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At least 325 records · Page 18

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NASA NTRS1995

Preferential heating of light ions during an ionospheric Ar(+) injection experiment

The Argon Release for Controlled Studies (ARCS) 4 sounding rocket was launched northward into high altitude from Poker Flat Research Range on February 23, 1990. The vehicle crossed geomagnetic field lines containing discrete auroral activity. An instrumented subpayload released 100-eV and 200-eV Ar(+) ion beams sequentially, in a direction largely perpendicular to both the local geomagnetic field and the subpayload spin axis. The instrumented main payload was separated along field lines from the beam emitting subpayload by a distance which increased at a steady rate of approximately 2.4 m/s. Three dimensional mass spectrometric ion observations of ambient H(+) and O(+) ions, obtained on board the main payload, are presented. Main payload electric field observations in the frequency range 0-16 kHz, are also presented. These observations are presented to demonstrate the operation of transverse ion acceleration, which was differential with respect to ion mass, primarily during 100-eV beam operations. The preferential transverse acceleration of ambient H(+) ions, as compared with ambient O(+) ions, during the second, third, fourth, and fifth 100-eV beam operations, is attributed to a resonance among the injected Ar(+) ions, beam-generated lower hybrid waves, and H(+) ions in the tail of the ambient thermal distribution. This work provides experimental support of processes predicted by previously published theory and simulations.

Pollock, C. J.↗

NASA NTRS1998

"Reagentless" flow injection determination of ammonia and urea using membrane separation and solid phase basification

Flow injection analysis instrumentation and methodology for the determination of ammonia and ammonium ions in an aqueous solution are described. Using in-line solid phase basification beds containing crystalline media. the speciation of ammoniacal nitrogen is shifted toward the un-ionized form. which diffuses in the gas phase across a hydrophobic microporous hollow fiber membrane into a pure-water-containing analytical stream. The two streams flow in a countercurrent configuration on opposite sides of the membrane. The neutral pH of the analytical stream promotes the formation of ammonium cations, which are detected using specific conductance. The methodology provides a lower limit of detection of 10 microgram/L and a dynamic concentration range spanning three orders of magnitude using a 315-microliters sample injection volume. Using immobilized urease to enzymatically promote the hydrolysis of urea to produce ammonia and carbon dioxide, the technique has been extended to the determination of urea.

NASA Center JSC↗

NASA NTRS1994

Preferential heating of light ions during an ionospheric AR(+) injection experiment

The ARCS 4 sounding rocket was launched northward into high altitude from Poker Flat Research Range on February 23, 1990. The vehicle crossed geomagnetic field lines containing discrete auroral activity. An instrumented subpayload released 100 ev and 200 ev Ar(+) ion beams sequentially, in a direction largely perpendicular to both the local geomagnetic field and the subpayload spin axis. The instrumented main payload was separated along field lines from the beam emitting subpayload by a distance which increased at a steady rate of approx. 2.4 m/s. Three-dimensional mass spectrometric ion observations of ambient H(+) and O(+) ions, obtained onboard the main payload, are presented. Main payload electric field observations in the frequency range 0-16 kHz, are also presented. These observations are presented to demonstrate the operation of transverse ion acceleration, that was differential with respect to ion mass, primarily during 100-ev beam operations. The preferential transverse acceleration of ambient H(+) ions, as compared with ambient O(+) ions during the second, third, fourth, and fifth 100-ev beam operations, is attributed to a resonance at the injected the beam drift velocity among the thermal H(+) ions and plasma waves generated by the injected beam and propagating at the beam drift speed. This work provides experimental support of processes predicted by previously published theory and simulations.

Pollock, C. J.↗

NASA NTRS1989

A review of atomic clock technology, the performance capability of present spaceborne and terrestrial atomic clocks, and a look toward the future

Clocks have played a strong role in the development of general relativity. The concept of the proper clock is presently best realized by atomic clocks, whose development as precision instruments has evolved very rapidly in the last decades. To put a historical prospective on this progress since the year AD 1000, the time stability of various clocks expressed in terms of seconds of time error over one day of operation is shown. This stability of operation must not be confused with accuracy. Stability refers to the constancy of a clock operation as compared to that of some other clocks that serve as time references. Accuracy, on the other hand, is the ability to reproduce a previously defined frequency. The issues are outlined that must be considered when accuracy and stability of clocks and oscillators are studied. In general, the most widely used resonances result from the hyperfine interaction of the nuclear magnetic dipole moment and that of the outermost electron, which is characteristic of hydrogen and the alkali atoms. During the past decade hyperfine resonances of ions have also been used. The principal reason for both the accuracy and the stability of atomic clocks is the ability of obtaining very narrow hyperfine transition resonances by isolating the atom in some way so that only the applied stimulating microwave magnetic field is a significant source of perturbation. It is also important to make resonance transitions among hyperfine magnetic sublevels where separation is independent, at least to first order, of the magnetic field. In the case of ions stored in traps operating at high magnetic fields, one selects the trapping field to be consistent with a field-independent transition of the trapped atoms.

Vessot, Robert F. C.↗

NASA NTRS1973

On the field anomaly of near wakes in a collisionless plasma.

A variational approach is presented for determining the electric field induced by charge separation in the near wake of a large negatively charged body moving at mesothermal speeds in a tenuous plasma. It is shown that the presence of a potential well in the wake is due to the charge separation resulting from the unequal mass motions with which the ambient electrons and ions move into the wake.

Liu, V. C.↗

NASA NTRS1978

An experiment to study energetic particle fluxes in and beyond the earth's outer magnetosphere

This experiment is designed to take advantage of the ISEE Mother/Daughter dual spacecraft system to study energetic particle phenomena in the earth's outer magnetosphere and beyond. Large geometric factor fixed voltage electrostatic analyzers and passively cooled semiconductor detector telescopes provide high time resolution coverage of the energy range from 1.5 to 300 keV for both ions and electrons. Essentially identical instrumentation is placed on the two spacecraft to separate temporal from spatial effects in the observed particle phenomena.

Anderson, K. A.↗

NASA NTRS1979

An electric propulsion long term test facility

An existing test facility was modified to provide for extended testing of multiple electric propulsion thruster subsystems. A program to document thruster subsystem characteristics as a function of time is currently in progress. The facility is capable of simultaneously operating three 2.7-kW, 30-cm mercury ion thrusters and their power processing units. Each thruster is installed via a separate air lock so that it can be extended into the 7m x 10m main chamber without violating vacuum integrity. The thrusters exhaust into a 3m x 5m frozen mercury target. An array of cryopanels collect sputtered target material. Power processor units are tested in an adjacent 1.5m x 2m vacuum chamber or accompanying forced convection enclosure. The thruster subsystems and the test facility are designed for automatic unattended operation with thruster operation computer controlled. Test data are recorded by a central data collection system scanning 200 channels of data a second every two minutes. Results of the Systems Demonstration Test, a short shakedown test of 500 hours, and facility performance during the first year of testing are presented.

Trump, G.↗

NASA NTRS1985

Far-infrared line observations of planetary nebulae. 1: The O 3 spectrum

Observations of the far-infrared fine structure lines of O III have been obtained for six planetary nebulae. The infrared measurements are combined with optical O III line fluxes to probe physical conditions in the gas. From the observed line intensity ratios, a simultaneous solution was obtained for electron temperature and density, as well as means of evaluating the importance of inhomogeneities. Densities determined from the far-infrared O III lines agree well density diagnostics from other ions, indicating a fairly homogeneous density in the emitting gas. Temperatures are determined separately from the O III 4363/5007 A and 5007 A/52 micron intensity ratios and compared. Systematically higher values are derived from the former ratio, which is expected from a nebula which is not isothermal. Allowance for the presence of temperature variations within these nebulae raises their derived oxygen abundances, determinations to be reconciled with the solar value.

Dinerstein, H. L.↗

NASA NTRS1985

Far-infrared line observations of planetary nebulae. I - The forbidden O III spectrum

Observations of the far-infrared fine structure lines of O III have been obtained for six planetary nebulae. The infrared measurements are combined with optical O III line fluxes to probe physical conditions in the gas. From the observed line intensity ratios, a simultaneous solution was obtained for electron temperature and density, as well as means of evaluating the importance of inhomogeneities. Densities determined from the far-infrared O III lines agree well with density diagnostics from other ions, indicating a fairly homogeneous density in the emitting gas. Temperatures are determined separately from the O III 4363/5007 A and 5007 A/52 micron intensity ratios and compared. Systematically higher values are derived from the former ratio, which is expected from a nebula which is not isothermal. Allowance for the presence of temperature variations within these nebulae raises their derived oxygen abundances, determinations to be reconciled with the solar value.

Dinerstein, H. L.↗

NASA NTRS1987

Non-enzymatic synthesis of the coenzymes, uridine diphosphate glucose and cytidine diphosphate choline, and other phosphorylated metabolic intermediates

Using urea and cyanamide, the two condensing agents considered to have been present on the primitive earth, uridine diphosphate glucose (UDPG), cytidine diphosphate choline (CDP-choline), glucose-1-phosphate (G1P), and glucose-6-phosphate (G6P) were synthesized under simulated prebiotic conditions. The reaction products were separated and identified using paper chromatography, thin layer chromatography, enzymatic analyses, and ion-pair reverse-phase high performance liquid chromatography. The possibility of nonenzymatic synthesis of metabolic intermediates on the primitive earth from simple precursors was thus demonstrated.

Mar, A.↗

NASA NTRS1988

GAS 450: A space payload for the People Central Coast Student Experimenters

The Get Away Special 450 is described. This discussion includes the peoples efforts, the experiments, lessons learned, and a few powerful positive steps toward community involvement. The following is a list of experiment titles: Guppies in Space; Electrophoresis of Enzymes in Microgravity; Diffusion of Ions in Solution; Space Cement; Bubbles in Space; Small Particle Studies; and Liquid Separation in Microgravity.

Ray, Glen↗

NASA NTRS1992

Charge, energy, and LET spectra measurements of charged particles in P0006 experiment of LDEF

Measurements are under way of the charged particle radiation environment of the LDEF satellite using stacks of plastic nuclear track detectors (PNTDs) placed in different locations of the satellite. In the initial work, the charge, energy, and linear energy transfer (LET) spectra of charged particles were measured with CR-39 double layer PNTDs located on the west end of the satellite. Primary and secondary stopping heavy ions as well as relativistic galactic cosmic rays (mostly iron particles) were measured separately. The results will be compared with similar measurements in other locations on LDEF with different orientation and shielding conditions. The remarkably detailed study of the charged particle radiation environment of the LDEF satellite will lead to a better understanding of the radiation environment of the Space Station Freedom. It will enable more accurate prediction of single event upsets (SEUs) in microelectronics and, especially, more accurate assessment of the risk, contributed by the different components of the radiation field to the health and safety of crew members.

Benton, E. V.↗

NASA NTRS1993

Waves generated in the vicinity of an argon plasma gun in the ionosphere

Wave and particle observations were made in the close vicinity of an argon plasma gun carned to over 600 km altitude on a sounding rocket. The gun was carned on a subpayload, separated from the main payload early in the flight. Twelve-second argon ion ejections were energized alternately with a peak energy of 100 or 200 eV. They produced waves, with multiple harmonics, in the range of ion cyclotron waves, 10 to 1000 Hz at rocket altitudes. Many of these waves could not be identified as corresponding to the cyclotron frequencies of any of the ions, argon or ambient, known to be present. In addition, the wave frequencies were observed to rise and fall and to change abruptly during a 12-s gun operation. The wave amplitudes, near a few hundred Hertz, were of the order of O. 1 V/m. Some of the waves may be ion-ion hybrid waves. Changes in ion populations were observed at the main payload and at the subpayload during gun operations. A gun-related, field-aligned, electron population also appeared.

Cahill, L. J., Jr.↗

NASA NTRS1998

From the Chemistry Lab to Licensing

This is a story of technology maturation and transfer, and licensing. It traces the history of the recently patented ion- exchange material (IEM) from the accidental discovery that this polymer, a battery separator of marginal performance, picked up copper from distilled water passing through corroded copper tubing in the laboratory, to a point where five organizations and one individual have applied for licenses to manufacture and market it or to use it in a wide variety of applications. This story discusses in detail the problems of converting an immature technology into a mature and eventually commercialized technology, without dedicated resources. Readers will develop an appreciation for how the obstacles to maturation and licensing of the technology were faced and overcome. The lessons learned will be discussed, with the hope of enhancing the technology transfer process.

Savino, Joseph M.↗

NASA NTRS2002

Microgravity Compatible Reagentless Instrumentation for Detection of Dissolved Organic Acids and Alcohols in Potable Water

The Organic Acid and Alcohol Monitor (OAAM) program has resulted in the successful development of a computer controlled prototype analyzer capable of accurately determining aqueous organic acids and primary alcohol concentrations over a large dynamic range with high sensitivity. Formic, acetic, and propionic acid were accurately determined at concentrations as low as 5 to 10 micrograms/L in under 20 minutes, or as high as 10 to 20 mg/L in under 30 minutes. Methanol, ethanol, and propanol were determined at concentrations as low as 20 to 100 micrograms/L, or as high as 10 mg/L in under 30 minutes. Importantly for space based application, the OAAM requires no reagents or hazardous chemicals to perform these analyses needing only power, water, and CO2 free purge gas. The OAAM utilized two membrane processes to segregate organic acids from interfering ions. The organic acid concentration was then determined based upon the conductiometric signal. Separation of individual organic acids was accomplished using a chromatographic column. Alcohols are determined in a similar manner after conversion to organic acids by sequential biocatalytic and catalytic oxidation steps. The OAAM was designed to allow the early diagnosis of under performing or failing sub-systems within the Water Recovery System (WRS) baselined for the International Space Station (ISS). To achieve this goal, several new technologies were developed over the course of the OAAM program.

Akse, James R.↗

NASA NTRS1974

Perturbation theory of structure in classical liquid mixtures: Application to metallic systems near phase separation

The partial structure factors of classical simple liquid mixtures near phase separation are dicussed. The theory is developed for particles interacting through pair potentials, and is thus appropriate both to insulating fluids, and also to metallic systems if these may be described by an effective ion-ion pair interaction. The motivation arose from consideration of metallic liquid mixtures, in which resistive anomalies have been observed near phase separation. A mean field theory correction appropriate to 3 pair potential for the effects of correlated motions in the reference fluid is studied. The work is cast in terms of functions which are closely related to the direct correlation functions of Ornstein and Zernike. The results are qualitatively in accord with physical expectations. Quantitative agreement with experiment seems to turn on the selection of the hard core reference potential in terms of the metallic effective pair potential. It is suggested that the present effective pair potentials are perhaps not properly used to calculate the metallic structure factors at long wavelength.

Henderson, R. L.↗

NASA NTRS1982

Evidence for impulsive ion acceleration during the 0312 UT flare of 1980 June 7

One of the basic problems concerning the physics of solar flares is related to the process which is responsible for the acceleration of both electrons and ions. It has been proposed that the acceleration process proceeds in two different phases. The first phase results in the acceleration of electrons to energies in the range from 10 to 100 KeV. Electrons and ions with energies exceeding 30 MeV are finally produced during the second phase. Attention is given to the observational evidence which shows that these two phases, if in fact they are separate, must operate within seconds of each other, and that this process must be able to repeat itself producing pulses of electrons and ions approximately every 10 seconds. The observations were made with the Gamma Ray Spectrometer (GRS) on the SMM satellite during the 0312 UT flare on June 7, 1980.

Forrest, D. J.↗

NASA NTRS1989

Chromospheric-coronal coupling during solar flares: Current systems and particle acceleration

Two-dimensional (three velocity) electrostatic particle simulations are used to investigate the particle heating and acceleration associated with the impulsive phase of a solar flare. A crossfield current in the high corona (which is presumably driven by reconnection processes) is used to initiate the flare. Due to the differential motion of the electrons and ions, currents, and associated quasi-static electric fields are generated with the primary current and balancing return current being on adjacent field lines. These currents extend from the corona down into the chromosphere. Electrons can be accelerated to energies exceeding 100 keV on short time scales via the quasi-static fields and wave-particle interactions. The spectra of these electrons has a broken power-law distribution which hardens in time. The spatially separate primary and return currents are closed by the cross-field acceleration of the ambient ions into the primary current regions. These ions are then accelerated upwards into the corona by the same quasi-static electric field accelerating the electrons downwards. This acceleration can account for the broadened stationary and weak blue shifted component seen in soft x ray line emissions and enhancements in heavy ion abundances seen in the solar wind in associations with solar flares.

Winglee, Robert M.↗