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At least 325 records · Page 18

The Tracer Gas Method of Determining the Charging Efficiency of Two-stroke-cycle Diesel Engines

A convenient method has been developed for determining the scavenging efficiency or the charging efficiency of two-stroke-cycle engines. The method consists of introducing a suitable tracer gas into the inlet air of the running engine and measuring chemically its concentration both in the inlet and exhaust gas. Monomethylamine CH(sub 3)NH(sub 2) was found suitable for the purpose as it burns almost completely during combustion, whereas the "short-circuited" portion does not burn at all and can be determined quantitatively in the exhaust. The method was tested both on four-stroke and on two-stroke engines and is considered accurate within 1 percent.

Schweitzer, P H↗

Contour advection with surgery: A technique for investigating finescale structure in tracer transport

We present a trajectory technique, contour advection with surgery (CAS), for tracing the evolution of material contours in a specified (including observed) evolving flow. CAS uses the algorithms developed by Dritschel for contour dynamics/surgery to trace the evolution of specified contours. The contours are represented by a series of particles, which are advected by a specified, gridded, wind distribution. The resolution of the contours is preserved by continually adjusting the number of particles, and finescale features are produced that are not present in the input data (and cannot easily be generated using standard trajectory techniques). The reliability, and dependence on the spatial and temporal resolution of the wind field, of the CAS procedure is examined by comparisons with high-resolution numerical data (from contour dynamics calculations and from a general circulation model), and with routine stratospheric analyses. These comparisons show that the large-scale motions dominate the deformation field and that CAS can accurately reproduce small scales from low-resolution wind fields. The CAS technique therefore enables examination of atmospheric tracer transport at previously unattainable resolution.

Waugh, Darryn W.↗

A Comparison of Measurements from ATMOS and Instruments Aboard the ER-2 Aircraft: Tracers of Atmospheric Transport and Halogenated Gases

We compare volume mixing ratio profiles of N2O, O3, NO(y), H2O, CH4, and CO in the mid-latitude lower stratosphere measured by the ATMOS Fourier transform spectrometer on the ATLAS-3 Space Shuttle Mission with in situ measurements acquired from the NASA ER-2 aircraft during Nov 1994. ATMOS and ER-2 observations of (N2O) show good agreement, as do measured correlations of (O3), (NO(y)), (H2O), and (CH4) with (N2O). Thus a consistent measure of the hydrogen (H2O, CH4) content of the lower stratosphere is provided by the two platforms. The similarity of (NO(y)) determined by detection of individual species by ATMOS and the total (NOy) measurement on the ER-2 provides strong corroboration for the accuracy of both techniques. A 25% discrepancy in lower stratospheric (CO) observed by ATMOS and the ER-2 remains unexplained. Otherwise, the agreement for measurements of long-lived tracers demonstrates the ability to combine ATMOS data with in situ observations for quantifying atmospheric transport.

Chang, A. Y.↗

Implementation of a Parallel Kalman Filter for Stratospheric Chemical Tracer Assimilation

A Kalman filter for the assimilation of long-lived atmospheric chemical constituents has been developed for two-dimensional transport models on isentropic surfaces over the globe. An important attribute of the Kalman filter is that it calculates error covariances of the constituent fields using the tracer dynamics. Consequently, the current Kalman-filter assimilation is a five-dimensional problem (coordinates of two points and time), and it can only be handled on computers with large memory and high floating point speed. In this paper, an implementation of the Kalman filter for distributed-memory, message-passing parallel computers is discussed. Two approaches were studied: an operator decomposition and a covariance decomposition. The latter was found to be more scalable than the former, and it possesses the property that the dynamical model does not need to be parallelized, which is of considerable practical advantage. This code is currently used to assimilate constituent data retrieved by limb sounders on the Upper Atmosphere Research Satellite. Tests of the code examined the variance transport and observability properties. Aspects of the parallel implementation, some timing results, and a brief discussion of the physical results will be presented.

Chang, Lang-Ping↗

Aviation Fuel Tracer Simulation: Model Intercomparison and Implications

An upper limit for aircraft-produced perturbations to aerosols and gaseous exhaust products in the upper troposphere and lower stratosphere (UT/LS) is derived using the 1992 aviation fuel tracer simulation performed by eleven global atmospheric models. Key Endings are that subsonic aircraft emissions: (1) have not be responsible for the observed water vapor trends at 40 deg N; (2) could be a significant source of soot mass near 12 km, but not at 20 km; (3) might cause a noticeable increase in the background sulfate aerosol surface area and number densities (but not mass density) near the northern mid-latitude tropopause; and (4) could provide a global, annual mean top of the atmosphere radiative forcing up to +0.006 W/sq m and -0.013 W/sq m due to emitted soot and sulfur, respectively.

Danilin, M. Y.↗

Simulation of Long Lived Tracers Using an Improved Empirically Based Two-Dimensional Model Transport Algorithm

We have developed a new empirically-based transport algorithm for use in our GSFC two-dimensional transport and chemistry model. The new algorithm contains planetary wave statistics, and parameterizations to account for the effects due to gravity waves and equatorial Kelvin waves. As such, this scheme utilizes significantly more information compared to our previous algorithm which was based only on zonal mean temperatures and heating rates. The new model transport captures much of the qualitative structure and seasonal variability observed in long lived tracers, such as: isolation of the tropics and the southern hemisphere winter polar vortex; the well mixed surf-zone region of the winter sub-tropics and mid-latitudes; the latitudinal and seasonal variations of total ozone; and the seasonal variations of mesospheric H2O. The model also indicates a double peaked structure in methane associated with the semiannual oscillation in the tropical upper stratosphere. This feature is similar in phase but is significantly weaker in amplitude compared to the observations. The model simulations of carbon-14 and strontium-90 are in good agreement with observations, both in simulating the peak in mixing ratio at 20-25 km, and the decrease with altitude in mixing ratio above 25 km. We also find mostly good agreement between modeled and observed age of air determined from SF6 outside of the northern hemisphere polar vortex. However, observations inside the vortex reveal significantly older air compared to the model. This is consistent with the model deficiencies in simulating CH4 in the northern hemisphere winter high latitudes and illustrates the limitations of the current climatological zonal mean model formulation. The propagation of seasonal signals in water vapor and CO2 in the lower stratosphere showed general agreement in phase, and the model qualitatively captured the observed amplitude decrease in CO2 from the tropics to midlatitudes. However, the simulated seasonal amplitudes were attenuated too rapidly with altitude in the tropics. Overall, the simulations with the new transport formulation are in substantially better agreement with observations compared with our previous model transport.

Fleming, E. L.↗

Aviation Fuel Tracer Simulation: Model Intercomparison and Implications

An upper limit for aircraft-produced perturbations to aerosols and gaseous exhaust products in the upper troposphere and lower stratosphere (UT/LS) is derived using the 1992 aviation fuel tracer simulation performed by eleven global atmospheric models. Key findings are that subsonic aircraft emissions: (1) have not been responsible for the observed water vapor trends at 40degN; (2) could be a significant source of soot mass near 12 km, but not at 20 km; (3) might cause a noticeable increase in the background sulfate aerosol surface area and number densities (but not mass density) near the northern mid-latitude tropopause; and (4) could provide a global, annual mean top of the atmosphere radiative forcing up to +0.006 W/sq m and -0.013 W/sq m due to emitted soot and sulfur, respectively.

Danilin, M. Y.↗

Stratospheric Tracers of Atmospheric Transport (STRAT) Campaign: ER-2 Participation

The NASA Stratospheric Tracers of Atmospheric Transport (STRAT) mission was initiated to advance knowledge of the major transport mechanisms of the upper troposphere-lower stratosphere. This is the region of the atmosphere within which exchange processes take place that critically determine the response of the climate system and ozone distribution to changing conditions triggered by the release of chemicals at the surface. The mission series that extended from October 1995 to November 1997 was extremely successful. The scientific advances that emerged from that mission include analyses of: (1)troposphere-to-stratosphere transport in the lowermost stratosphere from measurements of H2O, CO2, N2O, and O3; (2) the effects of tropical cirrus clouds on the abundance of lower stratospheric ozone; and (3) the role of HO(x) in super- and subsonic aircraft exhaust plumes; and dehydration and denitrification in the arctic polar vortex during the 1995-96 winter.

Anderson, James G.↗

Stratospheric Tracers of Atmospheric Transport (STRAT) Campaign: ER-2 Participation

The NASA Stratospheric Tracers of Atmospheric Transport (STRAT) mission was initiated to advance knowledge of the major transport mechanisms of the upper troposphere-lower stratosphere. This is the region of the atmosphere within which exchange processes take place that critically determine the response of the climate system and ozone distribution to changing conditions triggered by the release of chemicals at the surface. The mission series that extended from October 1995 to November 1997 was extremely successful. The scientific advances that emerged from that mission include analyses of: (1) troposphere-to-stratosphere transport in the lowermost stratosphere from measurements of H2O, CO2, N2O, and O3; (2) the effects of tropical cirrus clouds on the abundance of lower stratospheric ozone; (3) the role of HO(sub x) in super- and subsonic aircraft exhaust plumes; and (4) dehydration and denitrification in the arctic polar vortex during the 1995-96 winter. The abstracts from published papers are included.

Anderson, James G.↗

Stratospheric Tracers of Atmospheric Transport (STRAT) Campaign: ER-2 Participation

The NASA Stratospheric Tracers of Atmospheric Transport (STRAT) mission was initiated to advance knowledge of the major transport mechanisms of the upper troposphere-lower stratosphere. This is the region of the atmosphere within which exchange processes take place that critically determine the response of the climate system and ozone distribution to changing conditions triggered by the release of chemicals at the surface. The mission series that extended from October 1995 to November 1997 was extremely successful. The scientific advances that emerged from that mission include analyses of- troposphere-to-stratosphere transport in the lowermost stratosphere from measurements of H2O, CO2, N2O, and O3; the effects of tropical cirrus clouds on the abundance of lower stratospheric ozone; the role of HO, in super- and subsonic aircraft exhaust plumes; and dehydration and denitrification in the arctic polar vortex during the 1995-96 winter.

Anderson, James G.↗

A Comparison of Measurements from ATMOS and Instruments Aboard the ER-2 Aircraft: Tracers of Atmospheric Transport

We compare volume mixing ratio profiles of N2O, O3, NO(y) H2O, CH4, and CO in the mid-latitude lower stratosphere measured by the ATMOS Fourier transform spectrometer on the ATLAS-3 Space Shuttle Mission with in situ measurements acquired from the NASA ER-2 aircraft during Nov 1994. ATMOS and ER-2 observations of [N2O] show good agreement, as do measured correlations of [O3], [NO(y)], [H2O], and [CH4] with [N2O]. Thus a consistent measure of the hydrogen (H2O, CH4) content of the lower stratosphere is provided by the two platforms. The similarity of [NO(y)] determined by detection of individual species by ATMOS and the total [NO(y)] measurement on the ER-2 provides strong corroboration for the accuracy of both techniques. A 25% discrepancy in lower stratospheric [CO] observed by ATMOS and the ER-2 remains unexplained. Otherwise, the agreement for measurements of long-lived tracers demonstrates the ability to combine ATMOS data with in situ observations for quantifying atmospheric transport.

Chang, A. Y.↗

Simulation of Long Lived Tracers Using an Improved Empirically-Based Two-Dimensional Model Transport Algorithm

We have developed a new empirically-based transport algorithm for use in our GSFC two-dimensional transport and chemistry assessment model. The new algorithm contains planetary wave statistics, and parameterizations to account for the effects due to gravity waves and equatorial Kelvin waves. We will present an overview of the new algorithm, and show various model-data comparisons of long-lived tracers as part of the model validation. We will also show how the new algorithm gives substantially better agreement with observations compared to our previous model transport. The new model captures much of the qualitative structure and seasonal variability observed methane, water vapor, and total ozone. These include: isolation of the tropics and winter polar vortex, the well mixed surf-zone region of the winter sub-tropics and mid-latitudes, and the propagation of seasonal signals in the tropical lower stratosphere. Model simulations of carbon-14 and strontium-90 compare fairly well with observations in reproducing the peak in mixing ratio at 20-25 km, and the decrease with altitude in mixing ratio above 25 km. We also ran time dependent simulations of SF6 from which the model mean age of air values were derived. The oldest air (5.5 to 6 years) occurred in the high latitude upper stratosphere during fall and early winter of both hemispheres, and in the southern hemisphere lower stratosphere during late winter and early spring. The latitudinal gradient of the mean ages also compare well with ER-2 aircraft observations in the lower stratosphere.

Fleming, Eric L.↗

Inferring Small Scale Dynamics from Aircraft Measurements of Tracers

The millions of ER-2 and DC-8 aircraft measurements of long-lived tracers in the Upper Troposphere/Lower Stratosphere (UT/LS) hold enormous potential as a source of statistical information about subgrid scale dynamics. Extracting this information however can be extremely difficult because the measurements are made along a 1-D transect through fields that are highly anisotropic in all three dimensions. Some of the challenges and limitations posed by both the instrumentation and platform are illustrated within the context of the problem of using the data to obtain an estimate of the dissipation scale. This presentation will also include some tutorial remarks about the conditional and two-point statistics used in the analysis.

Sparling, L. C.↗

Investigation of the Physical Processes Governing Large-Scale Tracer Transport in the Stratosphere and Troposphere

This report summarizes work conducted from January 1996 through April 1999 on a program of research to investigate the physical mechanisms that underlie the transport of trace constituents in the stratosphere-troposphere system. The primary scientific goal of the research has been to identify the processes which transport air masses within the lower stratosphere, particularly between the tropics and middle latitudes. This research was conducted in collaboration with the Subsonic Assessment (SASS) of the NASA Atmospheric Effects of Radiation Program (AEAP) and the Upper Atmospheric Research Program (UARP). The SASS program sought to understand the impact of the present and future fleets of conventional jet traffic on the upper troposphere and lower stratosphere, while complementary airborne observations under UARP seek to understand the complex interactions of dynamical and chemical processes that affect the ozone layer. The present investigation contributed to the goals of each of these by diagnosing the history of air parcels intercepted by NASA research aircraft in UARP and AEAP campaigns. This was done by means of a blend of trajectory analyses and tracer correlation techniques.

Selkirk, Henry B.↗

Tracer-Based Determination of Vortex Descent in the 1999-2000 Arctic Winter

A detailed analysis of available in situ and remotely sensed N2O and CH4 data measured in the 1999-2000 winter Arctic vortex has been performed in order to quantify the temporal evolution of vortex descent. Differences in potential temperature (theta) among balloon and aircraft vertical profiles (an average of 19-23 K on a given N2O or CH4 isopleth) indicated significant vortex inhomogeneity in late fall as compared with late winter profiles. A composite fall vortex profile was constructed for November 26, 1999, whose error bars encompassed the observed variability. High-latitude, extravortex profiles measured in different years and seasons revealed substantial variability in N2O and CH4 on theta surfaces, but all were clearly distinguishable from the first vortex profiles measured in late fall 1999. From these extravortex-vortex differences, we inferred descent prior to November 26: 397+/-15 K (1sigma) at 30 ppbv N2O and 640 ppbv CH4, and 28+/-13 K above 200 ppbv N2O and 1280 ppbv CH4. Changes in theta were determined on five N2O and CH4 isopleths from November 26 through March 12, and descent rates were calculated on each N2O isopleth for several time intervals. The maximum descent rates were seen between November 26 and January 27: 0.82+/-0.20 K/day averaged over 50-250 ppbv N2O. By late winter (February 26-March 12), the average rate had decreased to 0.10+/-0.25 K/day. Descent rates also decreased with increasing N2O; the winter average (November 26-March 5) descent rate varied from 0.75+/-0.10 K/day at 50 ppbv to 0.40+/-0.11 K/day at 250 ppbv. Comparison of these results with observations and models of descent in prior years showed very good overall agreement. Two models of the 1999-2000 vortex descent, SLIMCAT and REPROBUS, despite theta offsets with respect to observed profiles of up to 20 K on most tracer isopleths, produced descent rates that agreed very favorably with the inferred rates from observation.

Greenblatt, Jeffery B.↗

Interstellar PAH Emission in the 11-14 micron Region: New Insights and a Tracer of Ionized PAHs

The Ames infrared spectral database of isolated, neutral and ionized polycyclic aromatic hydrocarbons (PAHs) shows that aromatic CH out-of-plane bending frequencies are significantly shifted upon ionization. For non-adjacent and doubly-adjacent CH groups, the shift is pronounced and consistently toward higher frequencies. The non-adjacent modes are blueshifted by an average of 27 per cm and the doubly-adjacent modes by an average of 17 per cm. For triply- and quadruply-adjacent CH out-of-plane modes the ionization shifts are more erratic and typically more modest. As a result of these ionization shifts, both the non-adjacent and doubly-adjacent CH out-of-plane modes move out of the regions classically associated with their respective vibrations in neutral PAHs. The doubly-adjacent modes of ionized PAHs tend to fall into the frequency range traditionally associated with the non-adjacent modes, while the non-adjacent modes are shifted to frequencies above those normally attributed to out-of-plane bending vibrations. Consequently, the origin of the interstellar infrared emission feature near 11.2 microns, traditionally attributed to the out-of-plane bending of non-adjacent CH groups on PAHs is rendered ambiguous. Instead, this feature likely reflects contributions from both non-adjacent CH units in neutral PAHs and doubly-adjacent CH units in PAH cations, the dominant charge state in the most energetic emission regions. This greatly relieves the structural constraints placed on the interstellar PAH population by the dominance of the 11.2 micron band in this region and eliminates the necessity to invoke extensive dehydrogenation of the emitting species. Furthermore, these results indicate that the emission between 926 and 904 per cm (10.8 and 11.1 microns) observed in many sources can be unambiguously attributed to the non-adjacent CH out-of-plane bending modes of moderately-sized (fewer than 50 carbon atom) PAH cations making this emission an unequivocal tracer of ionized interstellar PAHs.

Hudgins, Douglas M.↗

GCM Simulation of the Large-scale North American Monsoon Including Water Vapor Tracer Diagnostics

In this study, we have applied GCM water vapor tracers (WVT) to simulate the North American water cycle. WVTs allow quantitative computation of the geographical source of water for precipitation that occurs anywhere in the model simulation. This can be used to isolate the impact that local surface evaporation has on precipitation, compared to advection and convection. A 15 year 1 deg, 1.25 deg. simulation has been performed with 11 global and 11 North American regional WVTs. Figure 1 shows the source regions of the North American WVTs. When water evaporates from one of these predefined regions, its mass is used as the source for a distinct prognostic variable in the model. This prognostic variable allows the water to be transported and removed (precipitated) from the system in an identical way that occurs to the prognostic specific humidity. Details of the model are outlined by Bosilovich and Schubert (2002) and Bosilovich (2002). Here, we present results pertaining to the onset of the simulated North American monsoon.

Bosilovich, Michael G.↗

Polycyclic Aromatic Hydrocarbons and Astrophysics: The State of the Pah Model and a Possible Tracer of Nitrogen in Carbon-Rich Dust

Over the past fifteen years, thanks to significant, parallel advancements in observational, experimental, and theoretical techniques, tremendous strides have been made in our understanding of the role aromatic materials play in the interstellar medium (ISM). Twenty years ago, the possible existence of an abundant population of large, carbon-rich molecules in the ISM was unthinkable. Today, the unmistakable spectroscopic signatures of polycyclic aromatic hydrocarbon molecules (PAHs) - shockingly large molecules by the standards of traditional interstellar chemistry - are recognized throughout the Universe. In this paper, we will examine the current state of the interstellar PAH model and its utility as a diagnostic tool to derive insight into the nature of the interstellar PAH population. As an example of this application, we will examine the results of our recent spectroscopic studies of polycyclic aromatic nitrogen heterocycles (PANHs)-PAHs with an atom of nitrogen substituted into the aromatic skeleton-and discuss a possible tracer of such species amongst the interstellar PAH emission bands in the latest observational data.

Hudgins, Douglas M.↗