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At least 325 records · Page 18

Identification of Highly Fractionated (18)O-Rich Silicate Grains in the Queen Alexandra Range 99177 CR3 Chondrite

Carbonaceous chondrites contain a mixture of solar system condensates, presolar grains, and primitive organic matter. The CR3 chondrite QUE 99177 has undergone minimal al-teration [1], exemplified by abundant presolar silicates [2, 3] and anomalous organic matter [4]. Oxygen isotopic imaging studies of this meteorite have focused on finding submicrometer anomalous grains in fine-grained regions of thin sections. Here we present re-sults of an O isotopic survey of larger matrix grains.

Nguyen, A. N.↗

FINESSE: Field Investigations to Enable Solar System Science and Exploration

The FINESSE (Field Investigations to Enable Solar System Science and Exploration) team is focused on a science and exploration field-based research program aimed at generating strategic knowledge in preparation for the human and robotic exploration of the Moon, near-Earth asteroids (NEAs) and Phobos and Deimos. We follow the philosophy that "science enables exploration and exploration enables science." 1) FINESSE Science: Understand the effects of volcanism and impacts as dominant planetary processes on the Moon, NEAs, and Phobos & Deimos. 2) FINESSE Exploration: Understand which exploration concepts of operations (ConOps) and capabilities enable and enhance scientific return. To accomplish these objectives, we are conducting an integrated research program focused on scientifically-driven field exploration at Craters of the Moon National Monument and Preserve in Idaho and at the West Clearwater Lake Impact Structure in northern Canada. Field deployments aimed at reconnaissance geology and data acquisition were conducted in 2014 at Craters of the Moon National Monument and Preserve. Targets for data acquisition included selected sites at Kings Bowl eruptive fissure, lava field and blowout crater, Inferno Chasm vent and outflow channel, North Crater lava flow and Highway lava flow. Field investigation included (1) differential GPS (dGPS) measurements of lava flows, channels (and ejecta block at Kings Bowl); (2) LiDAR imaging of lava flow margins, surfaces and other selected features; (3) digital photographic documentation; (4) sampling for geochemical and petrographic analysis; (5) UAV aerial imagery of Kings Bowl and Inferno Chasm features; and (6) geologic assessment of targets and potential new targets. Over the course of the 5-week field FINESSE campaign to the West Clearwater Impact Structure (WCIS) in 2014, the team focused on several WCIS research topics, including impactites, central uplift formation, the impact-generated hydrothermal system, multichronometer dating of impact products, and using WCIS as an analog test site for crew studies of sampling protocols. The FINESSE team visited and mapped all of the major islands within West Clearwater Lake. Excellent cliff exposures around the coasts of many of the islands allowed a general stratigraphy of impactites to be defined. Notable differences to previous work includes the discovery of a monomict lithic breccia and a medium to coarse grained impact melt rock. In addition, ample rock samples were returned from West Clearwater for geochronology study. Geochronology work centers around laboratory analyses of these samples (and samples collected in the future or obtained from archives housed at the Canadian Geological Survey). Samples returned from the FINESSE field season have been evaluated for suitability for geochronologic analysis, and selected samples have been crushed for mineral separation and/or sawed for the preparation of polished petrologic thin sections. Heavy minerals (e.g., zircon, titanite, and apatite) will be separated from the crushed material for (U-Th)/He geochronology. The sections will be used for laser ablation 40Ar/39Ar research after neutron irradiation. This presentation will highlight the exciting science and exploration work conducted by FINESSE, as well as future plans for continued research.

Phobos & Deimos↗

Space Shuttle Stiffener Ring Foam Failure Analysis, a Non-Conventional Approach

The Space Shuttle Program made use of the excellent properties of rigid polyurethane foam for cryogenic tank insulation and as structural protection on the solid rocket boosters. When foam applications de-bond, classical methods of failure analysis did not provide root cause of the failure of the foam. Realizing that foam is the ideal media to document and preserve its own mode of failure, thin sectioning was seen as a logical approach for foam failure analysis to observe the three dimensional morphology of the foam cells. The cell foam morphology provided a much greater understanding of the failure modes than previously achieved.

cryogenic tank insulation↗

Chondrules and Opaque Phases in Unequilibrated R Chondrites: A Comprehensive Assessment of Their Formation

Equilibrated Rumuruti (R) chondrites record an oxygen fugacity between 0 and 3.5 log units below the fayalite-magnetite-quartz buffer, and a sulfur fugacity (fS2) 2 log units above the iron-troilite buffer. They are more than an order of magnitude more oxidized than the ordinary chondrites [1], and orders of magnitude more sulfidized than solar values. Although the R chondrites have the highest (delta)O-17 value of any meteorites, analyses of unequilibrated R chondrites indicate chondrule formation in an oxygen isotope reservoir similar to that of the ordinary chondrite chondrules. We present the relationship of the R chondrite parent body to pre-accretionary volatiles O and S based on our analyses of unequilibrated R chondrite material in two thin sections from the meteorite Mount Prestrud (PRE) 95404.

Miller, K. E.↗

Curating NASA's Past, Present, and Future Astromaterial Sample Collections

The Astromaterials Acquisition and Curation Office at NASA Johnson Space Center (hereafter JSC curation) is responsible for curating all of NASA's extraterrestrial samples. JSC presently curates 9 different astromaterials collections in seven different clean-room suites: (1) Apollo Samples (ISO (International Standards Organization) class 6 + 7); (2) Antarctic Meteorites (ISO 6 + 7); (3) Cosmic Dust Particles (ISO 5); (4) Microparticle Impact Collection (ISO 7; formerly called Space-Exposed Hardware); (5) Genesis Solar Wind Atoms (ISO 4); (6) Stardust Comet Particles (ISO 5); (7) Stardust Interstellar Particles (ISO 5); (8) Hayabusa Asteroid Particles (ISO 5); (9) OSIRIS-REx Spacecraft Coupons and Witness Plates (ISO 7). Additional cleanrooms are currently being planned to house samples from two new collections, Hayabusa 2 (2021) and OSIRIS-REx (2023). In addition to the labs that house the samples, we maintain a wide variety of infra-structure facilities required to support the clean rooms: HEPA-filtered air-handling systems, ultrapure dry gaseous nitrogen systems, an ultrapure water system, and cleaning facilities to provide clean tools and equipment for the labs. We also have sample preparation facilities for making thin sections, microtome sections, and even focused ion-beam sections. We routinely monitor the cleanliness of our clean rooms and infrastructure systems, including measurements of inorganic or organic contamination, weekly airborne particle counts, compositional and isotopic monitoring of liquid N2 deliveries, and daily UPW system monitoring. In addition to the physical maintenance of the samples, we track within our databases the current and ever changing characteristics (weight, location, etc.) of more than 250,000 individually numbered samples across our various collections, as well as more than 100,000 images, and countless "analog" records that record the sample processing records of each individual sample. JSC Curation is co-located with JSC's Astromaterials Research Office, which houses a world-class suite of analytical instrumentation and scientists. We leverage these labs and personnel to better curate the samples. Part of the cu-ration process is planning for the future, and we refer to these planning efforts as "advanced curation". Advanced Curation is tasked with developing procedures, technology, and data sets necessary for curating new types of collections as envi-sioned by NASA exploration goals. We are (and have been) planning for future cu-ration, including cold curation, extended curation of ices and volatiles, curation of samples with special chemical considerations such as perchlorate-rich samples, and curation of organically- and biologically-sensitive samples.

Zeigler, R. A.↗

Oriented Mineral Transformation in a Dark Inclusion from the Leoville Meteorite

Dark inclusions (DIs) in chondrites and achondrites are dark gray to black fragments that include a wide variety of materials that have experienced very different petrologic histories. Based on the law of inclusions, they are rocks that accreted prior to and are older than their host meteorites and possibly rep-resent an earlier generation of material. The origin of these inclusions and their relationship to their host meteorites is not always clear. They are interesting in that they represent lithologies that experienced different parent body histories than their host meteorites and are either exotic components or originated from different regions of the meteorite parent body. In many cases, DIs in CV chondrites have been altered to greater degrees than their host meteorites suggesting pre accretionary alteration [e.g., 1,2,3]. There is debate concerning whether or not these DIs record an earlier era of aqueous alteration and subsequent thermal metamorphism, and how these processes may have also affected the host CV materials. The present study is a description of a dark inclusion found in the Leoville meteorite (specifically, thin section USNM 3535-1). This inclusion has some interesting features that have considerable relevance for this discussion.

Buchanan, P. C.↗

3-D-Observation of Matrix of MIL 090657 Meteorite by Absorption-Phase Tomography

MIL 090657 meteorite (CR2.7) is one of the least altered primitive carbonaceous c hondrites [1]. This meteorite has amorphous silicates like GEMS (glass with embedded metal and sulfide), which are characteristically contained in cometary dust, in matrix [2,3] as with the Paris meteorite [4]. Three lithologies have been recognized; lithology-1 (L 1) dominated by submicron anhydrous silicates, lithology-2 (L2) by GEMS-like amorphous silicates and lithology-3 (L3) by phyllosilicates [2]. Organic materials are abundant in L 1 and L2 [2,3]. L 1 and L2 were further divided into sub-lithology respectively based on their textures and compositions [5]. These studies were performed by 2D SEM and TEM observations of sample surfaces and thin sections that are unable to reveal what constitute each lithology and how these lithologies are distributed and related to each other. This information will provide important insights into alteration and aggregation processes on asteroids and in the early solar nebula. In this study, MIL 090657 matrix was examined in 3D using two types of X-ray tomography; DET (dual-energy tomography) [6] and SIXM (scanning-imaging X-ray microscopy) [7]. Mineral phases can be discriminated based on absorption contrasts at two different X-ray energies in DET. In SIXM, materials composed of light elements such as water or organic materials can be identified based on phase and absorption contrasts. By combining these methods, we can discriminate not only organic materials from voids but also hydrous alteration products, such as hydrated silicates and carbonates, from anhydrous minerals [8]. In this study, we first observed cross sections of MIL 090657 matrix fragments C1 00 mm) in detail using FE-SEM/ EDS. Based on the results, three house-shaped samples (3 0 -50 mm) were extracted from L 1, L2 and their boundary (H1, H3 and H5, respectively) using FIB. 3D imaging of these samples were conducted at BL47XU of SPring-8, a synchrotron radiation facility, with -30-40 nm/ voxel and - 70-80 nm/ voxel at 7keV and 8keV in DET and -100 nm/ voxel at 8keV in SIXM. We found new lithologies that we named L4, L5 and L6 in H1 and H3 in addition to L 1 and L2. L4. L5 and L6 are mainly composed of probably phyllosilicates with different Fe contents. Sulfide and framboidal magnetite were recognized in L4. L5 includes magnetite and carbonate and L6 includes anhydrous silicates having cracks inside. L 1, L2, L4 and L5 are porous while few voids were observed in L6. L4 adjoins to L 1 with boundary, which is not very distinct. L2, L5 and L6 adjoin to each other, and the boundaries of L6 with L2 and L5 are clear. In H5, coarse mineral grains C5-1 0 mm) such as Fe-metal and enstatite are present in L 1 and L2. L 1-L2 boundary is not sharp in 3 D. In conclusion, we found a variety of lithologies by 3D observation for the first time, suggesting that t he MIL 0 90657 meteorite experienced complex alteration and aggregation histories. As L2 is dominated by amorphous silicates, which are extremely susceptible to aqueous alteration, t his is p resumed to be t he most primitive lithology. The contact between L2 and phyllosilicate-bearing lithologies (L5 and L6) with clear boundaries indicates that they were aggregated after aqueous alteration of L5 and L6. The indistinct boundary between L 1 and L2 is suggesting that these two lithologies might originally be the same aggregate composed of amorphous silicates and coarse mineral grains. L 1 might have experienced weak aqueous alteration followed by mild thermal alteration [2], while L2 did not undergo aqueous alteration.

Miyama, Sugimoto↗

40 Years of Collecting Martian Meteorites

This year marks the 40th anniversary of the first Martian meteorite found in Antarctica by ANSMET, ALH 77005. Since then, an additional 14 Martian meteorites have been found by the ANSMET team making for a total of 15 Martian meteorites in the Antarctic collection at Johnson Space Center. Of the 15 meteorites, some have been paired so the 15 meteorites actually represent a total of approximately 9 separate meteorites. The first Martian meteorite found by ANSMET was ALH 77005 (482.500 g), a lherzolitic shergottite. When collected, this meteorite was split as a part of the joint expedition with the National Institute of Polar Research (NIPR) Japan. Originally classified as an "achondrite-unique", it was re-classified as a Martian lherzolitic shergottites in 1982 [1]. This meteorite has been allocated to ~125 scientists for research and there are 181.964 g remaining at Johnson Space Center (JSC). Two years later, one of the most significant Martian meteorites of the collection at JSC was found at Elephant Moraine, EET 79001 (7942.000 g), a shergottite. This meteorite is the largest in the Martian collection at JSC and was the largest stony meteorite sample collected during the 1979 season. In addition to its size, this meteorite is of particular interest because it contains a linear contact separating two different igneous lithologies, basaltic and olivine-phyric. EET 79001 has glass inclusions that contain chemical compositions that are proportionally identical to the Martian atmosphere, as measured by the Viking spacecraft [2]. This discovery helped scientists to identify where the "SNC" meteorite suite had originated, and that we actually possessed Martian samples. This meteorite has been allocated to ~195 scientists for research and there are 5304.770 g of sample is available. Five years later, ANSMET found ALH 84001 (1930.900 g), the only Martian orthopyroxenite. This meteorite was initially classified as a diogenite but was reclassified as being a Martian meteorite in 1993 [3,4]. ALH 84001 is known as the "Life on Mars" meteorite, sparked debate about whether it contained evidence of Martian life [5] and significantly influenced the field of astrobiol-ogy. This sample has been allocated to 173 scientists for research and has 1426.694 g remaining at JSC. In 1988, another lherzolitic shergottite was found, LEW 88516, (13.203 g). This meteorite wasn't recognized in the field as an achondrite until it was broken during processing 2 years later. LEW 88516 has been allocated to 43 scientists for research and 5.351 g of this meteorite remains at JSC. Six years later a basaltic shergottite was found in the Queen Alexandra Range, QUE 94201 (12.020 g). This meteorite was believed to be of terrestrial origin until maskelynite was seen in a thin section. QUE 94201 has been allocated to 57 scientists for research and there are 3.629 g of this meteorite left at JSC. In 2003, the NASA Mars Exploration Program joined the ANSMET team with the hopes of finding another Martian mete-orite. During this expedition, MIL 03346 (715.200 g) was found. This meteorite is a nakhlite. MIL 03346 has been allocated to 98 scientists for research and there are 579.046 g of this sample remaining at JSC. Six years later, 3 more meteorites that have been paired with MIL 03346 were found, MIL 090030 (452.630 g), 090032 (532.190 g ) and 090136 (170.980 g). MIL 090030 has been allocated to 21 scientists for research and has 434.420 g remaining at JSC, MIL 090032 has been allocated to 21 scientists for re-search and has 508.710 g remaining at JSC and MIL 090136 has been allocated to 14 scientists for research and has 156.790 g remaining at JSC. During the 2004 expedition, 2 identical meteorites where found together on the ice, RBT 04261 (78.763 g) and RBT 04262 (204.600 g). These paired meteorites are olivine-phyric shergottites. RBT 04261 has been allocated to 33 scientists for research and has 32.335 g remaining at JSC. RBT 04262 has been allocated to 46 scientists for research and has 171.886 g remaining. In 2006, another olivine-phyric shergottite was found, LAR 06319 (78.572 g). This meteorite has 61.414 g remaining at JSC and has been allocated to 39 scientists for research. During the 2012 season, 3 more olivine-phyric shergottites were found at Larkman Nunatak, LAR 12011 (701.170 g), LAR 12095 (133.132 g) and LAR 12240 (57.596 g). LAR 12011 is paired with LAR 06319 and LAR 12095 and LAR 12240 are paired with each other. LAR 12011 has been allocated to 43 scientists for research and there are 685.778 g of LAR 12011 remaining at JSC. LAR 12095 has been allocated to 18 scientists for research and has 119.744 g remaining at JSC. LAR 12240 has been allocated to 10 scientists for research and has 52.231 g remaining at JSC. Martian meteorites are the only samples available from Mars because no mission has returned samples from there to date. All Martian meteorites are crustal rocks with most of them being crystallized magmas, so they are an important source for under-standing Martian geological history and volcanism. The ANSMET program has greatly contributed to the scientific community by collecting these meteorites

Funk, R. C.↗

Space Shuttle Stiffener Ring Foam Failure Analysis, a Non-Conventional Approach.

The Space Shuttle Program made use of the excellent properties of rigid polyurethane foam for cryogenic tank insulation and as structural protection on the solid rocket boosters. When foam applications de-bond, classical methods of failure analysis did not provide root cause of the failure of the foam. Realizing that foam is the ideal media to document and preserve its own mode of failure, thin sectioning was seen as a logical approach for foam failure analysis to observe the three dimensional morphology of the foam cells. The cell foam morphology provided a much greater understanding of the failure modes than previously achieved.

Foam↗

Remarkable Diversity of Refractory Inclusions in the Miller Range 090019 CO3.1 Chondrite

We have characterized the mineralogy, textures, bulk compositions, modal abundances and some mineral compositions in a suite of approximately 140 refractory inclusions from the MIL090019 carbonaceous chondrite. All of these 140 inclusions are found in a single thin section of this CO3.1 chondrite. These inclusions range from grossite- and hibonite-rich varieties, melilite-, spinel-, fassaite-diopside- and anorthite-rich types, and include a subset of aluminous AOAs (amoeboidal olivine aggregates). Grossite- and hibonite-bearing inclusions were discussed briefly in previous abstracts. X-ray mapping by energy dispersive spectrometry has permitted us to extract the bulk compositions of these inclusions from hyperspectral x-ray datasets. The bulk compositions of these inclusions represent the full range of recognized CAI (Calcium-Aluminum–rich Inclusions) types.

Ross, D. Kent↗

3d Crystallographic Orientation of Olivine in Bjurböle Chondrules

The crystallographic orientations of chondrule minerals can provide important insights into their formation and deformational history. For example, the orientations of the olivine bars and surrounding rim in barred olivine chondrules provide information and on the conditions of crystallization and the orientations and shapes of olivines within porphritic chondrules can record the reactions with the surrounding nebular gas during chondrule formation. Later deformation on the parent body can cause crystal-plastic deformation of chondrule minerals that is evident through their intracrystalline lattice misorientations. Typically these crystal orientations and lattice misorientations are determined using electron backscatter diffraction (EBSD) on thin sections but this gives only a 2D picture for what is actually a 3D texture. While it is possible to combine EBSD with serial sectioning to build a 3D dataset of texture, this is a destructive, time-intensive process. A recent technological development that enables non-destructive, 3D crystallographic orientation measurement is X-ray diffraction contrast tomography (DCT), which uses the X-ray diffraction of the crystal lattice to determine orientation. Originally only possible using monochromatic X-ray beams at 3rd generation synchrotron light sources, DCT has been recently adapted to polychromatic sources of laboratory X-ray microscopes (referred to as Lab-DCT). Up to this point LabDCT has only been applied to large, well-formed crystals of high symmetry (i.e., metals), but we recently acquired DCT datasets for a pair Bjurböle chondrules to determine the applicability of the technique to natural, mutlimineralic samples composed predominately of olivine (i.e., chondrules).

Hanna, R. D.↗

Analysis of WFPC-2 Core Samples for MMOD Discrimination

An examination of the Hubble Space Telescope Wide Field Planetary Camera 2 (WFPC-2) radiator assembly was conducted at NASA Goddard Space Flight Center during the summer of 2009. Immediately apparent was the predominance of impact features, identified as simple or complex craters, resident only in the thermal paint layer; similar features were observed during a prior survey of the WFPC-1 radiator. Larger impact features displayed spallation zones, darkened areas, and other features not observed in impacts onto bare surfaces. Craters were extracted by coring the radiator in the NASA Johnson Space Center’s Space Exposed Hardware cleanroom and were subsequently examined using scanning electron microscopy/energy dispersive X-ray spectroscopy to determine the likely origin, e.g., micrometeoritic or orbital debris, of the impacting projectile. Recently, a selection of large cores was re-examined using a new technique developed to overcome some limitations of traditional crater imaging and analysis. This technique, motivated by thin section analysis, examines a polished, lateral surface area revealed by cross-sectioning the core sample. This paper reviews the technique, the classification rubric as extended by this technique, and results to date.

Anz-Meador, P.↗

Chemical and Thermodynamic Constraints on the Thermal Evolution of Eucrites

Vesta is the only differentiated asteroid with a nearly intact crust, making it the candidate for studying early planetary differentiation. It is commonly thought that the howardite, eucrite, and diogenite (HED) clan of meteorites derive from Vesta, and thus the study of HEDs is important for understanding the evolution of primitive bodies in the early solar system [1]. Of particular interest are the unusual trace element abundances in Stannern group eucrites, which have been interpreted as partial melting and melt contamination events that occurred on the parent body during thermal metamorphism[2]. However, some samples that contain evidence of high temperature metamorphism, such as Elephant Moraine (EET) 90020, have anomalous REE patterns that have been interpret-ed multiple ways. For example [3] concluded that the loss of small degrees of partial melt depleted the sample in LREEs while [4] concluded that subsolidus diffusion better explained why depletion of only some highly incompatible elements is observed. The heterogeneous nature of this sample makes reconstructing its petrologic history challenging. Here, we conduct further petrographic and chemical studies on polished thin sections of EET 90020 and compare results to previous studies [3-5]. Additionally, we combine chemical analyses with thermodynamic models in order to refine the constraints on the post-crystallization thermal history of EET 90020. We additionally include studies of Graves Nunataks (GRA) 98098, which also contains evidence of high temperature metamorphism and anomalous geochemical signatures, as well as evidence of solid state diffusion at lower temperatures [6].

Gorce, Jennifer S.↗

Oxygen Isotopic Imaging of Refractory Inclusions from the Miller Range (MIL) 090019 CO3 Chondrite: A Perovskite Perspective

Calcium-Aluminum-rich Inclusions (CAIs) in primitive meteorites are the first solids to condense in the Solar System. The oxygen isotopic compositions recorded in various mineral components of CAIs provide clues about their origins and post-formation histories, recording processes such as condensation, melting, nebular alteration, and fluidrock reactions on the parent body. MIL 090019 is similar to some rare carbonaceous chondrites such as Acfer 094, DOM 08004/6 and ALH 77303 that contain high abundances of a variety of refractory inclusions. This provides an opportunity to study the oxygen isotopic record of different types of refractory inclusions within the same meteorite. We analyzed CAIs specifically targeting primary minerals that are direct nebular condensates, such as corundum and perovskite, with the goal of gaining insights into the O isotopic composition of the nebular gas(es) from which these CAIs condensed. As MIL 090019 is a classified as CO3.1, it shows some signs of thermal metamorphism, compared to the more primitive CO3 meteorites (e.g., DOM 08004/06). A second goal of this study is to search for evidence of nebular processes in phases such as perovskite and melilite that are susceptible to parent body alteration to varying degrees. We analyzed the oxygen isotopic compositions of various CAIs from the MIL 090019 CO3 carbonaceous chondrite by ion imaging using the NanoSIMS 50L (Nano Secondary Ion Mass Spectrometer) at JSC following methods described in. An advantage of ion imaging over traditional spot analyses is that it provides spatial context to the oxygen isotopic data. This work builds on previously reported oxygen isotopic composition of two other CAIs (CAI-44 and CAI-E2) from the same meteorite thin section.

Mane, P.↗

Condensation, Partial Melting and Evaporation Processes Influence the Bulk Compositions of Spinel-Cored Spherules in the CO3.1 Chondrite Miller Range 90019

Here we focus on spinel-cored spherule calcium-aluminum rich inclusions (CAI), dominantly ~75-80 microns in diameter in the CO3.1 chondrite Miller Range 90019, which make up ~ 12 % of the fine-grained CAIs in one thin section. Their mineralogical content ranges from rare grossite- and hibonite-bearing varieties, through perovskite-melilitebearing, to fassaite-bearing and finally anorthitebearing. Non-spherical CAIs have been divided into 4 other groups, defined based on mineralogical abundances. We also characterized a group of AOAs from this sample. No glass has been recognized in any inclusions. Some relatively evolved members (anorthite-, spinel- + fassaite-bearing) among the spherules are found engulfed in AOAs. We characterized the bulk compositions of ~145 CAIs and AOAs in this meteorite, derived from EDS-x-ray mapping of the inclusions. We determined bulk compositions both with and without Wark-Lovering rims (when present), which are largely composed of diopside  forsterite. The balance of the inclusions appear to have not been melted or partially melted, but rather they have textures that indicate they are condensates, often modified by extensive reaction with nebular gases. This presents the opportunity to examine effects on the bulk compositions of spherules resulting potentially from melting plus evaporation. Other aspects of this suite of refractory inclusions have been discussed in these abstracts. Oxygen isotope variations in one spherule were presented in [4]. The latter study showed a complex history of reaction with nebular gases possessing a variety of Oisotope compositions. Additional O isotopic studies of inclusions in this work are included in Mane et al.

Ross, D. K.↗

Preserving and Curating the Moon: Adventures in Lunar Core Processing

The lunar crust is the most easily accessible part of the Moon to both remote sensing and sample analyses and provides an archive of information about planetary formation, crustal evolution, and contains a wealth of information about the origin of the Earth-Moon system [e.g., 1-5]. The Apollo mission returned 382 kg of rocks, soil and core samples. Studies of these lunar samples are crucial for our understanding of the Moon’s formation and geological evolution, and for the past 50 years these returned samples have provided the foundation for lunar science [5]. The returned samples are stored and cared for in the lunar curation facility at NASA’s Johnson Space Center. This facility is comprised of a large suite of clean rooms, sample vaults for pristine and return samples, thin section labs, core and saw rooms, storage and working areas, and ancillary labs all designed to minimize contamination from the environment and other samples. Some of the returned samples were intentionally set aside and left unopened. Recently, the Apollo Next Generation Sample Analysis (ANGSA) initiative was designed to examine these pristine samples so the next generation of lunar scientists can further our insight into the Moon’s history. Here, we present the meticulous process that involves preparing for, and ultimately opening, one of the unopened core samples: Apollo 17 drive tube 73002,0,which was collected on the Moon from a landslide deposit near Lara Crater by astronauts Gene Cernan and Jack Schmitt. In order to open, examine, and curate 73002,0withminimalpotential contamination, great care had to be taken prior to opening its container. Beginning18 months before extrusion of the sample, all core processing equipment was pulled out of storage, identified, sorted, cleaned, and purged with nitrogen gas. However, limited institutional memory has made this step challenging as most of the former core processors from the Apollo area have retired or passed away. Twelvemonths prior to extrusion, table-top rehearsals were initiated to identify equipment and learn how it fits together and operates. Five months before extruding the real core, preparations further evolved to include the extrusion and dissection of a lunar core simulant. In addition, a mock-up glovebox was designed and built to allow for a more realistic practice environment. One month prior to extrusion, the actual core cabinet was prepared for use, which included fitting it with lights, a webcam, and power. The tool and equipment cleaning procedure was also modified to include increased cleanliness and sterility requirements. While still sealed, the core was CT scanned at the University of Texas at Austin to maximize its scientific return. Days before the extrusion, witness plates and foil were deployed inside the core cabinet to monitor potential particle and organic contamination within the cabinet. On Nov. 5th, 2019, core sample 73002,0 was successfully opened and extruded(Fig.1). Dissection of 73002,0 began immediately afterwards and is still under way. Processing this sample will help us prepare for future sampling missions and core extrusions and will enable new scientific discoveries about the Moon.

C H Krysher↗

The Cl isotope composition and halogen contents of Apollo-return samples

Lunar mare basalts are depleted in F and Cl by approximately an order of magnitude relative to mid-ocean ridge basalts and contain two Cl-bearing components with elevated isotopic compositions relative to the bulk-Earth value of ∼0‰. The first is a watersoluble chloride constituting 65 ± 10% of total Cl with δ37Cl values averaging 3.0 ± 4.3‰. The second is structurally bound chloride with δ37Cl values averaging 7.3 ± 3.5‰. These high and distinctly different isotopic values are inconsistent with equilibrium fractionation processes and instead suggest early and extensive degassing of an isotopically light vapor. No relationship is observed between F/Cl ratios and δ37Cl values, which suggests that lunar halogen depletion largely resulted from the Moon-forming Giant Impact. The δ37Cl values of apatite are generally higher than the structurally bound Cl, and ubiquitously higher than the calculated bulk δ37Cl values of 4.1 ± 4.0‰. The apatite grains are not representative of the bulk rock, and instead record localized degassing during the final stages of lunar magma ocean (LMO) or later melt crystallization. The large variability in the δ37Cl values of apatite within individual thin sections further supports this conclusion. While urKREEP (primeval KREEP [potassium/rare-earth elements/phosphorus]) has been proposed to be the source of the Moon’s high Cl isotope values, the ferroan anorthosites (FANs) have the highest δ37Cl values and have a positive correlation with Cl content, and yet do not contain apatite, nor evidence of a KREEP component. The high δ37Cl values in this lithology are explained by the incorporation of a >30‰ HCl vapor from a highly evolved LMO.

The Moon↗