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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1977

Emission measures, electron densities, and nonthermal velocities from optically thin UV lines near a quiet solar limb

Calibrated intensities and line widths are presented for 45 optically thin chromospheric and transition-zone UV lines observed in a quiet area near the solar limb. The observations were made over the wavelength range from 1175 to 1915 A with the slit spectrograph on the Skylab Apollo Telescope Mount. Three nonthermal-velocity components are derived from the transition-zone line widths: a main component of 23 km/s and two high-velocity components of 45 and 75 km/s, respectively, which contribute 5% to 10% of the averaged intensity. Absolute intensities are determined as a function of height, emission measures are obtained as functions of height as well as temperature, and electron densities are estimated from density-sensitive line ratios. The densities estimated from different sets of lines are found not to agree with each other, but the values obtained from the Si III multiplet between 1297 and 1301 A are considered to be the most reliable. An atmospheric model with inhomogeneous structures extending high above the solar surface is suggested.

Moe, O. K.↗
DOE OSTI2024

Phase stability in the Hf-N and Zr-N systems

Hf and Zr nitrides are promising compounds for many technologically important areas, including high-temperature structural applications, quantum computing, and solar and optical applications. Here, this article reports on a comprehensive first-principles statistical mechanics study of phase stability in the Hf-N and Zr-N binary systems. A high solubility of nitrogen in the hcp forms of Hf and Zr is predicted. The rocksalt forms of HfN and ZrN can also tolerate a high degree of off-stoichiometry through the introduction of nitrogen and metal vacancies. The Hf-N binary favors a family of stacking faulted parent crystal structures at intermediate nitrogen concentrations that host a unique form of short-range order among nitrogen interstitials and vacancies. These phases can accommodate some degree of configurational entropy and remain ordered to temperatures as high as 1200 K.

Monte Carlo methods↗
DOE OSTI2021

Increasing CO2 Conversion Efficiency with Optical Thermal Management in Concentrated Solar Reactors: New Dual-Stage Solar Reactor Design for Reduction of CO2 to Fuels

The proposed project will result in a new dual-stage solar chemical reactor designed to convert carbon dioxide (CO2) to value-added chemicals. Using sunlight as the main power source, a sustainable process will be developed that closes the loop on our industrial carbon cycle in an energy efficient and environmentally friendly manner. The hybrid photochemical and photothermal reactor design will vastly increase utilization of the solar spectrum and increase CO2 conversion efficiencies over Dimensional Energy’s current state-of-the-art.

10 SYNTHETIC FUELS↗
DOE OSTI2024

The Radical Atom: Mechanosynthetic 3D Printing of an Atomically Precise SPM Tip

This research effort sought to overcome current limitations in scanning probe-based atomic manipulation to enable atomically precise manufacturing (APM). Previous theoretical and experimental works on atom by atom and molecule by molecule fabrication of precise structures are limited to essentially to two-dimensions. APM will enable a paradigm shift in 21st century manufacturing practices in which every single atom in a electronic chip, device or machine can be placed in an exact and predefined position in three-dimensions. By providing a general method for generating reproducible SPM tip structure, this project will drive forward the entire field of atomically precise scanning probe microscopy, opening the door to positional control of nearly arbitrary covalent chemistry. Such control could, for example, be used in applications such as novel 2.5 or 3D microchip fabrication. The creation of a unique manufacturing method through APM has the potential to impact technologies at the theoretical limits of performance, weight, and utility including: solid-state quantum and spintronic computing systems, high efficiency optical antenna, solar power systems, defect engineered materials and extremely efficient catalysts. Although this experiment focused on pick-and-place non-scalable APM, the better understanding of the chemistry is crucial to the eventual goal of scalable APM. To place individual atoms into a specified location is a seminal aspiration of researchers and engineers in the many fields and may have early premium applications in medical devices and microelectronics.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2024

Self-Cleaning Highly Porous TiO 2 Coating Designed by Swelling-Assisted Sequential Infiltration Synthesis (SIS) of a Block Copolymer Template

Photocatalytic self-cleaning coatings with a high surface area are important for a wide range of applications, including optical coatings, solar panels, mirrors, etc. Here, we designed a highly porous TiO 2 coating with photoinduced self-cleaning characteristics and very high hydrophilicity. This was achieved using the swelling-assisted sequential infiltration synthesis (SIS) of a block copolymer (BCP) template, which was followed by polymer removal via oxidative thermal annealing. The quartz crystal microbalance (QCM) was employed to optimize the infiltration process by estimating the mass of material infiltrated into the polymer template as a function of the number of SIS cycles. This adopted swelling-assisted SIS approach resulted in a smooth uniform TiO 2 film with an interconnected network of pores. The synthesized film exhibited good crystallinity in the anatase phase. The resulting nanoporous TiO 2 coatings were tested for their functional characteristics. Exposure to UV irradiation for 1 h induced an improvement in the hydrophilicity of coatings with wetting angle reducing to unmeasurable values upon contact with water droplets. Furthermore, their self-cleaning characteristics were tested by measuring the photocatalytic degradation of methylene blue (MB). The synthesized porous TiO 2 nanostructures displayed promising photocatalytic activity, demonstrating the degradation of approximately 92% of MB after 180 min under ultraviolet (UV) light irradiation. Thus, the level of performance was comparable to the photoactivity of commercial anatase TiO 2 nanoparticles of the same quantity. Our results highlight a new robust approach for designing hydrophilic self-cleaning coatings with controlled porosity and composition.

36 MATERIALS SCIENCE↗
NASA NTRS1977

Influence of ground level SO2 on the diffuse to direct irradiance ratio in the middle ultraviolet

The dependence of the ratio of the diffuse to direct irradiances at the ground were examined for a wavelength of 315.1 nm. A passive remote sensing method based on ratio measurements for obtaining the optical thickness of SO2 in the vertical column was proposed. If, in addition to the ratio measurements, the SO2 density at the ground is determining using an appropriate point-sampling technique then some inference on the vertical extent of SO2 can be drawn. An analytic representation is presented of the ratio for a wide range of SO2 and aerosol optical thicknesses and solar zenith angles which can be inverted algebraically to give the SO2 optical thickness in terms of the measured ratio, aerosol optical thickness and solar zenith angle.

Klenk, K. F.↗
NASA NTRS1980

Spectrophotovoltaic orbital power generation

The feasibilty of a spectrophotovoltaic orbital power generation system that optically concentrates solar energy is demonstrated. A dichroic beam-splitting mirror is used to divide the solar spectrum into two wavebands. Absorption of these wavebands by GaAs and Si solar cell arrays with matched energy bandgaps increases the cell efficiency while decreasing the amount of heat that must be rejected. The projected cost per peak watt if this system is $2.50/W sub p.

Onffroy, J. R.↗
NASA NTRS1980

Dynamics of flare sprays

During solar cycle No. 20 new insight into the flare-spray phenomenon has been attained due to several innovations in solar optical-observing techniques (higher spatial resolution cinema-photography, tunable passband filters, multislit spectroscopy and extended angular field coronagraphs). From combined analysis of 13 well-observed sprays which occurred between 1969-1974 it is concluded that (1) the spray material originates from a preexisting active region filament which undergoes increased absorption some tens of minutes prior to the abrupt chromospheric brightening at the 'flare-start', and (2) the spray material is confined within a steadily expanding, loop-shaped (presumable magnetically controlled) envelope with part of the materials draining back down along one or both legs of the loop.

Tandberg-Hanssen, E.↗
NASA NTRS1980

Solar cell array design handbook - The principles and technology of photovoltaic energy conversion

Photovoltaic solar cell array design and technology for ground-based and space applications are discussed from the user's point of view. Solar array systems are described, with attention given to array concepts, historical development, applications and performance, and the analysis of array characteristics, circuits, components, performance and reliability is examined. Aspects of solar cell array design considered include the design process, photovoltaic system and detailed array design, and the design of array thermal, radiation shielding and electromagnetic components. Attention is then given to the characteristics and design of the separate components of solar arrays, including the solar cells, optical elements and mechanical elements, and the fabrication, testing, environmental conditions and effects and material properties of arrays and their components are discussed.

Rauschenbach, H. S.↗
NASA NTRS1986

Comparative accuracy of the Albedo, transmission and absorption for selected radiative transfer approximations

Illustrations of both the relative and absolute accuracy of eight different radiative transfer approximations as a function of optical thickness, solar zenith angle and single scattering albedo are given. Computational results for the plane albedo, total transmission and fractional absorption were obtained for plane-parallel atmospheres composed of cloud particles. These computations, which were obtained using the doubling method, are compared with comparable results obtained using selected radiative transfer approximations. Comparisons were made between asymptotic theory for thick layers and the following widely used two stream approximations: Coakley-Chylek's models 1 and 2, Meador-Weaver, Eddington, delta-Eddington, PIFM and delta-discrete ordinates.

King, M. D.↗
NASA NTRS1985

Deduction of coronal magnetic fields using microwave spectroscopy

Gyroresonance opacity renders the solar corona optically thick at frequencies which are low integral multiples of the local gyrofrequency. This causes the microwave spectrum of sunspots to be sensitive to the strength of coronal magnetic fields. The concept is illustrated by high spectral resolution observations of a sunspot acquired with the Owens Valley frequency-agile interferometer. The observed spectrum is compared to the results of three-dimensional atmospheric model calculations in which the sunspot field is represented by the potential field of a dipole located beneath the photosphere. The comparison enables the depth, orientation and magnetic moment of the dipole that best fits the observations to be determined. Since such observations require that the microwave emission be resolved spectrally, not spatially, the technique may be applicable to the study of stellar coronal fields.

Hurford, G. J.↗
NASA NTRS1986

Comparative accuracy of selected multiple scattering approximations

Doubling method computational results which have yielded plane albedo, total transmission and fractional absorption for plane-parallel atmospheres composed of cloud droplets are presently compared with data obtained with selected radiative transfer approximations. The relative and absolute accuracies of asymptotic theory for thick layers and delta-Eddington, Meador-Weaver (1980) and Coakley-Chylek (1975) approximations are compared as a function of optical thickness, solar zenith angle, and single scattering albedo. The delta-Eddington approximation is the most accurate for conservative scattering when the solar zenith angle is small, while Meador-Weaver is the most accurate for nonconservative scattering.

King, M. D.↗
NASA NTRS1987

Development of optical modulators for measurements of solar magnetic fields

The measurement of polarized light allows solar astronomers to infer the magnetic field on the Sun. The accuracy of these measurements is dependent on the stable retardation characteristics of the polarization modulators used to minimize the atmospheric effects seen in ground-based observations. This report describes the work by the Space Science Laboratory at Marshall Space Flight Center to improve two types of polarization modulators. As a result, the timing characteristics for both electrooptic crystals (KD*Ps) and liquid crystal devices (LCDs) have been studied and will be used to enhance the capabilities of the MSFC Vector Magnetograph.

West, E. A.↗