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At least 325 records · Page 18

Carbon Life Cycle Analysis of CO 2 -EOR for Net Carbon Negative Oil (NCNO) Classification (Final Report)

This final report summarizes the work that was conducted to achieve the project’s general objective of developing a clear and repeatable methodology to determine whether the oil produced in a conventional CO 2 enhanced oil recovery (CO 2 -EOR) operation can be classified as Net Carbon Negative Oil (NCNO). The report also summarizes the reservoir mass accounting methodology and the monitoring, verification, and accounting (MVA) methodology, which are critical elements that support the general objective and were conceived as project goals. Because the purpose is to classify the EOR product (crude oil) and not the EOR project itself, and as the rate of crude oil production varies significantly with time, the methodology uses a novel dynamic carbon lifecycle analysis (d-LCA) that links instant energy demand and associated greenhouse gas (GHG) emissions to instant operational performance. The EOR operational performance is assessed through CO 2 utilization rates, which relate usage of CO 2 to oil production This dynamic method provides a better understanding of the evolution of the environmental impact (CO 2 emissions) and mitigation (geologic CO 2 storage) associated with an expanded carbon capture, utilization and storage (CCUS) system, from start to closure of operations. The dynamic interplay between operational and environmental performance forms the basis of our CCUS technology analysis. The LCA part of the work is meant to complement previous NETL LCA work, and so it focused on EOR/storage efficiency, its variability through time, and the impact of this variability on LCA results. The environmental impact of the CCUS system was assessed for 3 system boundaries: (1) gate-to-gate, (2) gate-to-grave, and (3) cradle-to-grave. The environmental impact was also assessed considering the electricity displacement from other generation facilities. Another goal of our study was to use results to make recommendations on EOR field development strategies that are conducive to producing NCNO. Because field operational strategies have a significant impact on reservoir engineering parameters that affect both CO 2 storage and oil production (e.g., sweep efficiency, flood conformance, fluid saturation distribution), we conducted a scenario analysis that assesses the operational and environmental performance of four common and novel CO 2 -EOR field development strategies. Results show that all CO 2 -EOR evaluated scenarios start operating with a negative carbon footprint and, years into the project, transition into operating with a positive carbon footprint. Having achieved a result that proves that all CO 2 -EOR operations produce NCNO during the first years of production is critical in the context of the urgency of climate change mitigation. Transition points are significantly different in each scenario. ii In a cradle-to-grave CCUS system, if the capture facility displaces a conventional power source and credits are added for displacement, the adverse impact caused by the system expansion not only is reversed but transformed into a significant environmental benefit. The effect of the displacement more than compensates the emissions associated with the electricity generation requirements for the production of CO 2 , as much more electricity will be displaced. Results provide an understanding of the evolution of the system’s net carbon balance of all four field development strategies studied. This information can be useful to CO 2 -EOR operators seeking value in storing more CO 2 through a carbon credit program (e.g., the 45Q federal carbon credit program). Most importantly, this study serves as confirmation that CO 2 -EOR can be operationally designed to both enhance oil production and reduce greenhouse gas emissions to the atmosphere.

02 PETROLEUM↗

Assessment of the Deepwater Horizon oil spill impact on Gulf coast microbial communities

One of the major environmental concerns of the Deepwater Horizon oil spill in the Gulf of Mexico was the ecological impact of the oil that reached shorelines of the Gulf Coast. Here we investigated the impact of the oil on the microbial composition in beach samples collected in June 2010 along a heavily impacted shoreline near Grand Isle, Louisiana. Successional changes in the microbial community structure due to the oil contamination were determined by deep sequencing of 16S rRNA genes. Metatranscriptomics was used to determine expression of functional genes involved in hydrocarbon degradation processes. In addition, potential hydrocarbon-degrading Bacteria were obtained in culture. The 16S data revealed that highly contaminated samples had higher abundances of Alpha- and Gammaproteobacteria sequences. Successional changes in these classes were observed over time, during which the oil was partially degraded. The metatranscriptome data revealed that PAH, n-alkane, and toluene degradation genes were expressed in the contaminated samples, with high homology to genes from Alteromonadales, Rhodobacterales, and Pseudomonales. Notably, Marinobacter (Gammaproteobacteria) had the highest representation of expressed genes in the samples. A Marinobacter isolated from this beach was shown to have potential for transformation of hydrocarbons in incubation experiments with oil obtained from the Mississippi Canyon Block 252 (MC252) well; collected during the Deepwater Horizon spill. The combined data revealed a response of the beach microbial community to oil contaminants, including prevalence of Bacteria endowed with the functional capacity to degrade oil.

16S rRNA gene↗

Oil Hydrocarbon Degradation by Caspian Sea Microbial Communities

The Caspian Sea, which is the largest landlocked body of water on the planet, receives substantial annual hydrocarbon input from anthropogenic sources (e.g., industry, agriculture, oil exploration, and extraction) and natural sources (e.g., mud volcanoes and oil seeps). The Caspian Sea also receives substantial amounts of runoff from agricultural and municipal sources, containing nutrients that have caused eutrophication and subsequent hypoxia in the deep, cold waters. The effect of decreasing oxygen saturation and cold temperatures on oil hydrocarbon biodegradation by a microbial community is not well characterized. The purpose of this study was to investigate the effect of oxic and anoxic conditions on oil hydrocarbon biodegradation at cold temperatures by microbial communities derived from the Caspian Sea. Water samples were collected from the Caspian Sea for study in experimental microcosms. Major taxonomic orders observed in the ambient water samples included Flavobacteriales, Actinomycetales, and Oceanospirillales. Microcosms were inoculated with microbial communities from the deepest waters and amended with oil hydrocarbons for 17 days. Hydrocarbon degradation and shifts in microbial community structure were measured. Surprisingly, oil hydrocarbon biodegradation under anoxic conditions exceeded that under oxic conditions; this was particularly evident in the degradation of aromatic hydrocarbons. Important microbial taxa associated with the anoxic microcosms included known oil degraders such as Oceanospirillaceae. This study provides knowledge about the ambient community structure of the Caspian Sea, which serves as an important reference point for future studies. Furthermore, this may be the first report in which anaerobic biodegradation of oil hydrocarbons exceeds aerobic biodegradation.

microbial ecology↗

Determination of Carbonyl Functional Groups in Bio-oils by Potentiometric Titration: The Faix Method

We know that carbonyl compounds, present in bio-oils, are responsible for bio-oil property changes upon storage and during upgrading. Specifically, carbonyls cause an increase in viscosity (often referred to as 'aging') during storage of bio-oils. As such, carbonyl content has previously been used as a method of tracking bio-oil aging and condensation reactions with less variability than viscosity measurements. In addition, carbonyls are also responsible for coke formation in bio-oil upgrading processes. Given the importance of carbonyls in bio-oils, accurate analytical methods for their quantification are very important for the bio-oil community. Potentiometric titration methods based on carbonyl oximation have long been used for the determination of carbonyl content in pyrolysis bio-oils. Here, we present a modification of the traditional carbonyl oximation procedures that results in less reaction time, smaller sample size, higher precision, and more accurate carbonyl determinations. And while traditional carbonyl oximation methods occur at room temperature, the Faix method presented here occurs at an elevated temperature of 80 degrees C.

09 BIOMASS FUELS↗

Diurnal Pattern of Leaf, Flower and Fruit Specific Ambient Volatiles above an Oil Palm Plantation in Pará State, Brazil

Oil palm plantations are rapidly expanding in the tropics because of insatiable global demand for fruit oil to be used in food, biofuels and cosmetics. Here we show that three tissue-specific volatiles can be quantified in ambient air above an African-American hybrid oil palm plantation in Brazil and linked photosynthesis (isoprene), floral scent (estragole), and for the first time, fruit oil processing (6-methyl-5-hepten-2-one, MHO). Plant enclosure techniques verified their tissue specific emission sources with ambient concentrations displaying distinct diurnal patterns above the canopy. Isoprene concentrations were near zero at night, but dramatically increased during the day while estragole showed elevated concentrations at night suggesting a light-independent, temperature-driven emission pattern from flowers. MHO also showed elevated concentrations at night and both estragole and MHO increased during the day. Our observations demonstrate that the African-American oil palm hybrid is strong isoprene emitter and suggest that MHO is a specific oxidation product of lycopene released during the industrial processing of palm oil. This study highlights the potential value of quantifying volatile oil palm signals in the atmosphere as a novel, non-invasive method to better understand biological functioning and its interactions with the environment including carbon assimilation, floral-insect interactions, and fruit oil production/processing.

54 ENVIRONMENTAL SCIENCES↗

Techno‐economics of microalgae production and conversion to refinery‐ready oil with co‐product credits

Abstract The economics of the production of hydrotreated algal oil ( HTAO ) along with co‐production of animal feed and nutraceuticals (omega‐3 oils) was explored. Base case calculations were for commercial scale production of 10 000 barrels per day of HTAO with nutraceuticals claiming only 0.05% of the raw algae oil ( AO ). The sensitivity of economics to critical parameters was studied. The greatest sensitivity of sales price was to the algae doubling time. Doubling time might be reduced by increasing pond velocity or other mixing‐inducing means. Other important parameters were oil content, CAPEX , and moisture content of post‐extracted algal residue. Algal area weight productivity (g/m 2 /day) was calculated from four parameters: initial algal concentration, pond depth, residence time in pond, and algae doubling time. Using presently accepted operating parameter values and with co‐product credits, the estimated plant gate price was ~ $10/gal. However, it was shown that there is significant potential for enhanced economics through moderate improvements in many areas. Credits for co‐production of animal feed and nutraceuticals were $3.24/gal and $0.14/gal, respectively. At constant oil area productivity (gal/acre/yr), the trade‐off between oil content and area weight productivity favors oil content. In the limit of 100% oil content (no solid co‐product) a sale price of $7.90/gal was estimated. Hydrotreatment of AO was discussed. Municipal waste‐water tertiary treatment was briefly discussed but not deemed viable on a large scale. An easy‐to‐use Excel spreadsheet for material and energy balances and economics was developed as a flexible scouting tool. The symbol ‘$’ denotes US dollars. © 2015 Society of Chemical Industry and John Wiley & Sons, Ltd

Manganaro, James L.↗

Mercury concentrations in urine of amerindian populations near oil fields in the peruvian and ecuadorian amazon

Background: Mercury is a global contaminant with toxic, persistent effects on human health. Petroleum extraction is an important source of elemental mercury; little is known about human exposure levels near oil fields in the Amazon basin. Objectives: To characterize mercury levels in people living near oil production sites in the Peruvian and Ecuadorian Amazon, controlling for fish consumption, occupation, source of water and socio-demographic characteristics. Methods: Analyze mercury levels in urine samples using cold vapour atomic fluorescence spectrometry from 76 indigenous men and women in eight riverine communities situated near oil wells or pipelines. Subjects answered a questionnaire soliciting socio-demographic, occupational and dietary information. Data were analyzed using multiple linear regression modeling. Results: The mean value of U-Hg was 2.61 μg/g creatinine (95% CI: 2.14–3.08), with 7% of the sample recording values above the global background standard suggested by The World Health Organization (5 μg/g creatinine). Women who used water from a surface source had two and a half times the amount of mercury in their urine (mean=3.70 μg/g creatinine, 95% CI: 2.26–5.15) compared with women who used other water sources (mean =1.39 μg/g creatinine, 95% CI: 0.51–2.25). Men who were involved in an oil clean-up operation had twice as much mercury in their urine (mean =3.07 μg/g creatinine, 95% CI: 1.97–4.16) as did those who worked on other tasks (mean =1.56 μg/g creatinine, 95% CI: 1.48–2.65). Mercury levels were not associated with the number of fish meals per week. Conclusions: Indigenous peoples of the Peruvian and Ecuadorian Amazon living near oil production sites generally had urine mercury levels within the global background standard suggested by the World Health Organization. Increased levels of mercury in urine were detected for men involved in oil spill remediation and for women who relied on surface water for household needs. These findings signal the need for strict safety measures to limit the amount of oil entering the waterways in Andean Amazonia so as to protect the health of indigenous people. - Highlights: • 7% of participants had levels of inorganic mercury at or exceeding levels suggested by WHO (5 μg/g creatinine). • U-Hg levels were 2.5 times higher among women using surface water than those who drew on water from a well, spring or rain. • Men who had worked cleaning up an oil spill had more than twice the amount of mercury in their urine as men who did not.

54 ENVIRONMENTAL SCIENCES↗

Oil effect on CO 2 foam stabilized by a switchable amine surfactant at high temperature and high salinity

Despite the possible detrimental effect of oil on foam displacement processes in CO 2 EOR the effect of oil on dense CO 2 foams has received little attention relative to air foams or low density CO 2 foams. Herein, the effect of both a first contact miscible hydrocarbon (dodecane) and crude oil on CO 2 /water (C/W) foams generated by a switchable surfactant, C 12–14 N(EO) 2 was examined at dense CO 2 conditions at temperatures up to 120 °C (393 K) and 3400 psia (23 MPa). Upon increasing the fractional flow of dodecane, a gradual decrease in foam viscosity was observed as the foam becomes unstable. Since only two phases are present, traditional destabilization mechanisms for three phase oil/gas/water systems based on the entering and spreading are invalid. Therefore, an alternative mechanism is suggested whereby added dodecane strengthen the surfactant tail interactions with the nonaqueous phase (mixture of CO 2 and dodecane) to shift the hydrophilic-CO 2 philic balance (HCB) towards an unstable region. This mechanism is supported by a decrease of the CO 2 –water interfacial tension from ~5 mN/m to 0.5 mN/m for dodecane–water systems at 120 °C and 3400 psia. The effect of crude oil was more profound than for dodecane, whereby rapid destabilization of foam occurred at an oil fractional flow as low as 0.2. In this case, the immiscible portion of the crude oil can enter and spread at the lamellae to destabilize the foam as is evident in positive entering and spreading coefficients. Also, other foam destabilizing parameters such as temperature and capillary pressure were studied in the presence of oil and the results were consistent with those in the absence of oil.

nuclear (including radiation effects), carbon sequ↗

Bio-Oil Impact on Water Diffusion and Durability of Bitumen: Influence of Aging and Salinity

Bio-oils derived from inexpensive biomass offer environmentally friendly options for modifying bitumen for improved durability or rejuvenating aged material, although their impact on bitumen moisture resistance can be mixed. A better understanding of water diffusion into bitumen and its interactions with bio-oil compounds would aid the development of effective bio-oils. In this study, the effect of water exposure on bio-oil-modified bitumen blends was examined by de-wetting contact angle measurements and differential FTIR spectroscopy. The bio-oils improved the anti-stripping behavior of the bitumen but also increased water absorption which could weaken cohesive strength. Short-term thermal aging increased water diffusion for all bitumen blends including the control, probably due to the presence of more oxidized compounds. Negative peaks of alkanes and polar groups in the differential FTIR data suggest the co-diffusion of surfactant molecules towards the bitumen-water interface. Basic pH increased de-wetting of some bitumen blends from silica, possibly by attacking the silica surface itself. The presence of salt in solution altered the bitumen surface composition through the formation of salt complexes with bitumen or bio-oil compounds. In particular, the formation of calcium-carboxylate complexes appeared to greatly improve anti-stripping effects of bio-oils. Water diffusion into most of the bitumen blends was insensitive to pH or salt concentration except for a few notable outliers. Identifying the compounds responsible for increasing or decreasing water diffusion in these outlier cases would be valuable developing future bio-oil formations that avoid or promote those compounds.

Hung, Albert M.↗

Separation of switchgrass bio-oil by water/organic solvent addition and pH adjustment

Applications of bio-oil are limited by its challenging properties including high moisture content, low pH, high viscosity, high oxygen content, and low heating value. Separation of switchgrass bio-oil components by adding water, organic solvents (hexadecane and octane), and sodium hydroxide may help to overcome these issues. Acetic acid and phenolic compounds were extracted in aqueous and organic phases, respectively. Polar chemicals, such as acetic acid, did not partition in the organic solvent phase. Acetic acid in the aqueous phase after extraction is beneficial for a microbial-electrolysis-cell application to produce hydrogen as an energy source for further hydrodeoxygenation of bio-oil. Organic solvents extracted more chemicals from bio-oil in combined than in sequential extraction; however, organic solvents partitioned into the aqueous phase in combined extraction. When sodium hydroxide was added to adjust the pH of aqueous bio-oil, organic-phase precipitation occurred. As the pH was increased, a biphasic aqueous/organic dispersion was formed, and phase separation was optimized at approximately pH 6. The neutralized organic bio-oil had approximately 37% less oxygen and 100% increased heating value than the initial centrifuged bio-oil. In conclusion, the less oxygen content and increased heating value indicated a significant improvement of the bio-oil quality through neutralization.

09 BIOMASS FUELS↗

Red Mud Catalytic Pyrolysis of Pinyon Juniper and Single-Stage Hydrotreatment of Oils

Pinyon juniper biomass feedstocks, which cover a large acreage of rangeland in the western United States, are being eradicated and, therefore, considered as a convenient biomass feedstock for biofuel production. Pinyon juniper whole biomass (wood, bark, and leaves) were pyrolyzed in a pilot-scale bubbling fluidized-bed reactor at 450 °C, and the noncondensable gases were recycled to fluidize the reactor. Red mud was used as the in situ catalyst for the pyrolysis of the pinyon juniper biomass. The pyrolysis products were condensed in three stages, and products were analyzed for physicochemical properties. The condenser oil formed two phases with the aqueous fraction, whereas the electrostatic precipitator oils formed a single phase. The oil pH was 3.3; the higher heating value (HHV) was 28 MJ/kg; and the viscosity was less than 100 cP. There was a direct correlation between the viscosity of the oils and the alcohol/ether content of the oils, and this was also related to the aging rate of the oils. The catalytic pyrolysis oils were hydrotreated in a continuous single-stage benchtop hydrotreater to produce hydrocarbon fuels with a density of 0.80$-$0.82 cm 3 /g. The hydrotreater ran continuously for over 300 h with no significant catalyst deactivation or coke formation. This is the first time that such a long single-stage hydrotreatment has been demonstrated on biomass catalytic pyrolysis oils.

biomass↗

Competitive Adsorption of Lubricant Base Oil and Ionic Liquid Additives at Air/Liquid and Solid/Liquid Interfaces

Oil-soluble ionic liquids (ILs) have been proved as effective additives in lubricant oils through tribological experiments and post-test analytical analyses. Here, surface structures of lubricant base oil, oil-soluble ILs, and their mixtures at the air/liquid and solid/liquid interfaces have been studied using sum frequency generation (SFG) vibrational spectroscopy. At the air/base oil and air/IL interfaces, the alkyl chains of the studied compounds were shown to be conformationally disordered and their terminal methyl groups point outward at the liquid surface. The base oil dominates the air/(base oil + IL) interface due to its higher surface excess propensity and larger bulk concentration. At the solid (silica) surface, ILs adopt a structure with their charged headgroups in contact with the silica surface, while their alkyl chains are more conformationally ordered or packed compared to the air/IL interface. At the interface between silica and (base oil + IL) mixtures, ILs also preferentially adsorb to the silica surface with their layer structures somewhat different from those of ILs alone. These results showed that ILs can adsorb onto the solid surface even before tribological contacts are made. The insights obtained from this SFG study provide a better understanding of the role of ionic liquids in lubrication.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Molecular Dynamics Investigation of Oil Wetting on Synthetic Polymer Substrates

Understanding the interaction of polymer surfaces with nonpolar, low surface tension liquids, or whether a substrate is oleophobic versus oleophilic, is critical for applications ranging from antifingerprint coatings to oil–water separation membranes and oil spill remediation. Despite its technological importance, the molecular mechanisms underpinning polymer–oil wetting are not well characterized. Here, we employ molecular dynamics simulations to investigate the behavior of n-hexadecane in contact with chemically distinct polymer surfaces, spanning eight constitutional unit chemistries as well as amorphous and crystalline morphologies. This permits a critical examination of both thermodynamic and dynamic descriptors of oleophobicity, including oil contact angle, dewetting free energy, interfacial diffusivity, and a proposed “ghost probe energy,” which does not require explicit simulation of oil–polymer interactions. We find that the oil contact angle does not reliably distinguish oleophobic behavior across polymer chemistries, whereas other metrics provide clearer and more consistent differentiation. Analysis of the results reveals that polymer–oil wetting behavior is primarily governed by interfacial van der Waals interactions and modulated by surface flexibility and morphology. Collectively, this work establishes a computational framework for characterizing oil wetting and provides additional insight into what molecular-level factors dictate trends in oleophobicity.

lipids↗

Supercritical water co-liquefaction of LLDPE and PP into oil: properties and synergy

The major plastic wastes are always mixtures, which are difficult to separate to treat in practice. Because of some possible cross-reactions, the degradation behaviors of plastics could not be mathematically represented by a simple addition of each polymer according to their proportions. This work examines supercritical water (scH 2 O) to liquefy poly-ethylene and poly-propylene mixtures into an oil with special interest in the oil quality and positive effect. Additionally, linear low-density polyethylene (LLDPE) and polypropylene (PP) were chosen as parent materials because of their high proportions in plastic wastes. The results show that a high conversion rate of around 99.75% was achieved with as high as 90.7 wt% oil yield without additional catalysts or hydrogen. The scH 2 O co-liquefaction of the LLDPE/PP mixture was different from that of the single polymer along with an improvement in the oil yield. Cyclic hydrocarbon ( i.e. , cyclic) generation was promoted while the production of paraffins was hindered in scH 2 O co-liquefaction using a mixture of LLDPE/PP. TGA reveals that the scH 2 O co-liquefaction of LLDPE/PP mixtures generated more diesel and lubricant oils and less gasoline and (jet fuel + light diesel) oils, thus slightly lowering the oil quality. Overall, the supercritical fluid technology was a powerful and promising means to liquefy mixed plastic wastes into oil at a high conversion rate free of catalysts or hydrogen.

42 ENGINEERING↗

Triacylglycerol stability limits futile cycles and inhibition of carbon capture in oil-accumulating leaves

Engineering plant vegetative tissue to accumulate triacylglycerols (TAG, e.g. oil) can increase the amount of oil harvested per acre to levels that exceed current oilseed crops. Engineered tobacco (Nicotiana tabacum) lines that accumulate 15% to 30% oil of leaf dry weight resulted in starkly different metabolic phenotypes. In-depth analysis of the leaf lipid accumulation and 14 CO 2 tracking describe metabolic adaptations to the leaf oil engineering. An oil-for-membrane lipid tradeoff in the 15% oil line (referred to as HO) was surprisingly not further exacerbated when lipid production was enhanced to 30% (LEAFY COTYLEDON 2 (LEC2) line). The HO line exhibited a futile cycle that limited TAG yield through exchange with starch, altered carbon flux into various metabolite pools and end products, and suggested interference of the glyoxylate cycle with photorespiration that limited CO 2 assimilation by 50%. In contrast, inclusion of the LEC2 transcription factor in tobacco improved TAG stability, alleviated the TAG-to-starch futile cycle, and recovered CO 2 assimilation and plant growth comparable to wild type but with much higher lipid levels in leaves. Thus, the unstable production of storage reserves and futile cycling limit vegetative oil engineering approaches. The capacity to overcome futile cycles and maintain enhanced stable TAG levels in LEC2 demonstrated the importance of considering unanticipated metabolic adaptations while engineering vegetative oil crops.

59 BASIC BIOLOGICAL SCIENCES↗

First Ever Polymer Flood Field Pilot to Enhance the Recovery of Heavy Oils on Alaska’s North Slope – Polymer Injection Performance

Alaska North Slope (ANS) holds an estimated 20-30+ billion barrel heavy oil resources, yet the development pace has been very slow due to high development costs and low oil recovery using conventional waterflood and EOR methods. The objective of this pilot is to perform a field experiment to validate the use of an advanced polymer flooding technology to unlock the vast heavy oil resources on ANS. The advanced polymer flooding technology combines polymer flooding, low salinity water flooding, horizontal wells, and if necessary, injection conformance control treatments into one integrated process to significantly improve oil recovery from heavy oil reservoirs. Two pairs of horizontal injection and production wells have been deployed in an isolated fault block of the Schrader Bluff heavy oil reservoir at the Milne Point Field to conduct a polymer flood pilot. The pilot will acquire scientific knowledge and field performance data to optimize polymer flood design in the Schrader Bluff heavy oil reservoirs on ANS. Polymer injection started on August 28, 2018 using a custom made polymer blending and pumping unit. This paper focuses on the facility setup and polymer injection performance into the horizontal injectors drilled and completed in the Schrader Bluff heavy oil reservoir. Partially hydrolyzed polyacrylamide (HPAM) polymer was selected and the initial target viscosity was set at 45 centipoise. Polymer injection rate was set at 2200 bbl/day for one injector (J-23A) and 1200 bbl/day for the other (J-24A) based on production voidage. Injection pressure was controlled at below fracture pressure to prevent fracturing the reservoir and causing fast breakthroughs. Step rate and pressure falloff tests indicate that short term polymer injectivity is similar to water injectivity, which means that injectivity is mostly controlled by fluid mobility deep in the reservoir rather than that in the vicinity of the injection wellbore. Long term injection data indicate that polymer injectivity has been decreasing in both injectors as the reservoir is filled by polymer. No polymer has been observed in the production stream 7 months after the start of polymer injection compared with a 3-month breakthrough time with waterflood. This indicates that polymer significantly delays breakthrough time which will lead to increased sweep efficiency.

Ning, Samson↗

Literature Survey of Crude Oil Properties Relevant to Handling and Fire Safety in Transport

Several fiery rail accidents in 2013-2015 in the U.S. and Canada carrying crude oil produced from the Bakken region of North Dakota have raised questions at many levels on the safety of transporting this, and other types of crude oil, by rail. Sandia National Laboratories was commissioned by the U.S. Department of Energy to investigate the material properties of crude oils, and in particular the so-called "tight oils" like Bakken that comprise the majority of crude oil rail shipments in the U.S. at the current time. The current report is a literature survey of public sources of information on crude oil properties that have some bearing on the likelihood or severity of combustion events that may occur around spills associated with rail transport. The report also contains background information including a review of the notional "tight oil" field operating environment, as well a basic description of crude oils and potential combustion events in rail transport.

02 PETROLEUM↗

Assessment of CO 2 Storage Resources in Depleted Oil and Gas Fields in the Ship Shoal Area, Gulf of Mexico

The Gulf of Mexico is one of the most important regions in the United States for energy resources and infrastructure. Gulf of Mexico federal offshore oil and gas production accounts for 17% of total U.S. crude oil production and 5% of total U.S. gas production (EIA Gulf of Mexico Fact Sheet). This region presents an excellent combination of high need and significant opportunity for large scale geologic storage of CO 2 . The Ship Shoal Area is located about 20 miles offshore Louisiana within the Gulf Coast federal waters. Miocene and Pliocene sediments in the Ship Shoal Area are proven to provide excellent and secure traps for oil and gas. The Ship Shoal Area contains a large number of depleted oil and gas fields either currently abandoned, or planned for abandonment by 2025, which may provide very significant potential CO 2 storage capacity. GeoMechanics Technologies conducted a comprehensive research project to better characterize Neogene sediments in the Ship Shoal Area for high volume CO 2 storage. The data generated from literature, well data, well log, and formation evaluation were input into Rockwork 16 geologic software to create a detailed geologic model for the Ship Shoal study area. The geologic grids were then fed into TOUGH2, the gas migration model software and FLAC 3D, the geomechanical model software. The fluid flow modeling for both the Miocene and Pliocene simulation from both Block 107 and Block 84 indicated that Pliocene and Miocene are a good reservoir for the CO 2 sequestration. Thirty years of CO 2 injection (at a rate of 1 million metric tons CO 2 per year) and 30 years of observation simulations were run with the fluid flow modeling. The 3D geomechanical modeling for Ship Shoal Block 107 and Block 84 were developed to evaluate induced surface deformation and potential fault reactivation after 30 years CO 2 injection at base of Pliocene and at upper Miocene injection locations. Evaluation results indicate low to no risks for fault slips or fault reactivation. Twelve well bores and 76 well bores for Ship Shoal Blocks 84 and 107 respectively were reviewed for their cement history. Most wells (57 out of 76 and 7 out of 12 wells in Ship Shoal Block 107 and 84 respectively) have good integrity. Nineteen and 5 wells (in Ship Shoal Block 107 and 84 respectively) with no top plug, incomplete cement or Plug and Abandonment information are given yellow cautionary indicators. These cautionary wells may provide leakage paths of CO 2 through the well bores to the USDWs. Using our Quantitative Risk & Decision Analysis Tool (QRDAT) for caprock integrity evaluation, we compared Ship Shoal’s risk to that of In Salah, Sleipner, Kevin Dome, Loudon, Illinois Industrial CCS and Wilmington Graben. We found the risk at the Ship Shoal Blocks 84 and 107 fields are similar to the known CO 2 active sequestration sites, but lower than the Wilmington Graben turbidities offshore California studied site. The risk of natural seismicity in the Gulf of Mexico is relatively low. Geomechanics Technologies has documented the top 25 CO 2 emission sources within the close proximity of the Ship Shoal Block 84 and 107 fields. All the offshore and onshore pipelines have been digitized and can be viewed in an interactive website (http://www.geomechanicstech.com/shipshoal.html). We also performed a feasibility study on the potential for converting existing oil or gas pipelines for CO 2 transport. There are abandoned, idled and retired onshore and offshore pipelines. However, there is no standard specification for maximum pipeline pressures needed for CO 2 transport. It is a function of design, materials, and testing provided; thus it will be the responsibility of the pipeline operator to correctly determine, maintain and operate within the limits of the pipelines. There are a few transit corridors extending from onshore Louisiana (Cailou Bay) to offshore trunk-lines. The cost for constructing a pipeline has increased about 46% from 2015 to an average cost of $5,064,046 per mile in 2016. We use the NETL CO 2 storage resource mass estimate to calculate the potential resources for Ship Shoal Block 84 and 107 fields using the depleted oil and gas reservoir volume and sand volume generated from our geologic modeling. The estimated storage resource results are greater when using the sand volumes derived through geologic modeling than the oil and gas reservoir data. The difference is due to the depleted oil and gas reservoir information not accounting for the water-flooded sand located below the oil/gas-water contact or unproductive sand units. Resource calculation using the sand volume obtained through geologic modeling overestimate the storage capacity as the model accounts for all sand within the formation, not just the interconnected sand.

02 PETROLEUM↗