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At least 325 records · Page 18

Feasibility of Geophysical Monitoring of Carbon-Sequestrated Deep Saline Aquifers

As carbon dioxide (CO{sub 2}) is sequestered from the bottom of a brine reservoir and allowed to migrate upward, the effects of the relative permeability hysteresis due to capillary trapping and buoyancy driven migration tend to make the reservoir patchy saturated with different fluid phases over time. Seismically, such a patchy saturated reservoir induces an effective anisotropic behavior whose properties are primarily dictated by the nature of the saturation of different fluid phases in the pores and the elastic properties of the rock matrix. By combining reservoir flow simulation and modeling with seismic modeling, it is possible to derive these effective anisotropic properties, which, in turn, could be related to the saturation of CO{sub 2} within the reservoir volume any time during the post-injection scenario. Therefore, if time-lapse seismic data are available and could be inverted for the effective anisotropic properties of the reservoir, they, in combination with reservoir simulation could potentially predict the CO{sub 2} saturation directly from the time-lapse seismic data. It is therefore concluded that the time-lapse seismic data could be used to monitor the carbon sequestrated saline reservoirs. But for its successful implementation, seismic modeling and inversion methods must be integrated with the reservoir simulations. In addition, because CO{sub 2} sequestration induces an effective anisotropy in the sequestered reservoir and anisotropy is best detected using multicomponent seismic data compared to single component (P-wave) data, acquisition, processing, and analysis is multicomponent seismic data is recommended for these time-lapse studies. Finally, a successful implementation of using time-lapse seismic data for monitoring the carbon sequestrated saline reservoirs will require development of a robust methodology for inverting multicomponent seismic data for subsurface anisotropic properties.

54 ENVIRONMENTAL SCIENCES↗

Optimizing and Quantifying CO 2 Storage Resource in Saline Formations and Hydrocarbon Reservoirs

In an effort to reduce carbon dioxide (CO 2 ) emissions from large stationary sources, carbon capture and storage (CCS) is being investigated as one approach. This work assesses CO 2 storage resource estimation methods for deep saline formations (DSFs) and hydrocarbon reservoirs undergoing CO 2 enhanced oil recovery (EOR). Project activities were conducted using geologic modeling and simulation to investigate CO 2 storage efficiency. CO 2 storage rates and efficiencies in DSFs classified by interpreted depositional environment were evaluated at the regional scale over a 100-year time frame. A focus was placed on developing results applicable to future widespread commercial-scale CO 2 storage operations in which an array of injection wells may be used to optimize storage in saline formations. The results of this work suggest future investigations of prospective storage resource in closed or semiclosed formations need not have a detailed understanding of the depositional environment of the reservoir to generate meaningful estimates. However, the results of this work also illustrate the relative importance of depositional environment, formation depth, structural geometry, and boundary conditions on the rate of CO 2 storage in these types of systems. CO 2 EOR occupies an important place in the realm of geologic storage of CO 2 , as it is likely to be the primary means of geologic CO 2 storage during the early stages of commercial implementation, given the lack of a national policy and the viability of the current business case. This work estimates CO 2 storage efficiency factors using a unique industry database of CO 2 EOR sites and 18 different reservoir simulation models capturing fluvial clastic and shallow shelf carbonate depositional environments for reservoir depths of 1219 and 2438 meters (4000 and 8000 feet) and 7.6-, 20-, and 64-meter (25-, 66,- and 209-foot) pay zones. The results of this work provide practical information that can be used to quantify CO 2 storage resource estimates in oil reservoirs during CO 2 EOR operations (as opposed to storage following depletion) and the uncertainty associated with those estimates.

54 ENVIRONMENTAL SCIENCES↗

Saline: An API for Thermophysical Properties

An initial interface for thermophysical data was generalized for broader incorporation into modeling and simulation codes used for molten salt reactor analysis. A quality assurance review of the thermophysical properties data was conducted; errors were fixed, and improvements were made with consistency and accuracy to references. The Saline code application programming interface was created to facilitate access and integration of thermophysical properties. This report describes the thermophysical data, the quality assurance improvements, and the Saline interface.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Improvements in the Application of CO 2 Storage Efficiency Values for Deep Saline Formations

The accompanying report was prepared as a manuscript for submission to the Journal of Greenhouse Gas Control Technologies. It is important to accurately estimate the effective volumetric (CO 2 ) storage resource potential of a deep saline formation. As the amount of information about a formation increases, the accuracy of the calculation of storage potential should also increase. A critical component of the CO 2 storage equation is the storage efficiency factor, and new storage efficiency values are presented to accompany an increase in knowledge. A workflow was developed to properly assess the CO 2 storage potential of a deep saline formation using the methodology proposed by the U.S. Department of Energy when used in conjunction with the new storage efficiency values.

54 ENVIRONMENTAL SCIENCES↗

A Hierarchical Framework for CO2 Storage Capacity in Deep Saline Aquifer Formations

Carbon dioxide (CO 2 ) storage in deep saline aquifers is a vital option for CO 2 mitigation at a large scale. Determining storage capacity is one of the crucial steps toward large-scale deployment of CO 2 storage. Results of capacity assessments tend toward a consensus that sufficient resources are available in saline aquifers in many parts of the world. However, current CO 2 capacity assessments involve significant inconsistencies and uncertainties caused by various technical assumptions, storage mechanisms considered, algorithms, and data types and resolutions. Furthermore, other constraint factors (such as techno-economic features, site suitability, risk, regulation, social-economic situation, and policies) significantly affect the storage capacity assessment results. Consequently, a consensus capacity classification system and assessment method should be capable of classifying the capacity type or even more related uncertainties. We present a hierarchical framework of CO 2 capacity to define the capacity types based on the various factors, algorithms, and datasets. Finally, a review of onshore CO 2 aquifer storage capacity assessments in China is presented as examples to illustrate the feasibility of the proposed hierarchical framework.

58 GEOSCIENCES↗

The Complete Genome and Physiological Analysis of the Eurythermal Firmicute Exiguobacterium chiriqhucha Strain RW2 Isolated From a Freshwater Microbialite, Widely Adaptable to Broad Thermal, pH, and Salinity Ranges

Members of the genus Exiguobacterium are found in diverse environments from marine and fresh waters to permafrost and hot springs. As such, they can grow at a wide range of temperature, pH, salinity, and heavy-metal concentrations. Here we propose Exiguobacterium pavilionensis sp. nov. strain RW2 using phylogenetic, biochemical, and genome analyses. Isolated from a cold freshwater microbialite in Pavilion Lake, British Columbia, E. pavilionensis can grow between 4 and 50 °C, the broadest temperature range reported for the genus. The three Mbp circular genome includes a large set of core genes associated with stress responses to temperature, salinity and heavy metals that are conserved among all sequenced strains of Exiguobacterium spp., and which may explain their distribution across such a wide range of ecosystems. We also nominate potential pathways involved in carbonate precipitation (and therefore microbialite formation), as well as carotenoid biosynthesis that could lend the characteristic orange color to members of the genus. The unexpectedly high thermal tolerance of this cold-water bacterium, as well as its latent flagellum synthesis operons, suggest that this species may have had its evolutionary origins in a much warmer environment in which motility was important. These results provide further insight into the potential of Exiguobacterium to exploit a wide range of environmental conditions.

59 BASIC BIOLOGICAL SCIENCES↗

Glycerol Is an Osmoprotectant in Two Antarctic Chlamydomonas Species From an Ice-Covered Saline Lake and Is Synthesized by an Unusual Bidomain Enzyme

Glycerol, a compatible solute, has previously been found to act as an osmoprotectant in some marine Chlamydomonas species and several species of Dunaliella from hypersaline ponds. Recently, Chlamydomonas reinhardtii and Dunaliella salina were shown to make glycerol with an unusual bidomain enzyme, which appears to be unique to algae, that contains a phosphoserine phosphatase and glycerol-3-phosphate dehydrogenase. Here we report that two psychrophilic species of Chlamydomonas (C. spp. UWO241 and ICE-MDV) from Lake Bonney, Antarctica also produce high levels of glycerol to survive in the lake’s saline waters. Glycerol concentration increased linearly with salinity and at 1.3 M NaCl, exceeded 400 mM in C. sp. UWO241, the more salt-tolerant strain. We also show that both species expressed several isoforms of the bidomain enzyme. An analysis of one of the isoforms of C. sp. UWO241 showed that it was strongly upregulated by NaCl and is thus the likely source of glycerol. These results reveal another adaptation of the Lake Bonney Chlamydomonas species that allow them to survive in an extreme polar environment.

59 BASIC BIOLOGICAL SCIENCES↗

Energy and exergy analysis of a novel multiple-effect vapor chamber distillation system for high-salinity wastewater treatment

A novel modular thermally-driven multiple-effect vapor chamber distillation (MVCD) system is presented for compact and portable desalination applications. The MVCD system consists of several vapor chambers connected in series with the condenser section of the upstream vapor chambers serving as the evaporator section of the following effect. A heat transfer model accounting for the major thermal resistances was developed to predict the heat transfer and distilled water production rates. A mass transfer analysis was performed to evaluate the effect of the accumulation of the non-condensable gasses within the chambers. An exergy analysis was also conducted to quantify the efficiency of the system from the viewpoint of the second law of thermodynamics. It was found that for a fixed number of effects, increasing the hot-end temperature increased the distillation rate and decreased the second law efficiency. On the other hand, increasing the number of effects at a fixed hot-end temperature resulted in increased distillation rate and second law efficiency. The increased salinity of the feed water resulted in smaller distillation rates and greater second law efficiency. For all the cases, it was found that sensible heat recovery from the discharging fluids could improve the gained output ratio (GOR) and the second law efficiency by about 10%. Here, the quantitatively, at a hot-end temperature of 70°C, feed water salinity of 35 ppt and recovery ratio of 36%, the MVCD system with six effects and energy recovery from the discharging fluids yielded a GOR of 5.0 and a second law efficiency of 3.8%.

42 ENGINEERING↗

Salinity surveys using an airborne microwave radiometer

The Barnes PRT-5 infrared radiometer and L-band channel of the multifrequency microwave radiometer are used to survey the distribution of surface water temperature and salinity. These remote sensors were flown repetitively in November 1971 over the outflow of the Mississippi River into the Gulf of Mexico. Data reduction parameters were determined through the use of flight data obtained over a known water area. With these parameters, the measured infrared and microwave radiances were analyzed in terms of the surface temperature and salinity.

Paris, J. F.↗

Comparison of water immersion and saline infusion as a means of inducing volume expansion in man

The study compares the natriuresis induced by head-out water immersion to that of a standard saline infusion and assesses the relative effectiveness of these two techniques as volume determinants of renal sodium and water handling in humans in a seated posture. The data obtained show that the volume stimulus of immersion is identical to that of standard saline-induced extracellular fluid volume expansion (ECVE) in normal seated subjects. The ability of head-out water immersion to induce a natriuresis without a concomitant increase in total blood volume and with a decrease in body weight suggests that water immersion may be preferred as an investigative tool for assessing the effects of ECVE in man.

Epstein, M.↗

Effects of environmental changes on marsh vegetation with special reference to salinity

A literature survey primarily concerned with brackish and salt marshes located along the eastern coast of North America and the Gulf Coast was presented. The review concentrated upon the vegetation of the marshes, particularly in regard to distribution, composition, succession, and productivity. Special efforts were made to include major works concerned with the Louisiana and Mississipi coastal marshes. It appears that spring to early summer (weeks 18-34 of the year; April - mid-July) is the best period of time to categorize the communities. It is during this time of the year that the communities appear most stable in regard to species composition. This allows a strong correlation to be drawn between the salinity of the region and the dominant species of the community. As such, this would seem to be best period in which to sample the marsh via air or land for differences in vegetation and salinity.

Smalley, A. E.↗

Reversal of bedrest-induced orthostatic intolerance by lower body negative pressure and saline

Six healthy male volunteers underwent two 1-week periods of bedrest, each preceded and followed by 2-week control and recovery periods. The daily metabolic diet contained 150 mEq of sodium. Following one 7-day bedrest period, each man was subjected to LBNP at a level of -30 mm Hg for 4 hr while consuming 1000 ml of beef bouillon containing 154 mEq of sodium. After the other bedrest period, each man simply consumed the bouillon without LBNP treatment during 4 hr of continued bedrest. Measurements of plasma volume and orthostatic tolerance were made before and after each treatment period. After combined LBNP and saline therapy, plasma volume and response to LBNP testing showed a return to pre-bedrest levels. Saline consumption alone had a lesser effect. With continuation of bedrest in three subjects, the beneficial effects of these measures appeared to be largely gone after 18 hr.

Hyatt, K. H.↗

Distinguishing saline from nonsaline rangelands with Skylab imagery

A flight line in Starr County, Texas, was used to test the feasibility of distinguishing saline from nonsaline rangelands using very small scale (1:3,000,000), Skylab satellite imagery. Film optical density readings were made on six different films (four black-and-white, one conventional, and one infrared color) using various film/filter combinations. Differentiating between saline and nonsaline rangelands was possible by using microdensitometry on black-and-white Skylab imagery.

Everitt, J. H.↗

Remote sensing of the Chesapeake Bay plume salinity via microwave radiometry

The NASA-Langley-developed L-Band microwave radiometer was used to remotely measure sea surface salinity during the Chesapeake Bay plume studies. Obtained measurements of microwave brightness temperatures of the sea surface were combined with measurements of sea surface temperature obtained with an infrared radiometer and inverted to produce corresponding values of sea surface salinity. Results from the plume measurements, which indicate the southward extent of the plume along the Virginia-North Carolina coast, are presented and discussed. Additional measurements obtained for the Delaware Bay Mouth flight, and the James River-Shelf flight, are also discussed.

Kendall, B. M.↗

The role of sulfur in osmoregulation and salinity tolerance in cyanobacteria, algae, and plants

Organosulfur compounds are involved in osmoregulation and salinity tolerance in some cyanobacteria and photosynthetic eukaryotes. Glycinebetaine, the osmolyte of the halotolerant cyanobacterium, Aphanothece halophytica, requires the sulfonium compound. S-adenosyl-methionine (SAM) for its synthesis. Glutamate is the nitrogen source, SAM is the methyl carbon and serine the carbon backbone source of this unique osmolyte. Inhibitor studies suggest that photorespiration interacts with sulfur metabolism to control betaine synthesis in cyanobacteria. The limiting factor for SAM synthesis is formate from photorespiration. SAM is, in turn, the methyl donor for betaine synthesis from serine. The nitrogen component of serine is from glutamate. Betaine synthesis is hypothesized to be regulated via potassium. The biosynthesis of dimethyl-B-propiothetin (DMPT, which is the same as beta-dimethyl sulfonioprpionate) and diacylsulfoquinovosylglycerol were elucidated as having their roles in osmoregulation and salinity tolerance. The relation between these sulfolipids and the sulfur cycle was discussed.

Yopp, J. H.↗

Errors in radiometric remote sensing of sea-surface temperature and salinity

Techniques for remote measurement of sea-surface physical temperature and salinity using radiometric measurements from aircraft or satellite are reviewed. Studies have been conducted to determine the sensitivity of the errors in surface temperature and salinity to errors in the measured brightness temperatures using combinations of UHF, L, S, and C-band measurements. These investigations were made using values of conductivity, static dielectric constant, and relaxation time derived from the regression equations of Klein and Swift (1977). Results of the error sensitivity study are presented in the form of error contour plots which permit the calculation of errors in the estimation of the physical parameters for given errors in the raw radiometric measurements.

Britt, C. L., Jr.↗

Microbial mats in playa lakes and other saline habitats: Early Mars analog?

Microbial mats are cohesive benthic microbial communities which inhabit various Terra (Earth-based) environments including the marine littoral and both permanent and ephemeral (playa) saline lakes. Certain geomorphological features of Mars, such as the Margaritifer Sinus, were interpreted as ancient, dried playa lakes, presumably formed before or during the transition to the present Mars climate. Studies of modern Terran examples suggest that microbial mats on early Mars would have had the capacity to survive and propagate under environmental constraints that would have included irregularly fluctuating regimes of water activity and high ultraviolet flux. Assuming that such microbial communities did indeed inhabit early Mars, their detection during the Mars Rover Sample Return (MRSR) mission depends upon the presence of features diagnostic of the prior existence of these communities or their component microbes or, as an aid to choosing suitable landing, local exploration or sampling sites, geomorphological, sedimentological or chemical features characteristic of their playa lake habitats. Examination of modern Terran playas (e.g., the Lake Eyre basin) shows that these features span several orders of magnitude in size. While stromatolites are commonly centimeter-meter scale features, bioherms or fields of individuals may extend to larger scales. Preservation of organic matter (mats and microbes) would be favored in topographic lows such as channels or ponds of high salinity, particularly those receiving silica-rich groundwaters. These areas are likely to be located near former zones of groundwater emergence and/or where flood channels entered the paleo-playa. Fossil playa systems which may aid in assessing the applicability of this particular Mars analog include the Cambrian Observatory Hill Beds of the Officer Basin and the Eocene Wilkins Peak Member of the Green River Formation.

Bauld, John↗