Mechanical properties of highly filled elastomers. I - Relationship between filler characteristics, shear moduli, and tensile properties
Effect of size and amount of NaCl filler on mechanical properties of polyurethane rubber
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Effect of size and amount of NaCl filler on mechanical properties of polyurethane rubber
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Copolymerization of fluorocarbon vinyl ethers
Phosphines as initiators of polymerization of hexafluorobutyne-2
Oxidation resistant elastomeric polymer synthesis studies of hydroxamic acid and isocyanate
Tensile strength and low temperature properties of homopolymers
Device consisting of a rotating mechanism, a frame with multiple wide bands of rubber, and a fluid bath, demonstrates the feasibility of a human operated device capable of cooling or producing heat. This invention utilizes the basic thermodynamic properties of natural rubber.
Synthesis and chemical properties of elastomeric polymers resistant to effects of fluorine, oxygen difluoride, nitrogen tetroxide, and similar agents
In the search for superior materials from which to make gaskets for pneumatic and hydraulic systems, promising materials were selected and tested. The testing was conducted in two phases. Those materials that passed the tests of Phase 1 were tested in Phase 2, and categorized in the order of preference.
Constant force creep measurements were made at three stress levels on samples of an ammonium perchlorate filled butadiene-acrylic acid copolymer in vacuum and in the atmosphere (air, 50% relative humidity) at a temperature of 28 C. The creep compliance of the samples decreased as much as 50% after 14 days of vacuum exposure. Shift factors were developed which, when applied to the atmospheric compliance measurements, predicted the behavior in vacuum. The experimental results led to the following conclusions: (1) shift factors can be applied to predict compliance behavior in vacuum from measurements in air, and (2) the shift factors are independent of stress but increase in magnitude with increasing vacuum exposure.
A program was conducted to evaluate an in situ dynamic modulus measurement on a solid propellant exposed to vacuum environment. The prediction of long-term vacuum exposure effects is examined.
Attempts to prepare low molecular weight, curable poly-(fluoroalkoxyphosphazenes) have been successful. Derivatization of /Cl2PN/n polymer with alkoxides gave functionally reactive terpolymers. These terpolymers could be crosslinked with polyisocyanates at room temperature. Attempts to control molecular weight have not been as successful. The effects of (Cl2PN)3 monomer purity, use of (Cl2PN)3,4 mixture, and early termination of the bulk polymerization of (Cl2PN)3 were studied briefly. Both low and high molecular weight polymers were obtained. Reaction of NH4Cl with PCl5 with subsequent heating to give chain extension gave either gels of oils with molecular weights of several thousand. The stabilization of poly-(fluoroalkoxyphosphazene) was investigated. The results generally were inconclusive, but acids were found to be deleterious while bases had little discernible effect. Improvements in stability by modification of end groups was inconclusive.
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Both high and low molecular weight, curable poly(fluoroalkoxy phosphazene) terpolymers were prepared. These terpolymers resulted from reaction of (Cl2PNn) polymer with alkoxides derived from CF3CH2OH and C3F7CH2OH, and an alkoxide derived from CH3CH(OH)C2H4OH. The terpolymers were crosslinked with polyisocyanates at room temperature. High molecular weight materials were converted into isocyanate prepolymers which as films underwent moisture cures at room temperature. Prepolymer solutions were stable for several days, and showed good adhesion. Also the effects of polymerization of (Cl2PN)3 were studied. Purified octachlorophosphazene, thiocyanate salts, or hydrogen chloride were employed in attempts to decrease molecular weight. Hydrogen chloride was found to be a good agent for preparation of low molecular weight poly(dichloro phosphazene).
Accuracy of biaxial test equipment to examine the nonlinear mechanical behavior of thin sheet specimens of elastomeric materials has been hampered by lack of precise determination of the force distribution along the sides of the specimen. It has been necessary to use an effective width established by approximate means to obtain the stress from the overall force applied along the edges. To avoid this experimental difficulty, individual miniature proof-ring load cells utilizing semiconductor strain gages have been developed and applied to the support hooks for the thin sheet specimens. Typical results are shown for time-dependent stress distributions for all degrees of biaxiality. An accurate evaluation of the effective specimen width is now possible.
Method has been developed for fabrication of lightweight ducts that are three times stronger than aluminum ducts. Method can be used to produce either flexible or rigid ducts.
Flame retardant elastomeric compositions are described comprised of either spandex type polyurethane having incorporated into the polymer chain halogen containing polyols, conventional spandex type polyurethanes in physical admixture with flame retardant additives, or fluoroelastomeric resins in physical admixture with flame retardant additives. Methods are described for preparing fibers of the flame retardant elastomeric materials and articles of manufacture comprised of the flame retardant clastomeric materials and non elastic materials such as polybenzimidazoles, fiberglass, nylons, etc.
Test results indicate that most effective fire-and smoke-retardant fillers are inorganic hydrates and carbonates that release water and/or carbon dioxide. Most effective filler tested was hydrated sodium silicate. Effectiveness is due to high water content and formation of viscous molten glass when heated. Glass tends to inhibit polymer combustion and to promote formation of char residue.