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At least 325 records · Page 18

Broadband differential absorption sensor for detecting gaseous species

A remote sensor system comprising a laser transmitter that emits a pulse of broadband laser illumination comprising a plurality of wavelengths and a receiver configured to detect laser illumination backscatter. The sensor system further includes a computing system configured to determine a plurality of species number densities along a travel path of the laser illumination. Determining the plurality of species number densities includes determining a first number density of a first species based on a first set of optical transmission values from the backscatter data for a first subset of wavelengths of the plurality of wavelengths and a first attenuation cross-section of the first species. Additional species are determined based on additional sets of optical transmission values from the backscatter data for additional subsets of wavelengths of the plurality of wavelengths and additional cross-sections of additional species.

Smith, Mark W.↗

Three-colour digital holographic microscopy based on a Mach – Zender interferometer and a solid-state RGB laser

We have developed a facility for recording colour digital holograms involving a Mach – Zender interferometer and a pulsed solid-state RGB laser, which radiates simultaneously at three wavelengths: 451, 532, and 634 nm. These wavelengths are obtained in the conversion of the radiation of a pulsed Nd{sup 3+} : YAG laser (1064 nm), which operates in the regime of intracavity parametric oscillation at a wavelength of 1570 nm, with the subsequent conversion of its frequencies to the red, green, and blue spectral regions in nonlinear KTP-crystal elements. The combination of this three-wavelength pulsed light source with the Mach – Zender interferometer provides the simultaneous recording of three spectral digital holograms with one matrix RGB radiation detector. Pulsed three-colour digital holography shows promise for the analysis of fast processes and rapidly varying colour phase objects. (paper)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Multi-orbital-phase and Multiband Characterization of Exoplanetary Atmospheres with Reflected Light Spectra

Direct imaging of widely separated exoplanets from space will obtain their reflected light spectra and measure atmospheric properties. Previous calculations have shown that a change in the orbital phase would cause a spectral signal, but whether this signal may be used to characterize the atmosphere has not been shown. We simulate starshade-enabled observations of the planet 47 UMa b, using the present most realistic simulator Starshade Imaging Simulation Toolkit for Exoplanet Reconnaissance to estimate the uncertainties due to residual starlight, solar glint, and exozodiacal light. We then use the Bayesian retrieval algorithm ExoReL{sup R} to determine the constraints on the atmospheric properties from observations using a Roman- or Habitable Exoplanet Observatory (HabEx)-like telescope, comparing the strategies to observe at multiple orbital phases or in multiple wavelength bands. With a ∼20% bandwidth in 600–800 nm on a Roman-like telescope, the retrieval finds a degenerate scenario with a lower gas abundance and a deeper or absent cloud than the truth. Repeating the observation at a different orbital phase or at a second 20% wavelength band in 800–1000 nm, with the same integration time and thus degraded signal-to-noise ratio (S/N), would effectively eliminate this degenerate solution. Single observation with a HabEx-like telescope would yield high-precision constraints on the gas abundances and cloud properties, without the degenerate scenario. These results are also generally applicable to high-contrast spectroscopy with a coronagraph with a similar wavelength coverage and S/N, and can help design the wavelength bandwidth and the observation plan of exoplanet direct-imaging experiments in the future.

79 ASTRONOMY AND ASTROPHYSICS↗

Photoluminescence Excitation Spectroscopy of Monolithic Perovskite/Silicon Tandem Solar Cells

The contributions of each subcell to the total photoluminescence (PL) spectrum of a monolithic perovskite/silicon tandem solar cell are distinguished using a variable wavelength excitation laser source. Here, in the results, a strong overlap of the PL spectrum is shown, originating from the sub‐bandgap region of the perovskite top cell with the emission from the silicon bottom cell, even with near‐infrared excitation wavelengths. Consequently, an excitation laser wavelength of at least 815 nm is required for a dominant PL signal from the silicon bottom cell, and a wavelength no longer than 750 nm is needed for a dominant PL signal from the perovskite top cell in the investigated tandem solar cell. Moreover, a shoulder in the sub‐bandgap emission of the perovskite top cell almost coincides with the PL response region of the silicon bottom cell, which can cause signal confusion in subcell characterization.

14 SOLAR ENERGY↗

Evolution of {delta}ferrite in a CF3 cast stainless steel upon neutron irradiation to 3, 5, 10, 20, and 40 dpa

The microstructural evolution of delta ferrite in a CF3 cast stainless steel irradiated to 3, 5, 10, 20, and 40 dpa with two dose rates was studied with atom probe tomography (APT) and transmission electron mi-croscopy. Spinodal decomposition and G-phase precipitates induced by neutron irradiation and thermal aging were quantified systematically. The neutron irradiation significantly enhances the spinodal decom-position in delta ferrite as both the spinodal wavelength (i.e. a characteristic repeat distance) and am-plitude (i.e. magnitude of elemental concentration fluctuation) increase after irradiation. The wavelength only varies slightly when the dose increases from 5 to 40 dpa, while the amplitude increases dramatically from 10 to 20 dpa and starts to saturate before 20 dpa. The dose rate and irradiation temperature also have a notable effect on the spinodal wavelength and amplitude. The study shows that higher dose rate promotes a larger wavelength at given irradiation doses. Regarding the G-phase precipitates, a slightly lower irradiation temperature would result in a smaller mean size of G-phase precipitates, while a lower irradiation dose rate would lead to a larger G-phase precipitates at a given temperature and dose. Over-all, the spinodal decomposition and G-phase precipitates in the delta ferrite continue to evolve with the increasing dose beyond 10 dpa. This study confirms that the formation of G-phase precipitates at the in-terdomain region between alpha and alpha-prime is facilitated by the Si and Mo atoms rejected from Fe rich alpha phase and the Ni and Mn atoms rejected from Cr rich alpha-prime phase. Neutron irradiation plays a dominant role in the ferrite instability, and the effect of prior thermal aging at 400 degrees C for 10,000 hours is negligible as the dose is 3 dpa and above.

duplex stainless steel↗

Excited-State Dynamics and Nonlinear Optical Properties of Hyperpolarizable Chromophores Based on Conjugated Bis(terpyridyl)Ru(II) and Palladium and Platinum Porphyrinic Components: Impact of Heavy Metals upon Supermolecular Electro-Optic Properties

A new series of strongly coupled oscillators based upon (porphinato)Pd, (porphinato)Pt, and bis(terpyridyl)-ruthenium(II) building blocks is described. These RuPPd, RuPPt, RuPPdRu, and RuPPtRu chromophores feature bis- (terpyridyl)Ru(II) moieties connected to the (porphinato)metal unit via an ethyne linker that bridges the 4!-terpyridyl and porphyrin macrocycle meso-carbon positions. Pump–probe transient optical data demonstrate sub-picosecond excited singlet-to-triplet-state relaxation. The relaxed lowest-energy triplet (T 1 ) excited states of these chromophores feature absorption manifolds that span the 800–1200 nm spectral region, microsecond triplet-state lifetimes, and large absorptive extinction coefficients [ε(T 1 → T n ) > 4 × 10 4 M –1 cm –1 ]. Dynamic hyperpolarizability (β λ ) values were determined from hyper-Rayleigh light scattering (HRS) measurements carried out at several incident irradiation wavelengths over the 800–1500 nm spectral region. Relative to benchmark RuPZn and RuPZnRu chromophores which showed large βHRS values over the 1200–1600 nm range, RuPPd, RuPPt, RuPPdRu, and RuPPtRu displayed large βHRS values over the 850–1200 nm region. Generalized Thomas–Kuhn sum (TKS) rules and experimental hyperpolarizability values were utilized to determine excited state-to-excited state transition dipole terms from experimental electronic absorption data and thus assessed frequency-dependent β λ values, including two- and three-level contributions for both β zzz and β xzx tensor components to the RuPPd, RuPPt, RuPPdRu, and RuPPtRu hyperpolarizability spectra. Furthermore, these analyses qualitatively rationalize how the βzzz and βxzx tensor elements influence the observed irradiation wavelength-dependent hyperpolarizability magnitudes. The TKS analysis suggests that supermolecules related to RuPPd, RuPPt, RuPPdRu, and RuPPtRu will likely feature intricate dependences of experimentally determined βHRS values as a function of irradiation wavelength that derive from substantial singlet–triplet mixing, and complex interactions among multiple different β tensor components that modulate the long wavelength regime of the nonlinear optical response.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Massively scalable Kerr comb-driven silicon photonic link

Abstract The growth of computing needs for artificial intelligence and machine learning is critically challenging data communications in today’s data-centre systems. Data movement, dominated by energy costs and limited ‘chip-escape’ bandwidth densities, is perhaps the singular factor determining the scalability of future systems. Using light to send information between compute nodes in such systems can dramatically increase the available bandwidth while simultaneously decreasing energy consumption. Through wavelength-division multiplexing with chip-based microresonator Kerr frequency combs, independent information channels can be encoded onto many distinct colours of light in the same optical fibre for massively parallel data transmission with low energy. Although previous high-bandwidth demonstrations have relied on benchtop equipment for filtering and modulating Kerr comb wavelength channels, data-centre interconnects require a compact on-chip form factor for these operations. Here we demonstrate a massively scalable chip-based silicon photonic data link using a Kerr comb source enabled by a new link architecture and experimentally show aggregate single-fibre data transmission of 512 Gb s −1 across 32 independent wavelength channels. The demonstrated architecture is fundamentally scalable to hundreds of wavelength channels, enabling massively parallel terabit-scale optical interconnects for future green hyperscale data centres.

Rizzo, Anthony (ORCID:000000034752797X)↗

Multicolor multifocal 3D microscopy using in-situ optimization of a spatial light modulator

Abstract Multifocal microscopy enables high-speed three-dimensional (3D) volume imaging by using a multifocal grating in the emission path. This grating is typically designed to afford a uniform illumination of multifocal subimages for a single emission wavelength. Using the same grating for multicolor imaging results in non-uniform subimage intensities in emission wavelengths for which the grating is not designed. This has restricted multifocal microscopy applications for samples having multicolored fluorophores. In this paper, we present a multicolor multifocal microscope implementation which uses a Spatial Light Modulator (SLM) as a single multifocal grating to realize near-uniform multifocal subimage intensities across multiple wavelength emission bands. Using real-time control of an in-situ-optimized SLM implemented as a multifocal grating, we demonstrate multicolor multifocal 3D imaging over three emission bands by imaging multicolored particles as well as Escherichia coli ( E. coli ) interacting with human liver cancer cells, at $$\sim 2.5$$ ∼ 2.5 multicolor 3D volumes per second acquisition speed. Our multicolor multifocal method is adaptable across SLM hardware, emission wavelength band locations and number of emission bands, making it particularly suited for researchers investigating fast processes occurring across a volume where multiple species are involved.

47 OTHER INSTRUMENTATION↗

The eROSITA Final Equatorial-Depth Survey (eFEDS): Identification and characterization of the counterparts to point-like sources

In November 2019, eROSITA on board of the Spektrum-Roentgen-Gamma (SRG) observatory started to map the entire sky in X-rays. After the four-year survey program, it will reach a flux limit that is about 25 times deeper than ROSAT. During the SRG performance verification phase, eROSITA observed a contiguous 140 deg 2 area of the sky down to the final depth of the eROSITA all-sky survey (eROSITA Final Equatorial-Depth Survey; eFEDS), with the goal of obtaining a census of the X-ray emitting populations (stars, compact objects, galaxies, clusters of galaxies, and active galactic nuclei) that will be discovered over the entire sky. This paper presents the identification of the counterparts to the point sources detected in eFEDS in the main and hard samples and their multi-wavelength properties, including redshift. To identify the counterparts, we combined the results from two independent methods (NWAY and ASTROMATCH), trained on the multi-wavelength properties of a sample of 23k XMM-Newton sources detected in the DESI Legacy Imaging Survey DR8. Then spectroscopic redshifts and photometry from ancillary surveys were collated to compute photometric redshifts. Of the eFEDS sources, 24 774 of 27 369 have reliable counterparts (90.5%) in the main sample and 231 of 246 sources (93.9%) have counterparts in the hard sample, including 2514 (3) sources for which a second counterpart is equally likely. By means of reliable spectra, Gaia parallaxes, and/or multi-wavelength properties, we have classified the reliable counterparts in both samples into Galactic (2695) and extragalactic sources (22 079). For about 340 of the extragalactic sources, we cannot rule out the possibility that they are unresolved clusters or belong to clusters. Inspection of the distributions of the X-ray sources in various optical/IR colour-magnitude spaces reveal a rich variety of diverse classes of objects. The photometric redshifts are most reliable within the KiDS/VIKING area, where deep near-infrared data are also available. This paper accompanies the eROSITA early data release of all the observations performed during the performance and verification phase. Together with the catalogues of primary and secondary counterparts to the main and hard samples of the eFEDS survey, this paper releases their multi-wavelength properties and redshifts.

79 ASTRONOMY AND ASTROPHYSICS↗

Laue-DIALS: Open-source software for polychromatic x-ray diffraction data

Most x-ray sources are inherently polychromatic. Polychromatic (“pink”) x-rays provide an efficient way to conduct diffraction experiments as many more photons can be used and large regions of reciprocal space can be probed without sample rotation during exposure—ideal conditions for time-resolved applications. Analysis of such data is complicated, however, causing most x-ray facilities to discard >99% of x-ray photons to obtain monochromatic data. Key challenges in analyzing polychromatic diffraction data include lattice searching, indexing and wavelength assignment, correction of measured intensities for wavelength-dependent effects, and deconvolution of harmonics. We recently described an algorithm, Careless, that can perform harmonic deconvolution and correct measured intensities for variation in wavelength when presented with integrated diffraction intensities and assigned wavelengths. Here, we present Laue-DIALS, an open-source software pipeline that indexes and integrates polychromatic diffraction data. Laue-DIALS is based on the dxtbx toolbox, which supports the DIALS software commonly used to process monochromatic data. As such, Laue-DIALS provides many of the same advantages: an open-source, modular, and extensible architecture, providing a robust basis for future development. We present benchmark results showing that Laue-DIALS, together with Careless, provides a suitable approach to the analysis of polychromatic diffraction data, including for time-resolved applications.

97 MATHEMATICS AND COMPUTING↗

Experiments on the single-mode Richtmyer–Meshkov instability with reshock at high energy densities

Here, the hydrodynamic instability growth of a reshocked single-mode interface between high energy density fluids is studied. A laser-driven shock wave is used to drive an initially solid, sinusoidal interface between a dense plastic (1.43 g/cc) and a light foam (≈ 0.110 g/cc). After the interface has grown to a nonlinear state where the amplitude is of order of the wavelength, it is reshocked. The reshock compresses the nonlinear perturbation, which then grows at about twice the rate. While the pre-reshock growth rate is sensitive to the initial amplitude and wavelength of the perturbation, the post-reshock growth rate is comparatively insensitive to the initial condition. Qualitatively, we observe that the perturbations are less coherent after reshock, consistent with the idea that having a reshock accelerates the transition to turbulence. We find that some memory of the initial condition remains, even after reshock at late time: it appears if the initial perturbations have large enough wavelengths, and the flow structure of size comparable to the initial wavelength persists through reshock. Our results agree with design simulations and are consistent with the phenomenology of reshock studies in conventional gaseous shock tubes.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Portable diagnostic package for Thomson scattering and optical emission spectroscopy on Princeton field-reversed configuration 2 (PFRC 2)

An Advanced Research Projects Agency-Energy funded diagnostic system has been deployed to the Princeton field-reversed configuration 2 (PFRC-2) device, located at Princeton Plasma Physics Laboratory. The Portable Diagnostic Package (PDP), designed at Oak Ridge National Laboratory, allows for the measurement of Thomson Scattering (TS) for electron density and temperature and Optical Emission Spectroscopy (OES) for ion temperature, impurity density, and ion velocity. A tunable spectrometer on the PDP with three gratings provides the flexibility to measure low (1 eV) and high (1000 eV) electron temperature ranges from TS. Additionally, using a second spectrometer, the OES diagnostic can survey light emission from various ion excitation levels for wide wavelength ranges. The electron density (<2 × 10 19 m –3 ) of plasmas generated in PFRC-2 has been below the PDP TS discrimination threshold, which has made TS signal detection challenging against a high-background of laser stray light. The laser stray light was iteratively reduced by making modifications to the entrance and exit geometry on PFRC-2. Rayleigh scattering experiments on PFRC have yielded the TS discrimination sensitivity to be >1 × 10 20 m –3 for the PDP. A recently implemented narrow-band notch spectral filter that masks the second harmonic 532 nm Nd:YAG laser wavelength has increased the system’s TS light discrimination sensitivity 65 times compared to the instance when the notch filter was not implemented. The hardware implementation including design changes to the flight tubes and Brewster windows will be discussed, along with results from Rayleigh and rotational Raman scattering sensitivity analyses, which were used to establish a quantitative figure of merit on the system performance. Further, the Raman scattering calibration with the notch filter has improved the PDP electron density threshold to 1 ± 0.5 × 10 18 m –3 .

47 OTHER INSTRUMENTATION↗

Optical constants of polycrystalline Al 0.25 Ga 0.75 P and Al 0.9 Ga 0.1 As determined by variable-angle spectroscopic ellipsometry

The optical constants of single-crystal Al x Ga 1-x P and Al x Ga 1-x As have been widely studied at various Al compositions but have not yet been thoroughly investigated as polycrystalline materials. Using variable-angle spectroscopic ellipsometry, we estimate and analyze the optical constants of polycrystalline Al 0.25 Ga 0.75 P and Al 0.9 Ga 0.1 As that were non-epitaxially deposited at deposition temperatures of either 250 or 420 °C, and with various dopant species, dopant concentrations, and V/III flux ratios. Here, for wavelengths of 350–400 nm, decreasing the V/III ratio increases the refractive index of Be-doped polycrystalline Al 0.25 Ga 0.75 P. For wavelengths >500 nm, as the targeted Be dopant concentration increases for polycrystalline Al 0.25 Ga 0.75 P, the amount the extinction coefficient increases and the indirect bandgap decreases depends on the V/III ratio. Furthermore, Si-doped polycrystalline Al 0.25 Ga 0.75 P has significantly smaller extinction coefficient values than when it is Be-doped, for the same V/III ratio and targeted doping concentration, at wavelengths >500 nm. Based on our findings, we hypothesize that the dopant species, dopant concentration, and the V/III ratio dictate various types of defect concentrations, which then affect the optical constants and indirect bandgap of polycrystalline Al 0.25 Ga 0.75 P. Additionally, for wavelengths >500 nm, we find that polycrystalline Al 0.25 Ga 0.75 P and Al 0.9 Ga 0.1 As have the lowest extinction coefficient values when deposited at 420 °C, as opposed to 250 °C. Thus, we hypothesize that the deposition temperature is the most significant factor in dictating the optical constants of these polycrystalline III-Vs. Ultimately, this work demonstrates alternative methods to tune the optical constants of polycrystalline Al 0.25 Ga 0.75 P and Al 0.9 Ga 0.1 As, as opposed to tuning the Al composition.

42 ENGINEERING↗

Design of AlGaN-Zn(Si,Ge)N2 quantum wells for high-efficiency ultraviolet light emitters

The effect of inserting a nm-scale layer of Zn(Si,Ge)N2 into an AlGaN quantum well structure designed for light emission in the wavelength range from 255 to 305 nm is investigated here. The enhanced confinement of the hole within the quantum well results in an enhancement of the overlap of the hole and electron wave functions, resulting in an enhancement of the radiative recombination rate. In this theoretical calculation, for emission at a 270 nm wavelength, the enhancement in the wavefunction overlap can reach a factor of 7 when compared to an AlGaN quantum well device specifically engineered for optimal emission at the identical wavelength. Increases of almost an order of magnitude in both the peak spontaneous emission intensity and the radiative recombination rate are predicted. The peak emission wavelength can be tuned from 255 to 305 nm by adjusting the width and/or the composition of the inserted layer. The proposed structures provide a route to higher efficiency ultraviolet practical light emitting diodes and lasers.

Physics↗

Multiparameter optical fiber sensing for energy infrastructure through nanoscale light–matter interactions: From hardware to software, science to commercial opportunities

Monitoring of energy infrastructure through robust yet economical sensing platforms is becoming an area of increased importance, with ubiquitous applications including the electrical grid, natural gas and oil transportation pipelines, H2 infrastructure (storage and transportation), carbon storage, power generation, and subsurface environments. Plasmonic and functional nanomaterial enabled fiber optic sensors show excellent promise for a wide range of sensing applications due to their versatility to be engineered for specific analytes of interest while retaining inherent advantages of the optical fiber sensor platform. Through the design of novel sensing layers, the optical transduction mechanism and wavelength dependence can also be tailored for ease of integration with low-cost interrogation systems enabling an inexpensive yet highly functional optical fiber sensing platform. In addition, recent advances in artificial intelligence and machine learning theoretical methods have been leveraged to simultaneously extract multiple parameters through multi-wavelength interrogation such that unique wavelengths can also serve as unique sensing elements, analogous to electronic nose sensor technologies. The concept of an optical fiber based “photonic nose” via multiple interrogation wavelengths and/or sensor nodes offers a compelling platform technology to realize multiparameter speciation of chemical analytes within complex gas mixtures. In this Perspective, we further generalize the notion of multiparameter sensing through the novel “photonic nervous system” concept based upon low-cost, functionalized optical fiber sensor probes monitoring a variety of distinct analyte classes (physical, chemical, electromagnetic, etc.) simultaneously to provide broad situational awareness via integrated sensors.

Su, Yang-Duan (ORCID:0000000214820902)↗

Full-wave model for the lower hybrid wave electric field vector with synthetic turbulence on Alcator C-Mod

The effects of synthetic turbulence on lower hybrid (LH) wave field magnitude and polarization are studied on Alcator C-Mod. Three synthetic turbulence models are evaluated to assess the impact of filaments, holes, and periodic fluctuations on the LH wave electric fields. For all three cases, the synthetic turbulence can greatly impact the LH wave magnitude and polarization. Back scattering, interference and edge/SOL absorption of the LH wave is observed. This impact is shown to depend on the wavelength and amplitude of the fluctuations. The strongest effect appears for fluctuations at high amplitudes and wavelengths comparable to the LH wavelength. This synthetic turbulence model can be used as inputs into a synthetic diagnostic to calculate the lower hybrid wave field magnitude and direction measured by dynamic Stark effect spectroscopy. It will be shown that fluctuations at these high amplitudes and wavelengths may explain the experimentally measured results. Here, the effect of fluctuations on modifying LH polarization are also shown to be anti-correlated with SOL power losses, similar to recently observed experimental trends on Alcator C-Mod. These SOL losses may have detrimental impact on LHCD efficiency.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Suppression of MHD modes with active phase-control of probe-injected currents

Abstract Active phase-control of probe-injected current is shown to both suppress and amplify long-wavelength rotating magnetohydrodynamic instabilities in the HBT-EP tokamak. Four probes are connected in quadrature and energized to drive non-axisymmetric currents through the edge of the tokamak, creating magnetic perturbations comparable to previously-studied saturated kink modes or resonant magnetic perturbations that are generated by an external control coil array. Measurements of the magnetic perturbations from the probe-injected currents determine a set of current-carrying helical filaments used to model active feedback control of resistive wall modes. These experiments suggest current-injection feedback may be an effective alternative to external control coils for control of RWMs and other long-wavelength kink-like modes at the edge of tokamaks.

Physics↗

A study of radiation tolerance in optical cements

We study the effect ionizing radiation has on light transmission in the wavelength range 190–1100 nm for a number of optically clear epoxies. We find that the transmittance of traditional, commercially available, optical epoxies show significant degradation for exposures of 1×10 12 MIPs/cm 2 . Degradation of light transmission progresses from the shortest wavelengths at low doses to longer wavelengths as the dose increases. In epoxy joints that are 0.1 mm thick, we observe that more than 5% of the light is lost for wavelengths less than 400 nm for traditional optical epoxies. Our studies have identified an optically clear epoxy that shows little degradation for radiation exposures up to 5.9× 10 14 MIPs/cm 2 (≈ 220 kGy).

Radiation-hard detectors↗