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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1956

Drag Interference Between a Pointed Cylindrical Body and Triangular Wings of Various Aspect Ratios at Mach Numbers of 1.50 and 2.02

The drag of a body alone, six triangular wings of various aspect ratios, and the combinations were measured at Mach numbers of 1.50 and 2.02 at a Reynolds number of 5.5 million (based on the body length). The experimental drag-interference results were in accordance with calculations based on NACA RM A9E19, 1949, with skin-friction effects taken into account, the interference effect being principally the result of fixing transition on the body by adding a wing.

BODIES↗
NASA NTRS1956

Lift and Pitching-moment Interference Between a Pointed Cylindrical Body and Triangular Wings of Various Aspect Ratios at Mach Numbers of 1.50 and 2.02

The lift and pitching-moment characteristics of a body alone, six triangular wings of various aspect ratios, and the combinations were measured at Mach numbers of 1.50 and 2.02 at a Reynolds number of 5.5 million (based on the body length) for angles of attack up to 5.5 degrees. The total lift and pitching-moment interference were determined and compared with theory. The agreement was found to be good.

RESEARCH TECHNIQUE - CORRECTIONS↗
NASA NTRS2001

Fast prototyping of high-aspect ratio, high-resolution x-ray masks by gas-assisted focused ion beam

The capacity of chemically-assisted focused ion beam (fib) etching systems to undertake direct and highly anisotropic erosion of thin and thick gold (or other high atomic number [Z])coatings on x-ray mask membranes/substrates provides new levels of precision, flexibility, simplification and rapidity in the manufacture of mask absorber patterns, allowing the fast prototyping of high aspect ratio, high-resolution masks for deep x-ray lithography.

fast prototyping of high-aspect ratio high-resolut↗
DOE OSTI2024

Novel Fast Cure Silicone Inks for Single-Step, Support-Free 3D Printing of Tall, Overhanging, and High Aspect Ratio Structures

Silicone elastomers have a broad variety of applications, such as soft robotics, biomedical devices, and structural metamaterials. The extrusion-based method known as direct ink write (DIW) has enabled the production of additively manufactured silicone structures. However, this method is limited to manufacturing mostly planar or pseudo-3D structures. Due to the low self-supporting capabilities of extruded strands for traditional silicone-based “inks,” obtaining tall or overhanging structures, or structures comprised by thin walls is not feasible. Here, in this study, a novel Fast Cure silicone-based ink is demonstrated that enables manufacturing of complex 3D structures. The Fast Cure ink is a two-part mixture and silicone structures are produced by inline mixing and coextrusion of a part containing a catalyst (part A) and a part containing a crosslinker (part B). By the virtue of crosslinking, the extruded strands rapidly rigidize, increasing their self-supportive capacity. Hence, structures can be obtained with superior shape retention and previously unobtainable parts are realized that are tall, with aspect ratios higher than 3, and have overhanging features, achieving inclination angles smaller than 35° with respect to the printing plane. These minimal sag parts are achieved without requiring extra curing or mechanisms, support structures, or suspension baths.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Unlocking Larger Scales and Aspect Ratios in 3D Printed Glass: Coupling Active Mixing and UV Curing for Advanced Printability and Crack Resistance

Recent developments in additive manufacturing (AM) of glass via silica-filled inks have facilitated fabrication of previously unattainable geometries and compositions. However, the maximum processable size of 15 mm limits the use of these prints in applications such as optics. A key limitation lies in the trade-off between material printability and green strength: increasing silica content in the feedstock improves crack resistance and reduces shrinkage but results in dramatic changes in viscoelastic properties that hinder flowability. Here, this paper presents a novel approach that offers expanded versatility in processable size, feedstock formulation, and printing. Described here is a direct ink writing (DIW) system coupled with an active high-shear micromixer and UV light source, capable of simultaneously printing multiple inks with a wide range of rheological properties. Choice of silica sourc, solvent, UV-curable binder, and dispersant is used to tune the ink rheology and improve printability and mechanical properties. Imparting high shear with the micromixer while UV-curing the extrudate allows for increased ink viscosities and reduced nozzle diameters, enabling printing finer feature sizes. With these advances, thin-walled high-aspect ratio structures and a crack-free glass disk measuring 44 mm in diameter are demonstrated, an increase of 3× in the greatest dimension compared to current state-of-the-art.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Assessing multimetric aspects of sustainability: Application to a bioenergy crop production system in East Tennessee

This paper connects the science of sustainability theory with applied aspects of sustainability deployment. A suite of 35 sustainability indicators spanning six environmental, three economic, and three social categories has been proposed for comparing the sustainability of bioenergy production systems across different feedstock types and locations. A recent demonstration-scale switchgrass-to-ethanol production system located in East Tennessee is used to assess the availability of sustainability indicator data and associated measurements for the feedstock production and logistics portions of the biofuel supply chain. Knowledge pertaining to the available indicators is distributed within a hierarchical decision tree framework to generate an assessment of the overall sustainability of this no-till switchgrass production system relative to two alternative business-as-usual scenarios of unmanaged pasture and tilled corn production. The relative contributions of the social, economic and environmental information are determined for the overall trajectory of this bioenergy system s sustainability under each scenario. Within this East Tennessee context, switchgrass production shows potential for improving environmental and social sustainability trajectories without adverse economic impacts, thereby leading to potential for overall enhancement in sustainability within this local agricultural system. Given the early stages of cellulosic ethanol production, it is currently difficult to determine quantitative values for all 35 sustainability indicators across the entire biofuel supply chain. This case study demonstrates that integration of qualitative sustainability indicator ratings may increase holistic understanding of a bioenergy system in the absence of complete information.

09 BIOMASS FUELS↗
DOE OSTI2018

Economic Aspects of RBMK Service Life Characteristics Restoration

The economic aspects of the R&D complex to support RBMK operation under conditions of graphite distortion, development and adoption of the restoration technology for the service characteristics of the graphite stack are examined. The results of a technical-economic analysis of the restoration of the graphite stack of RBMK power-generating units, performed on the basis of a modeling scenario, are presented. Comparative economic indices of electricity production, proceeds, and investment resources are presented for the studied scenarios. It is shown that the restoration of the graphite stack in NPP with RBMK is economically efficient.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2021

Information-theoretic aspects of Werner states

Highlights: • The rich structures of Werner states are reviewed. • Werner states are characterized in terms of quantum uncertainty. • Information-theoretic aspects of Werner states are revealed. In a seminal study of quantum states with Einstein–Podolsky–Rosen correlations (entanglement) admitting a hidden-variable model (Werner, 1989), Werner introduced the dichotomy of entanglement/separability and devised a family of highly symmetric states, now termed the Werner states, some of which exhibit entanglement but no Bell nonlocality. It turns out that the Werner states have a rich structure of correlations and constitute a paradigm which has played an innovative role in both theoretical and experimental explorations of quantum information. Given the theoretical significance and wide applications of the Werner states, here we first give a concise review of information contents of the Werner states, and then present an information-theoretic characterization of them in terms of the Wigner–Yanase skew information: The Werner states are identified as the states with the minimum quantum uncertainty with respect to a natural family of observables (i.e., the generators of the diagonal unitary group). For this purpose, we introduce a measure of quantum uncertainty which is of independent interest in studying asymmetry, coherence, and uncertainty, and reveal its fundamental properties. We further identify the Bell triplet states as the opposite states of the Werner states in the sense that they have the maximal amount of quantum uncertainty. Analogously, we provide a similar characterization of the isotropic states as the minimum quantum uncertainty states with respect to a closely related family of operators.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Application of neutron imaging to investigate fundamental aspects of durability of cement-based materials: A review

Service life and durability of reinforced concrete structures have become crucial issues in all industrialized countries because of their economic and ecological relevance. Limited durability is frequently due to deterioration of steel and cement-based materials, such as mortar and concrete, by interactions with water and aggressive aqueous solutions. Neutron imaging has proved to be a powerful non-destructive technique to study quantitatively water content and water movement in porous materials. A neutron beam is much more attenuated by hydrogen in water than by most other elements present in cement-based materials. In this review, focus is placed on applications of both two-dimensional neutron radiography and three-dimensional neutron tomography to investigate specific aspects of durability and deterioration of cement-based materials. Examples of results obtained by qualitative and quantitative investigations of moisture movement in cracked and uncracked cement-based materials are presented. Self-healing, efficiency of water repellent treatment, internal curing, frost damage, fire spalling, ettringite formation and observations of various reinforced concrete components are addressed. The results obtained by neutron imaging provide a solid basis for better understanding of deterioration mechanisms of cement-based materials. Recent improvements of neutron imaging facilities have allowed unexpected possibilities to study complex processes in cement-based materials. The potential for further research based on this promising technology is outlined and discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Dispersion of cryogenic hydrogen through high-aspect ratio nozzles

Liquid hydrogen is increasingly being used as a delivery and storage medium for stations that provide compressed gaseous hydrogen for fuel cell electric vehicles. In efforts to provide scientific justification for separation distances for liquid hydrogen infrastructure in fire codes, the dispersion characteristics of cryogenic hydrogen jets (50–64 K) from high aspect ratio nozzles have been measured at 3 and 5 bar abs stagnation pressures. These nozzles are more characteristic of unintended leaks, which would be expected to be cracks, rather than conventional round nozzles. Spontaneous Raman scattering was used to measure the concentration and temperature field along the major and minor axes. Within the field of interrogation, the axis-switching phenomena was not observed, but rather a self-similar Gaussian-profile flow regime similar to room temperature or cryogenic hydrogen releases through round nozzles. The concentration decay rate and half-widths for the planar cryogenic jets were found to be nominally equivalent to that of round nozzle cryogenic hydrogen jets indicating a similar flammable envelope. The results from these experiments will be used to validate models for cryogenic hydrogen dispersion that will be used for simulations of alternative scenarios and quantitative risk assessment.

08 HYDROGEN↗
DOE OSTI2021

The effect of aspect ratio on the mechanical behavior of Li metal in solid-state cells

The Li metal anode is necessary for solid-state batteries to dramatically exceed the energy density of state-of-the-art conventional Li-ion batteries. To enable the Li metal anode, the mechanical properties of Li metal under compression in a commercially relevant cell configuration must be determined. This work examines the compression creep behavior of Li metal coupled with a relevant model solid-state electrolyte (Li 6.5 La 3 Ta 0.5 Zr 1.5 O 12 ) and current collector (Ni) as a function of applied stress (1–10 MPa) and Li foil thickness (100–700 μm). At 1 MPa applied stress, the strain rate of all Li foil thicknesses under compression was almost four orders of magnitude lower than what is predicted from tensile creep tests. Steady-state creep behavior was observed for Li foil ≥350 μm at 5 MPa and ≥250 μm at 10 MPa. Conversely, sustained creep deformation was not observed for 100 and 150 μm Li foils at any applied stress. It is suggested that friction at the Li/LLZO and Li/Ni interfaces leads to the formation of hydrostatic stress that controls Li deformation at low aspect ratios. Finally, these results have implications for battery pack stack pressure requirements, particularly relating to void formation during stripping and Li metal filament penetration during plating.

25 ENERGY STORAGE↗
DOE OSTI2018

Analysis of impact toughness scatter in simulated coarse-grained HAZ of E550 grade offshore engineering steel from the aspect of crystallographic structure

Highlights: • Crystallographic structure evolution in CGHAZ caused by variation of prior austenite grain size was analyzed quantitatively. • Variant selection rules changed from CP (close-packed plane) to Bain grouping with decreasing of prior austenite grain size. • A possible correlation between impact toughness scatter and crystallographic structure was established. - Abstract: This study aims at providing a new insights into the impact toughness scatter from the aspect of crystallographic structure. It demonstrated that the large impact toughness scatter associated much to the microstructure diversity. The crystallographic structure with evident scatter will display obvious discrepancy. In this work, three groups of samples simulated coarse-grained heat affected zone (CGHAZ) of an offshore engineering steel were obtained at different cooling rates. The Charpy test results showed that the toughness decreases dramatically with the decrease of cooling rate. However, the largest scatter in impact toughness occurred in the sample with medium cooling rate (15 °C/s), which was attributed to the heterogeneity in crystallographic structures. The visualization of crystallographic features showed that the prior austenite grain size has a significant effect on bainitic variant selection, which governed the effective grain size and crack propagation mechanism. CP (close-packed plane) grouping of variants is more likely to take place in large austenite grain, indicating that the size of CP region is larger than Bain zone, and the crack is short and flexural. On the contrary, in smaller austenite grain, Bain grouping of variants that always forms low angle grain boundary and favors crack propagation dominates the transformation, and it will promote the crack to propagate through the entire Bain zone and then yield large long crack. However, these two cases can co-exist in the same sample at medium cooling rate, indicating that the cleavage fracture is controlled by the effective grain size (Bain-zone size) and the scatter in impact toughness is associated much to the proportion and relative location between fine and coarse Bain zones.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Perspectives on the basic and applied aspects of crassulacean acid metabolism (CAM) research

Here, due to public concerns about the decreasing supply of blue water and increasing heat and drought stress on plant growth caused by urbanization, increasing human population and climate change, interest in crassulacean acid metabolism (CAM), a specialized type of photosynthesis enhancing water-use efficiency (WUE) and drought tolerance, has increased markedly. Significant progress has been achieved in both basic and applied research in CAM plants since the beginning of this century. Here we provide a brief overview of the current status of CAM research, and discuss future needs and opportunities in a wide range of areas including systems biology, synthetic biology, and utilization of CAM crops for human benefit, with a focus on the following aspects: application of genome-editing technology and high-throughput phenotyping to functional genomics research in model CAM species and genetic improvement of CAM crops, challenges for multi-scale metabolic modeling of CAM systems, opportunities and new strategies for CAM pathway engineering to enhance WUE and drought tolerance in C 3 (and C 4 ) photosynthesis crops, potential of CAM species as resources for food, feed, natural products, pharmaceuticals and biofuels, and development of CAM crops for ecological and aesthetic benefits.

59 BASIC BIOLOGICAL SCIENCES↗
DOE OSTI2021

Satellite solar-induced chlorophyll fluorescence and near-infrared reflectance capture complementary aspects of dryland vegetation productivity dynamics

Mounting evidence indicates dryland ecosystems play an important role in driving the interannual variability and trend of the terrestrial carbon sink. Nevertheless, our understanding of the seasonal dynamics of dryland ecosystem carbon uptake through photosynthesis [gross primary productivity (GPP)] remains relatively limited due in part to the limited availability of long-term data and unique challenges associated with satellite remote sensing across dryland ecosystems. Here, we comprehensively evaluated longstanding and emerging satellite vegetation proxies in their ability to capture seasonal dryland GPP dynamics. Specifically, we evaluated: 1) reflectance-based proxies normalized difference vegetation index (NDVI), soil adjusted vegetation index (SAVI), near infrared reflectance index (NIR v ), and kernel NDVI (kNDVI) from the MODerate resolution Imaging Spectroradiometer (MODIS); and 2) newly available physiologically-based proxy solar-induced chlorophyll fluorescence (SIF) from the TROPOspheric Monitoring Instrument (TROPOMI). As a performance benchmark, we used GPP estimates from a robust network of 21 western United States eddy covariance tower sites that span representative gradients in dryland ecosystem climate and functional composition. We found that NIR v and SIF were the best performing GPP proxies and captured complementary aspects of seasonal GPP dynamics across dryland ecosystem types. NIR v offered better performance than the other proxies across relatively low-productivity, sparsely non-evergreen vegetated sites (R 2 = 0.59 ± 0.13); whereas SIF best captured seasonal dynamics across relatively high-productivity sites, including evergreen-dominated sites (R 2 = 0.74 ± 0.07). Notably, across grass-dominated sites, all reflectance-based proxies (NDVI, SAVI, NIRv and kNDVI) showed significant seasonal bias (hysteresis) that strengthened with the total fraction of woody vegetation cover, likely due to seasonal patterns in woody vegetation reflectance that are unrelated to or decoupled from GPP. In conclusion, future efforts to fully integrate the complementary strengths of NIR v and SIF could significantly improve our understanding and representation of dryland GPP dynamics in satellite-based models.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Strong gradient effects on neoclassical electron transport and the bootstrap current in large aspect ratio tokamaks

Standard approaches to neoclassical theory do not extend into regions of strong gradients in tokamaks such as the pedestal and internal transport barriers. Here, we calculate the modifications to neoclassical electron physics inside strong gradient regions of large aspect ratio tokamaks in the banana regime. We show that these modifications are due to the different ion flow and the strong poloidal variation of the potential. We also provide a physical interpretation of the mechanisms that drive poloidal asymmetries and hence a poloidal electric field. We apply our model to two specific example cases of pedestal profiles, calculating the neoclassical electron flux and the bootstrap current. We find that, depending on the ion flow, weak gradient neoclassical theory overestimates or underestimates the neoclassical electron transport and the bootstrap current in regions with strong gradients. We show that the determination of the mean parallel flow is more complex than in weak gradient neoclassical theory. For vanishing turbulence, we can determine the radial electric field for a given flow profile in the pedestal.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

Hierarchical Self-Assembly of Carbon Dots into High-Aspect-Ratio Nanowires

Here, we report a spontaneous and hierarchical self-assembly mechanism of carbon dots prepared from citric acid and urea into nanowire structures with large aspect ratios (>50). Scattering-type scanning near-field optical microscopy (s-SNOM) with broadly tunable mid-IR excitation was used to interrogate details of the self-assembly process by generating nanoscopic chemical maps of local wire morphology and composition. s-SNOM images capture the evolution of wire formation and the complex interplay between different chemical constituents directing assembly over the nano- to microscopic length scales. We propose that residual citrate promotes tautomerization of melamine surface functionalities to produce supramolecular shape synthons comprised of melamine-cyanurate adducts capable of forming long-range and highly directional hydrogen-bonding networks. This intrinsic, heterogeneity-driven self-assembly mechanism reflects synergistic combinations of high chemical specificity and long-range cooperativity that may be harnessed to reproducibly fabricate functional structures on arbitrary surfaces.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2021

Ultrathin, High-Aspect Ratio, and Free-Standing Magnetic Nanowires by Exfoliation of Ferromagnetic Quasi-One-Dimensional van der Waals Lattices

Driven by numerous discoveries of novel physical properties and integration into functional devices, interest in one-dimensional (1D) magnetic nanostructures has grown tremendously. Traditionally, such structures are accessed with bottom-up techniques, but these require increasing sophistication to allow precise control over crystallinity, branching, aspect ratio, and surface termination, especially when approaching the subnanometer regime in magnetic phases. In this work, we show that mechanical exfoliation of bulk quasi-one-dimensional crystals, a method similar to those popularized for two-dimensional van der Waals (vdW) lattices, serves as an efficient top-down method to produce ultrathin freestanding nanowires that are both magnetic and semiconducting. We use CrSbSe 3 as a representative quasi-1D vdW crystal with strong magnetocrystalline anisotropy and show that it can be exfoliated into nanowires with an average cross-section of 10 ± 2.8 nm. The CrSbSe 3 nanowires display reduced Curie–Weiss temperature but higher coercivity and remanence than the bulk phase. The methodology developed here for CrSbSe 3 , a representative for a vast class of 1D vdW lattices, serves as a blueprint for investigating confinement effects for 1D materials and accessing functional nanowires that are difficult to produce via traditional bottom-up methods.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Statistics of the NiCoCr medium-entropy alloy: Novel aspects of an old puzzle

Abstract We study the K -state phenomenon in the NiCoCr medium-entropy alloy using first-principles techniques jointly with the efficient Wang–Landau Monte Carlo and simulated annealing algorithms. Our theoretical results successfully explain the existence of the peak around 940 K in the experimental specific heat curve that characterizes the K -state phenomenon and give a fine picture of its atomic origin. The peak is caused by the maximum change of the local configurations characterized by the short-range-order (SRO) parameters at that temperature. The maximum change in SRO parameters is dominated by the nearest-neighbor interactions of atoms but substantially tuned by the many-body interactions. One surprising aspect revealed by the reciprocal-space SRO parameters is that the Ni–Co pair distribution is not random even above the ordering transition temperature, dramatically different from Ni–Cr and Co–Cr, indicating the system cannot be treated as a pseudo binary alloy. This prototypical example shows the complicated nature of multicomponent alloys, different from binary alloys. Our methods can be directly used to study the important K -state phenomenon observed in a number of other composition-concentrated alloys regardless of their number of components.

Pei, Zongrui (ORCID:0000000307484629)↗