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At least 325 records · Page 18

Technology Assessment and Experimentation Plan

An assessment is given of the critical and enhancing technologies necessary to build the basic personal terminal (BPT), the supplier, and the Network Management Center (NMC). The experimentation plan for testing the Personal Access Satellite System (PASS) utilizing ACTS is detailed. The experiment plan gives a list of candidate experiments and describes the proposed experimental set-up. ACTS will be used in the Microwave Switch Matrix (MSM) mode. The Microwave Switch Matrix - Link Evaluation Terminal (MSM-LET) at the NASA Lewis Research Center will serve as the microwave front-end for the PASS supplier and the NMC. Link budgets are given for both the forward and return links between the supplier and the basic personal terminal. The equipment required for the experiments is identified.

Estabrook, Polly↗

Theoretical modelling and meteorological analysis for the AASE mission

Providing real time constituent data analysis and potential vorticity computations in support of the Airborne Arctic Stratospheric Experiment (AASE) is discussed. National Meteorological Center (NMC) meteorological data and potential vorticity computations derived from NMC data are projected onto aircraft coordinates and provided to the investigators in real time. Balloon and satellite constituent data are composited into modified Lagrangian mean coordinates. Various measurements are intercompared, trends deduced and reconstructions of constituent fields performed.

Schoeberl, Mark R.↗

Global atmospheric circulation statistics, 1000-1 mb

The atlas presents atmospheric general circulation statistics derived from twelve years (1979-90) of daily National Meteorological Center (NMC) operational geopotential height analyses; it is an update of a prior atlas using data over 1979-1986. These global analyses are available on pressure levels covering 1000-1 mb (approximately 0-50 km). The geopotential grids are a combined product of the Climate Analysis Center (which produces analyses over 70-1 mb) and operational NMC analyses (over 1000-100 mb). Balance horizontal winds and hydrostatic temperatures are derived from the geopotential fields.

Randel, William J.↗

Extratropical aspects of the 40-50 day oscillation in length-of-day and atmospheric angular momentum

The 40-50-d oscillation in length-of-day (LOD) and AAM is investigated using the 12-yr overlap between two records: AAM data, compiled from the NMC, and LOD variation from the JPL Kalman-filtered earth rotation series. The NMC records are analyzed by latitude belts, in the light of the UCLA GCM results, in order to identify possibly distinct sources of the AAM oscillation in the midlatitudes and the tropics. Results suggest that two intraseasonal oscillations exist in the earth-atmosphere system: a tropical 50-d oscillation associated with the convectively driven waves of the type first described by Madden and Julian (1971) and a midlatitude 40-d oscillation associated with the interaction of nonzonal flow with topography.

Dickey, J. O.↗

Evolution of atmospheric fronts over the ocean as observed with the special sensor microwave/imager and the Geosat altimeter

Integrated water vapor gradients and rain occurrence inferred from SSM/I are used to locate and trace the evolution of the atmospheric fronts for two midlatitude cyclones across the North Pacific. When compared to the NMC frontal locations advected to the time of the satellite pass, a good overall agreement is found between the SSM/I and the NMC locations of the fronts. The Geosat altimeter and the SSM/I overflew the two cyclones with several hours difference, locating the frontal positions at different times. The position of the occluded, warm, and cold fronts are detected along the altimeter track as well as regions of high wind speed associated with the cyclonic systems. These regions of high wind speeds associated with the fronts are also sensed by the SSM/I and, allowing for the time difference between the two satellites, are in good agreement with the Geosat measurements.

Mognard, Nelly M.↗

Integration of satellite and surface data using a radiative-convective oceanic boundary-layer model

A mixing-line boundary-layer model is used to retrieve cloud-top height from satellite-derived cloud-top temperatures, using 700-hPa National Meteorological Center (NMC) analyses and the Comprehensive Ocean and Atmosphere Data Set (COADS) surface data as supporting datasets. Results are compared with the fixed-lapse-rate method of retrieving boundary-layer depth from sea surface temperatures (SST) and cloud-top temperatures. A radiative-convective equilibrium boundary-layer model is used to retrieve boundary-layer structure given SST and surface wind, satellite cloud-top temperatures and cloud fraction, and the 700-hPa NMC thermodynamic analyses. Good agreement is found between the COADS data and the model solutions for low-level temperature and moisture. This suggests that equilibrium boundary-layer models may be of use over remote oceans in the retrieval of boundary-layer structure.

Betts, Alan K.↗

Design of a WINDSAT observing system simulation experiment

The following topics are addressed: (1) motivation for the National Meteorological Center (NMC) simulation project; (2) history of the NMC simulation project; (3) experimental design of the WINDSAT observing system simulation experiment; (4) preparation of the simulated observations; and (5) strengths and weaknesses of the experimental design.

Dey, Clifford H.↗

Ozone and stratospheric height waves for opposite phases of the QBO

The stratospheric quasi-biennial oscillation (QBO) provides an important source of interannual variations in the Northern Hemisphere. O'sullivan and Salby (1990) related extra-tropical eddy transport with the phase of the tropical QBO. When the tropical wind is easterly, the zero wind line is shifted into the winter hemisphere. Enhanced wave activity in middle latitudes acts to weaken the polar vortex. When the tropical wind is in the westerly phase the situation reverses. Heights at 30 mb and ozone configurations are contrasted in this paper for these two QBO phases. When the winter vortex deforms due to the amplification of planetary waves 1 and 2, extends westward and equatorward, the complementary band of low vorticity air spirals in toward the pole from lower latitudes. Sometimes, these planetary waves break (Juckes and McIntyre, 1987) and an irreversible mixing of air takes place between high and mid-latitudes. Global ozone patterns, as obtained form satellite observations, appear to be affected by planetary wave breaking (Leovy et al. 1985). This mixing results on regions with uniform ozone and potential vorticity. In the Southern Hemisphere (SH), Newman and Randel (1988) using Total Ozone Mapping Spectrometer (TOMS) data and the NMC analyses have found strong spatial correlation between the October mean temperature in the lower stratosphere and total ozone for the 1979 through 1986 years. Recently Nogues-Paegle et al.(1992) analyzed SH ozone and height data from 1986 to 1989. They found that leading empirical orthogonal functions (EOFs) for both ozone and 50 mb heights exhibit zonal wave 1 and 2 and that the correlations between ozone and 50 mb principal components (PCs) are high. The results were found to be consistent with a linear planetary wave advecting a passive tracer. In this paper, the dominant patterns of variability for 30 mb NMC heights and TOMS total ozone are obtained for the winter to summer transition (January to May) in the Northern Hemisphere (NH) for the years 1987-1990.

Mo, Kingtse C.↗

Southern hemisphere low level wind circulation statistics from the Seasat scatterometer

Analyses of remotely sensed low-level wind vector data over the Southern Ocean are performed. Five-day averages and monthly means are created and the month-to-month variability during the winter (July-September) of 1978 is investigated. The remotely sensed winds are compared to the Australian Bureau of Meteorology (ABM) and the National Meteorological Center (NMC) surface analyses. In southern latitudes the remotely sensed winds are stronger than what the weather services' analyses suggest, indicating under-estimation by ABM and NMC in these regions. The evolution of the low-level jet and the major stormtracks during the season are studied and different flow regimes are identified. The large-scale variability of the meridional flow is studied with the aid of empirical orthogonal function (EOF) analysis. The dominance of quasi-stationary wave numbers 3,4, and 5 in the winter flows is evident in both the EOF analysis and the mean flow. The signature of an exceptionally strong blocking situation is evident in July and the special conditions leading to it are discussed. A very large intraseasonal variability with different flow regimes at different months is documented.

Levy, Gad↗

Angular momentum exchange among the solid Earth, atmosphere, and oceans: A case study of the 1982-1983 El Nino event

The 1982-1983 El Nino/Southern Oscillation (ENSO) event was accompanied by the largest interannual variation in the Earth's rotation rate on record. In this study we demonstrate that atmospheric forcing was the dominant cause for this rotational anomaly, with atmospheric angular momentum (AAM) integrated from 1000 to 1 mbar (troposphere plus stratosphere) accounting for up to 92% of the interannual variance in the length of day (LOD). Winds between 100 and 1 mbar contributed nearly 20% of the variance explained, indicating that the stratosphere can play a significant role in the Earth's angular momentum budget on interannual time scales. Examination of LOD, AAM, and Southern Oscillation Index (SOI) data for a 15-year span surrounding the 1982-1983 event suggests that the strong rotational response resulted from constructive interference between the low-frequency (approximately 4-6 year) and quasi-biennial (approximately 2-3 year) components of the ENSO phenomenon, as well as the stratospheric Quasi-Biennial Oscillation (QBO). Sources of the remaining LOD discrepancy (approximately 55 and 64 microseconds rms residual for the European Centre for Medium-Range Forecasting (EC) and U.S. National Meteorological Center (NMC) analyses) are explored; noise and systematic errors in the AAM data are estimated to contribute 18 and 33 microseconds, respectively, leaving a residual (rms) of 40 (52) microseconds unaccounted for by the EC (NMC) analysis. Oceanic angular momentum contributions (both moment of inertia changes associated with baroclinic waves and motion terms) are shown to be candidates in closing the interannual axial angular momentum budget.

Dickey, J. O.↗

New Mission Concept Study: Energetic X-Ray Imaging Survey Telescope (EXIST)

This Report summarizes the activity carried out under the New Mission Concept (NMC) study for a mission to conduct a sensitive all-sky imaging survey in the hard x-ray (HX) band (approximately 10-600 keV). The Energetic X-ray Imaging Survey Telescope (EXIST) mission was originally proposed for this NMC study and was then subsequently proposed for a MIDEX mission as part of this study effort. Development of the EXIST (and related) concepts continues for a future flight proposal. The hard x-ray band (approximately 10-600 keV) is nearly the final band of the astronomical spectrum still without a sensitive imaging all-sky survey. This is despite the enormous potential of this band to address a wide range of fundamental and timely objectives - from the origin and physical mechanisms of cosmological gamma-ray bursts (GRBs) to the processes on strongly magnetic neutron stars that produce soft gamma-repeaters and bursting pulsars; from the study of active galactic nuclei (AGN) and quasars to the origin and evolution of the hard x-ray diffuse background; from the nature and number of black holes and neutron stars and the accretion processes onto them to the extreme non-thermal flares of normal stars; and from searches for expected diffuse (but relatively compact) nuclear line (Ti-44) emission in uncatalogued supernova remnants to diffuse non-thermal inverse Compton emission from galaxy clusters. A high sensitivity all-sky survey mission in the hard x-ray band, with imaging to both address source confusion and time-variable background radiations, is very much needed.

Source record↗

Li-Ion Batteries for Space Applications: High Specific Energy and Wide-Operating Temperature

Compared to the conventional Ni-Co oxides (with or without AI additions), the NMC (1/3:1/3:1/3) cathode provides marginal improvement in specific capacity. However, some of the formulations based on the solid solutions of layered Li2Mn03 and LiM02 (M = Mn0.5Ni0.5} have shown capacities as high as 250 mAh/g, combined with high cell voltages (4.5 V) and with the likelihood of enhanced thermal stability. Multi-component electrolytes with low EC-proportions and selected co-solvents provide significant improvement in the low temperature performance, down to -60 C, combined with the non-flammable attribute from the co-solvents. The NMC cathode shows good compatibility with the carbonate-based low temperature electrolytes. Impressive performances have been realized at low temperatures of <= 30 C. Electrolytes with high salt concentration and high EC content fare well at room temperatures, while the formulations with low EC content and low salt concentration are preferred at low temperatures. DPA studies reveal increased SEI growth on the electrodes, especially anode, upon irradiation. Performance of low temperature electrolytes in prototype cells corroborate the findings from laboratory cells.

storage↗

The Evaluation of Triphenyl Phosphate as a Flame Retardant Additive to Improve the Safety of Lithium-Ion Battery Electrolytes

With the intent of improving the safety characteristics of lithium ion cells, electrolytes containing flame retardant additives have been investigated. A number of triphenyl phosphate-containing electrolytes were evaluated in both coin cells and experimental three electrode lithium-ion cells (containing reference electrodes). A number of chemistries were investigated, including MCMB carbon/LiNi(0.8)Co(0.2)O2 (NCO), graphite/LiNi(0.8)Co(0.15)Al(0.05)O2 (NCA), Li/Li(Li(0.17)Ni(0.25)Mn(0.58))O2, Li/LiNiMnCoO2 (NMC) and graphite/LiNiMnCoO2 (NMC), to study the effect that different electrolyte compositions have upon performance. A wide range of TPP-containing electrolytes were demonstrated to have good compatibility with the C/NCO, C/NCA, and Li/NMC systems, however, poor performance was initially observed with the high voltage C/NMC system. This necessitated the development of improved electrolytes with stabilizing additives, leading to formulations containing lithium bis(oxalato)borate (LiBOB) that displayed substantially improved performance.

rechargable batteries↗

Validation of the Fast-Neutron Multiplicity Expressions for Fissile Mass Estimation

Neutron multiplicity analysis is a non-destructive assay technique that involves measurement of the multiplets of neutrons that are emitted from fission of fissile material. Typically, multiplicity analysis is conducted by means of a neutron multiplicity counting (NMC) system that uses capture-based thermal-neutron detectors (e.g., 3He-gas detectors). To relieve the reliance on such detectors, we have developed a fast-neutron multiplicity counting (FNMC) system that uses scatter-based, organic scintillators to directly detect the fast fission neutrons emitted from the sample. One challenge with FNMC systems, however, is that they are prone to effects of neutron cross-talk, where a single neutron may scatter and cause more than one detection event. This leads to an overestimate of the fission rate (F) and inaccurate estimation of other sample parameters such as the leakage multiplication (M) and the alpha-ratio (a) when using the traditional capture-based NMC equations. We have formulated fully generalized multiplicity expressions that account for cross-talk effects for any arbitrary order N. The validity of these expressions were verified with MCNPX-PoliMi simulations and experimental measurements; this paper will present the validation of the proposed generalized multiplicity expressions. Californium-252 and Pu metal plates were measured using the FNMC system and the data was used for neutron multiplicity analysis to estimate sample parameters F, M, and a. We demonstrate that accounting for neutron cross-talk effects of order N = 2 and 3 improves the accuracy of the estimated sample parameters.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

High capacity and stable cathode materials

High energy density cathode materials, such as LiNiXMnYCoZO2 (NMC) cathode materials, with improved discharge capacity (hence energy density) and enhanced cycle life are described. A solid electrolyte, such as lithium phosphate infused inside of secondary particles of the cathode material demonstrates significantly enhanced structural integrity without significant or without any observable particle cracking occurring during charge/discharge processes, showing high capacity retention of more than 90% after 200 cycles at room temperature. In certain embodiments the disclosed cathode materials (and cathodes made therefrom) are formed using nickel-rich NMC and/or are used in a battery system with a non-aqueous dual-Li salt electrolytes.

25 ENERGY STORAGE↗

Machine Learning Approaches for Nuclear Material Accounting Data from Irradiation and Reprocessing

We are currently exploring data analysis methods for their ability to strengthen the synthesis and evaluation of information generated within domestic and international safeguard regimes. Safeguard data typically includes rich heterogenous datasets amenable to advanced data analytics methods, such as machine learning. We have converted transactional data containing both numerical and categorical attributes from a domestic nuclear material control and accountability (NMC&A) system into a low-dimensional numerical structure via linear principal component analysis. This data representation allows for global structure discovery via cluster analysis, which can characterize the typical behavior of each of the primary types of transaction events. Furthermore, the structure of the top principal components captures the “typical behavior” of the data and is thus amenable to anomaly detection through statistical hypothesis testing. We explored this capability by generating erroneous permutations of the data and computing the Q-residual quantity increase associated with the information loss when these data are projected into the low-dimensional principal component analysis space representative of typical transactions.Future work will focus on identifying data transformations (e.g., graph networks) that more closely align with the inherent structure of these transactions to explain more salient information and disambiguate the underlying nuclear process—in this case, irradiation and reprocessing—from artifacts of NMC&A system transactional record keeping data.

Drescher, Adam↗

High capacity and stable cathode materials

High energy density cathode materials, such as LiNixMnyCozO2 (NMC) cathode materials, with improved discharge capacity (hence energy density) and enhanced cycle life are described. A solid electrolyte, such as lithium phosphate infused inside of secondary particles of the cathode material demonstrates significantly enhanced structural integrity without significant or without any observable particle cracking occurring during charge/discharge processes, showing high capacity retention of more than 90% after 200 cycles at room temperature. In certain embodiments the disclosed cathode materials (and cathodes made therefrom) are formed using nickel-rich NMC and/or are used in a battery system with a non-aqueous dual-Li salt electrolytes.

25 ENERGY STORAGE↗

Examination of New Theory for Neutron Multiplicity Counting of Non-Point-Like Sources of Special Nuclear Material

The purpose of a nondestructive assay is to accurately verify the declared mass of special nuclear material (SNM) samples in a limited amount of time. One measurement modality is neutron multiplicity counting (NMC), which relates time-correlated neutron detection rates to the mass of SNM present. Traditional theory assumes point-like sources, which can be ill-posed for kilogram-quantity, bulk samples. Recent theory was developed to improve NMC accuracy for non-point-like samples. This work preliminarily examines the theory with measured data. The OSCAR prototype (a 3-by-4 array of 5.08-cm-thick, 5.08-cm-diameter trans-stilbene organic scintillators) measures configurations of 29.41-49.00 kg of highly enriched uranium (93wt% 235 U). Adjusted factorial moments for the emitted neutron multiplicity distributions are used to account for the shape and type of SNM being measured.

252Cf↗