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At least 325 records · Page 18

NASA-UVA Light Aerospace Alloy and Structures Technology program (LA2ST)

The objective of the LA2ST Program is to conduct interdisciplinary graduate student research on the performance of next generation, light-weight aerospace alloys, composites, and thermal gradient structures in collaboration with NASA-Langley researchers. The general aim is to produce relevant data and basic understanding of material mechanical response, environment/corrosion behavior, and microstructure; new monolithic and composite alloys; advanced processing methods; new solid and fluid mechanics analyses; measurement and modeling advances; and a pool of educated students for aerospace technologies. Specific technical objectives are presented for each of the following research projects: time-temperature dependent fracture in advanced wrought ingot metallurgy, and spray deposited aluminum alloys; cryogenic temperature effects on the deformation and fracture of Al-Li-Cu-In alloys; effects of aging and temperature on the ductile fracture of AA2095 and AA2195; mechanisms of localized corrosion in alloys 2090 and 2095; hydrogen interactions in aluminum-lithium alloys 2090 and selected model alloys; mechanisms of deformation and fracture in high strength titanium alloys (effects of temperature and hydrogen and effects of temperature and microstructure); evaluations of wide-panel aluminum alloy extrusions; Al-Si-Ge alloy development; effects of texture and precipitates on mechanical property anisotropy of Al-Cu-Mg-X alloys; damage evolution in polymeric composites; and environmental effects in fatigue life prediction - modeling crack propagation in light aerospace alloys.

Starke, Edgar A., Jr.↗

Outbursts in Symbiotic Binaries

Two models have been proposed for the outbursts of symbiotic stars. In the thermonuclear model, outbursts begin when the hydrogen burning shell of a hot white dwarf reaches a critical mass. After a rapid increase in the luminosity and effective temperature, the white dwarf evolves at constant luminosity to lower effective temperatures, remains at optical maximum for several years, and then returns to quiescence along a white dwarf cooling curve. In disk instability models, the brightness rises when the accretion rate from the disk onto the central white dwarf abruptly increases by factors of 5-20. After a few month to several year period at maximum, both the luminosity and the effective temperature of the disk decline as the system returns to quiescence.

Mushotzky, Richard↗

Outbursts in Symbiotic Binaries

Two models have been proposed for the outbursts of symbiotic stars. In the thermonuclear model, outbursts begin when the hydrogen burning shell of a hot white dwarf reaches a critical mass. After a rapid increase in the luminosity and effective temperature, the white dwarf evolves at constant luminosity to lower effective temperatures, remains at optical maximum for several years, and then returns to quiescence along a white dwarf cooling curve. In disk instability models, the brightness rises when the accretion rate from the disk onto the central white dwarf abruptly increases by factors of 5-20. After a few month to several year period at maximum, both the luminosity and the effective temperature of the disk decline as the system returns to quiescence. If most symbiotic stars undergo thermonuclear eruptions, then symbiotics are probably poor candidates for type I supernovae. However, they can then provide approx. 10% of the material which stars recycle back into the interstellar medium. If disk instabilities are the dominant eruption mechanism, symbiotics are promising type Ia candidates but recycle less material into the interstellar medium.

Sonneborn, George↗

Effect of Temperature on Fiber-Optic Delay

Fiber/jacket interactions affect performance. Attenuation and phase measurements made to assess effect of temperature on signal delay and attenuation in two fiber-optic cable samples.

Bergman, L. A.↗

Effects of temperature transients at fan inlet of a turbofan engine

The effects of fan inlet temperature transients on the performance and stability of a turbofan engine were determined. The experiment was conducted at 90 and 74 percent of low-pressure-rotor military speed (9525 rpm) and with fan inlet temperature distortions having circumferential extents of 90 deg, 180 deg, 270 deg, and 360 deg. Temperature transients were controlled by varying the magnitude and rate of change of the inlet temperature rise. The engine response ranged from a momentary compressor pressure disturbance to low-pressure-compressor stall. The compressor distortion limits decreased with decreasing low-pressure-rotor speed and increased with increasing circumferential extent of distortion. Analysis of the data suggests strongly that the distortion limits of the compressor are a function of a critical magnitude of inlet temperature rise and are independent of the temperature rise rate.

Abdelwahab, M.↗

Quantum Joule expansion of one-dimensional systems

Here, we investigate the Joule expansion of nonintegrable quantum systems that contain bosons or spinless fermions in one-dimensional lattices. A barrier initially confines the particles to be in half of the system in a thermal state described by the canonical ensemble and is removed at time t = 0. We investigate the properties of the time-evolved density matrix, the diagonal ensemble density matrix, and the corresponding canonical ensemble density matrix with an effective temperature determined by the total energy conservation using exact diagonalization. The weights for the diagonal ensemble and the canonical ensemble match well for high initial temperatures that correspond to negative effective final temperatures after the expansion. At long times after the barrier is removed, the time-evolved Rényi entropy of subsystems bigger than half can equilibrate to the thermal entropy with exponentially small fluctuations. The time-evolved reduced density matrix at long times can be approximated by a thermal density matrix for small subsystems. Few-body observables, like the momentum distribution function, can be approximated by a thermal expectation of the canonical ensemble with strongly suppressed fluctuations. The negative effective temperatures for finite systems go to non-negative temperatures in the thermodynamic limit for bosons, but there is a true thermodynamic effect for fermions, which is confirmed by finite-temperature density matrix renormalization group calculations. We propose the Joule expansion as a way to dynamically create negative temperature states for fermion systems with repulsive interactions.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Effect of temperature on surface noise

An experimental work is discussed whose objective was to obtain data that show the effect of temperature and temperature fluctuations on surface noise. This was accomplished experimentally by immersing a small chord airfoil in the turbulent airstream of a hot jet. The theory and experiment reported by Olsen (1976) provided a guide for designing and validating the hot jet experiment and for interpreting the data. It is shown that increased temperature causes a small decrease in the sound levels; at the same time it causes a shift in the spectra that is smaller but similar to the shift observed with subsonic hot jet noise.

Olsen, W.↗

Chromospheric activity and TiO bands in M giants

Low-resolution IUE spectra of 23 cool giant stars ranging from K3 through M6 have been used to examine chromospheric activity in late-type giants. Previous studies have suggested a decrease in the fractional flux, normalized to bolometric flux, of the Mg II resonance lines (an indicator of chromospheric activity) with effective temperature. Using more accurately determined effective temperatures, this decrease is confirmed and found to be more rapid than previously suggested. A strong correlation is found between relative TiO band strengths, as measured by the Wing TiO index, and the level of chromospheric activity, as measured by Mg II fluxes. Cool giants which have weak TiO bands relative to the mean TiO strengths for stars of similar color also have Mg II lines that are weaker than the mean. Changes in composition and in chromospheric activity as a consequence of aging are suggested as a possible origin of this interesting relation.

Steiman-Cameron, T. Y.↗

The Effects of Temperature, Humidity and Aircraft Fluid Exposure on T800H/3900-2 Composites Bonded with AF-555M Adhesive

Fiber reinforced resin matrix composites and structural adhesives have found increased usage on commercial and military aircraft in recent years. Due to the lack of service history of these relatively new material systems, their long-term aging performance has not been well established. In this study, single lap shear specimens (SLS) were fabricated by secondary bonding of Scotch-Weld(TradeMark) AF-555M between pre-cured adherends comprised of T800H/3900-2 uni-directional laminates. The adherends were co-cured with wet peel-ply for surface preparation. Each bond-line of the SLS specimen was measured to determine thickness and inspected visually using an optical microscope for voids. A three-year environmental aging plan for the SLS specimens at 82 C (180 F) and 85% relative humidity was initiated. SLS strengths were measured for both controls and aged specimens at room temperature and 82 C. The effect of this exposure on lap shear strength and failure modes to date is reported. In addition, the effects of water, saline water, deicing fluid, JP-5 jet fuel and hydraulic fluid on both the composite material and the adhesive bonds were investigated. The up to date results on the effects of these exposures will be discussed.

Miner, Gilda A.↗

Phase evolution in two-phase alloys during severe plastic deformation

Herein, phase evolution in FCC metals with strongly interacting alloy components during severe plastic deformation is investigated using molecular dynamics simulations. Specifically, we study the alloy microstructure in steady state, nucleation and growth of precipitates in supersaturated alloys, and the decomposition of precipitates in undersaturated alloys. The results are compared to a modified effective temperature model, providing a physical understanding for the atomic processes underlying the model and a perspective on its strengths and weaknesses. Key observations in this work are nucleation and growth of precipitates during SPD at a temperature of 100 K; Gibbs-Thomson-like behavior relating solubility to precipitate size under steady-state shearing; a direct relationship between the effective temperature and the shear modulus; and the importance of cluster agglomeration during precipitate growth. The study also reveals that the mechanisms of forced chemical mixing depends on precipitate size, adding complications for effective temperature models describing inhomogeneous systems. The simulations are shown to provide good semiquantitative agreement with experimental findings reported in the literature.

36 MATERIALS SCIENCE↗

Effects of temperature and humidity cycling on the strengths of textile reinforced carbon/epoxy composite materials

Results are presented from an experimental evaluation of the combined effects of temperature and humidity cycling on AS4/3501-6 composites (unstitched, Kevlar 29 stitched, and S-2 glass stitched uniweave fabric) and AS4/E905L composites (2-D, S-2 glass stitched 2-D, and 3-D braided fabric). The AS4/3501-6 uniweave material had a quasi-isotropic layup, whereas the AS4/E905L materials were braided in a (+/-30 deg/0 deg)(sub s) orientation. Data presented include compression strengths and compression-compression fatigue results for uncycled composites and cycled composites (160, 480, 720, and 1280 cycles from 140 deg F at 95 percent relative humidity to -67 deg F). To observe the presence of microcracking within the laminates, photomicrographs were taken of each material type at the end of each cycling period. Microcracks were found to be more prevalent within stitched laminates, predominantly around individual stitches. The glass stitched laminates showed significant microcracking even before cycling. Less microcracking was evident in the Kevlar stitched materials, whereas the unstitched uniweave material developed microcracks only after cycling. The 3-D braid did not develop microcracks. The static compression strengths of the unstitched and Kevlar stitched uniweave materials were degraded by about 10 percent after 1280 temperature/humidity cycles, whereas the reduction in compression strength for the glass stitched uniweave was less than 3 percent. The reduction in compression strength for the glass stitched 2-D braid was less than 8 percent. The unstitched 2-D and 3-D braids did not lose strength from temperature/humidity cycling. The compression-compression fatigue properties of all six material types were not affected by temperature/humidity cycling.

Cano, Roberto J.↗

Relative quantum yield of I-asterisk(2P1/2) in the tunable laser UV photodissociation of i-C3F7I and n-C3F7I - Effect of temperature and exciplex emission

Wavelength-specific relative quantum yields of metastable I from pulsed laser photodissociation of i-C3F7I and n-C3F7I in the range 265-336 nm are determined by measuring the time-resolved infrared emission from the atomic I(P-2(1/2) P-2(3/2) transition. It is shown that although this yield appears to be unity from 265 to 298 nm, it decreases dramatically at longer wavelengths. Values are also reported for the enhancement of emission from metastable I due to exciplex formation at several temperatures. The exciplex formation emission increases linearly with parent gas pressure, but decreases with increasing temperature. Absorption spectra of i- and n-C3F7I between 303 and 497 K are presented, and the effect of temperature on the quantum yields at selected wavelengths greater than 300 nm, where increasing the temperature enhances the absorption considerably, are given. The results are discussed in regard to the development of solar-pumped iodine lasers.

Smedley, J. E.↗

Effect of temperature on capacity fade in silicon-rich anodes

Coin half-cells containing 80 wt% silicon electrodes are assembled and cycled at the similar to C/10 rate in the temperature range of 25-55 degrees C. To the best of our knowledge, this is the first time that the effect of temperature is reported for such high-silicon-containing cells. Two different electrolytes are used in this study, a baseline electrolyte and the baseline electrolyte +10 wt% fluoroethylene carbonate (FEC). Analysis of the capacity vs. cycle count data by curve fitting reveals that the addition of FEC markedly affects the capacity loss mechanism. Without FEC, the kinetic rate law for the capacity loss mechanism can be described as the sum of two logistic growth models. With the addition of FEC, the rate law depends on ln(t). Clearly, the addition of FEC has a profound effect on the mechanism of capacity loss. Interestingly, X-ray photoelectron spectroscopy (XPS) shows that the composition of the solid electrolyte interphase (SEI) layer changes markedly from mostly organic to mostly inorganic in the presence of FEC and how it varies at the different temperatures tested, especially in the absence of FEC.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Thermonuclear breakup reactions of light nuclei. I - Processes and effects

Temperature and density conditions are considered for the occurrence of breakup reactions of light nuclei in astrophysical plasmas. The proton-induced endothermic process is shown to be the principal mechanism for nuclear breakdown in a plasma. The phenomenon occurs at a temperature of about 1 MeV, which is a fraction of the typical binding energy per nucleon in nuclei. The temperature for breakup of He-4 is about twice as large, because of the higher binding energy. Depending on the temperature attained in the plasma, the initial concentration of elements heavier than hydrogen can be depleted. However, if it attains a temperature of about 1 MeV, breaking up the metals (C, N, O, Ne, Mg) but not He-4, an increase in the He-4 abundance by as much as 10 percent can result, since these elements essentially break down to alpha particles.

Guessoum, Nidhal↗

Investigating the Effects of Temperature on the Signatures of Shocks Propagated Through Impacts into Minerals Found in Comets and Asteroids

Comets and asteroids are subjected to extremely cold conditions throughout their lifetimes. During their sojourns in the solar system, they are subjected to collisions at speeds that are easily capable of generating shock waves in their constituent materials. In addition to ices, more common silicate minerals such as olivines and pyroxenes are important components of these objects. The collision-induced shocks could affect the spectral signatures of those mineral components, which could in turn be detected telescopically. We have embarked on a project to determine how impact-generated shock might affect the reflectance spectra and structures of select silicates as both impact speed and target temperature are varied systematically. While the effects of impact speed (in the form of shock stress) on numerous materials have been and continue to be studied, the role of target temperature has received comparatively little attention, presumably because of the operational difficulties it can introduce to experimentation. Our experiments were performed with the vertical gun in the Experimental Impact Laboratory of the Johnson Space Center. A liquid-nitrogen system was plumbed to permit cooling of the target container and its contents under vacuum to temperatures as low as -100 C (173 K). Temperatures were monitored by thermocouples mounted on the outside of the target container. Because those sensors were not in contact with the target material at impact, the measured temperatures are treated as lower limits for the actual values. Peridot (Mg-rich olivine) and enstatite (Mg-rich orthopyroxene) were used as targets, which involved the impact of alumina (Al2O3) spheres at speeds of 2.0 - 2.7 km s(exp -1) and temperatures covering 25 C to -100 C (298 K to 173 K). We have begun collecting and analyzing data in the near to mid-IR with a Fourier-transform infrared spectrometer, and preliminary analyses show that notable differences in absorption-band strength and position occur as functions of both impact speed (peak shock stress) and initial temperature.

Lederer, Susan M.↗

Effect of Temperature on Thrombogenicity Testing of Biomaterials in an In Vitro Dynamic Flow Loop System

To develop and standardize a reliable in vitro dynamic thrombogenicity test protocol, the key test parameters that could impact thrombus formation need to be investigated and understood. In this study, we evaluated the effect of temperature on the thrombogenic responses (thrombus surface coverage, thrombus weight, and platelet count reduction) of various materials using an in vitro blood flow loop test system. Whole blood from live sheep and cow donors was used to assess four materials with varying thrombogenic potentials: negative-control polytetrafluoroethylene (PTFE), positive-control latex, silicone, and high-density polyethylene (HDPE). Blood, heparinized to a donor-specific concentration, was recirculated through a polyvinyl chloride tubing loop containing the test material at room temperature (22–24°C) for 1 hour, or at 37°C for 1 or 2 hours. The flow loop system could effectively differentiate a thrombogenic material (latex) from the other materials for both test temperatures and blood species ( p < 0.05). However, compared with 37°C, testing at room temperature appeared to have slightly better sensitivity in differentiating silicone (intermediate thrombogenic potential) from the relatively thromboresistant materials (PTFE and HDPE, p < 0.05). These data suggest that testing at room temperature may be a viable option for dynamic thrombogenicity assessment of biomaterials and medical devices.

Engineering↗

Insights into the thermo-hydraulic properties of compacted MX80 bentonite during hydration under elevated temperature

In high-level radioactive waste geological repositories, compacted bentonite undergoes coupled thermo-hydraulic processes due to heat released from a central waste canister and groundwater imbibition from the surrounding host rock. An understanding of these processes is essential for long-term simulations of radionuclide migration and canister corrosion, which requires an understanding of temperature effects on the coupled thermo-hydraulic properties governing these processes. In this study, a tank-scale radial infiltration test was used to investigate water imbibition processes in compacted bentonite under a central heater temperature of 200 °C that simulates high thermal gradients in a repository. Interpretation of this test focuses on evaluation of the liquid water wetting front during hydration and the interpretation of the temperature-dependent transient soil water retention curve (SWRC), thermal conductivity function (TCF), and hydraulic conductivity function (HCF). The SWRC during imbibition follows a temperature-dependent wetting path. Temperature effects on the hydraulic conductivity of bentonite in saturated conditions had the greatest effect on the shape of the HCF, with minimal temperature effects at higher suctions. The transient thermal conductivity data matched well with a new TCF linked with the SWRC shape. Although the bentonite layer was restrained, local deformations during hydration may have affected the shapes of the TCF and HCF.

Engineering↗