Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Na”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1983

Some spectral plasma diagnostics for prominences and structures in the middle chromosphere

The present investigation is concerned with the statistical equilibrium of the low-lying levels of Na, Sr(+), and Ba(+) under conditions appropriate to structures just above the solar surface. The solar and atomic data required for this objective are largely available with an adequate precision. However, the metastable (2)D term photoionization cross sections had to be calculated. In the calculations a variant of the scaled Thomas-Fermy method suggested by Kahler (1971) was used. The Na and Sr(+) resonance lines are readily measurable in ordinary prominences. The Ba(+) are weak. It is shown that the ratio of Na to Sr(+) resonance-line integrated intensities provides a useful and sensitive electron-density diagnostic for prominences, yielding values in the neighborhood of 10 to the 11th per cu cm. The statistical equilibrium solutions are applied to an analysis of data from the flash spectrum at eclipse.

Landman, D. A.↗
NASA NTRS1983

Bed-rest studies - Fluid and electrolyte responses

Confinement in the horizontal position for 2 to 3 weeks results in a chronic decrease in plasma volume, increased interstitial fluid volume, and unchanged or slightly increased extracellular fluid volume. Concentrations of blood electrolytes, glucose, and nitrogenous constituents remain within normal limits of variability when maintenance levels of isometric or isotonic exercise are performed for 1 hr/day. Hematocrit and plasma osmolality can be elevated significantly throughout bed rest (BR). Significant diuresis occurs on the first day, and increases in urine Na and Ca continue throughout BR, although voluntary fluid intake is unchanged. Urine Na and K are evaluated during the second week of BR in spite of stabilization of PV and extracellular volume. The initial diuresis probably arises from extracellular fluid while subsequent urine loss above control levels must come from the intracellular fluid. Preservation of the extracellular volume takes precedance over maintenance of the intracellular fluid volume. The functioning of a natriuretic factor (hormone) to account for the continued increased loss of Na in the urine is suggested. Previously announced in STAR as N83-24160

Greenleaf, J. E.↗
NASA NTRS1984

Physical conditions in the cool parts of prominences. II - The Mg triplet lines

The statistical equilibrium of Mg under prominence conditions is considered. It is shown that the principal lines of the triplet system can serve as an equivalent to the Na D lines for spectral diagnostic purposes. Like the Na D lines, these Mg lines are relatively easy to measure in prominences and exhibit small optical depths. It is demonstrated that potential complications due to possible radiative transfer effects in the Mg resonance transition (3 1S0 - 3 1P1) have little consequence for the triplet populations. The results are used to repeat the spectral analysis of Landman (1983) using the Mg multiplets in place of the Na ones. The results of the two analyses are in general agreement. The finding of a low degree of H ionization in the cool prominence regions and a correspondingly high gas pressure is confirmed.

Landman, D. A.↗
NASA NTRS1986

Sputtering of sodium on the planet Mercury

It is shown here that ion sputtering cannot account for the observed neutral sodium vapor column density on Mercury, but that it is an important loss mechanism for Na. Photons are likely to be the dominant stimulus, both directly through photodesorption and indirectly through thermal desorption of absorbed Na. It is concluded that the atmosphere produced is characterized by the planet's surface temperature, with the ion-sputtered Na contributing to a lesser, but more extended, component of the atmosphere.

Mcgrath, M. A.↗
NASA NTRS1989

Conservation of body calcium by increased dietary intake of potassium: A potential measure to reduce the osteoporosis process during prolonged exposure to microgravity

During the 1988 NASA Summer Faculty Fellowship Program, it was proposed that the loss of skeletal calcium upon prolonged exposure to microgravity could be explained, in part, by a renal maladjustment characterized by an increased urinary excretion of calcium. It was theorized that because the conservation of body fluids and electrolytes depends upon the energy of adenosine triphosphate and enzymes that control the use of its energy for renal ion transport, an induction of renal sodium and potassium-dependent adenosine triphosphatase (Na + K ATPase) by oral loading with potassium would increase the reabsorption of sodium directly and that of calcium indirectly, leading to improved hydration and to reduced calcium loss. Preliminary studies showed the following. Rats drinking water containing 0.2 M potassium chloride for six to 13 days excreted in urine 22 muEq of calcium and 135 muEq of sodium per 100 grams of body weight per day. The corresponding values for control rats drinking tap water were 43 muEq and 269 muEq respectively. Renal Na + K ATPase activity in potassium loaded rats was higher than in controls. Thus, oral potassium loading resulted in increased Na + K ATPase activity and diminished urinary excretion of calcium and of sodium as predicted by the hypothesis. An extension of these studies to humans has the potential of resulting in development of harmless, non-invasive, drug-free, convenient measures to reduce bone loss and other electrolyte and fluid problems in space travelers exposed to prolonged periods of microgravity.

Nechay, Bohdan R.↗
NASA NTRS1989

On the nearest molecular clouds. III - MBM 40, 53, 54, and 55

In an attempt to determine the distances to four high-latitude molecular clouds (HLCs), echelle spectra near the Na I D lines, accurate MK spectral types, and photoelectric photometry for 25 nearby stars have been obtained. Fairly firm distance limits may be placed on MBM 40 (d smaller than or equal to 140 pc) and MBM 53 (d greater than or equal to 110 pc and less than or equal to 155 pc), based on the presence or absence of strong interstellar Na I absorption towards stars projected on or near those HLCs. Weak interstellar absorption lines observed toward many of the stars located near MBM 54 and 55 make the distances to those clouds less certain (about 265 pc for both). Interstellar CH absorption at 4300 A was detected in the spectrum of HD 218662, located behind MBM 53 with a CH column density of 2.1 x 10 to the 13th per sq cm, thus implying a CH abundance comparable to that observed in other molecular clouds. Morphological and velocity agreement among CO emission, the Na I absorption, the 100 micron infrared cirrus emission, and the 21 cm H I emission near these HLCs suggest a close association of the interstellar material responsible for those phenomena.

Welty, D. E.↗
NASA NTRS1990

Geochemistry and genesis of the angrites

The major and trace elements were analyzed in samples of LEW86010, LEW87051, and Angra dos Reis angrites were analyzed using INAA and fused-bead EMP techniques. Results suggest that all three angrites originated on a volatile-depleted (Na-poor) but oxidized parent body or on several bodies. The combination of low Na and high FeO/MnO found in these samples suggests that the extreme Na depletion was caused by parent-body outgassing during differentiation, rather than by nebular processes. It was also found that the refractory-element abundances observed in LEW86010 and LEW87051 are related via olivine control; it is suggested that LEW86010 may be a residual melt from a LEW87051-like precursor or that LEW87051 formed from a LEW86010-like precursor via olivine accumulation. On the other hand, the Angra dos Reis displayed an unusual refractory element pattern suggesting that either the angrite parent body was heterogeneous or that Angra dos Reis was formed on a parent body different from that of the other two angrites.

Mittlefehldt, David W.↗
NASA NTRS1991

Narrowband lidar technique for sodium temperature and Doppler wind observations of the upper atmosphere

A new two-frequency lidar for measuring mesospheric Na temperature profiles is described that uses a stabilized CW single-mode dye laser oscillator (rms frequency jitter less than 1 MHz) followed by a pulsed dye power amplifier (140 MHz FWHM linewidth) that is pumped by an injection-locked Nd:YAG laser. The laser oscillator is tuned to the two operating freqencies by observing the Doppler-free structure of the Na D2 fluorescence spectrum in a vapor cell. The lidar technique and initial observations of the temperature profile between 82 and 102 km at Ft. Collins, CO are described. Absolute temperature accuracies at the Na layer peak of better than + or - 3 K with a vertical resolution of 1 km and an integration period of approximately 5 min were achieved in this initial experiment. Finally, a multiple frequency technique for the simultaneous measurement of both temperature and Doppler wind profiles is discussed.

Bills, Richard E.↗
NASA NTRS1992

SO2 on Venus: A final cross-calibration with Pioneer Venus

In our previous report, we noted that we had successfully completed all of the IUE observations which were proposed. A total of 7 Venus spectra were obtained. In the present reporting period, essentially all of the associated data reduction and analysis activities were completed, and Drs. Stern, Barker, and Na met to collaborate on data interpretation. The model atmosphere used in this analysis is similar to the one used in the analysis of the Pioneer Venus observations (Esposito, et al. 1979, 1988) and the previous IUE observations (Na, et al. 1990). In this model, sulfuric acid aerosols with a radius of about 1 micron are mixed uniformly with Rayleigh scattering gases throughout the cloud layer. There are two wavelength-independent absorbers. First, the aerosols are assumed to have a single scattering albedo of 0.98, and second a pure absorbing layer with an optical depth of 0.2 is added at an altitude of 75 mbar. The variable parameters in this model are the mixing ratios of SO2 at the cloud top (40 mbar level), and the scale height of SO2 at the same altitude. Model spectra were calculated using a radiative transfer code utilizing a Markov Chain method. Each model calculation takes into account the multiple scattering and the vertical inhomogeneity of the atmosphere. We reported those initial results at the 1992 meeting of the AAS Division of Planetary Sciences (Barker, Stern, and Na 1992) The important finding we have reached is that the 1991 IUE observations indicate that the long-term decline in Venus SO2 abundance has either halted or reversed. Our simultaneous groundbased measurements made on the McDonald Observatory 2.7 m corroborate this result. We are now preparing a paper describing these IUE results for publication in Icarus. With the IUE results reduced, we are also beginning a project to compare the 1991 IUE results to Pioneer Venus UV spectra made on the same dates.

Stern, S. Alan↗
NASA NTRS1992

Sodium-sulfur Cell Technology Flight Experiment (SSCT)

The sodium-sulfur battery is emerging as a prime high-temperature energy storage technology for space flight applications. A Na-S cell demonstration is planned for a 1995-96 NASA Space Shuttle flight which focuses on the microgravity effects on individual cells. The experiment is not optimized for battery performance as such. Rather, it maximizes the variety of operating conditions which the Na-S cell is capable of in a relatively short 5-day flight. The demonstration is designed to reveal the effects of microgravity by comparison with ground test control cells experiencing identical test conditions but with gravity. Specifically, limitations of transport dynamics and associated cell performance characteristics should be revealed. The Na-S Cell Technology Flight Experiment consists of three separate experiments designed to determine cell operating characteristics, detailed electrode kinetics and reactant distributions.

Halbach, Carl R.↗
NASA NTRS1992

The formation of helioseismology lines. III - Partial redistribution effects in weak solar resonance lines

This paper investigates the formation of the Na I D2, K I 769.9 nm and Ba II 455.4 nm resonance lines in the solar atmosphere allowing for partial frequency redistribution (PRD). We show that the influence of PRD is negligible on the solar disk in all three lines for a model of the average quiet-Sun, and even for the more extreme case of a model with a steeper photospheric temperature decline. At the solar limb PRD does affect the intensity profile of the Na I and Ba II resonance lines, but not that of the K I line. Finally, we find that effects of PRD are more pronounced at the limb in the Na I D2 and Ba II 455.4 nm lines when the photospheric temperature gradient is steep.

Uitenbroek, H.↗
NASA NTRS1992

High temperature conductivity of potassium-beta(double prime)-alumina

Potassium beta(double prime)-alumina (BDPA) single crystals have been reported by several groups to leave higher ionic conductivity than sodium BDPA crystals at room temperature, and similar conductivities are obtained at temperatures up to 600-700 K. Potassium BDPA ceramics have been reported to have significantly poorer conductivities than those of sodium BDPA ceramics, but conductivity measurements at temperatures above 625 K have not been reported. In this study, K(+)-BDPA ceramics were prepared from Na(+)-BDPA ceramic using a modified version of the exchange reaction with KCl vapor reported by Crosbie and Tennenhouse (1982), and the conductivity has been measured in K vapor at temperatures up to 1223 K, using the method of Cole et al. (1979). The results indicate reasonable agreement with earlier data on K(+)-BDPA ceramic measured in a liquid K cell, but show that the K(+)-BDPA ceramic's conductivity approaches that of Na(+)-BDPA ceramic at higher temperatures, being within a factor of four at 700 K and 60 percent of the conductivity of Na(+)-BDPA at T over 1000 K. Both four-probe dc conductivity and four probe ac impedance measurements were used to characterize the conductivity. A rather abrupt change in the grain boundary resistance suggesting a possible phase change in the intergranular material, potassium aluminate, is seen in the ac impedance behavior.

Williams, R. M.↗
NASA NTRS1993

Vaporization by shock loading of albite, jadeite, and pyrex glass: Experimental study

Produced by shock experiments impact melts of albite, jadeite, and Pyrex glass demonstrate a loss of both Na and Al relative to Si, which can be due to selective vaporization. It is suggested that the high volatility of Al is related to volatility of a Na-Al compound of proposed NaAlO2 composition. The similar loss of Al and Na seems to be possible during tektite-forming processes. A degree of selective vaporization and modification of a melt chemical composition during impact processes is still poorly understood. The selective vaporization of some elements has been shown by shock experiments. The vaporization and condensation processes can take place in the lunar regolith. On this basis, there are hypotheses explaining differentiation of planetary bodies through the impact vaporization. On the other hand, studies of tektites, impact glasses, and lunar soils show that bulk compositions of impact melts are not modified significantly. In order to estimate degree of the vaporization during shock fusion, chemical compositions of experimentally produced impact melts were studied. We chose Al-containing compositions, because a high volatilization of Al during unequlibrated evaporization had been demonstrated.

Badjukov, D. D.↗
NASA NTRS1993

Alkali-granitoids as fragments within the ordinary chondrite Adzhi-Bogdo: Evidence for highly fractionated, alkali-granitic liquids on asteroids

Adzhi-Bogdo is an ordinary chondrite regolith breccia (LL3-6) that fell October 30, 1949 in Gobi Altay, Mongolia. The rock consists of submm- to cm-sized fragments embedded in a fine-grained elastic matrix. The breccia contains various types of clasts, some of which must be of foreign heritage. Based on chemical compositions of olivine some components have to be classified as L-type. Components of the breccia include chondrules, impact melts (some are K-rich, similar to those found in other LL-chondrites, highly recrystalized rock fragments ('granulites'), pyroxene-rich fragments with achondritic textures, and alkali-granitoidal fragments that mainly consist of K-feldspar and quartz or tridymite. Probably, this is the first report on granitoids from asteroids. It can be ruled out that these fragments represent huge rock assemblages of the parent body like granites do on Earth. Therefore, to avoid misunderstandings, these rocks will be designated as granitoids. In one thin section four granitoids were observed. The main phases within these clasts are K-feldspar and SiO2-phases. Minor phases include albite, Cl-apatite, whitlockite, ilmenite, zircon, Ca-poor pyroxene, and an unidentified Na,Ti-bearing silicate. Based on chemical composition and on optical properties quartz appears to be the SiO2-phase in two fragments, whereas tridymite seems to occur in the other two. The calculated formula of the unknown Na,Ti-rich silicate is very close to (Na,Ca)2.7(Fe,Mg)6(Ti)1.3(Si)7(O)24. Quartz and K-feldspar can reach sizes of up to 700 microns. Thus, the fragments can be described as coarse-grained (by chondritic standards). This is especially the case considering that quartz and K-feldspar are very rare minerals in ordinary chondrites. Representative analyses of minerals from some granitoidal clasts are given. Based on the mineral compositions and the modal abundances the bulk compositions were calculated. Besides these granitoidal rocks, pyroxene-rich fragments occur that show exsolution textures that are similar to those found in eucrites.

Bischoff, A.↗
NASA NTRS1993

Solar wind-induced secondary ions and their relation to lunar surface composition

Based on previous laboratory experiments simulating solar wind sputtering of lunar surface materials, it appears that solar wind ions sputter secondary ions in sufficient numbers to be measured from low-altitude lunar orbit. Solar wind protons are hundreds of times less efficient than those used in standard secondary ion mass spectrometry; nevertheless secondary ions of Na, Mg, Al, Si, K, Ca, Mn, Ti and Fe were observed sputtered from sample simulants of mare and highland soils. These secondary ion fluxes depend both on concentration in the soil and on probability of ionization; yields of easily ionized elements such as K and Na are relatively much greater than those for the more electronegative elements and compounds. The principal geochemical indicator elements Na, Mg, Al, Si, K, Ca, Ti, Mn and Fe are nevertheless detectable. However, it has not been shown that the observed secondary ions vary strictly one-to-one with their concentrations in the geochemically distinct soil simulants used here. While we have a first order understanding of secondary ion sputtering, it is not clear that the observed ion yields can be linked with great accuracy to the simulant's composition. The simulants were analyzed by electron microprobe to establish their detailed composition. The observed secondary ion fluxes can then be compared with the microprobe results. For example Ti(+) fluxes from the three simulants correspond to the true composition with accuracies of better than 10 percent for the high-Ti basalt, and about 20 percent for the low-Ti simulant. The highlands simulant produced a statistically insignificant Ti(+) count rate. Here we discuss the results of further SIMS experiments using the ASU/Center for Solid State Science facility. With careful isolation and preparation of samples, we avoid the problems of the previous experiments. In particular, we will make use of ground-up sample to mimic the sputtering behavior of regolith, and will avoid charging by placing the soil on a conducting indium substrate. We report the results of a blind test of the SIMS technique using a sample of unknown composition.

Elphic, R. C.↗
NASA NTRS1994

Atmospheres of the Moon and Mercury

Mercury and the Moon have long been considered to be similar objects, but this view was based on limited information at visible wavelengths. It is now known that real differences exist in the atmospheres and in the rock types as deduced from mid-infrared observations. Lunar Ar and perhaps Ne were observed from Apollo landed experiments in spite of a large local background. An ultraviolet spectrometer (UVS) in orbit placed upper limits on a number of gases including H and O. At Mercury, the UVS on Mariner 10 measured H, He, and perhaps O and again a number of upper limits for other gases. Less than a decade ago, emissions of Na and K were observed from the ground, with abundances 2 orders of magnitude smaller on the Moon than on Mercury. It is likely that impacting meteoroids bring a significant amount of water to Mercury, whose atmosphere should therefore contain water vapor. This notion is supported by the recent discovery of radar-bright polar deposits almost certainly composed of ice. A variety of origins is likely for the different components. Impact of meteoroids could supply water, Na, and K, and could also vaporize surface material; Na, K, and Ar could be degassed from the crust. H is probably from the solar wind, and He could reasonably come from degassing or the solar wind. A substantial loss process for all components is photoionization (or dissociation); ions on one side are swept away into the solar wind and on the other are swept back to the surface. This process is complicated at Mercury by its permanent magnetic field, but there is little doubt that both loss and recycling still occur. Some of the recycling probably occurs by way of the magnetotail through night side auroral precipitation; atoms implanted in the surface will diffuse back into the atmosphere shortly after dawn, an effect that seems to be present for K. Finally the light atoms H and He have high enough velocities to escape directly, an effect that may be enhanced by the suprathermal velocity distributions that are likely to be present.

Hunten, D. M.↗
NASA NTRS1994

The temporal evolution of the 4-14 micron spectrum of V1974 Cygni (Nova Cygni 1992)

We present 4-14 micron spectra of the ONeMg nova V1974 Cygni (Nova Cygni 1992) obtained during 1992 May on the NASA Kuiper Airborne Observatory (KAO) and from the NASA 1.52 m infrared telescope at Mount Lemmon, Arizona in 1992 October/November with the HIFOGS mid-infrared spectrometer. The spectra at both epochs showed continuum emission from thermal bremstrahlung (free-free radiation) with emission lines from hydrogen and (Ne II), (Ar III), and Ne VI). During May, approximately = 80 days after outburst, the dominant emission lines in the mid-infrared spectra were a blend of three lines (Pf-alpha, Hu-beta, H11-7) near 7.5 microns and (Ne II) at 12.8 microns. By October (approximately 160 days later), the hydrogen emission had virtually disappeared, the (Ne II) 12.8 micron line had weakened considerably, and a pronounced (Ne VI) emission line had appeared at 7.6 microns. This behavior confirms that V1974 Cyg is similar to the prototypical slow ONeMg 'neon nova', Nova QU Vulpeculae (1984 No. 2). The remarkable evolution of the spectrum suggests that the ionization conditions changed drastically between 1992 May and 1992 October. We find that the ejecta of V1974 Cyg were overabundant in neon with respect to silicon by a factor of approximately 10 relative to the solar photosphere. We present new model calculations of infrared sodium forbidden line emission from (Na III) 7.319 microns (Na IV) 9.039 microns, and (Na IV) 21.29 microns that can be compared with recent model predictions of sodium synthesis in ONeMg nova outbursts. We conclude that sodium abundances in ONeMg novae can be determined by observations of infrared coronal lines of sodium that are accssible to the Infrared Space Observatory (ISO) and instruments at the NASA Infrared Telescope Facility (IRTF).

Gehrz, R. D.↗
NASA NTRS1994

Geochemical evidence for mixing of three components in martian orthopyroxenite ALH 84001

ALH 84001, a ferroan martian orthopyroxenite, originally consisted of three petrographically defined components: a cumulus assemblage of orthopyroxene + chromite, a trapped melt assemblage of orthopyroxene(?) + chromite + maskelynite + apatite + augite +/- pyrite, and a metasomatic assemblage of carbonate +/- pyrite. We present the results of Instrumental Neutron Activation Analysis (INAA) study of five bulk samples of ALH 84001, combined with Scanning Ion Mass Spectrometer (SIMS) data on the orthopyroxene, in order to attempt to set limits on the geochemical characteristics of the latter two components, and therefore on the petrogenesis of ALH 84001. The INAA data support the petrographic observations, suggesting that there are at least three components in ALH 84001. We will assume that each of the three geochemically required components can be equated with one of the petrographically observed components. Both trapped melt and metasomatic components in ALH 84001 have higher Na than orthopyroxene based on compositions of maskelynite, apatite, and carbonate. For the metasomatic component, we will assume its Na content is that of carbonate, while for a trapped melt component, we will use a typical Na content inferred for martian meteorite parent melts, approximately 1 wt% Na2O. Under these assumptions, we can set limits on the Light Rare Earth Elements/Heavy Rare Earth Elements (LREE/HREE) ratios of the components, and use this information to compare the petrogenesis of ALH 84001 with other martian meteorites. The above calculations assume that the bulk samples are representative of different portions of ALH 84001. We will also evaluate the possible heterogeneous distribution of mineral phases in the bulk samples as the cause of compositional heterogeneity in our samples.

Mittlefehldt, D. W.↗