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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

Electrocoagulation of high-salinity produced water: lessons learned from its early applications in unconventional reservoir plays

Ample research has demonstrated that electrocoagulation is a versatile technology capable of facilitating the removal of a wide range of physical, biological, organic, and inorganic constituents such as suspended solids, turbidity, bacteria, viruses, oil and grease, organic carbon (including chemical and biological oxygen demand), silica, fluoride, and so on. Despite its purported advantages and extensive lab-scale evaluations, it has not yet been widely adopted for water and wastewater treatment and reuse at commercial scale. This is symptomatic of a chasm between its technological capabilities on one hand and field performance and reputation on the other. Herein, we opine as to why this might be the case using our collective experiences with the oil and gas industry as an exemplar. In this study, we highlight scientific, technological, engineering, and business issues that need to be addressed to realize the full potential of this promising technology.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

A screening model for predicting injection well pressure buildup and plume extent in CO 2 geologic storage projects

We present a new screening model for predicting injection well pressure buildup and CO 2 plume migration for CO 2 geologic sequestration projects. The model requires only limited information and is quite accurate when compared to detailed simulation results. Such models can assist project developers during the early days of project planning (e.g., for 45Q related projects), and also help regulators perform simple checks against detailed numerical models. The screening model consists of two correlations: one for injectivity index in terms of the slope of the CO 2 fractional flow curve, and the second for total storage efficiency within the footprint of plume as a function of gravity number and slope of the CO 2 fractional flow curve. Using these two correlations, as well as a knowledge of some basic reservoir characteristics and estimates of fluid properties from standard correlations, the injection-well pressure buildup and CO 2 plume extent in the formation can be readily estimated. Finally, the new correlations show a good match with the results of the underlying simulations, and also provide good agreement with independent calculations for two example problems.

42 ENGINEERING↗
DOE OSTI2019

The Role of Chemistry in Fracture Pattern Development and Opportunities to Advance Interpretations of Geological Materials

Abstract Fracture pattern development has been a challenging area of research in the Earth sciences for more than 100 years. Much has been learned about the spatial and temporal complexity inherent to these systems, but severe challenges remain. Future advances will require new approaches. Chemical processes play a larger role in opening‐mode fracture pattern development than has hitherto been appreciated. This review examines relationships between mechanical and geochemical processes that influence the fracture patterns recorded in natural settings. For fractures formed in diagenetic settings (~50 to 200 °C), we review evidence of chemical reactions in fractures and show how a chemical perspective helps solve problems in fracture analysis. We also outline impediments to subsurface pattern measurement and interpretation, assess implications of discoveries in fracture history reconstruction for process‐based models, review models of fracture cementation and chemically assisted fracture growth, and discuss promising paths for future work. To accurately predict the mechanical and fluid flow properties of fracture systems, a processes‐based approach is needed. Progress is possible using observational, experimental, and modeling approaches that view fracture patterns and properties as the result of coupled mechanical and chemical processes. A critical area is reconstructing patterns through time. Such data sets are essential for developing and testing predictive models. Other topics that need work include models of crystal growth and dissolution rates under geological conditions, cement mechanical effects, and subcritical crack propagation. Advances in machine learning and 3‐D imaging present opportunities for a mechanistic understanding of fracture formation and development, enabling prediction of spatial and temporal complexity over geologic timescales. Geophysical research with a chemical perspective is needed to correctly identify and interpret fractures from geophysical measurements during site characterization and monitoring of subsurface engineering activities.

58 GEOSCIENCES↗
DOE OSTI2019

Rotating disk electrode cell

A rotating disk electrode cell has a housing with a reservoir configured to receive a sample for an electrochemical experiment. A shaft is positioned in the housing such that the shaft is free to rotate around the longitudinal axis of the shaft and such that both ends of the shaft are located inside of the housing.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

An argument for using anaerobes as microbial cell factories to advance synthetic biology and biomanufacturing

Anaerobes thrive in the absence of oxygen and are an untapped reservoir of biotechnological potential. Therefore, bioprospecting efforts focused on anaerobic microbial diversity could rapidly uncover new enzymes, pathways, and chassis organisms to drive biotechnology innovation. Despite their potential utility, anaerobic fermenters are viewed as inefficient from a biochemical perspective because their metabolisms produce fewer ATP (~2) per molecule of glucose processed than heterotrophic respirers (~32–38 ATP). While aerobes excel at ATP generation, they are often less efficient than anaerobes at processes that compete with ATP generation for cellular resources. This perspective highlights how anaerobic adaptations are advantageous for synthetic biology and biomanufacturing applications through the engineering of microbial cell factories. We further highlight emerging applications of anaerobic bioprocessing, including the use of anaerobic metabolisms for lignocellulosic bioprocessing, human and environmental health, and value-added bioproduction.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2023

Seismic Monitoring at the Farnsworth CO2-EOR Field Using Time-Lapse Elastic-Waveform Inversion of 3D-3C VSP Data

During the Development Phase of the U.S. Southwest Regional Partnership on Carbon Sequestration, supercritical CO2 was continuously injected into the deep oil-bearing Morrow B formation of the Farnsworth Unit in Texas for Enhanced Oil Recovery (EOR). The project injected approximately 94 kilotons of CO2 to study geologic carbon storage during CO2-EOR. A three-dimensional (3D) surface seismic dataset was acquired in 2013 to characterize the subsurface structures of the Farnsworth site. Following this data acquisition, the baseline and three time-lapse three-dimensional three-component (3D-3C) vertical seismic profiling (VSP) data were acquired at a narrower surface area surrounding the CO2 injection and oil/gas production wells between 2014 and 2017 for monitoring CO2 injection and migration. With these VSP datasets, we inverted for subsurface velocity models to quantitatively monitor the CO2 plume within the Morrow B formation. We first built 1D initial P-wave (Vp) and S-wave (Vs) velocity models by upscaling the sonic logs. We improved the deep region of the Vp and Vs models by incorporating the deep part of a migration velocity model derived from the 3D surface seismic data. We improved the shallow region of 3D Vp and Vs models using 3D traveltime tomography of first arrivals of VSP downgoing waves. We further improved the 3D baseline velocity models using elastic-waveform inversion (EWI) of the 3D baseline VSP upgoing data. Our advanced EWI method employs alternative tomographic and conventional gradients and total-variation-based regularization to ensure the high-fidelity updates of the 3D baseline Vp and Vs models. We then sequentially applied our 3D EWI method to the three time-lapse datasets to invert for spatiotemporal changes of Vp and Vs in the reservoir. Our inversion results reveal the volumetric changes of the time-lapse Vp and Vs models and show the evolution of the CO2 plume from the CO2 injection well to the oil/gas production wells.

42 ENGINEERING↗
DOE OSTI2026

Modeling supercritical CO 2 flow and mineralization in reactive host rocks with PFLOTRAN v7.0

Understanding the flow and reactivity of CO 2 injected into geological reservoirs is important for many subsurface applications including secure geologic carbon storage (GCS), critical mineral extraction, enhanced geothermal systems (EGS), and enhanced oil recovery (EOR). Traditionally, subsurface CO 2 injection for GCS applications has focused on geologic formations with favorable subsurface configurations for CO 2 migration and trapping through non-reactive mechanisms such as structural, solubility, and petrophysical trapping. Recently, CO 2 -reactive rocks such as mafic and ultramafic basalts have been investigated for their potential to react with injected CO 2 in situ to simultaneously dissolve host rock minerals and mineralize CO 2 as carbonates. Engineering rapid CO 2 mineralization in the subsurface is attractive because of the increased density of stored CO 2 , the additional safety factors associated with solidification, and the potential to extract valuable critical minerals. Here we present recent developments in the parallel flow and reactive transport simulator PFLOTRAN to model coupled CO 2 -brine flow and reactive transport for a wide range of injection and production applications involving reactive CO 2 -brine systems. These developments are based on the well established and trusted CO 2 flow capabilities in the STOMP-CO 2 simulator. New capabilities added to PFLOTRAN include new CO 2 -brine equations of state with optional thermal coupling, several new constitutive relationships like capillary pressure smoothing and scanning path hysteresis, a fully implicit well model, and native linkage with PFLOTRAN's well-established reactive transport libraries. A series of benchmarks between PFLOTRAN and STOMP-CO 2 verify the newly developed CO 2 -brine flow capabilities. Demonstrations of coupled CO 2 -brine flow modeling and reactive transport show how CO 2 mineralization can be engineered in reactive host rocks. Finally, an example use case involving copper leaching by CO 2 and critical mineral extraction is presented to showcase the strengths of this new implementation. Several limitations still remain, including limited availability of field data to parameterize models. Future work should constrain the evolution of mineral surface area during mineralization and the temperature and/or pH dependence of geochemical reactions for specific systems of interest.

Critical Minerals↗
NASA NTRS1988

Simulation of water vapor condensation on LOX droplet surface using liquid nitrogen

The formation of ice or water layers on liquid oxygen (LOX) droplets in the Space Shuttle Main Engine (SSME) environment was investigated. Formulation of such ice/water layers is indicated by phase-equilibrium considerations under conditions of high partial pressure of water vapor (steam) and low LOX droplet temperature prevailing in the SSME preburner or main chamber. An experimental investigation was begun using liquid nitrogen as a LOX simulant. A monodisperse liquid nitrogen droplet generator was developed which uses an acoustic driver to force the stream of liquid emerging from a capillary tube to break up into a stream of regularly space uniformly sized spherical droplets. The atmospheric pressure liquid nitrogen in the droplet generator reservoir was cooled below its boiling point to prevent two phase flow from occurring in the capillary tube. An existing steam chamber was modified for injection of liquid nitrogen droplets into atmospheric pressure superheated steam. The droplets were imaged using a stroboscopic video system and a laser shadowgraphy system. Several tests were conducted in which liquid nitrogen droplets were injected into the steam chamber. Under conditions of periodic droplet formation, images of 600 micron diameter liquid nitrogen droplets were obtained with the stroboscopic video systems.

Powell, Eugene A.↗
NASA NTRS1975

ATS-6 - Cesium bombardment engine north-south stationkeeping experiment

Two 0.004 N thrust cesium bombardment ion thrustors have been developed and used for north-south stationkeeping in the geostationary Applications Technology Satellite-6 (ATS-6). The thrustor subsystems are mounted on the north and south faces of the earth viewing module such that 0.0026 N of thrust is applied normal to the orbit plane and 0.0036 N is applied radially upward. The change in the orbit inclination of the satellite is maintained at zero by operating the two thrustors alternately so that their thrust components, normal to the orbital plane, are symmetrically applied about the nodal crossings. Initial operation of the thrustors was successful. There was no interference with the satellite communications systems and the predicted spacecraft operating potential was verified. Subsequent trials failed due to a defect in the operation of the propellant reservoirs in zero g. A feed line valve is under development to correct this difficulty.

Worlock, R. M.↗
NASA NTRS2011

In-Situ Missions for the Exploration of Titan's Lakes

The lakes of Titan represent an increasingly tantalizing target for future exploration. As Cassini continues to reveal more details the lakes appear to offer a particularly rich reservoir of knowledge that could provide insights to Titan's formation and evolution, as well as an ideal location to explore Titan's potential for pre-biotic chemistry. A recent study of Titan Lake Probe missions was undertaken as one of several dozen studies commissioned by the National Research Council (NRC) Planetary Decadal Survey to explore the technical readiness, feasibility and affordability of scientifically promising mission scenarios. This in-depth study focused on an in-situ examination of a hydrocarbon lake on the Saturnian moon Titan--a target that presents unique scientific opportunities as well as several unique engineering challenges (e.g., submersion systems and cryogenic sampling) to enable those measurements. Per direction from the NRC Planetary Decadal Survey Satellites Panel, and after an initial trade-space examination, study architectures focused on three possible New Frontiers-class missions and a more ambitious Flagship-class lander intended as the in-situ portion of a larger collaborative mission. Detailed point designs were developed to explore these four potential mission options, including consideration of flight system and mission designs, as well as operations on and under the lake's surface and scenarios for data return. In this paper we present an overview of the science objectives of the missions, the mission architecture and surface.

Elliott, John O.↗
DOE OSTI2020

Glass 3D Printing of Microfluidic Pressure Sensor Interrogated by Fiber-Optic Refractometry

This letter reports a novel fused silica microfluidic device with pressure sensing capability that is fabricated by integrated additive and subtractive manufacturing (IASM) method. The sensor consists of a capillary and a 3D printed glass reservoir, where the reservoir volume change under pressure manifests liquid level deviation inside the capillary, thus realizing the conversion between small pressure change into large liquid level variation. Thanks to the design flexibility of this unique IASM method, the proposed microfluidic device is fabricated with liquid-in-glass thermometer configuration, where the reservoir is sealed following a novel 3D printing assisted glass bonding process. And liquid level is interrogated by a fiber-optic sensor based on multimode interference (MMI) effect. This proposed microfluidic device is attractive for chemical and biomedical sensing because it is flexible in design, and maintains good chemical and mechanical stability, and adjustable sensitivity and range.

42 ENGINEERING↗
DOE OSTI2021

Paying it Forward: How an Emerging Unconventional Play can Hit the Ground Running

While every tight oil play is unique, there are lessons that can be transferred from one play to another to improve the efficiency and pace of production operations and development. These improvements may not fit precisely in every basin or play but generally hold to themes that can be tested against and built upon. Themes such as the quantity of proppant, longer lateral length, or the number of stages can be directly tied to increased productivity. However, there are diminishing returns on these investment activities for which each operator, within a given play, will be required to identify and mitigate against. This is especially true as the industry steps in and begins developing new tight oil plays. In their nascent stages, these plays may have limited well penetrations and, as a result, limited geological and performance data from which to extrapolate. Pulling together an understanding of where the industry currently resides in terms of how to exploit these resources can provide a boost in terms of working towards greatly improved well completions. In 2019, the US EIA estimated that nearly 8 million barrels of oil per day were produced from tight oil reservoirs in the United States (US EIA, 2020). This represents over 60% of the domestic crude production, originating from multiple reservoirs in the Permian Basin (TX) as well as the Bakken (MT, ND), Eagle Ford (TX), Niobrara (CO, WY), and Anadarko Basin (OK) formations, among others. As such, there are 1,000s of wells across these numerous tight oil plays that can relate an informative story. To build this story, the interplay of geology, well spacing, lateral length, and stimulation, all critical to economic success, will be explored. This paper proposes to look back at these mature tight oil (and gas) basins and bring forth an understanding of what lessons can be applied to the emerging Powder River Basin tight oil reservoirs (Mowry and the Turner/Frontier). The authors will delve into the four broad topics of geology, well spacing, lateral length, and stimulation, highlighting case studies to demonstrate those lessons from established tight oil plays that will underpin planned activities at a Field Laboratory Test Site in the southern Powder River Basin.

02 PETROLEUM↗
DOE OSTI2022

Colloid-Facilitated Actinide Transport in a Cementitious-Impacted SRS Groundwater

The objective of this report is to provide a literature review relevant to the question of whether colloid facilitated transport of plutonium is enhanced in a cementitious groundwater system on the Savannah River Site (SRS). Contaminant transport is commonly described as taking place in a system with a mobile aqueous phase and an immobile solid phase. There has been an increasing awareness of a third phase, a mobile solid phase, also referred to as a mobile colloidal phase. Mobile colloids consist of organic and/or inorganic submicron-particles that move with groundwater flow. When radionuclides are associated with the mobile colloids, the net effect is that radionuclides can move faster through the subsurface system than would be predicted by transport models that do not include mobile colloids. It is important to distinguish between subsurface colloids and subsurface mobile colloids. The subsurface environment includes an enormous reservoir of colloids, but only a tiny fraction, if any, are mobile. Mobile colloid formation is commonly described as involving a three-step process: genesis, stabilization, and transport. It was concluded that there is a strong likelihood that submicron colloids of plutonium exist near the source term, (i.e., the genesis step is likely completed). While such particles have not been directly detected, it is highly likely that plutonium could either attach to submicron particles in the sediment or that submicron plutonium fragments exist at the source. However, the tendency for these plutonium colloids to move in the SRS subsurface is extremely low, especially in engineered cementitious environments where the ionic strength of the solution and the elevated concentrations of divalent cations greatly curtails colloid suspension stability (i.e., the stabilization step is likely not completed). Together these data strongly indicate that plutonium-bearing colloids would likely exist in the near field of a tank closure facility, but the colloids would be unlikely to be mobile, thereby providing a vector for enhanced transport. Under cementitious leachate impacted groundwater conditions, it is reasonable to assume plutonium transport occurs primarily as a two-phase system, a mobile aqueous phase and an immobile solid phase.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Biofilm Feedbacks Alter Hydrological Characteristics of Fractured Rock Impacting Sulfidogenesis and Treatment

Flow-through fractures dominate the movement of fluids in a variety of natural as well as engineered subsurface systems. Microbial activities in fractured rock impact subsurface energy recovery, storage, and waste disposal. It has been recognized that understanding how the contrasting permeability between fracture and matrix interacts with microbial metabolism under thermal and hydrological gradients is key to effective utilization of the subsurface, yet such studies are sparse. Microorganisms mediate the production of hydrogen sulfide (also known as souring) in oil-bearing geological formations. We conducted a comprehensive experimental study of a novel 2D fractured rock system to understand these complex interactions and demonstrated how biofilm development can impact fracture flow, which subsequently feedbacks to moderate sulfidogenesis. Elevated temperature relevant to reservoir conditions interacted with the injection of cold fluid and formed a thermal gradient away from fractures, creating thermal niches for microbial activities in the fractured rock. Finally, results showed that while fracture flows were dominant in the beginning, with time, growth of the biofilm in the fractures reduced permeability, effectively moderating the initial fracture-matrix contrast, and limited microbial accessibility to nutrients and subsequent reactions rates.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2024

Approaches for the Simulation of Coupled Processes in Evolving Fractured Porous Media Enabled by Exascale Computing

Models have historically represented fractured porous media with continuum descriptions that characterize the media using bulk parameters. The impact of small-scale features is not captured in these models, although they may be controlling the performance of subsurface applications. Pore-scale models can simulate processes in small-scale features by representing the pore space geometry explicitly but are computationally expensive for large domains. The alternative multiscale approach entails the combination of pore-scale and continuum-scale descriptions in a single framework. We use Chombo-Crunch, a computational capability that discretizes complex geometries with an adaptive, embedded boundary method to contrast these two approaches. Chombo-Crunch takes advantage of recent computational performance and memory bandwidth improvements resulting from the emergence of exascale computing resources. These combined improvements enable the efficient simulation of reactive transport in fractured media with a high degree of fidelity and the ability to capture the control small-scale processes exert on the overall medium evolution.

42 ENGINEERING↗
DOE OSTI2024

Investigation of acoustic waves under subsurface conditions to improve the predictions of rock mechanical properties and natural fracture characteristics

Mechanical properties and natural fracture characteristics are critical to investigate for subsurface engineering applications, including carbon storage, well drilling, and stimulation, as they govern rock stability, fluid flow, and mechanical behavior under stress. This dissertation integrates experimental and machine learning approaches to enhance the prediction and understanding of these properties by analyzing acoustic wave behavior under varied subsurface conditions. First, the influence of temperature, pore pressure, and supercritical CO2 (scCO2) saturation on poroelastic properties is examined using Gray Berea sandstone samples. The results show that temperature and pore pressure significantly affect the bulk modulus and Biot’s coefficient, while scCO2 saturation impacts rock compressibility, informing strategies for effective geological carbon storage. The study extends this understanding by experimentally evaluating the impact of reservoir depletion on the dynamic mechanical properties of the emerging Caney shale in South Oklahoma with the employment of unsupervised machine learning to predict static mechanical properties across the Caney shale. Integrating petrophysical data and chemostratigraphy, the workflow—featuring K-means clustering, principal component analysis (PCA), and inverse distance weighting (IDW)—improves stratigraphic characterization and the estimation of static-to-dynamic modulus ratios, which is vital for optimizing drilling and stimulation strategies. Finally, the work explores how natural fracture characteristics in shale influence acoustic waveforms and shear wave splitting (SWS) analysis. Experimental data on fractured samples under different stress and temperature conditions, combined with machine learning models such as K-nearest neighbors (KNN) and extreme gradient boosting (XGBoost), reveal key fracture properties impacting SWS and wave propagation. Together, these studies provide a comprehensive framework for linking acoustic wave behavior with rock properties, advancing the methods for monitoring and predicting geomechanical changes. The insights offered valuable implications for safer, more efficient CO2 injection, hydrocarbon extraction, and subsurface management.

Elkholy, Sherif↗
DOE OSTI2025

Newberry SHR Demonstration Project – Bipartisan Infrastructure Law Enhanced Geothermal (EGS) Pilot Demonstration (Abstract)

This project will create an Engineered Geothermal System (EGS) comprising two or more wells drilled to a depth of 4.25 km into superhot rock (SHR) with a temperature of 425 °C at Newberry Volcano in Central Oregon. An EGS is a manufactured heat exchanger in which water is injected in a deep injection well, or injector, to extract heat from the hot rock at depth and steam is returned to the surface in a production well, or producer, to generate electricity. In this project, the SHR EGS will be made using new methods and technologies to stimulate and connect hydraulic and natural fractures to enable multiple flow pathways between wells, allowing for optimal heat mining from the reservoir rock. The new technologies are designed to operate at rock temperatures much higher than those encountered in traditional geothermal. Following EGS completion, water will be injected into the injector well and steam extracted from the producer well in a long-term connectivity flow test demonstrating SHR reservoir evolution with time and use. Success will be measured by demonstrating the efficacy of new technologies and by producing economic quantities of steam (>40 MWth).

15 GEOTHERMAL ENERGY↗
DOE OSTI2026

Small Reservoirs Offer a New Perspective on Flood Reduction in Large Basins

The flood reduction potential of individual reservoirs within a large river network continuum remains poorly understood due to the complex interplay between reservoir characteristics and network properties. Here we investigate whether a collection of relatively small reservoirs can play a significant role in mediating downstream floods and assess how that role may be influenced by reservoir network properties compared to traditionally known reservoir characteristics. Our unique contribution was the simulation of downstream flood inundation maps alongside peak flows for each of the 81 major reservoirs (6 × 104 to 8 × 109 m3) across 15,000 river reach segments, integrated into a process-based hydrologic model covering a 415,000 km2 region in the Texas Gulf Coast, United States. The three key takeaways from our study are as follows. (a) Smaller reservoirs can substantially reduce downstream flooding, suggesting that inclusion of large reservoirs—the traditional approach in flood risk management studies—may present only a partial picture. (b) Flood reduction by smaller reservoirs is more effective upstream, although this phenomenon may be linked with aridity and overall water availability. (c) While reservoir size matters, it is not the primary factor determining its downstream flood reduction potential; the influence of network properties, such as catchment area, the count of upstream reservoirs, the cumulative maximum storage capacity of upstream reservoirs, and Stream Order (i.e., location), is equally and often more important. The broader impact of our findings goes beyond just floods, providing foundational insights for addressing emerging challenges such as aging dams and river connectivity.

Patel, Krutikkumar [University of Texas at Arlingt↗