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At least 325 records · Page 18

Effect of secondary gas-phase reactions (SGR) in pyrolysis of carbon feedstocks for anisotropic carbon materials production – 1: Controlling SGR to modify intermediate coal tar species to improve pitch anisotropy

To meet the increasing demand for graphitizable carbon products, such as needle coke and carbon fiber, more carbon feedstocks capable of forming anisotropy should be utilized. Non-coking coals are widely available but are not typically suitable for producing anisotropic carbons due to lacking proper coal chemistry. This work used secondary gas-phase reactions (SGR) during coal pyrolysis to improve the coal tar chemistry of a non-coking coal for anisotropic carbon production. SGR pyrolysis temperatures and residence times were varied (T = 800–900°C and τ = 0–2.5 s), and analysis of the intermediate coal tar products showed that as these SGR pyrolysis conditions increased, the oxygen and aliphatic concentrations decreased, whereas aromatic contents and molecular weights increased. Without any SGR, microscopy of the thermally-treated coal tar pitch product revealed that the coal tar pitch was isotropic; however, upon using increased SGR pyrolysis conditions, the resulting coal tar pitch samples substantially increased in the percentage and quality of anisotropy formation. Further, the products' analyses show clear trends of modified chemical properties in the intermediate coal tar and improved anisotropy results. Thus, the results presented in this work show that by controlling the SGR during pyrolysis of a non-coking coal, this approach can modify the coal tar chemistry towards a precursor more suitable for quality anisotropic carbon material production.

01 COAL, LIGNITE, AND PEAT↗

BIRD: A general interface for sparse distributed memory simulators

Kanerva's sparse distributed memory (SDM) has now been implemented for at least six different computers, including SUN3 workstations, the Apple Macintosh, and the Connection Machine. A common interface for input of commands would both aid testing of programs on a broad range of computer architectures and assist users in transferring results from research environments to applications. A common interface also allows secondary programs to generate command sequences for a sparse distributed memory, which may then be executed on the appropriate hardware. The BIRD program is an attempt to create such an interface. Simplifying access to different simulators should assist developers in finding appropriate uses for SDM.

Rogers, David↗

Electron Cloud Simulations for the Electron-Ion Collider in Brookhaven National Laboratory

For high-intensity circular accelerators and storage rings, if the secondary electron emission yield (SEY) of the vacuum chamber surfaces is high, an EC (Electron Cloud) could build up with the passage of the circulating beam. The presence of EC can strongly affect the beam quality, such as transverse instabilities, transverse emittance growth, and beam loss. Furthermore, the heat load from EC can exceed the available cryogenic capability. For the RHIC superconducting (SC) arc magnets, to be used for the hadron storage ring of the Electron-Ion Collider (EIC), the dynamic heat load budget is 0.5 W/m to the 4.5 K stainless steel beam pipe. This can limit the maximum beam bunches or intensity of the EIC, hence diminishing the luminosity provided by the EIC. The EC has affected the beam instability and significantly contributed to cryogenic heat load in the Large Hadron Collider (LHC). Positron storage rings for which ECs have been a critical factor in the design and performance include KEKB in Japan and EC buildup remains one of the concerns for future high-intensity accelerators design. EC considerations have driven the SuperKEKB collider design and the positron damping ring for the proposed International Linear Collider (ILC). The LHC luminosity upgrade is contingent on reducing the bunch spacing to 25 ns; at this bunch spacing, severe EC buildup has been observed. The success of the upgrade is likely contingent on limiting EC buildup. To study the EC heat load, we did some EC simulations with PyECLOUD code for the dipole, quadrupole, sextupole magnets, and the warm (drift) section of the EIC hadron storage ring. PyECLOUD is an EC simulation code developed by CERN. The code has been validated and used to study EC in the LHC, SPS, and PS. To eliminate EC buildup, the sources of electrons must be minimized. First, we will reduce the production of electrons due to residual gas ionization by specifying the maximum gas density, which requires a vacuum chamber with low electron-stimulated desorption (ESD) yields and a sufficient (preferably distributed) pumping speed. Second, we should reduce the secondary electrons with a lower secondary electron yield (SEY) material.

43 PARTICLE ACCELERATORS↗

Magnetosphere-Ionosphere Energy Interchange in the Electron Diffuse Aurora

The diffuse aurora has recently been shown to be a major contributor of energy flux into the Earth's ionosphere. Therefore, a comprehensive theoretical analysis is required to understand its role in energy redistribution in the coupled ionosphere-magnetosphere system. In previous theoretical descriptions of precipitated magnetospheric electrons (E is approximately 1 keV), the major focus has been the ionization and excitation rates of the neutral atmosphere and the energy deposition rate to thermal ionospheric electrons. However, these precipitating electrons will also produce secondary electrons via impact ionization of the neutral atmosphere. This paper presents the solution of the Boltzman-Landau kinetic equation that uniformly describes the entire electron distribution function in the diffuse aurora, including the affiliated production of secondary electrons (E greater than 600 eV) and their ionosphere-magnetosphere coupling processes. In this article, we discuss for the first time how diffuse electron precipitation into the atmosphere and the associated secondary electron production participate in ionosphere-magnetosphere energy redistribution.

Diffuse aurora↗

Analysis of the Flow About Delta Wings with Leading Edge Separation at Supersonic Speeds

A research program was conducted to develop an improved theoretical flow model for the flow about sharp edge delta wings with leading-edge separation at supersonic speeds. The flow model incorporates a representation of the secondary separation region which occurs just inboard of the leading edge on such wings and is based on a slender-wing theory whereby the full three-dimensional problem is reduced to a quasi two-dimensional problem in the cross-flow plane. The secondary separation region was modeled by a surface distribution of singularities or a linearized type of cavity representation. The primary vortex and separation were modeled by a concentrated vortex and cut in the cross-flow potential which represents its feeding sheet. The cross-flow solutions for the cavity model were obtained, but these solutions have physical significance only in a very restricted range of angle of attack. The reasons for the failure of the flow model are discussed. The analysis is presented so that other interested researchers may critically review the work.

Nenni, J. P.↗

Theory of photoelectron thermalization and transport in the ionosphere

A new theoretical approach for calculating the equilibrium photoelectron flux energy and pitch angle distribution in the ionosphere is presented. Photoelectron transport, secondary electron production, and energy degradation by the excitation of the discrete energy states of the neutral atmospheric constituents and by continuous energy transfer to the ambient thermal electron gas are included in a manner consistent with the Boltzmann equation which constitutes the foundation of the theory. A difference equation, suitable for numerical solution, is given, and a numerical method for the solution of this equation is discussed in detail.

Mantas, G. P.↗

Fluctuations of inverted V electron fluxes

Fluctuations of low-energy electron fluxes during an inverted V event on Nov. 5, 1975 were detected by fixed-energy electrostatic analyzers used in the LEE (low-energy electron) experiment onboard the AE-D satellite. The flux fluctuations were observed at energies of 0.78, 1.38, and 2.62 keV, when these energies were below that of the monoenergetic beam. This suggests that the fluctuations might occur over a wide range of energies. The fluctuations were confined within a pitch angle of 15 degrees, the amplitude increasing with decreasing pitch angle. The oscillation frequencies centered around 1.75 Hz. Fluctuations at two energies were generally correlated. The heating of secondary electrons, deduced from an analysis of the distribution function, is attributed to anomalous heating by electron plasma wave turbulence, whose intensity was modulated by a low-frequency wave. The results are consistent with a model, according to which auroral precipitating electron beams enhance the anomalous resistivity at the topside ionosphere through parametric instabilities.

Lin, C. S.↗

An interstellar precursor mission

A mission out of the planetary system, launched about the year 2000, could provide valuable scientific data as well as test some of the technology for a later mission to another star. Primary scientific objectives for the precursor mission concern characteristics of the heliopause, the interstellar medium, stellar distances (by parallax measurements), low-energy cosmic rays, interplanetary gas distribution, and the mass of the solar system. Secondary objectives include investigation of Pluto. The mission should extend to 400-1000 AU from the sun. A heliocentric hyperbolic escape velocity of 50-100 km/sec or more is needed to attain this distance within a reasonable mission duration (20-50 years). The trajectory should be toward the incoming interstellar gas. For a year 2000 launch, a Pluto encounter and orbiter can be included. A second mission targeted parallel to the solar axis would also be worthwhile. The mission duration is 20 years, with an extended mission to a total of 50 years. A system using one or two stages of nuclear electric propulsion (NEP) was selected as a possible baseline. The most promising alternatives are ultralight solar sails or laser sailing, with the lasers in earth orbit, for example. The NEP baseline design allows the option of carrying a Pluto orbiter as a daughter spacecraft.

Jaffe, L. D.↗

Channels and valleys on Mars

Tentative conclusions about the origins of channels and valleys on Mars based on the consensus of investigators who have studied the problem are presented. The morphology of outflow channels is described in detail, and the morphology, distribution, and genesis of Martian valleys are addressed. Secondary modification of channels and valleys by mass-wasting phenomena, eolian processes, cratering, and mantling by lava flows is discussed. The physics of the flows needed to account for the immense volumes of Martian outflow channels is considered in detail, including the possible influence of debris flows and mudflows, glaciers, and ice sheets. It is concluded that Mars once probably possessed an atmosphere with higher temperatures and pressures than at present which played an essential role in an active hydrological cycle.

Baker, V. R.↗

Gamma rays from the Crab Pulsar 0531+21

Results are reported for observations of PSR 0531 + 21 performed with a gamma ray double Compton scatter telescope launched on a balloon. The operation of the telescope and the handling of the data are described. Phase diagrams for the pulsar and energy distributions for gamma rays from the primary and secondary pulses are shown and discussed. The results indicate that these observations are the first of gamma ray lines from neutrons captured on protons or iron in pulsars. Arguments supporting this interpretation are given.

Long, J. L.↗

Spacecraft 2000

The Spacecraft 2000 program has been conceived by NASA with the objective to maintain the U.S. in a strong technical position in the space arena. The program is to involve a cooperative NASA/industry effort with long-range technology development aims. The technology areas addressed are related to spacecraft power, spacecraft energy storage, power management and distribution, autonomous operation-control, onboard systems integration, secondary propulsion, communications technologies, and systems/subsystems technology verification. Aspects of Spacecraft 2000 interactions with industry are discussed, taking into account visitations of NASA personnel to selected industrial concerns, most critical concerns (general), major technical concern, technology drivers for future spacecraft power systems, technology considerations for secondary propulsion, and questions of commercialization. Plans related to a Spacecraft 2000 program formulation are also considered.

Faymon, K. A.↗

Comparison of distributed reacceleration and leaky-box models of cosmic-ray abundances (Z = 3-28)

A large collection of elemental and isotopic cosmic-ray data has been analyzed using the leaky-box transport model with and without reacceleration in the interstellar medium. Abundances of isotopes and elements with charges Z = 3-28 and energies E = 10 MeV/nucleon-1 TeV/nucleon were explored. Our results demonstrate that reacceleration models make detailed and accurate predictions with the same number of parameters or fewer as standard leaky-box models. Ad hoc fitting parameters in the standard model are replaced by astrophysically significant reacceleration parameters. Distributed reacceleration models explain the peak in secondary-to-primary ratios around 1 GeV/nucleon. They diminish the discrepancy between rigidity-dependent leakage and energy-independent anisotropy. They also offer the possibility of understanding isotopic anomalies at low energy.

Letaw, John R.↗

Ground-based measurements of galactic cosmic ray fragmentation in shielding

The mean free path for nuclear interactions of galactic cosmic-rays is comparable to shielding and tissue thicknesses present in human interplanetary exploration, resulting in a significant fraction of nuclear reaction products at depth. In order to characterize the radiation field, the energy spectrum, the angular distribution, and the multiplicity of each type of secondary particles must also be known as a function of depth. Reactions can take place anywhere in a thick absorber; therefore, it is necessary to know these quantities as a function of particle energy for all particles produced. HZE transport methods are used to predict the radiation field; they are dependent on models of the interaction of man-made systems with the space environment to an even greater extent than methods used for other types of radiation. Hence, there is a major need to validate these transport codes by comparison with experimental data. The most cost-effective method of validation is a comparison with ground-based experimental measurements. A research program to provide such validation measurements using neon, iron and other accelerated heavy ion beams will be discussed and illustrated using results from ongoing experiments and their comparison with current transport codes. The extent to which physical measurements yield radiobiological predictions will be discussed.

NASA Discipline Radiation Health↗

Optical analysis of Cassegrainian concentrator systems

Cone optics procedures have been developed to treat optical systems employing multiple reflectors. The objective of the procedures is to develop efficient techniques to treat multiple reflections of cones when the secondary reflecting surface is curved - in fact, curved differently in different directions. The particular optical system under consideration is the Cassegrainian Concentrator System - a system consisting of a paraboloidal primary reflector and a confocal hyperboloidal secondary reflector. Multiple reflection cone optics methodology as well as preliminary results for the flux distributions and intercept factors based on it are presented in this paper. It is shown that neglecting local curvature effects of the secondary reflector, i.e. even in the differential solid angle within the sun's cone, may overestimate the peak of the flux distribution at the receiver aperture by a factor of two or more.

Bass, A. H., Jr.↗

The Distribution of Interplanetary Dust between 0.96 and 1.04 au as Inferred from Impacts on the STEREO Spacecraft Observed by the Heliospheric Imagers

The distribution of dust in the ecliptic plane between 0.96 and 1.04 au has been inferred from impacts on the two Solar Terrestrial Relations Observatory (STEREO) spacecraft through observation of secondary particle trails and unexpected off-points in the heliospheric imager (HI) cameras. This study made use of analysis carried out by members of a distributed webbased citizen science project Solar Stormwatch. A comparison between observations of the brightest particle trails and a survey of fainter trails shows consistent distributions. While there is no obvious correlation between this distribution and the occurrence of individual meteor streams at Earth, there are some broad longitudinal features in these distributions that are also observed in sources of the sporadic meteor population. The different position of the HI instrument on the two STEREO spacecraft leads to each sampling different populations of dust particles. The asymmetry in the number of trails seen by each spacecraft and the fact that there are many more unexpected off-points in the HI-B than in HI-A indicates that the majority of impacts are coming from the apex direction. For impacts causing off-points in the HI-B camera, these dust particles are estimated to have masses in excess of 10 (exp−17) kg with radii exceeding 0.1 μm. For off-points observed in the HI-A images, which can only have been caused by particles travelling from the anti-apex direction, the distribution is consistent with that of secondary 'storm' trails observed by HI-B, providing evidence that these trails also result from impacts with primary particles from an anti-apex source. Investigating the mass distribution for the off-points of both HI-A and HI-B, it is apparent that the differential mass index of particles from the apex direction (causing off-points in HI-B) is consistently above 2. This indicates that the majority of the mass is within the smaller particles of this population. In contrast, the differential mass index of particles from the anti-apex direction (causing off-points in HI-A) is consistently below 2, indicating that the majority of the mass is to be found in larger particles of this distribution.

Davis, C. J.↗

A Machine Learning-Based Method to Estimate Transformer Primary-Side Voltages with Limited Customer-Side AMI Measurements

Distribution control applications such as volt/var optimization, network reconfiguration, and distribution automation require accurate knowledge of the distribution system state. The lack of sufficient sensors on the primary side of distribution networks often limits the accuracy of the control decisions by these applications. The deployment of advanced metering infrastructure (AMI) provides utilities an opportunity to translate the AMI data on the secondary onto the primary so that it can be used as pseudo-measurements to augment the limited existing measurements on the primary. This paper develops a machine learning based approach for estimating service transformer primary-side voltages by using limited secondary-side AMI measurement. The machine learning model is developed by using random forest algorithm. The estimated primary-side voltages can be used by utilities as pseudo-measurements for distribution control applications. The detailed secondary model topology, which is an essential input data for many existing algorithms, is not required for the proposed method. The performance of the proposed method is validated by using AMI measurements from the field and an actual distribution feeder model of San Diego Gas & Electric Company.

advanced metering infrastructure↗

Intercomparison and Evaluation of Global Aerosol Microphysical Properties Among Aerocom Models of a Range of Complexity

Many of the next generation of global climate models will include aerosol schemes which explicitly simulate the microphysical processes that determine the particle size distribution. These models enable aerosol optical properties and cloud condensation nuclei (CCN) concentrations to be determined by fundamental aerosol processes, which should lead to a more physically based simulation of aerosol direct and indirect radiative forcings. This study examines the global variation in particle size distribution simulated by 12 global aerosol microphysics models to quantify model diversity and to identify any common biases against observations. Evaluation against size distribution measurements from a new European network of aerosol supersites shows that the mean model agrees quite well with the observations at many sites on the annual mean, but there are some seasonal biases common to many sites. In particular, at many of these European sites, the accumulation mode number concentration is biased low during winter and Aitken mode concentrations tend to be overestimated in winter and underestimated in summer. At high northern latitudes, the models strongly underpredict Aitken and accumulation particle concentrations compared to the measurements, consistent with previous studies that have highlighted the poor performance of global aerosol models in the Arctic. In the marine boundary layer, the models capture the observed meridional variation in the size distribution, which is dominated by the Aitken mode at high latitudes, with an increasing concentration of accumulation particles with decreasing latitude. Considering vertical profiles, the models reproduce the observed peak in total particle concentrations in the upper troposphere due to new particle formation, although modelled peak concentrations tend to be biased high over Europe. Overall, the multimodel- mean data set simulates the global variation of the particle size distribution with a good degree of skill, suggesting that most of the individual global aerosol microphysics models are performing well, although the large model diversity indicates that some models are in poor agreement with the observations. Further work is required to better constrain size-resolved primary and secondary particle number sources, and an improved understanding of nucleation an growth (e.g. the role of nitrate and secondary organics) will improve the fidelity of simulated particle size distributions.

Cloud physics↗

Investigation of mixing in a turbofan exhaust duct. II Computer code application and verification

A three-dimensional analysis of turbofan forced mixer nozzle aerodynamics demonstrates that the complex flow structure is dominated by geometrically induced secondary flow rather than by turbulence. The test apparatus consisted of a fixed upstream model section and a rotating shroud. The Mach number of the fan and core streams at the mixing plane (lobe exit) was 0.45, the bypass ratio was about 4, and the Reynolds number based on the shroud radius was 1,100,000. The three velocity components near the exit plane of the lobes were measured using flow angularity probes to provide information about the mixer inflow conditions for turbulent computations. The validity of a previous computer code was demonstrated in a comparison of the nozzle exit temperature data with the computed temperature distributions. The mechanism most responsible for the generation of secondary flow within the lobes is due to the turning of the fan and core streams in opposite radial directions.

Povinelli, L. A.↗