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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Diagnosis of PV Cell Antireflective Coating Degradation Resulting from Hot-Humid, High Voltage Potential Aging

Corrosion of the antireflective coating on a photovoltaic cell ("ARc corrosion") has previously been observed in studies using hot-humid test conditions with external high-voltage (HV) bias. This study primarily focuses on known vulnerable, legacy aluminum back surface field (Al-BSF) cells in mini-modules (MiMos) put through comparative stepped stress tests. Each cell type had MiMos at +1500 V, -1500 V, or unbiased ("Voc") potential, which were sequentially subjected to test conditions of 60deg C/60% relative humidity (RH) for 96 h, as in International Electrotechnical Commission (IEC) Technical Specification 62804-1; 70 deg C/70% RH for 200 h; and 85 deg C/85% RH for 200 h. Characterizations at each step included visual camera and electroluminescence (EL) imaging, colorimetry, and current-voltage (I-V) curve tracing. Final characterizations included: Suns-Voc; spatial mapping of external quantum efficiency (EQE); high-resolution photoluminescence (PL), EL, and dark lock-in thermography (DLIT) imaging. Forensics were performed on extracted cores, including scanning electron microscopy (SEM) with energy-dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and scanning Auger microscopy (SAM). Forensics were also conducted on MiMos from previous studies that underwent stepped HV aging and separate outdoor aged full-sized modules. ARc corrosion was specifically seen for the glass/encapsulant/cell side of the +1500V (HV+) stressed MiMos and modules. Appearance, color, and reflectance were the most distinguishing characteristics relative to glass corrosion, gridline-corrosion and -delamination as well as other concurrent degradation modes. SEM/EDS and SAM identified conversion of silicon nitride to hydrated silica, hydrous silica, or hydrated amorphous silica, which preferentially occurred at the edges and tips of the pyramidal textured cell surface.

14 SOLAR ENERGY↗
DOE OSTI2021

Effect of Humidity on the Reactive Uptake of Ammonia and Dimethylamine by Nitrogen-Containing Secondary Organic Aerosol

This study investigated the uptake of ammonia (NH3) by secondary organic aerosol (SOA) particles generated via limonene photooxidation or ozonolysis as well as the uptake of dimethylamine (DMA) by limonene ozonolysis, α-cedrene photooxidation, or toluene photooxidation SOA in an environmental chamber between 0–50% relative humidity. In addition to the acid-base equilibrium uptake, NH3 and DMA can react with SOA carbonyl compounds converting them into nitrogen-containing organic compounds (NOCs). The effective reactive uptake coefficients for the formation of NOCs from ammonia were measured on the order of 10−5. The observed DMA reactive uptake coefficients ranged from 10−5 to 10−4. Typically, the reactive uptake coefficient decreased with increasing relative humidity. This is consistent with NOC formation by a condensation reaction between NH3 or DMA with SOA, which produces water as a product. Ammonia is more abundant in the atmosphere than amines. However, the larger observed reactive uptake coefficient suggests that amine uptake may also be a potential source of organic nitrogen in particulate matter.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Effect of Humidity-Triggered Controlled-Release 1-Methylcyclopropene (1-MCP) on Postharvest Quality of Papaya Fruit

Papaya (Carica papaya L.) is a valuable economic crop that is widely cultivated in tropical and subtropical regions but has a short storage and shelf life. Exploring effective strategies to improve the postharvest quality of papaya is important. This study explored the effect of humidity-triggered controlled-release 1-methylcyclopropene (1-MCP) sheets on the postharvest quality of papaya fruit. ‘Rainbow’ papayas underwent cold storage at 10 ± 0.5 °C, RH 85% ± 2% for 14 days, and then were transferred to 20 ± 0.5 °C, RH 85% ± 2% for 10 days to simulate shelf life. The 1-MCP sheets were cut into different sizes and placed in storage containers in advance to create corresponding concentrations at 0.5, 1.0, 2.0, and 4.0 ppm. Results showed that 1-MCP treatment inhibited fruit softening, and reduced weight loss and peel color deterioration without causing any physiological disorders. The 1.0–2.0 ppm 1-MCP-treated fruit received the highest score for papaya flavor and sweetness respectively and the lowest score for off-flavor. The humidity-triggered controlled-release 1-MCP sheets are effective and convenient, and they can serve as an important tool for regulating postharvest papaya ripening with economic benefits.

Agriculture↗
DOE OSTI2023

Direct Ink-Write Printing of Ceramic Clay with an Embedded Wireless Temperature and Relative Humidity Sensor

This research presents a simple method to additively manufacture Cone 5 porcelain clay ceramics by using the direct ink-write (DIW) printing technique. DIW has allowed the application of extruding highly viscous ceramic materials with relatively high-quality and good mechanical properties, which additionally allows a freedom of design and the capability of manufacturing complex geometrical shapes. Clay particles were mixed with deionized (DI) water at different ratios, where the most suitable composition for 3D printing was observed at a 1:5 w/c ratio (16.2 wt.%. of DI water). Differential geometrical designs were printed to demonstrate the printing capabilities of the paste. In addition, a clay structure was fabricated with an embedded wireless temperature and relative humidity (RH) sensor during the 3D printing process. The embedded sensor read up to 65% RH and temperatures of up to 85 °F from a maximum distance of 141.7 m. The structural integrity of the selected 3D printed geometries was confirmed through the compressive strength of fired and non-fired clay samples, with strengths of 70 MPa and 90 MPa, respectively. This research demonstrates the feasibility of using the DIW printing of porcelain clay with embedded sensors, with fully functional temperature- and humidity-sensing capabilities.

42 ENGINEERING↗
DOE OSTI2019

Data from: Evapotranspiration is resilient in the face of land cover and climate change in a humid temperate catchment

In temperate humid catchments, evapotranspiration returns more than half of the annual precipitation to the atmosphere, thereby determining the balance available to recharge groundwaters and support stream flow and lake levels. Changes in evapotranspiration rates and therefore catchment hydrology could be driven by changes in land use or climate. Here we examine the catchment water balance over the past 50 y for a catchment in southwest Michigan covered by cropland, grassland, forest, and wetlands. Over the study period about 27% of the catchment has been abandoned from row-crop agriculture to perennial vegetation and about 20% of the catchment has reverted to deciduous forest, and the climate has warmed by 1.14°C. Despite these changes in land use, precipitation and stream discharge, and by inference catchment-scale evapotranspiration, have been stable over the study period. The remarkably stable rates of evapotranspirative water loss from the catchment across a period of significant land cover change suggest that rainfed annual crops and perennial vegetation do not differ greatly in evapotranspiration rates, and this is supported by measurements of evapotranspiration from various vegetation types based on soil water monitoring in the same catchment. Compensating changes in the other meteorological drivers of evaporative water demand besides air temperature—wind speed, atmospheric humidity, and net radiation—are also possible, but cannot be evaluated due to insufficient local data across the 50-y period. Regardless of the explanation, this study shows that the water balance of this landscape has been resilient in the face of both land cover and climate change over the past 50 y.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

Observations and implications of liquid–liquid phase separation at high relative humidities in secondary organic material produced by α -pinene ozonolysis without inorganic salts

Particles consisting of secondary organic material (SOM) are abundant in the atmosphere. In order to predict the role of these particles in climate, visibility and atmospheric chemistry, information on particle phase state (i.e., single liquid, two liquids and solid) is needed. Our paper focuses on the phase state of SOM particles free of inorganic salts produced by the ozonolysis of α -pinene. Phase transitions were investigated in the laboratory using optical microscopy and theoretically using a thermodynamic model at 290 K and for relative humidities ranging from < 0.5 to 100%. In the laboratory studies, a single phase was observed from 0 to 95% relative humidity (RH) while two liquid phases were observed above 95% RH. For increasing RH, the mechanism of liquid–liquid phase separation (LLPS) was spinodal decomposition. The RH range over which two liquid phases were observed did not depend on the direction of RH change. In the modeling studies, the SOM took up very little water and was a single organic-rich phase at low RH values. At high RH, the SOM underwent LLPS to form an organic-rich phase and a water-rich phase, consistent with the laboratory studies. The presence of LLPS at high RH values can have consequences for the cloud condensation nuclei (CCN) activity of SOM particles. In the simulated Köhler curves for SOM particles, two local maxima were observed. Depending on the composition of the SOM, the first or second maximum can determine the critical supersaturation for activation. Recently researchers have observed inconsistencies between measured CCN properties of SOM particles and hygroscopic growth measured below water saturation (i.e., hygroscopic parameters measured below water saturation were inconsistent with hygroscopic parameters measured above water saturation). Furthermore, the work presented here illustrates that such inconsistencies are expected for systems with LLPS when the water uptake at subsaturated conditions represents the hygroscopicity of an organic-rich phase while the barrier for CCN activation can be determined by the second maximum in the Köhler curve when the particles are water rich.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Influence of relative humidity on the heterogeneous oxidation of secondary organic aerosol

Abstract. Secondary organic aerosol (SOA) is a complex mixture of hundreds of semi-volatile to extremely low-volatility organic compounds that are chemically processed in the atmosphere, including via heterogeneous oxidation by gas-phase radicals. Relative humidity (RH) has a substantial impact on particle phase, which can affect how SOA evolves in the atmosphere. In this study, SOA from dark α -pinene ozonolysis is heterogeneously aged by OH radicals in a flow tube at low and high RH. At high RH (RH = 89 %) there is substantial loss of particle volume (~60 %) at an equivalent atmospheric OH exposure of 3 weeks. In contrast, at low RH (RH = 25 %) there is little mass loss (< 20 %) at the same OH exposure. Mass spectra of the SOA particles were measured as a function of OH exposure using a vacuum ultraviolet aerosol mass spectrometer (VUV-AMS). The mass spectra observed at low RH overall exhibit minor changes with oxidation and negligible further changes above an OH exposure = 2×10 12 molecule cm -3 s suggesting limited impact of oxidation on the particle composition. In contrast, the mass spectra observed at high RH exhibit substantial and continuous changes as a function of OH exposure. Further, at high RH clusters of peaks in the mass spectra exhibit unique decay patterns, suggesting different responses of various species to oxidation. A model of heterogeneous oxidation has been developed to understand the origin of the difference in aging between the low- and high-RH experiments. Differences in diffusivity of the SOA between the low- and high-RH experiments alone can explain the difference in compositional change but cannot explain the difference in mass loss. Instead, the difference in mass loss is attributable to RH-dependent differences in the OH uptake coefficient and/or the net probability of fragmentation, with either or both larger at high RH compared to low RH. These results illustrate the important impact of relative humidity on the fate of SOA in the atmosphere.

Li, Ziyue (ORCID:0000000191017737)↗
DOE OSTI2018

Effect of relative humidity on the composition of secondary organic aerosol from the oxidation of toluene

The effect of relative humidity (RH) on the chemical composition of secondary organic aerosol (SOA) formed from low-NO x toluene oxidation in the absence of seed particles was investigated. SOA samples were prepared in an aerosol smog chamber at < 2 % RH and 75 % RH, collected on Teflon filters, and analyzed with nanospray desorption electrospray ionization high-resolution mass spectrometry (nano-DESI–HRMS). Measurements revealed a significant reduction in the fraction of oligomers present in the SOA generated at 75 % RH compared to SOA generated under dry conditions. In a separate set of experiments, the particle mass concentrations were measured with a scanning mobility particle sizer (SMPS) at RHs ranging from < 2 to 90 %. It was found that the particle mass loading decreased by nearly an order of magnitude when RH increased from < 2 to 75–90 % for low-NO x toluene SOA. The volatility distributions of the SOA compounds, estimated from the distribution of molecular formulas using the “molecular corridor” approach, confirmed that low-NO x toluene SOA became more volatile on average under high-RH conditions. In contrast, the effect of RH on SOA mass loading was found to be much smaller for high-NO x toluene SOA. The observed increase in the oligomer fraction and particle mass loading under dry conditions were attributed to the enhancement of condensation reactions, which produce water and oligomers from smaller compounds in low-NO x toluene SOA. The reduction in the fraction of oligomeric compounds under humid conditions is predicted to partly counteract the previously observed enhancement in the toluene SOA yield driven by the aerosol liquid water chemistry in deliquesced inorganic seed particles.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Regularized inversion of aerosol hygroscopic growth factor probability density function: application to humidity-controlled fast integrated mobility spectrometer measurements

Abstract. Aerosol hygroscopic growth plays an important role in atmospheric particle chemistry and the effects of aerosol on radiation and hence climate. The hygroscopic growth is often characterized by a growth factor probability density function (GF-PDF), where the growth factor is defined as the ratio of the particle size at a specified relative humidity to its dry size. Parametric, least-squares methods are the most widely used algorithms for inverting the GF-PDF from measurements of the humidified tandem differential mobility analyzer (HTDMA) and have been recently applied to the GF-PDF inversion from measurements of the humidity-controlled fast integrated mobility spectrometer (HFIMS). However, these least-squares methods suffer from noise amplification due to the lack of regularization in solving the ill-posed problem, resulting in significant fluctuations in the retrieved GF-PDF and even occasional failures of convergence. In this study, we introduce nonparametric, regularized methods to invert the aerosol GF-PDF and apply them to HFIMS measurements. Based on the HFIMS kernel function, the forward convolution is transformed into a matrix-based form, which facilitates the application of the nonparametric inversion methods with regularizations, including Tikhonov regularization and Twomey's iterative regularization. Inversions of the GF-PDF using the nonparameteric methods with regularization are demonstrated using HFIMS measurements simulated from representative GF-PDFs of ambient aerosols. The characteristics of reconstructed GF-PDFs resulting from different inversion methods, including previously developed least-squares methods, are quantitatively compared. The result shows that Twomey's method generally outperforms other inversion methods. The capabilities of Twomey's method in reconstructing the pre-defined GF-PDFs and recovering the mode parameters are validated.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

Large fluxes and rapid turnover of mineral-associated carbon across topographic gradients in a humid tropical forest: insights from paired 14 C analysis

It has been proposed that the large soil carbon (C) stocks of humid tropical forests result predominantly from C stabilization by reactive minerals, whereas oxygen (O 2 ) limitation of decomposition has received much less attention. We examined the importance of these factors in explaining patterns of C stocks and turnover in the Luquillo Experimental Forest, Puerto Rico, using radiocarbon ( 14 C) measurements of contemporary and archived samples. Samples from ridge, slope, and valley positions spanned three soil orders (Ultisol, Oxisol, Inceptisol) representative of humid tropical forests, and differed in texture, reactive metal content, O 2 availability, and root biomass. Mineral-associated C comprised the large majority (87 ± 2%, n = 30) of total soil C. Turnover of most mineral-associated C (66 ± 2%) was rapid (11 to 26 years; mean and SE: 18 ± 3 years) in 25 of 30 soil samples across surface horizons (0–10 and 10–20 cm depths) and all topographic positions, independent of variation in reactive metal concentrations and clay content. Passive C with centennial–millennial turnover was typically much less abundant (34 ± 3%), even at 10–20 cm depths. Carbon turnover times and concentrations significantly increased with concentrations of reduced iron (Fe(II)) across all samples, suggesting that O 2 availability may have limited the decomposition of mineral-associated C over decadal scales. Steady-state inputs of mineral-associated C were statistically similar among the three topographic positions, and could represent 10–25% of annual litter production. Observed trends in mineral-associated Δ 14 C over time could not be fit using the single-pool model used in many other studies, which generated contradictory relationships between turnover and Δ 14 C as compared with a more realistic two-pool model. The large C fluxes in surface and near-surface soils documented here are supported by findings from paired 14 C studies in other types of ecosystems, and suggest that most mineral-associated C cycles relatively rapidly (decadal scales) across ecosystems that span a broad range of state factors.

Hall, S. J.↗
NASA NTRS1972

Temperature and humidity control of simulated human breath

Subsystem was developed for breathing metabolic simulator which adjusts temperature and humidity of air to levels of human exhaled breath. Temperature-humidity subsystem is described, consisting of aluminum enclosure with 400 watt heat sheet glued to bottom, vertical separators, inlet connection, and check valve.

Bartlett, R. G.↗
NASA NTRS1971

A Study of the Effects of Relative Humidity on Small Particle Adhesion to Surfaces

Ambient dust ranging in size from less than one micron up to 140 microns was used as test particles. Relative humidities of 33% to 100% were used to condition test surfaces after loading with the test particles. A 20 psi nitrogen blowoff was used as the removal mechanism to test for particle adhesion. Particles were counted before and after blowoff to determine retention characteristics. Particle adhesion increased drastically as relative humidity increased above 50%. The greatest adhesion changes occurred within the first hour of conditioning time. Data are presented for total particle adhesion, for particles 10 microns and larger, and 50 microns and larger.

Whitfield, W. J.↗
NASA NTRS1973

Hydrochloric acid aerosol formation by the interaction of hydrogen chloride with humid air

The conditions in which hydrochloric acid aerosol is predicted by the interaction of hydrogen chloride gas with the water vapor in humid air are analyzed. The liquid gas phase equilibrium for the HCL-H2O system is expressed in terms of relative humidity and hydrogen chloride concentration as parts per million, units commonly used in pollution studies. Presented are the concentration (wt %) of HC1 in the aerosol and the concentration of aerosol (ppm) predicted.

Rhein, R. A.↗
NASA NTRS1976

Breadboard CO2 and humidity control system

A regenerable CO2 and humidity control system is being developed for potential use on shuttle as an alternate to the baseline lithium hydroxide (LiOH)/condensing heat exchanger system. The system utilizes a sorbent material, designated HS-C, to adsorb CO2 and water vapor from the cabin atmosphere. The material is regenerated by exposing it to space vacuum. A half-size breadboard system, utilizing a flight representative HS-C canister, was designed, built, and performance tested to shuttle requirements for total CO2 and total humidity removal. The use of a new chemical matrix material allowed significant optimization of the system design by packing the HS-C chemical into the core of a heat exchanger which is manifolded to form two separate and distinct beds. Breadboard system performance was proven by parametric testing and simulated mission testing over the full range of shuttle crew sizes and metabolic loadings. Vacuum desorption testing demonstrated considerable savings in previously projected shuttle vacuum duct sizing.

Boehm, A. M.↗
NASA NTRS1977

Equations for the determination of humidity from dewpoint and psychrometric data

A general expression based on the Claperon-Clausius differential equation that relates saturation vapor pressure, absolute temperature, and the latent heat of transformation was derived that expresses saturation vapor pressure as a function of absolute temperature. This expression was then used to derive general expressions for vapor pressure, absolute humidity, and relative humidity as functions of either dewpoint and ambient temperature or psychrometric parameters. Constants for all general expressions were then evaluated to give specific expressions in both the international system of units and U.S. customary units for temperatures above and below freezing.

Parish, O. O.↗
NASA NTRS1976

CO2 and humidity removal system for extended Shuttle missions - Equilibrium testing and performance analysis

In Shuttle orbiter cabins, lithium hydroxide (LiOH) canisters are currently planned to be used for CO2 adsorption and condensing heat exchangers for humidity control. In this paper a more effective CO2 and humidity removal method is proposed by replacing the LiOH component with HS-C adsorbent (a polyethylenimine coated acrylic ester), thus eliminating the low temperature constraints on the active thermal control system. Since the adsorption of CO2 and H2O are reversible, a double bed configuration operating cyclicly is planned to provide continuous atmospheric control. Apparatus and the experimental procedure to test the adsorption equilibrium are described and some of the indicative results, tabulated by computers, are presented with the help of exponential expressions and differential equations. By using a computer model of the Shuttle HS-C system, performance predictions are made.

Davis, S. H.↗
NASA NTRS1977

Effect of ambient temperature and humidity on emissions of an idling gas turbine

The effects of inlet pressure, temperature, and humidity on the oxides of nitrogen produced by an engine operating at takeoff power setting were investigated and numerous correction factors were formulated. The effect of ambient relative humidity on gas turbine idle emissions was ascertained. Experimentally, a nonvitiating combustor rig was employed to simulate changing combustor inlet conditions as generated by changing ambient conditions. Emissions measurements were made at the combustor exit. For carbon monoxide, a reaction kinetic scheme was applied within each zone of the combustor where initial species concentrations reflected not only local combustor characteristics but also changing ambient conditions.

Kauffman, C. W.↗