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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Laboratory studies of UV emissions of H2 by electron impact - The Werner- and Lyman-band systems

The vacuum ultraviolet electron-impact-induced fluorescence emissions of H2 were studied for the Lyman and Werner band systems in the range of 120-170 nm, using an optical system containing a photomultiplier and a spectrometer, over an energy range from threshold to 400 eV. The emission cross sections for the Lyman and Werner transitions at 100 eV are determined. The cross-section ratio is in excellent agreement with theoretical calculations and experimental data for the optical oscillator strengths. The cross-section for cascading to the B state is stated as a percentage of the total emission cross section at both 100 and 300 eV, increasing substantially at 20 eV. The vibrational population distribution of the B state is found to be a function of electron-impact energy as the importance of cascading relative to direct excitation changes with electron-impact energy.

Ajello, J. M.↗
NASA NTRS1982

Effective photodissociation cross sections for molecular oxygen and nitric oxide in the Schumann-Runge bands

Accurate calculations of the atmospheric opacity and the photodissociation rate of molecular oxygen in the Schumann-Runge bands (175-205) are necessary for modeling chemistry in the terrestrial upper atmosphere. The present investigation is concerned with a single simple parameterization of effective cross sections which can be used to calculate both O2 opacity and dissociation rates. Use is made of a zenith angle dependent factor which accounts for variations shown in detailed calculations. The conducted analysis is based on the results of Frederick and Hudson (1980). Attention is given to molecular oxygen effective cross sections and nitric oxide effective cross sections. It is found that the depth of the atmosphere to which solar radiation in the 175-200 nm spectral region penetrates is a sensitive function of the rotational line widths in the Schumann-Runge bands. The oscillator strength for each band measures the cross section integrated over the band while the line width determine how the absorption is distributed in wavenumber.

Allen, M.↗
NASA NTRS1982

Molecular processes in comets

Potential energy curves for the two lowest 2 sigma- states of OH are computed at the configuration-interaction level using four different basis sets. Electronic transition dipole moments connecting the excited 1 2 sigma- and 2(D) 2 sigma- states with each other and with he ground X2pi state are presented as functions of internuclear distance. The theoretical absorption oscillator strengths for the D 2 sigma-(v prime=0) reverser to X 2pi (v prime prime=0) transition are in good agreement with the empirical value derived from astronomical measurements. The photodissociation cross sections for absorption rom the v prime prime=0,1, and levels of the ground state into the continuum of the 1 2 sigma- state are calculated, and the interstellar and cometary photodissociation rates are derived.

Dalgarno, A.↗
NASA NTRS1982

Electron impact cross sections for the 2,2P state excitation of lithium

Electron impact excitation of the 2p 2P state of Li was studied at 10, 20, 60, 100, 150 and 200 eV. Relative differential cross sections in the angular range 3-120 deg were measured and then normalized to the absolute scale by using the optical f value. Integral and momentum transfer cross sections were obtained by extrapolating the differential cross sections to 0 deg and to 180 deg. The question of normalizing electron-metal-atom collision cross sections in general was examined and the method of normalization to optical f values in particular was investigated in detail. It has been concluded that the extrapolation of the apparent generalized oscillator strength (obtained from the measured differential cross sections) to the zero momentum transfer limit with an expression using even powers of the momentum transfer and normalization of the limit to the optical f value yields reliable absolute cross sections.

Vuskovic, L.↗
NASA NTRS1984

A search for interstellar H2O(+) in diffuse clouds

Searches for H2O(+) toward HD 187982, Zeta Oph, O micron Per, and Zeta Per have yielded significant upper limits for H2O(+) when compared with existing models for similar lines of sight. Using available oscillator strength data, the column density for HD 187982, for example, cannot exceed 3 x 10 to the 12th per sq cm H2O(+) molecules. The most sensitive measurement for H2O(+) toward Zeta Oph is apparently limited by a blend with upper atmospheric H2O(+), which is also present in the HD 187982 spectrum.

Federman, S. R.↗
NASA NTRS1984

Interstellar magnesium abundances

An improved evaluation of the Mg II 1240 A doublet oscillator strength is used in conjunction with recently published Copernicus observations to derive accurate Mg II column densities toward 74 stars. These imply an average of 40 percent of interstellar magnesium is in the gaseous phase. Magnesium depletion is examined as a function of various interstellar extinction and density parameters, and the results are briefly discussed in terms of current depletion theories.

Murray, M. J.↗
NASA NTRS1984

Radiative lifetimes of the second negative system of O2(+)

The dipole moment of the A2Pi(u)-X2Pi(g) transition of O2(+) is calculated as a function of internuclear distance using ab initio methods. The band absorption oscillator strengths and band transition probabilities of the second negative system are derived and the resulting lifetimes are compared with experimental data. The high-lying v double prime levels of the ground state may decay into low-lying v prime levels of the excited state. The corresponding radiative lifetimes are calculated.

Wetmore, R. W.↗
NASA NTRS1984

On the need for spectroscopic data in ultraviolet stellar spectral synthesis calculations

A general discussion of the quality of spectroscopic data for ultraviolet (less than 3000 A) spectral synthesis calculations is presented. It is pointed out that progress in the generation of complete and accurate lists of atomic lines, and in the computation and measurement of accurate transition probabilities of the spectra of many elements is lagging behind current and near-term observational capabilities. Theoretical syntheses of the line profiles in the spectra of three middle-to-late B type stars (Pi Cet, 134 Tau, and vCap) are computed. The computations are found to be complicated and ambiguous due to the low accuracy of the oscillator strengths used in the analysis. Some characteristics of star-to-star variations in elemental abundances are discussed.

Adelman, S. J.↗
NASA NTRS1984

Studies of the chemistry of vibrationally and electronically excited species in planetary upper atmospheres

The vibrational distribution of O2(+) in the atmospheres of Venus and Mars was investigated to compare with analogous values in the Earth's atmosphere. The dipole moment of the Z(2) Pi sub u - X(2) Pi sub g transition of O2(+) is calculated as a function of internuclear distance. The band absorption oscillator strengths and band transition probabilities of the second negative system are derived. The vibrational distribution of O2(+) in the ionosphere of Venus is calculated for a model based on data from the Pioneer Venus neutral mass spectrometer.

Fox, J. L.↗
NASA NTRS1984

Fundamental Equations of the LIF Hydroxyl Measurements, Appendix a

The equation relating OH concentration to the observed detector count rate for a given laser flux is defined. That equation, which will be referred to henceforth as the central equation for absolute sensitivity, will be cast in terms of standard spectroscopic quantities such as oscillator strengths, Hoenl-London factors, rotational and vibrational quantum numbers, etc., such that it may be tested directly under laboratory conditions. The working expressions used by each of the OH laser induced fluorescence (LIF) groups will be related to this central equation, thereby establishing a common language for the comparison of experimental results and the definition of LIF system performance. The relevant structural details of the OH radical via a spectroscopic description of the energy levels and transitions employed in the LIF method are detailed. The central equation relating observed count rate to absolute concentration will be derived, and that equation will be related to the observed quantities cited by each of the experimental groups engaged in the measurement of OH in the Earth's atmosphere.

Source record↗
NASA NTRS1984

Absolute OH absorption cross sections (for lidar measurements)

Experimental data are employed to calculate absorption cross sections for several rotational lines in the OH A-X system. The cross sections are computed as functions of the spectral and line widths and temperature of a laser beam, and account for lifetimes and branching ratios. Detection limits for the P1(2) transition of the (1,0) band were examined. The oscillator strengths and cross-sections obtained are important for quantifying OH concentrations in the stratosphere from lidar return signals.

Mcgee, T. J.↗
NASA NTRS1984

The detection of the FlPi(u)-XlSigma(+)g system of diatomic carbon toward X Persei

The 0-0 vibrational band of the F1Pi(u)-X1Sigma(+)g electronic system of C2 has been detected with the IUE in the interstellar medium along the line of sight toward X Per. A column density of 3 (+ or - 1) x 10 to the 12th/f(00) per sq cm was derived by a profile fitting method. The lower limit for 0-0 band oscillator strength was determined from a comparison of the upper limits of observations of the A-X and D-X systems, and an excitation temperature of 40 K was also obtained from the profile fitting. A statistical calculation of the level population with radiative pumping shows that the 0-0 band profile corresponds to a range of values for kinetic temperature, density, and near-IR radiation. An upper limit of 50 K for kinetic temperature was determined from the statistical equilibrium analysis.

Lien, D. J.↗
NASA NTRS1986

The abundance of interstellar sulphur and zinc in high density sight-lines

On the basis of early absorption line studies of individual lines of sight with the Copernicus satellite, chlorine, sulphur and zinc were classed together as elements which showed little or no depletion, relative to hydrogen, in the interstellar medium. The abundances of other less volatile elements, such as Fe and Mg were found to vary widely from one sight-line to another with gas-phase abundances in some cases being orders of magnitude below their solar counterparts. Detailed studies are reported of the depletion/density behavior of two other volatile elements which were previously considered to be virtually undepleted, S and Zn, using equivalent width data from both Copernicus and IUE observations. The results provide further evidence that the established dependence of depletion on n bar (H) extends to volatile elements and show that their use as tracers of metallicity, or for estimating hydrogen column densities, may lead to large errors in sight-lines through dense regions. It now appears that such elements may take part in the surface chemistry of grains and be important constituents of grain mantle material, although they probably do not contribute significantly to the bulk mass of grains. Due to the very similar atomic masses and ionization potentials of sulphur and phosphorous, the thermal velocity distributions of the singly ionized species of these elements in interstellar clouds should be very similar. However, a comparison of Doppler widths (b-values) derived for SIT and PIT in the same sight-lines from the Bohlin et al Copernicus equivalent width measurements has revealed an unexpected systematic discrepancy of a factor of approx. 1.7. This Discrepancy indicates that the normally adopted oscillators strengths of the PII lambda lambda 1153 and 1302 A lines may require revision.

Harris, A. W.↗
NASA NTRS1986

Differential electron scattering cross sections for the first optically forbidden and resonance transitions in Mg II, Zn II and Cd II

Differential electron scattering cross sections have been measured for dipole-forbidden and resonance transitions in Mg II, Zn II and Cd II in the angular range theta = 4-17 deg at 50 eV. These provide the first recorded angular distributions for an optically forbidden transition. It is found that while the cross section for excitation of the 4s (2)S-3d(9)4s(2) (2)D transition in Zn II is small, those for the 3s (2)S-3d (2)D, 4s (2)S (unresolved lines) in Mg II, and the 5s (2)S-4d(9)5s(2) D in Cd II are comparable in magnitude with the cross sections for resonance excitation. In addition, for Cd II it is found that the allowed and forbidden transitions have very similar angular distributions, and it is proposed that excitation to the 2D state may be dominated by a virtual 'double-dipole' transition via the 2P state. Also, the total excitation cross section of the resonance 2P state in Cd II is a factor of four higher than that predicted by the Gaunt factor approximation, suggesting that the accepted value for the oscillator strength may be too low.

Williams, I. D.↗
NASA NTRS1986

The 1088 A feature toward reddened stars

An analysis of the interstellar feature near 1088 A in spectra obtained with the Copernicus satellite suggests that neutral chlorine is the absorber. The mean wavelength, as determined from 15 lines of sight, of 1088.052 + or - 0.023 A compares favorably with the chlorine line at 1088.062 A. A strong correlation with Cl I 1347 A indicates an oscillator strength for 1088 A of 0.04. Above a threshold at N(H2) of roughly 10 to the 19th/sq cm, the equivalent width of 1088 A varies approximately with N(H2). The variation with H2 is similar to the variation of Na I and C I with H2.

Federman, S. R.↗
NASA NTRS1986

Quantitative photoabsorption and fluorescence study of H2O and D2O at 50-190 nm

The photoabsorption cross sections and the fluorescence quantum yields of H2O and D2O were measured in the 50-190 nm region using synchrotron radiation as a light source. The oscillator strengths for the Rydberg states of H2O and D2O were determined from the absorption cross sections measured. The processes for the production of fluorescence from the excited species H(asterisk) (n greater than 2), D(asterisk) (n greater than 2), OH(asterisk) (A) and OD(asterisk) (A) are discussed. The upper limit for the dissociation energy of D(D-OD) was determined, from the threshold of the OD(A-X) fluorescence, to be 5.14 + or - 0.01 eV. The upper limit for the cross section of visible fluorescence from the excited H2O(+) ions was determined to be 2 x 10 to the -19th sq cm. A comparison between the photoexcitation spectra of H2O and D2O is made.

Lee, L. C.↗
NASA NTRS1987

Opacity project - Astrophysical and fusion applications

An overview is presented of a project to calculate large quantities of accurate atomic data for radiative processes of importance in the precise determination of opacities in stellar atmospheres, and for astrophysical and laboratory applications in general. Work is in progress on the oscillator strengths, photoionization cross sections, damping constants, etc., for all atoms and ions in hydrogen through neon isoelectronic sequences going up to iron.

Pradhan, A. K.↗