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At least 325 records · Page 18

The extensional rheology of non-Newtonian materials

It has been proposed to measure the extensional viscosity function of a non-Newtonian polymer solution in a reduced gravity environment as part of the Advanced Fluid Module. In ground-based extensional measurements, the no-sip boundary condition at solid-fluid interfaces always result in appreciable shear gradients in the test fluid; however the removal of gravitational body forces permits controlled extensional deformation of containerless test samples and the first unambiguous measurements of this kind. Imperative to successful implementation of this experiment is the generation and subsequent deformation of a stable cylindrical column of test fluid. A study of the generation and deformation of liquid bridges demonstrates that Newtonian liquid bridges undergo capillary breakup as anticipated when stretched beyond a critical aspect ratio; non-Newtonian liquid bridges, however, are stabilized by the strain-hardening phenomenon exhibited by these materials. Numerical simulations of Newtonian breakup are compared with experimental results, and show that previous ground-based attempts at measuring the extensional viscosity of Newtonian fluids are of limited accuracy.

Spiegelberg, Stephen H.↗

Spectral emissivity measurements of land-surface materials and related radiative transfer simulations

Spectral radiance measurements have been made in the laboratory and in the field for deriving spectral emissivities of some land cover samples with a spectroradiometer and an auxiliary radiation source in the wavelength range 2.5-14.5 micrometers. A easy and quick four-step method (four steps to measure the sample and a diffuse reflecting plate surface under sunshine and shadowing conditions, respectively) has been used for simultaneous determination of surface temperature and emissivity. We emphasized in-situ measurements in combination with radiative transfer simulations, and an error analysis for basic assumptions in deriving spectral emissivity of land-surface samples from thermal infrared measurements.

Wan, Z.↗

Mixing processes within the polar night jet

Lagrangian material line simulations are performed using U.K. Meteorological Office simulated winds and temperatures to examine mixing processes in the middle- and lower-stratospheric polar night jet during the 1992 Southern Hemisphere spring and Northern Hemisphere winter. The Lagrangian simulations are undertaken to provide insight into the effects of mixing within the polar night jet on observations of the polar vortex made by instruments onboard the Upper Atmosphere Research Satellite (UARS) during these periods. A moderate to strong kinematic barrier to large-scale isentropic exchange, similar to the barrier identified in General Circulation Model (GCM) simulations, is identified during both of these periods. Characteristic timescales for mixing by large-scale isentropic motions within the polar night jet range from 20 days in the Southern Hemisphere lower stratosphere to years in the Northern Hemisphere middle stratosphere. The long mixing timescales found in the Northern Hemisphere polar night jet do not persist. Instead, the Northern Hemisphere kinematic barriers are broken down as part of the large-scale stratospheric response to a strong tropospheric blocking event. A series of Lagrangian experiments are conducted to investigate the sensitivity of the kinematic barrier to diabatic effects and to small-scale inertial gravity wave motions. Differential diabatic descent is found to have a significant impact on mixing processes within the Southern Hemisphere middle-stratospheric jet core. The interaction between small-scale displacements by idealized, inertial gravity waves and the large-scale flow is found to have a significant impact on mixing within the polar night jet in both hemispheres. These sensitivity experiments suggest that scales of motion that are unresolved in global assimilated datasets may contribute to mass exchange across the kinematic barrier to large-scale isentropic motion.

Pierce, R. Bradley↗

Finite Element and Plate Theory Modeling of Acoustic Emission Waveforms

A comparison was made between two approaches to predict acoustic emission waveforms in thin plates. A normal mode solution method for Mindlin plate theory was used to predict the response of the flexural plate mode to a point source, step-function load, applied on the plate surface. The second approach used a dynamic finite element method to model the problem using equations of motion based on exact linear elasticity. Calculations were made using properties for both isotropic (aluminum) and anisotropic (unidirectional graphite/epoxy composite) materials. For simulations of anisotropic plates, propagation along multiple directions was evaluated. In general, agreement between the two theoretical approaches was good. Discrepancies in the waveforms at longer times were caused by differences in reflections from the lateral plate boundaries. These differences resulted from the fact that the two methods used different boundary conditions. At shorter times in the signals, before reflections, the slight discrepancies in the waveforms were attributed to limitations of Mindlin plate theory, which is an approximate plate theory. The advantages of the finite element method are that it used the exact linear elasticity solutions, and that it can be used to model real source conditions and complicated, finite specimen geometries as well as thick plates. These advantages come at a cost of increased computational difficulty, requiring lengthy calculations on workstations or supercomputers. The Mindlin plate theory solutions, meanwhile, can be quickly generated on personal computers. Specimens with finite geometry can also be modeled. However, only limited simple geometries such as circular or rectangular plates can easily be accommodated with the normal mode solution technique. Likewise, very limited source configurations can be modeled and plate theory is applicable only to thin plates.

Prosser, W. H.↗

Analytical Prediction of Damage Growth in Notched Composite Panels Loaded in Axial Compression

A progressive failure analysis method based on shell elements is developed for the computation of damage initiation and growth in stiffened thick-skin stitched graphite-epoxy panels loaded in axial compression. The analysis method involves a step-by-step simulation of material degradation based on ply-level failure mechanisms. High computational efficiency is derived from the use of superposed layers of shell elements to model each ply orientation in the laminate. Multiple integration points through the thickness are used to obtain the correct bending effects through the thickness without the need for ply-by-ply evaluations of the state of the material. The analysis results are compared with experimental results for three stiffened panels with notches oriented at 0, 15 and 30 degrees to the panel width dimension. A parametric study is performed to investigate the damage growth retardation characteristics of the Kevlar stitch lines in the pan

Ambur, Damodar R.↗

Universal Responses of Cyclic-Oxidation Models Studied

Oxidation is an important degradation process for materials operating in the high-temperature air or oxygen environments typical of jet turbine or rocket engines. Reaction of the combustion gases with the component material forms surface layer scales during these oxidative exposures. Typically, the instantaneous rate of reaction is inversely proportional to the existing scale thickness, giving rise to parabolic kinetics. However, more realistic applications entail periodic startup and shutdown. Some scale spallation may occur upon cooling, resulting in loss of the protective diffusion barrier provided by a fully intact scale. Upon reheating, the component will experience accelerated oxidation due to this spallation. Cyclic-oxidation testing has, therefore, been a mainstay of characterization and performance ranking for high-temperature materials. Models simulate this process by calculating how a scale spalls upon cooling and regrows upon heating (refs. 1 to 3). Recently released NASA software (COSP for Windows) allows researchers to specify a uniform layer or discrete segments of spallation (ref. 4). Families of model curves exhibit consistent regularity and trends with input parameters, and characteristic features have been empirically described in terms of these parameters. Although much insight has been gained from experimental and model curves, no equation has been derived that can describe this behavior explicitly as functions of the key oxidation parameters.

Smialek, James L.↗

Length dependence of carbon nanotube thermal conductivity and the "problem of long waves"

We present the first calculations of finite length carbon nanotube thermal conductivity that extend from the ballistic to the diffusive regime, throughout a very wide range of lengths and temperatures. The long standing problem of vanishing scattering of the "long wavelength phonf dramatically here, making the thermal conductivity diverge as the nanotube length increases. We show that the divergence disappears if 3-phonon scattering processes are considered to second or higher order. Nevertheless, for defect free nanotubes, the thermal conductivity keeps increasing up to very large lengths (10 gm at 300 K). Defects in the nanotube are also able to remove the long wavelength divergence.

Evaluation Studies↗

Metallized Gelled Propellants Combustion Experiments in a Pulse Detonation Engine

A series of combustion tests were performed with metallized gelled JP 8/aluminum fuels in a Pulse Detonation Engine (PDE). Nanoparticles of aluminum were used in the 60 to 100 nanometer diameter. Gellants were also of a nanoparticulate type composed of hydrocarbon alkoxide materials. Using simulated air (a nitrogen-oxygen mixture), the ignition potential of metallized gelled fuels with nanoparticle aluminum was investigated. Ignition of the JP 8/aluminum was possible with less than or equal to a 23-wt% oxygen loading in the simulated air. JP 8 fuel alone was unable to ignite with less than 30 percent oxygen loaded simulated air. The tests were single shot tests of the metallized gelled fuel to demonstrate the capability of the fuel to improve fuel detonability. The tests were conducted at ambient temperatures and with maximal detonation pressures of 1340 psia.

Palaszewski, Bryan↗

Modeling Ablation of Fibrous Materials from Bulk to Knudsen Regime

Material-environment interactions are analyzed at microscopic scale to explain the lower than expected density observed by post-flight analysis of the char layer on the Stardust shield. Mass transfer, ablation (oxidation), and surface recession of fibrous material is simulated in 3D using a Monte-Carlo simulation tool. Ablation is found to occur either at the surface or in volume depending on Knudsen and Thiele number values. This study supports the idea of volume ablation followed by possible carbon fiber spallation that may explain post-flight analyses.

Lachaud, Jean↗

Consolidating NASA's Arc Jets

The paper describes the consolidation of NASA's high powered arc-jet testing at a single location. The existing plasma arc-jet wind tunnels located at the Johnson Space Center were relocated to Ames Research Center while maintaining NASA's technical capability to ground-test thermal protection system materials under simulated atmospheric entry convective heating. The testing conditions at JSC were reproduced and successfully demonstrated at ARC through close collaboration between the two centers. New equipment was installed at Ames to provide test gases of pure nitrogen mixed with pure oxygen, and for future nitrogen-carbon dioxide mixtures. A new control system was custom designed, installed and tested. Tests demonstrated the capability of the 10 MW constricted-segmented arc heater at Ames meets the requirements of the major customer, NASA's Orion program. Solutions from an advanced computational fluid dynamics code were used to aid in characterizing the properties of the plasma stream and the surface environment on the calorimeters in the supersonic flow stream produced by the arc heater.

Consolidation↗

Coordinated Analysis of an Experimentally Space Weathered Carbonaceous Chondrite

The surfaces of airless bodies experience solar wind irradiation and micrometeorite impacts, a process collectively known as space weathering. These mechanisms alter the chemical composition, microstructure, and optical properties of surface materials and considerable work has been done to understand this phenomenon in lunar and ordinary chondritic materials. However, ongoing sample return missions Hayabusa2 to asteroid Ryugu and OSIRIS-REx to asteroid Bennu have prompted the need to study the effects of space weathering on hydrated, organic-rich materials, especially in the context of early results. Understanding space weathering of these samples is critical for properly interpreting remote sensing data during asteroid encounters, for sample site selection, and for the eventual study of returned samples. We can better understand space weathering of carbonaceous materials by simulating these processes in the laboratory. Recent experiments have shown that the changes in spectral characteristics of carbonaceous chondrites are not consistent among experiments, suggesting additional work is needed before these results can inform our understanding of spectral variations on asteroidal surfaces. Similarly, substantial work remains to characterize the chemical and microstructural effects of these processes in order to correlate these features with spectral changes. Here, we build on our previous work, presenting new results of the pulsed laser irradiation of the Murchison (CM2) meteorite to simulate micrometeorite impacts and the progressive space weathering of carbonaceous surfaces.

Thompson, M. S.↗

Corrosion on Mars: Effect of the Mars Environment on Spacecraft Materials

This report presents the results of a one-year project, funded by NASA’s Kennedy Space Center Innovation Fund in FY18, to conduct a theoretical study on the effect of the Mars environment on spacecraft materials. Corrosion resistance is one of the most important properties in selecting materials for landed spacecraft and structures that will support surface operations for the human exploration of Mars. Currently, the selection of materials is done by assuming that the corrosion behavior of a material on Mars will be the same as that on Earth. This is understandable since there is no data on the corrosion resistance of materials in the Mars environment. However, given that corrosion is defined as the degradation of a metal that results from its chemical interaction with the environment, it cannot be assumed that corrosion is going to be the same in both environments since they are significantly different. The goal of this research was to develop a systematic approach to understand corrosion of spacecraft materials on Mars by conducting a literature search of available data, relevant to corrosion in the Mars environment. This project was motivated by the suggestion, by a team of researchers, that some of the structural degradation observed on Curiosity's wheels may have been caused by corrosive interactions with the transient liquid brines, reported to be present on Mars, while the most significant damage was attributed to rock scratching. An extensive literature search, on data relevant to corrosion on Mars, confirmed the need to investigate the interaction between materials, used for spacecraft and structures designed to support long-term surface operations on Mars, and the Mars environment. Previous preliminary experiments, designed to look at the interaction between aerospace aluminum alloy (AA7075-T73) and the gases present in the Mars atmosphere, at 20 degC and a pressure of 700 Pa, showed that there is an interaction between the small amount of oxygen present in the Mars gas and the alloy, when there is a scratch that removes the protective aluminum oxide film. Further studies are needed to consider many other important components of the Mars environment that can affect this interaction such as: the presence of brines, the interaction between these brines and materials, the effect of radiation on these interactions, and the possible catalytic effects of the clays present in the Martian regolith. This theoretical study provides strong justification to conduct experimental work to investigate the interaction between spacecraft materials with simulated Martian environments to reduce Mars exploration costs.

Calle, Luz M.↗

Corrosion Resistance of Materials in the Mars Environment

This paper presents the results of a literature search of available data relevant to corrosion resistance of materials in the Mars environment, as a background for future experimental work. Corrosion resistance is one of the most important properties in selecting materials for landed spacecraft and structures that will support surface operations for the human exploration of Mars. Currently, the selection of materials is done by assuming that the corrosion behavior of a material on Mars will be the same as that on Earth. This is understandable since there is no data available on the corrosion resistance of materials in the Mars environment. However, given that corrosion is defined as the degradation of a metal that results from its chemical interaction with the environment, it cannot be assumed that corrosion is going to be the same in both environments, since they are significantly different. This theoretical study was motivated by the suggestion, by a team of researchers, that some of the structural degradation observed on Curiosity's wheels may have been caused by corrosive interactions with the transient liquid brines, reported to be present on Mars, while the most significant damage was attributed to mechanical damage. An extensive literature search, on data relevant to corrosion on Mars, confirmed the need to investigate the interaction between materials, used for spacecraft and structures designed to support long-term surface operations on Mars, and the Mars environment. Experimental studies are needed to investigate the corrosion behavior of materials in relevant components of the Mars environment such as: the Mars atmosphere, the presence of brines, the interaction between these brines and materials, the effect of radiation on these interactions, and the possible catalytic effects of the clays present in the Martian regolith. The findings from this theoretical study provide strong justification to conduct experimental work to investigate the interaction between spacecraft materials with simulated Martian environments to reduce Mars exploration costs.

Calle, Luz M.↗

Quantum Computing to Accelerate High Fidelity Computational Materials Modeling

In this CIF we worked to develop quantum algorithms for material science simulations based on new ideas recently proposed on plane wave basis sets. Many body simulations are not generally performed in plane wave basis sets on classical hardware, but with newly proposed quantum algorithms, it is possible this will be a highly efficient basis set to run quantum simulations on quantum hardware. Using state of the art classical simulations we ran small test simulations to estimate the resources that will be needed to run such plane wave algorithms on quantum hardware. We demonstrate our approach for a series of atoms and molecular systems.

Norman Tubman↗

Thermo-Optical Properties of Lunar Dust Simulants

Lunar dust coverage can significantly impact the thermo-optical properties of external surfaces for spacecraft and systems operating in the Lunar orbit or on the Lunar surface. This impacts the thermal control of these vehicles. Testing must be done to determine how much surface optics are affected by varying levels of lunar dust coverage. Optics and Particle Size Distributions (PSDs) of the dust simulant used in these tests are critical to the results. Many lunar dust simulants are available for testing, but their thermooptical properties are not well characterized. To resolve this unknown, 13 different lunar dust simulants’ IR emissivity and solar absorptivity were measured and are presented with their PSDs here.

lunar dust↗

Thermo-Optical Properties of Lunar Dust Simulants

Lunar dust coverage can significantly impact the thermo-optical properties of external surfaces for spacecraft and systems operating in the Lunar orbit or on the Lunar surface. This impacts the thermal control of these vehicles. Testing must be done to determine how much surface optics are affected by varying levels of lunar dust coverage. Optics and Particle Size Distributions (PSDs) of the dust simulant used in these tests are critical to the results. Many lunar dust simulants are available for testing, but their thermooptical properties are not well characterized. To resolve this unknown, 13 different lunar dust simulants’ IR emissivity and solar absorptivity were measured and are presented with their PSDs here.

lunar dust↗