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Temperature dependence of the biaxial modulus, intrinsic stress and composition of plasma deposited silicon oxynitride films

Silicon oxynitride films were deposited by plasma-enhanced chemical-vapor deposition. The elemental composition was varied between silicon nitride and silicon dioxide: SiO(0.3)N(1.0), SiO(0.7)N(1.6), SiO(0.7)N(1.1), and SiO(1.7)N(0.%). These films were annealed in air, at temperatures of 40-240 C above the deposition temperature (260 C), to determine the stability and behavior or each composition. the biaxial modulus, biaxial intrinsic stress, and elemental composition were measured at discrete intervals within the annealing cycle. Films deposited from primarily ammonia possessed considerable hydrogen (up to 38 at.%) and lost nitrogen and hydrogen at anneal temperatures (260-300 C) only marginally higher than the deposition temperature. As the initial oxygen content increased a different mechanism controlled the behavior or the film: The temperature threshold for change rose to approximately equal to 350 C and the loss of nitrogen was compensated by an equivalent rise in the oxygen content. The transformation from silicon oxynitride to silica was completed after 50 h at 400 C. The initial biaxial modulus of all compositions was 21-3- GPa and the intrinsic stress was -30 to 85 MPa. Increasing the oxygen content raised the temperature threshold where cracking first occurred; the two film compositions with the highest initial oxygen content did not crack, even at the highest temperature (450 C) investigated. At 450 C the biaxial modulus increased to approximately equal to 100 GPa and the intrinsic stress was approximately equal to 200 MPa. These increases could be correlated with the observed change in the film's composition. When nitrogen was replaced by oxygen, the induced stress remained lower than the biaxial strength of the material, but, when nitrogen and hydrogen were lost, stress-relieving microcracking occurred.

Harding, David R.↗

Ulysses observations of energetic ions over the south pole of the Sun

The Ulysses spacecraft began its journey out-of-the-ecliptic in February of 1992, when it encountered the planet Jupiter. In April of 1993, the spacecraft had reached 29 deg S, and from then on was completely immersed in the flow from the southern polar coronal hole. Accelerated ions were observed, recurring with a main peak once per solar rotation, with the intensity at the peak slowly decreasing with increasing latitude. This decrease continued to the end of 1993, when the spacecraft was at approximately 50 deg S. During the first three months of 1994 the intensity of the accelerated ions rose again, due either to an increase in magnetic activity on the sun or a reconfiguration of the heliospheric magnetic field. Recurrent accelerated ions were still being seen at the beginning of July 1994, when the spacecraft was at a latitude of 70 deg S, although with reduced intensity. The accelerated ions were no longer seen at latitudes higher than 70 deg S, the ion intensity staying constant at around the cosmic ray background level. This continued on until the highest latitude reached, 80.2 deg S, on 13 September 1994. The spacecraft then began its journey back towards lower latitudes, a small increase in the particle intensity being observed at the end of October whilst at approximately 72 deg S, and thereafter no more increases until the end of 1994, when the spacecraft was at approximately 45 deg S. We present interpretations for this asymmetry in latitude dependence.

Sanderson, T. R.↗

The 3-D effects in the long-term solar wind speed rise observed by Voyager 2 in early 1994

In early 1994, Voyager 2 at 42-43 AU near heliolatitude 10 deg S observed over a period of approximately 100 days a remarkable sequence of quasi-recurrent stream fronts, wherein the background (ambient) speed rose steadily from approximately 450 to approximately 550 km/s while the mean period of the streams decreased from the usual 25 days down to approximately 20 days. A qualitative explanation for this effect can be derived from IMP observations, which show that the amplitude of the stream structure at 1 AU increased monotonically in late 1993, concurrent with major secular evolution in the corona. The reduction in period, then, amounts to a doppler shift due to the progressive overtaking of successively faster streams in the sequence. Attempts to model this process quantitatively with 1-D dynamic simulations falter on three accounts: (1) the reduction in period is overestimated, (2) the simulation predicts many more fronts surviving to 43 AU than are observed by Voyager; (3) the density variations are much too large. It is argued that inclusion of the 3-D geometry in the simulation would resolve most all these shortcomings. Using a series of calculations executed with 1-D, 2-D, and 3-D MHD models of hypothetical tilted-dipole flows, we show that: (1) the radial propagation velocities of 3-D fronts are less than those of 1-D or 2-D fronts, owing to the tilt of (and increased shearing across) the interaction surfaces hence the overtaking rate of successive streams is reduced; (2) in a tilted-dipole geometry, the reverse fronts should largely disappear from the equatorial plane by 43 AU, effectively halving the number of fronts to be observed (see companion paper on predominance of forward fronts at Voyager); and (3) the density enhancements would be much smaller than predicted by a 1-D model.

Pizzo, V. J.↗

Reengineering legacy software to object-oriented systems

NASA has a legacy of complex software systems that are becoming increasingly expensive to maintain. Reengineering is one approach to modemizing these systems. Object-oriented technology, other modem software engineering principles, and automated tools can be used to reengineer the systems and will help to keep maintenance costs of the modemized systems down. The Software Technology Branch at the NASA/Johnson Space Center has been developing and testing reengineering methods and tools for several years. The Software Technology Branch is currently providing training and consulting support to several large reengineering projects at JSC, including the Reusable Objects Software Environment (ROSE) project, which is reengineering the flight analysis and design system (over 2 million lines of FORTRAN code) into object-oriented C++. Many important lessons have been learned during the past years; one of these is that the design must never be allowed to diverge from the code during maintenance and enhancement. Future work on open, integrated environments to support reengineering is being actively planned.

Pitman, C.↗

F/A-18A Inlet Flow Characteristics During Maneuvers with Rapidly Changing Angle of Attack

The performance and distortion levels of the right inlet of the F/A-18A High Alpha Research Vehicle were assessed during maneuvers with rapidly changing angle-of-attack at the NASA Dryden Flight Research Center, Edwards, California. The distortion levels were compared with those produced by current inlet-engine compatibility evaluation techniques. The objective of these analyses was to determine whether the results obtained for steady aerodynamic conditions were adequate to describe the inlet-generated distortion levels that occur during rapid aircraft maneuvers. The test data were obtained during 46 dynamic maneuvers at Mach numbers of 0.3 and 0.4. Levels of inlet recovery, peak dynamic circumferential distortion, and peak dynamic radial distortion of dynamic maneuvers for a General Electric F404-GE-400 turbofan engine were compared with estimations based on steady aerodynamic conditions. The comparisons were performed at equivalent angle-of-attack, angle-of-sideslip, and Mach number. Results showed no evidence of peak inlet distortion levels being elevated by dynamic maneuver conditions at high angle-of-attack compared with steady aerodynamic estimations. During sweeps into high angle-of-attack, the peak distortion levels of the dynamic maneuvers rarely rose to steady aerodynamic estimations. The dynamic maneuvers were shown to be effective at identifying conditions when discrete changes in inlet behavior occur.

Yuhas, Andrew J.↗

Hugh L. Dryden's Career in Aviation and Space: Monographs in Aerospace History - No. 5

Hugh Latimer Dryden led a life rich in paradox. Born in obsurity, he attained international prominence. Indifferent to self-advancement, he nonetheless rose to the pinnacle of the aeronautics profession and subsequently assumed a pivotal role in the initial period of space exploration. Although a research scientist of the first order, he nurtured within himself a profoundly spiritual outlook.

Gorn, Michael H.↗

Control of the Diurnal Pattern of Methane Emission from Emergent Aquatic Macrophytes by Gas Transport Mechanisms

Methane emissions from Typha latifolia (L.) showed a large mid-morning transient peak associated with rising light levels. This peak was also associated with a steep decline in lacunal CH, concentrations near the stem base. This pattern contrasted sharply with emissions from Peltandra virginica (L.) that gradually rose to a peak in the mid-afternoon corresponding to elevated air temperatures. Internal CH4 concentrations within P. virginica stems did not change significantly over the diurnal period. Stomatal conductance appeared to correlate directly with light levels in both plant types and were not associated with peak CH4 emission events in either plant. These patterns are consistent with a convective throughflow and diffusive gas ventilation systems for Typha and Peltandra, respectively. Further effects of the convective throughflow in T. latifolia were evident in the elevated CH4 concentrations measured within brown leaves as contrasted to the near ambient levels measured within live green leaves. Experimental manipulation of elevated and reduced CO2 levels in the atmosphere surrounding the plants and of light/dark periods suggested that stomatal aperture has little or no control of methane emissions from T. latifolia.

Whiting, Gary J.↗

A Photographic Study of Liquid Hydrogen Under Simulated Zero Gravity Conditions

The transient behavior of liquid hydrogen, under conditions of zero gravity, was studied photographically. The hydrogen was subjected to weightlessness by dropping a Dewar containing this liquid from a height of 9 feet. During the weightless period of approximately 3/4 second, the liquid rose along the walls of the Dewar into the original vapor space. The rise occurred at constant velocity for practically the entire duration of this period. Adhesive forces were concluded to be the primary cause of the liquid rise along the wall.

Brazinsky, Irving↗

Ethylene Production by Plants in a Closed Environment

Ethylene production by 20-sq m stands of wheat, soybean, lettuce and potato was monitored throughout growth and development in NASA's Controlled Ecological Life Support System (CELSS) Biomass Production Chamber. Chamber ethylene concentrations rose during periods of rapid growth for all four species, reaching 120 parts per billion (ppb) for wheat, 60 ppb for soybean, and 40 to 50 ppb for lettuce and potato. Following this, ethylene concentrations declined during seed fill and maturation (wheat and soybean), or remained relatively constant (potato). Lettuce plants were harvested during rapid growth and peak ethylene production. The highest ethylene production rates (unadjusted for chamber leakage) ranged from 0.04 to 0.06 ml/sq m/day during rapid growth of lettuce and wheat stands, or approximately 0.8 to 1.1 ml/g fresh weight/h. Results suggest that ethylene production by plants is a normal event coupled to periods of rapid metabolic activity, and that ethylene removal or control measures should be considered for growing crops in a tightly closed CELSS.

Wheeler, R. M.↗

Potentiation of Hormonal Responses to Hemorrhage and Fasting, but not Hypoglycemia in Conscious Adrenalectomized Rats

Bilateral adrenalectomy (ADRX) in rats removes the source of two major stress-responsive hormones, corticosterone and epinephrine. To test how ADRX rats with-stand stress, we performed the following experiments in adult male rats provided with indwelling femoral arterial and venous cannulae and either ADRX or sham-adrenalectomized (Sham) 3 days later and given 0.5% NaCl to drink. Five to 6 days after adrenal surgery the rats were studied after either a 15 ml/kg.5 min hemorrhage or after an overnight fast followed by insulin-induced hypoglycemia. In fed unstressed ADRX rats, basal mean arterial blood pressure was slightly decreased; heart rate was increased; blood volume, vasopressin, and oxytocin concentrations were not different from sham values; and renin and norepinephrine were significantly elevated. The recovery of arterial pressure after hemorrhage in the ADRX rats was similar to that in the sham group over a 5-h period; however, the responses of vasopressin and oxytocin were significantly greater, and those of renin and norepinephrine were markedly potentiated in the ADRX group. Heart rate recovered faster in the ADRX group and was elevated, compared to the sham value, for most of the 5-h period. Restitution of blood volume was attenuated in the ADRX group, although the restitution of plasma protein was not different between the groups. A significant difference in the change in plasma osmolality between groups after hemorrhage may account for the attenuated restitution of blood volume. After an overnight fast, which reduced blood volume in both groups of rats, the plasma renin concentration rose still further in ADRX rats; the differences in other measured variables observed between fed ADRX and sham groups remained the same. The insulin-induced 50% decrease in glucose caused minor effects on arterial blood pressure and heart rate and occasioned responses in renin and norepinephrine of similar magnitudes in the two groups. We conclude that in the absence of the adrenals, rats restore arterial pressure after hemorrhage remarkably well through potentiation of the responses of other vasoactive neural and hormonal systems. In these studies the marked potentiation of the renin response suggests that the renin-angiotensin system may be important in the maintenance of arterial blood pressure after reductions in blood volume.

Darlington, Daniel N.↗

Polar Vortex Conditions during the 1995-96 Artic Winter: Meteorology and MLS Ozone

The 1995-96 northern hemisphere (NH) 205 winter stratosphere was colder than in any of the previous 17 winters, with lower stratospheric temperatures continuously below the type 1 (primarily HN03) polar stratospheric cloud (PSC) threshold for over 2 1/2 months. Upper tropospheric ridges in late Feb and early Mar 1996 led to the lowest observed NH lower stratospheric temperatures, and the latest observed NH temperatures below the type 2 (water ice) PSC threshold. Consistent with the unusual cold and chemical processing on PSCS, Upper Atmosphere Research Satellite (UARS) MLS observed a greater decrease in lower stratospheric ozone (03) in 1995-96 than in any of the previous 4 NH winters. 03 decreased throughout the vortex over an altitude range nearly as large as that typical of the southern hemisphere (SH). The decrease between late Dec 1995 and early Mar 1996 was about 2/3 of that over the equivalent SH period. As in other NH winters, temperatures in 1996 rose above the PSC threshold before the spring equinox, ending chemical processing in the NH vortex much earlier than is usual in the SH. A downward trend in column 03 above 100 hPa during Jan and Feb 1996 appears to be related to the lower stratospheric 03 depletion.

Manney, G. L.↗

Interface structure of co-rotating interaction regions

Plasma and particle observations on Ulysses during its passes through the southern and northern heliosphere have revealed that, inside the streamer belt, the large-scale structure of the quiet global heliosphere is dominated by corotating interaction regions (CIRs). Therefore, considerable attention is now being given to the internal plasma structure of CIRs, and in particular, to the manifestations of the stream interfaces that should mark their origins as interactions between low speed solar wind (in the low-latitude streamer belt) and high speed solar wind (from the equatorial extensions of the high latitude polar coronal holes). The SWICS and HI-SCALE experiments on Ulysses combine plasma and energetic particle measurements that are of considerable utility for such studies because, between them, they cover the proton energy range from 10 eV to 5 MeV. These measurements are used, together with magnetic field data, to study the remarkable series of CIRs that occurred during the period beginning July 1992 and the end of 1993 as Ulysses rose from the ecliptic to a southern heliographic latitude of 48 deg. The structure of the regions between the forward and reverse shocks were previously analyzed in terms of the proton specific entropy argument log that should exhibit a discontinuous jump at the stream interface. It was claimed that the stream interface, defined with respect to specific entropy, is also associated with a discontinuity in energetic proton intensities. The energetic particle data (greater than 60 keV) and how they were ordered with respect to interfaces and with respect to the magnetic field were examined.

Ogilvie, K. W.↗

XTE J1946+274 = GRO J1944+26

C. A. Wilson, M. H. Finger, R. S. Wilson, and D. M. Scott, Marshall Space Flight Center, NASA, report for the BATSE team: "Pulsations from a previously-uncatalogued x-ray pulsar in the Vul-Cyg region have been detected with BATSE in the energy band 20-50 keV from Sept. 8 through Sept. 14. A preliminary location (95-percent confidence) is bounded by R.A. = 19h 34m to 19h 54m and Decl. = +22o.5 to +30o.5 (equinox 2000.0). GRO J1944+26 rose from a 20-50-keV rms pulsed flux of < 15 mCrab on Sept. 7 to 27 +/- 3 mCrab on Sept. 13. Observations between Sept. 8 and 14 are consistent with a barycentric pulse frequency of 0.06315331 (6) Hz on Sept. 11.0 UT, with a frequency derivative of 2.2(2) x 10(exp -12) Hz/s. The pulse profile in the band 20-50 keV has a single asymmetric peak.

Smith, D. A.↗

A Flexible Statechart-to-Model-Checker Translator

Many current-day software design tools offer some variant of statechart notation for system specification. We, like others, have built an automatic translator from (a subset of) statecharts to a model checker, for use to validate behavioral requirements. Our translator is designed to be flexible. This allows us to quickly adjust the translator to variants of statechart semantics, including problem-specific notational conventions that designers employ. Our system demonstration will be of interest to the following two communities: (1) Potential end-users: Our demonstration will show translation from statecharts created in a commercial UML tool (Rational Rose) to Promela, the input language of Holzmann's model checker SPIN. The translation is accomplished automatically. To accommodate the major variants of statechart semantics, our tool offers user-selectable choices among semantic alternatives. Options for customized semantic variants are also made available. The net result is an easy-to-use tool that operates on a wide range of statechart diagrams to automate the pathway to model-checking input. (2) Other researchers: Our translator embodies, in one tool, ideas and approaches drawn from several sources. Solutions to the major challenges of statechart-to-model-checker translation (e.g., determining which transition(s) will fire, handling of concurrent activities) are retired in a uniform, fully mechanized, setting. The way in which the underlying architecture of the translator itself facilitates flexible and customizable translation will also be evident.

Rouquette, Nicolas↗

Iron, Manganese and Copper Release from Synthetic Hydroxyapatite

Kinetic stir-flow dissolution experiments were performed on iron- (Fe-SHA), manganese- (Mn-SHA), and copper- (Cu-SHA) containing synthetic hydroxyapatites. Solution treatments consisted of de-ionized water, citric acid and DTPA. Initially, Mn concentrations were higher than Cu concentrations and Fe concentrations were the lowest in all treatments. At later times Mn and Cu concentrations dropped in the DTPA treatment while Fe rose to the concentration similar to Mn and Cu. At all times, metal release concentrations in the water and citric acid treatments followed the trend of Mn>Cu>Fe. Rietveld analysis of x-ray diffraction data and ^31P NMR indicated that the metals substituted for Ca in the SHA structure. However, EPR data suggested that a metal (hydr)oxide phase existed either on the SHA surface or between the SHA crystallites. The metal concentration trend of Mn>Cu>Fe suggested that the initial solution metal concentrations are dependent on the dissolution of (hydr)oxides from SHA surfaces or between SHA crystallites. Similar metal concentrations at later times in the DTPA experiments suggests that metal concentrations were controlled by the release of Mn, Cu, or Fe from the SHA structure.

Sutter, B.↗

The Precambrian Biogeochemical Carbon Isotopic Record: Contributions of Thermal Versus Biological Processes

Superplumes offer a new approach for understanding global C cycles. Isotopes help to discern the impacts of geological, environmental and biological processes ujpun the evolution of these cycles. For example, C-13/C-12 values of coeval sedimentary organics and carbonates give global estimates of the fraction of C buried as organics (Forg), which today lies near 0.2. Before Oxygenic photosynthesis arose, our biosphere obtained reducing power for biosynthesis solely from thermal volatiles and rock alteration. Thus Forg was dominated by the mantle redox state, which has remained remarkably constant for greater than Gy. Recent data confirm that the long-term change in Forg had been small, indicating that the mantle redox buffer remains important even today. Oxygenic photosynthesis enabled life to obtain additional reducing power by splitting the water molecule. Accordingly, biological organic production rose above the level constrained by the mantle-derived flux of reduced species. For example, today, chemoautotrophs harvesting energy from hydrothermal emanations can synthesize at most between 0.2 x 10(exp 12) and 2x 10(exp 12) mol C yr-1 of organic C globally. In contrast, global photosynthetic productivity is estimated at 9000 x 10(exp 12) mol C yr-1. Occasionally photosynthetic productivity did contribute to dramatically -elevated Forg values (to 0.4 or more) as evidenced by very high carbonate C-13/C-12. The interplay between biological, tectonic and other environmental factors is illustrated by the mid-Archean to mid-Proterozoic isotopic record. The relatively constant C-13/C-12 values of Archean carbonates support the view that photosynthetically-driven Forg increases were not yet possible. In contrast, major excursions in C-13/C-12, and thus also in Forg, during the early Proterozoic confirmed the global importance of oxygenic photosynthesis by that time. Remarkably, the superplume event at 1.9 Ga did not trigger another major Forg increase, despite the favorable conditions for organic burial that were evidenced by elevated sea levels and higher black shale abundances. Perhaps those superplume-rated processes that favored enhanced organic burial were offset by the ability of mantle-derived redox buffering, which was enhanced during the superplume event, to limit excursions in Forg.

DesMarais, David J.↗

The End of Comet Shoemaker-Levy 9

The pieces of the former Comet Shoemaker-Levy 9 struck Jupiter during the week of July 16-22 1994. We divide the general impact phenomena into four phases: (1) Atmospheric entry should have been accompanied by an entry flash, probably only detectable by the Galileo spacecraft. (2) Aerodynamic forces cause the impactor to explode. We show that the apparent altitude of the explosions is consistent with the analytical model proposed by Zahnle and Chyba et al, with numerical models calculated by Mac Low and Zahnle and Yabe et al., and with dynamically-based estimates of fragment masses Suggested by Scotti and Melosh and Asphaug and Benz. (3) The explosion produces a fireball that propagates most quickly up the wake, as predicted by Takata et al. and Crawford et al. The fireball's luminosity fades over a timescale of 30-60 seconds. (4) Each explosion produced a plume that reached thousands of kilometers above the cloud-tops. The plumes appear to have been dusty and SO illuminated when they reached sunlight. The plumes rose and fell over a period of ten or twenty minutes, governed by the simple laws of ballistics. When plume material (dust) fell back on the atmosphere it was reheated and glowed brightly in the thermal infrared for a period of order ten to twenty minutes; a large fraction of the impact energy was spent thus. Geometry introduces additional factors that complicate interpretation of the observed light curves.

Zahnle, K. J.↗

Tracking Virtual Trajectories

Current models of smooth pursuit eye movements assume that it is largely driven by retinal image motion. We tested this hypothesis by measuring pursuit of elliptical motion (3.2s, 0.9 Hz, 1.4 deg x 1.6 deg, 4 randomly interleaved phases) of either a small spot ("real" motion) or of a line-figure diamond viewed through apertures such that only the motion of four isolated oblique line segments was visible ("virtual" motion). Each segment moved sinusoidally along a linear trajectory yet subjects perceived a diamond moving along an elliptical path behind the aperture. We found, as expected, that real motion produced accurate tracking (N = 2) with mean gain (over horizontal and vertical) of 0.9, mean phase of -6 deg (lag), mean relative phase (H vs V) of 90 +/- 8 deg (RMS error). Virtual motion behind an X-shaped aperture (N= 4 with one naive) yielded a mean gain of 0.7, mean phase of -11 deg, mean relative phase of 87 +/- 15 deg. We also measured pursuit with the X-shaped aperture using a higher segment luminance which prevents the segments from being grouped into a coherently moving diamond while keeping the motion otherwise identical. In this incoherent case, the same four subjects no longer showed consistent elliptical tracking (RMS error in relative phase rose to 60 deg) suggesting that perceptual coherence is critical. Furthermore, to rule out tracking of the centroid, we also used vertical apertures so that all segment motion was vertical (N = 3). This stimulus still produced elliptical tracking (mean relative phase of 84 +/- 19 deg), albeit with a lower gain (0.6). These data show that humans can track moving objects reasonably accurately even when the trajectory can only be derived by spatial integration of motion signals. Models that merely seek to minimize retinal or local stimulus motion cannot explain these results.

Stone, Leland S.↗