimeter Measurements of Forest Canopy Structure

Laser altimeter measurements of forest stands with distinct structures and compositions have been acquired at 532 nm (green) and 1064 nm (near-infrared) wavelengths and parallel and perpendicular polarization states using the Slope Imaging Multi-polarization Photon Counting Lidar (SIMPL). The micropulse, single photon ranging measurement approach employed by SIMPL provides canopy structure measurements with high vertical and spatial resolution. Using a height distribution analysis method adapted from conventional, 1064 nm, full-waveform lidar remote sensing, the sensitivity of two parameters commonly used for above-ground biomass estimation are compared as a function of wavelength. The results for the height of median energy (HOME) and canopy cover are for the most part very similar, indicating biomass estimations using lidars operating at green and near-infrared wavelengths will yield comparable estimates. The expected detection of increasing depolarization with depth into the canopies due to volume multiple-scattering was not observed, possibly due to the small laser footprint and the small detector field of view used in the SIMPL instrument. The results of this work provide pathfinder information for NASA's ICESat-2 mission that will employ a 532 nm, micropulse, photon counting laser altimeter.

Harding, David J.↗

Evaluating soil moisture and yield of winter wheat in the Great Plains using Landsat data

Locating areas where soil moisture is limiting to crop growth is important for estimating winter-wheat yields on a regional basis. In the 1975-76 growing season, we evaluated soil-moisture conditions and winter-wheat yields for a five-state region of the Great Plains using Landsat estimates of leaf area index (LAI) and an evapotranspiration (ET) model described by Kanemasu et al (1977). Because LAI was used as an input, the ET model responded to changes in crop growth. Estimated soil-water depletions were high for the Nebraska Panhandle, southwestern Kansas, southeastern Colorado, and the Texas Panhandle. Estimated yields in five-state region ranged from 1.0 to 2.9 metric ton/ha.

Heilman, J. L.↗

Numerical Simulations of the Geospace Response to the Arrival of an Idealized Perfect Interplanetary Coronal Mass Ejection

Abstract Previously, Tsurutani and Lakhina (2014, https://doi.org/10.1002/2013GL058825 ) created estimates for a “perfect” interplanetary coronal mass ejection and performed simple calculations for the response of geospace, including . In this study, these estimates are used to drive a coupled magnetohydrodynamic‐ring current‐ionosphere model of geospace to obtain more physically accurate estimates of the geospace response to such an event. The sudden impulse phase is examined and compared to the estimations of Tsurutani and Lakhina (2014, https://doi.org/10.1002/2013GL058825 ). The physics‐based simulation yields similar estimates for Dst rise, magnetopause compression, and equatorial values as the previous study. However, results diverge away from the equator. values in excess of 30 nT/s are found as low as magnetic latitude. Under southward interplanetary magnetic field conditions, magnetopause erosion combines with strong region one Birkeland currents to intensify the response. Values obtained here surpass those found in historically recorded events and set the upper threshold of extreme geomagnetically induced current activity at Earth.

79 ASTRONOMY AND ASTROPHYSICS↗

The large area crop inventory experiment - A major demonstration of space remote sensing

The NASA-U.S. Department of Agriculture Large Area Crop Inventory Experiment (LACIE), aimed at using multispectral remote sensing data from Landsat 1 and 2 to generate accurate annual global crop production forecasts, is discussed. The forecasts take into account meteorological conditions as well as yield and acreage, and may be used to increase the discrimination of U.S. harvest estimates down to regional levels and to provide more accurate early-season predictions. Sample problems involving the determination of wheat harvests and the monitoring of drought conditions are described. Difficulties related to misidentification of abnormally-developing plantations, the automatic classification of homogeneous spectral groups, the computerized generation of colored maps, and the estimation of yields during years when exceptional meteorological conditions prevail are also considered. Samples of Landsat-generated classification maps for Western U.S. and for the Saratov, U.S.S.R. crop regions are given.

Macdonald, R. B.↗

Correlation of S-Band Weather Radar Reflectivity and ACTS Propagation Data in Florida

Previous work has shown that Ka-band attenuation due to rainfall and corresponding S-band reflectivity are highly correlated. This paper reports on work whose goal is to determine the feasibility of estimation and, by extension, prediction of one parameter from the other using the Florida ACTS propagation terminal (APT) and the nearby WSR-88D S-band Doppler weather radar facility operated by the National Weather Service. This work is distinguished from previous efforts in this area by (1) the use of a single-polarized radar, preventing estimation of the drop size distribution (e.g., with dual polarization) and (2) the fact that the radar and APT sites are not co-located. Our approach consists of locating the radar volume elements along the satellite slant path and then, from measured reflectivity, estimating the specific attenuation for each associated path segment. The sum of these contributions yields an estimation of the millimeter-wave attenuation on the space-ground link. Seven days of data from both systems are analyzed using this procedure. The results indicate that definite correlation of S-band reflectivity and Ka-band attenuation exists even under the restriciton of this experiment. Based on these results, it appears possible to estimate Ka-band attenuation using widely available operational weather radar data. Conversely, it may be possible to augment current radar reflectivity data and coverage with low-cost attenuation or sky temperature data to improve the estimation of rain rates.

Wolfe, Eric E.↗

Diurnal and Seasonal Solar Induced Chlorophyll Fluorescence and Photosynthesis in a Boreal Scots Pine Canopy

Solar induced chlorophyll fluorescence has been shown to be increasingly an useful proxy for the estimation of gross primary productivity (GPP), at a range of spatial scales. Here, we explore the seasonality in a continuous time series of canopy solar induced fluorescence (hereafter SiF) and its relation to canopy gross primary production (GPP), canopy light use efficiency (LUE), and direct estimates of leaf level photochemical efficiency in an evergreen canopy. SiF was calculated using infilling in two bands from the incoming and reflected radiance using a pair of Ocean Optics USB2000+ spectrometers operated in a dual field of view mode, sampling at a 30 min time step using custom written automated software, from early spring through until autumn in 2011. The optical system was mounted on a tower of 18 m height adjacent to an eddy covariance system, to observe a boreal forest ecosystem dominated by Scots pine. (Pinus sylvestris) A Walz MONITORING-PAM, multi fluorimeter system, was simultaneously mounted within the canopy adjacent to the footprint sampled by the optical system. Following correction of the SiF data for O2 and structural effects, SiF, SiF yield, LUE, the photochemicsl reflectance index (PRI), and the normalized difference vegetation index (NDVI) exhibited a seasonal pattern that followed GPP sampled by the eddy covariance system. Due to the complexities of solar azimuth and zenith angle (SZA) over the season on the SiF signal, correlations between SiF, SiF yield, GPP, and LUE were assessed on SZA <50° and under strictly clear sky conditions. Correlations found, even under these screened scenarios, resulted around ~r2 = 0.3. The diurnal responses of SiF, SiF yield, PAM estimates of effective quantum yield (ΔF/Fm′), and meteorological parameters demonstrated some agreement over the diurnal cycle. The challenges inherent in SiF retrievals in boreal evergreen ecosystems are discussed.

photosynthetic↗

CDGPS-Based Relative Navigation for Multiple Spacecraft

This thesis investigates the use of Carrier-phase Differential GPS (CDGPS) in relative navigation filters for formation flying spacecraft. This work analyzes the relationship between the Extended Kalman Filter (EKF) design parameters and the resulting estimation accuracies, and in particular, the effect of the process and measurement noises on the semimajor axis error. This analysis clearly demonstrates that CDGPS-based relative navigation Kalman filters yield good estimation performance without satisfying the strong correlation property that previous work had associated with "good" navigation filters. Several examples are presented to show that the Kalman filter can be forced to create solutions with stronger correlations, but these always result in larger semimajor axis errors. These linear and nonlinear simulations also demonstrated the crucial role of the process noise in determining the semimajor axis knowledge. More sophisticated nonlinear models were included to reduce the propagation error in the estimator, but for long time steps and large separations, the EKF, which only uses a linearized covariance propagation, yielded very poor performance. In contrast, the CDGPS-based Unscented Kalman relative navigation Filter (UKF) handled the dynamic and measurement nonlinearities much better and yielded far superior performance than the EKF. The UKF produced good estimates for scenarios with long baselines and time steps for which the EKF would diverge rapidly. A hardware-in-the-loop testbed that is compatible with the Spirent Simulator at NASA GSFC was developed to provide a very flexible and robust capability for demonstrating CDGPS technologies in closed-loop. This extended previous work to implement the decentralized relative navigation algorithms in real time.

Mitchell, Megan Leigh↗

Sensitivity of closed-loop eigenvalues and robustness

Analytical results are obtained in a present investigation of the way in which full state feedback controller and estimator eigenvalues in a closed-loop linear control system affect these eigenvalues' sensitivity with respect to uncertain plant parameters. A controller eigenvalue lying near an estimator eigenvalue yields large eigenvalue sensitivity, which should be reduced through the separation of controller eigenvalues from estimator eigenvalues.

Adamian, A.↗

Revised estimates for ozone reduction by shuttle operation

Previous calculations by five different modeling groups of the effect of space shuttle operations on the ozone layer yielded an estimate of 0.2 percent ozone reduction for the Northern Hemisphere at 60 launches per year. Since these calculations were made, the accepted rate constant for the reaction between hydroperoxyl and nitric oxide to yield hydroxyl and nitrogen dioxide, HO2 + NO yields OH + NO2, was revised upward by more than an order of magnitude, with a resultant increase in the predicted ozone reduction for chlorofluoromethanes by a factor of approximately 2. New calculations of the shuttle effect were made with use of the new rate constant data, again by five different modeling groups. The new value of the shuttle effect on the ozone layer was found to be 0.25 percent. The increase resulting from the revised rate constant is considerably less for space shuttle operations than for chlorofluoromethane production, because the new rate constant also increases the calculated rate of downward transport of shuttle exhaust products out of the stratosphere.

Potter, A. E.↗

Sub‐0.6 eV Inverted Metamorphic GaInAs Cells Grown on Inp and GaAs Substrates for Thermophotovoltaics and Laser Power Conversion

Abstract Inverted metamorphic Ga 0.3 In 0.7 As photovoltaic converters with sub‐0.60 eV bandgaps grown on InP and GaAs are presented. Threading dislocation densities are 1.3 ± 0.6 × 10 6 and 8.9 ± 1.7 × 10 6 cm −2 on InP and GaAs, respectively. The devices generate open‐circuit voltages of 0.386 and 0.383 V, respectively, under irradiance producing a short‐circuit current density of ≈10 A cm −2 , yielding bandgap‐voltage offsets of 0.20 and 0.21 V. Power and broadband reflectance measurements are used to estimate thermophotovoltaic (TPV) efficiency. The InP‐based cell is estimated to yield 1.09 W cm −2 at 1100 °C versus 0.92 W cm −2 for the GaAs‐based cell, with efficiencies of 16.8 versus 9.2%. The efficiencies of both devices are limited by sub‐bandgap absorption, with power weighted sub‐bandgap reflectances of 81% and 58%, respectively, the majority of which is assumed to occur in the graded buffers. The 1100 °C TPV efficiencies are estimated to increase to 24.0% and 20.7% in structures with the graded buffer removed, if previously demonstrated reflectance is achieved. These devices also have application to laser power conversion in the 2.0–2.3 µm atmospheric window. Peak laser power converter efficiencies of 36.8% and 32.5% are estimated under 2.0 µm irradiances of 1.86 and 2.81 W cm −2 , respectively.

14 SOLAR ENERGY↗

Evaluation of usefulness of Skylab EREP S-190 and S-192 imagery in multistage forest surveys

The author has identified the following significant results. The digital timber volume prediction system was tested with another test area in the Trinity Alps. The estimated gain in precision was somewhat lower than the estimate for the first test area (35%). A combined interpretation of the two areas was made, yielding an estimated gain of 44%, with high statistical significance. This interpretation was used to calibrate the system for an interpretation of 43 primary sample units distributed over 1600 square miles. Preliminary results indicate that a gain of 35% can be realized over this large area in northern California.

Langley, P. G.↗