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At least 325 records · Page 18

Fire control method and analytical model for large liquid hydrocarbon pool fires

The dominate parameter governing the behavior of a liquid hydrocarbon (JP-5) pool fire is wind speed. The most effective method of controlling wind speed in the vicinity of a large circular (10 m dia.) pool fire is a set of concentric screens located outside the perimeter. Because detailed behavior of the pool fire structure within one pool fire diameter is unknown, an analytical model supported by careful experiments is under development. As a first step toward this development, a regional pool fire model was constructed for the no-wind condition consisting of three zones -- liquid fuel, combustion, and plume -- where the predicted variables are mass burning rate and characteristic temperatures of the combustion and plume zones. This zone pool fire model can be modified to incorporate plume bending by wind, radiation absorption by soot particles, and a different ambient air flow entrainment rate. Results from the zone model are given for a pool diameter of 1.3 m and are found to reproduce values in the literature.

Fenton, D. L.↗

Tropospheric ozone - Seasonal behavior, trends, and anthropogenic influence

In the present analysis of tropospheric ozone data, attention is given to spatial and temporal variations. Two modes of seasonal behavior are noted for surface ozone at mid-latitudes: a broad summer maximum within a few hundred km of industrial/urban areas in Europe and the U.S., and a minimum in summer or autumn in sparcely populated regions that are remote from industrial activity. These and limited historical data indicate that summertime concentrations of ozone near the surface in the rural areas of Europe and the U.S. may have increased between 20 and 100 percent since the 1940s. It is suggested that the summer maximum in ozone and other observed trends are due to photochemical production associated with anthropogenic emissions of NO(x), hydrocarbons, and CO from fossil fuel combustion.

Logan, J. A.↗

Evaluation of candidate alloys for the construction of metal flex hoses in the STS launch environment

Various vacuum jacketed cryogenic supply lines at the Shuttle launch site use convoluted flexible expansion joints. The atmosphere at the launch site has a very high salt content, and during a launch, fuel combustion products include hydrochloric acid. This extremely corrosive environment has caused pitting corrosion failure in the flex hoses, which were made of 304L stainless steel. A search was done to find a more corrosion resistant replacement material. This study focused on 19 metal alloys. Tests which were performed include electrochemical corrosion testing, accelerated corrosion testing in a salt fog chamber, long term exposure at the beach corrosion testing site, and pitting corrosion tests in ferric chloride solution. Based on the results of these tests, the most corrosion resistant alloys were found to be (in order) Hastelloy C-22, Inconel 625, Hastelloy C-276, Hastelloy C-4, and Inco Alloy G-3. Of these top five alloys, the Hastelloy C-22 stands out as being the best of those tested for this application.

Ontiveros, Cordelia↗

Oceanographic wide field sensor

The Oceanographic Wide Field Sensor (SeaWiFS) science project will provide measurements of ocean color from space to which will support research into: (1) the character of ocean physical and biological processes; (2) to assess the global oceanic biomass; and (3) to better understand the role of oceanic processes in modulating the Earth's biogeochemical cycles, including the CO2 cycle as it is affected by fossil fuel combustion. The present work extends previous work to study the feasibility of an ocean color mission using the proposed compact Wide-Field Sensor (SeaWiFS) and the EOSAT Corporation's LANDSAT-6 satellite. A Phase A study was conducted which defines a NASA Facility Data System and accompanying Science Program for the EOSAT Company's commercial ocean color instrument called SeaWiFS to be launched on board LANDSAT-6 in 1991.

Kirk, R. G.↗

Evaluation of candidate alloys for the construction of metal flex hoses in the STS launch environment

Various vacuum jacketed cryogenic supply lines at the Shuttle launch site use convoluted flexible expansion joints. The atmosphere at the launch site has a very high salt content, and during a launch fuel combustion products include hydrochloric acid. This extremely corrosive environment has caused pitting corrosion failure in the flex hoses, which were made out of 304L stainless steel. A search was done to find a more corrosion resistant replacement material. Nineteen metal alloys were tested. Tests which were performed include electrochemical corrosion testing, accelerated corrosion testing in a salt fog chamber, long term exposure at the beach corrosion testing site, and pitting corrosion tests in ferric chloride solution. Based on the results, the most corrosion resistant alloys were found to be, in order, Hastelloy C-22, Inconel 625, Hastelloy C-276, Hastelloy C-4, and Inco Alloy G-3. Of these top five alloys, the Hastelloy C-22 stands out as being the best of the alloys tested.

Macdowell, Louis G., III↗

Localized corrosion of high performance metal alloys in an acid/salt environment

Various vacuum jacketed cryogenic supply lines at the Space Shuttle launch site at Kennedy Space Center use convoluted flexible expansion joints. The atmosphere at the launch site has a very high salt content, and during a launch, fuel combustion products include hydrochloric acid. This extremely corrosive environment has caused pitting corrosion failure in the thin walled 304L stainless steel flex hoses. A search was done to find a more corrosion resistant replacement material. The study focussed on 19 metal alloys. Tests which were performed include electrochemical corrosion testing, accelerated corrosion testing in a salt fog chamber, and long term exposure at a beach corrosion testing site. Based on the results of these tests, several nickel based alloys were found to have very high resistance to this corrosive environment. Also, there was excellent agreement between the electrochemical tests and the actual beach exposure tests. This suggests that electrochemical testing may be useful for narrowing the field of potential candidate alloys before subjecting samples to long term beach exposure.

Macdowell, L. G.↗

A Planar-Fluorescence Imaging Technique for Studying Droplet-Turbulence Interactions in Vaporizing Sprays

Droplet turbulence interactions directly affect the vaporization and dispersion of droplets in liquid sprays and therefore play a major role in fuel oxidizer mixing in liquid fueled combustion systems. Proper characterization of droplet turbulence interactions in vaporizing sprays require measurement of droplet size velocity and size temperature correlations. A planar, fluorescence imaging technique is described which is being developed for simultaneously measuring the size, velocity, and temperature of individual droplets in vaporizing sprays. Preliminary droplet size velocity correlation measurements made with this technique are presented. These measurements are also compared to and show very good agreement with measurements made in the same spray using a phase Doppler particle analyzer.

Santavicca, Dom A.↗

Group evaporation

Liquid fuel combustion process is greatly affected by the rate of droplet evaporation. The heat and mass exchanges between gas and liquid couple the dynamics of both phases in all aspects: mass, momentum, and energy. Correct prediction of the evaporation rate is therefore a key issue in engineering design of liquid combustion devices. Current analytical tools for characterizing the behavior of these devices are based on results from a single isolated droplet. Numerous experimental studies have challenged the applicability of these results in a dense spray. To account for the droplets' interaction in a dense spray, a number of theories have been developed in the past decade. Herein, two tasks are examined. One was to study how to implement the existing theoretical results, and the other was to explore the possibility of experimental verifications. The current theoretical results of group evaporation are given for a monodispersed cluster subject to adiabatic conditions. The time evolution of the fluid mechanic and thermodynamic behavior in this cluster is derived. The results given are not in the form of a subscale model for CFD codes.

Shen, Hayley H.↗

Lewis Research Center R and D Facilities

The NASA Lewis Research Center (LeRC) defines and develops advanced technology for high priority national needs. The work of the Center is directed toward new propulsion, power, and communications technologies for application to aeronautics and space, so that U.S. leadership in these areas is ensured. The end product is knowledge, usually in a report, that is made fully available to potential users--the aircraft engine industry, the energy industry, the automotive industry, the space industry, and other NASA centers. In addition to offices and laboratories for almost every kind of physical research in such fields as fluid mechanics, physics, materials, fuels, combustion, thermodynamics, lubrication, heat transfer, and electronics, LeRC has a variety of engineering test cells for experiments with components such as compressors, pumps, conductors, turbines, nozzles, and controls. A number of large facilities can simulate the operating environment for a complete system: altitude chambers for aircraft engines; large supersonic wind tunnels for advanced airframes and propulsion systems; space simulation chambers for electric rockets or spacecraft; and a 420-foot-deep zero-gravity facility for microgravity experiments. Some problems are amenable to detection and solution only in the complete system and at essentially full scale. By combining basic research in pertinent disciplines and generic technologies with applied research on components and complete systems, LeRC has become one of the most productive centers in its field in the world. This brochure describes a number of the facilities that provide LeRC with its exceptional capabilities.

Source record↗

Theoretical determination of chemical rate constants using novel time-dependent methods

The work completed within the grant period 10/1/91 through 12/31/93 falls primarily in the area of reaction dynamics using both quantum and classical mechanical methodologies. Essentially four projects have been completed and have been or are in preparation of being published. The majority of time was spent in the determination of reaction rate coefficients in the area of hydrocarbon fuel combustion reactions which are relevant to NASA's High Speed Research Program (HSRP). These reaction coefficients are important in the design of novel jet engines with low NOx emissions, which through a series of catalytic reactions contribute to the deterioration of the earth's ozone layer. A second area of research studied concerned the control of chemical reactivity using ultrashort (femtosecond) laser pulses. Recent advances in pulsed-laser technologies have opened up a vast new field to be investigated both experimentally and theoretically. The photodissociation of molecules adsorbed on surfaces using novel time-independent quantum mechanical methods was a third project. And finally, using state-of-the-art, high level ab initio electronic structure methods in conjunction with accurate quantum dynamical methods, the rovibrational energy levels of a triatomic molecule with two nonhydrogen atoms (HCN) were calculated to unprecedented levels of agreement between theory and experiment.

Dateo, Christopher E.↗

STS-73 Flight Day 14

On this fourteenth day of the STS-73 sixteen day mission, the crew Cmdr. Kenneth Bowersox, Pilot Kent Rominger, Payload Specialists Albert Sacco and Fred Leslie, and Mission Specialists Kathryn Thornton, Catherine 'Cady' Coleman, and Michael Lopez-Alegria are shown performing several of the spaceborne experiments onboard the United States Microgravity Lab-2 (USML-2). The experiments shown include the Drop Physics Module (DPM) experiment, the Surface Tension Driven Convection Experiment (STDCE), the Geophysical Fluid Flow Cell (GFFC) experiment, and an experiment on fuel combustion and combustion products. Bowersox, Sacco, Thornton, and Rominger (the red team) were interviewed by high school students from Worcester, Massachusetts, who asked questions regarding the mission's experiments and general questions about living in space. Earth views included a black and white image of the Earth's atmospheric boundary layers.

Source record↗

Latitudinal distribution of black carbon soot in the upper troposphere and lower stratosphere

Black carbon soot from the upper troposphere and lower stratosphere has been systematically collected at latitudes from 90 deg N to 45 deg S. The measured latitudinal distribution of this soot at 10 to 11 km altitude is found to covary with commercial air traffic fuel use, suggesting that aircraft fuel combustion at altitude is the principal source. In addition, at latitudes where the commercial air traffic is high, measured black carbon soot values are high even at 20 km altitude, suggesting that aircraft-generated soot injected just above the tropopause may be transported to higher altitudes. During the volcanically influenced period in which these samples were collected, the number abundances, total mass, and calculated total surface area of black carbon soot are 2-3 orders of magnitude lower than similar measures of sulfuric acid aerosol. During volcanically quiescent periods, the calculated total surface area of black carbon soot aerosol is of the same order of magnitude as that of the background sulfuric acid aerosol. It appears from this comparison that black carbon soot is only capable of influencing lower stratosphere or upper troposphere chemistry during periods when the aerosol budget is not dominated by volcanic activity. It remains to determine the extent to which black carbon soot particles act as nuclei for sulfuric acid aerosol formation. However, mass balance calculations suggest that aircraft soot injected at altitude does not represent a significant source of condensation nuclei for sulfuric acid aerosols.

Blake, David F.↗

Biomass Burning Influences on the Composition of the Remote South Pacific Troposphere: Analysis Based on Observations from PEM Tropics-A

Airborne, in-situ measurements from PEM-Tropics-A (September/October 1996) are analyzed to show the presence of distinct pollution plumes in the middle-tropical troposphere of the remote South Pacific (10-30degS). These elevated plumes cause a relative maximum at about 5-7km attitude in the vertical distribution of primary and secondary species characteristic of fuel combustion and biomass burning (CO, C2H2, C2H6, CH3Cl, PAN, O3). Similar plumes were also observed at mid-latitudes in the middle troposphere during three flights east of New Zealand (40-45degS). In all, pollution plumes with CO larger than 100 ppb were observed 24 times on 7 separate flight days south of the equator. The observed plumes were generally embedded in very dry air. Ten-day back trajectory analysis supports the view that these originated from the biomass burning regions of South Africa (and South America) and were transported to the South Pacific along long-distance subsiding trajectories. The chemical composition of the southern Pacific troposphere analyzed from the PEM-Tropics-A data is compared with data from the tropical regions of the northern Pacific (PEM-West-A) and southern Atlantic (TRACE-A) during the same Sept/Oct time period. Sizable perturbations in the abundance of ozone and its key precursors, resulting from the transport of pollution originating from biomass burning sources, are observed in much of the Southern Hemispheric troposphere.

Singh, H. B.↗

Stratospheric Age Spectra and Mean Ages From In Situ Observations of Carbon Dioxide

Tropospheric CO2 mixing ratios exhibit latitudinally varying seasonal and interannual oscillations superimposed on the long-term positive trend due to fossil fuel combustion. In situ observations of CO2 obtained from 1992-2000 using the NASA ER-2 aircraft and high-altitude balloons show that these time-varying signals propagate into the stratosphere, providing information about the transport history of sampled air. We have used these data to derive age spectra and mean ages that can be compared with results from models of the stratospheric circulation. Age spectra have been derived for altitudes below approximately 20 km for the tropics and for northern midlatitudes, where there is sufficient data and where the amplitudes of the seasonal and interannual oscillations are large enough to be detected. The midlatitude CO2 data are consistent with bimodal age spectra, which may result from a subtropical "barrier" to horizontal exchange. Seasonally resolved mean ages are available with nearly pole-to-pole coverage below 20 km and in the tropics and at middle and high northern latitudes up to the maximum altitude reached by the balloons (approximately 30 km). The oldest air sampled was in the Arctic polar vortex with a mean age of 6.5 +/- 0.5 years.

Andrews, Arlyn E.↗

Measuring Rocket Engine Temperatures with Hydrogen Raman Spectroscopy

Optically accessible, high pressure, hot fire test articles are available at NASA Marshall for use in development of advanced rocket engine propellant injectors. Single laser-pulse ultraviolet (UV) Raman spectroscopy has been used in the past in these devices for analysis of high pressure H2- and CH4-fueled combustion, but relies on an independent pressure measurement in order to provide temperature information. A variation of UV Raman (High Resolution Hydrogen Raman Spectroscopy) is under development and will allow temperature measurement without the need for an independent pressure measurement, useful for flows where local pressure may not be accurately known. The technique involves the use of a spectrometer with good spectral resolution, requiring a small entrance slit for the spectrometer. The H2 Raman spectrum, when created by a narrow linewidth laser source and obtained from a good spectral resolution spectrograph, has a spectral shape related to temperature. By best-fit matching an experimental spectrum to theoretical spectra at various temperatures, a temperature measurement is obtained. The spectral model accounts for collisional narrowing, collisional broadening, Doppler broadening, and collisional line shifting of each Raman line making up the H2 Stokes vibrational Q-branch spectrum. At pressures from atmospheric up to those associated with advanced preburner components (5500 psia), collisional broadening though present does not cause significant overlap of the Raman lines, allowing high resolution H2 Raman to be used for temperature measurements in plumes and in high pressure test articles. Experimental demonstrations of the technique are performed for rich H2-air flames at atmospheric pressure and for high pressure, 300 K H2-He mixtures. Spectrometer imaging quality is identified as being critical for successful implementation of technique.

Wehrmeyer, Joseph A.↗