Time-dependent chemistry in dense molecular clouds. II - Ultraviolet photoprocessing and infrared spectroscopy of grain mantles
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Dhendecourt, L. B.↗
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Infrared spectroscopy of Jupiter and Saturn
The origin of carbon monoxide has been a puzzle for some time, and it has become apparent that CO serves as a tracer of disequilibrium processes in the Jovian atmosphere. High resolution spectra with a Fabry-Perot spectrometer was obtained. From a detailed synthetic spectral analysis of the CO line profiles, it was established that the CO is located in the troposphere of Jupiter. It must therefore be a product of convection upward from hotter levels in the deep atmosphere, and is not a product of infall of material from above the stratosphere. Six lines of CO in Saturn was detected, a surprising result because disequilibrium models predicted that the CO mixing ratio would be too low to be observable if upward convection is the dominant mechanism. Therefore several possibilities for the origin of the CO now exist, none completely satisfactory at this time.
Knacke, R. F.↗
Submillimeter and Far-Infrared Spectroscopy of M17 and S106: UV-Heated, Quiescent Molecular Gas?
Measurements of CO line emission toward the interface between molecular cloud and HII region in M17, and the center of the bipolar nebula S106 are discussed. The warm quiescent molecular gas is in the interface between the exciting OB stars and the surrounging molecular cloud. Comparison of the submillimeter, far-IR, and millimeter CO line intensities and profiles suggests a model in which clumps of relatively cool gas (T = 50 K) have warm surfaces or are embedded in a warm surrounding medium. Heating of the warm, quiescent molecular gas by collisions with dust grains can be excluded. Slow shocks or heating by photoelectrons are possible. The most promising mechanism is photoelectric heating. The existence of a substantial amount of warm, quiescent molecular gas in UV illuminated regions may be of importance locally in most OB star formation regions and globally in external galaxies with large rates of star formation.
Harris, A. I.↗
Composition of the lunar highland crust from near-infrared spectroscopy
An attempt is made to synthesize NIR reflectance spectra of the lunar highlands to obtain global information about the composition of the lunar near-side crust. Major rock types identified include noritic, anorthositic, gabbric, and troctolitic compositions. Seventy-five percent of the areas that represent samples from the upper 1-2 km of lunar crust exhibit noritic compositions with different amounts of pyroxene and/or brecciation alteration. The data demonstrate that the lunar near-side crust is clearly mineralogically heterogeneous, both laterally and vertically, and not well mixed below 1-2 km.
Pieters, C. M.↗
Infrared spectroscopy of IRC + 10420
High resolution 1.6, 3.3 and 4.6 micron spectra were obtained on the F8 supergiant star IRC + 10420 on June 9-11, 1984, using the 4 m Mayall telescope and Fourier Transform Spectrometer at Kitt Peak. IRC + 10420 is distinguished by its hydrogen maser, unusual for stars of this type. The measured column densities of CO led to an estimated isotopic carbon ratio of 7-11, supporting a model of the object as a highly evolved star. The redshift is interpreted as due to scattering by outward-moving circumstellar dust grains. The IR spectrum of IRC + 10420 suggests that the object is a post-asymptotic branch star still surrounded by the thick dust shell it produced while it was much cooler.
Fix, John D.↗
Infrared spectroscopy of the lower stratosphere with a balloon-borne cryogenic Fourier spectrometer
The IR limb emission of the lower stratosphere has been measured using a balloon-borne liquid nitrogen-cooled Michelson interferometer with liquid helium-cooled Si:Ga detectors. Portions of the thermal emission spectrum have been recorded between 650 and 2000/cm with an unapodized spectral resolution of 0.03/cm. This is the highest spectral resolution limb emission thus far obtained. A preliminary description is given of these data along with a discussion of the significant features. Species identified to date include CO2, O3, CFCl3, CF2Cl2, H2O, CH4, HNO3, N2O, NO2, and ClONO2. A tentative identification is made for NO, representing the first direct spectroscopic detection of NO in emission.
Kunde, Virgil G.↗
Fourier transform infrared spectroscopy of the NO3 nu-2 and nu-3 bands - Absolute line strength measurements
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Friedl, Randall R.↗
Submillimeter and far-infrared spectroscopy of M17 and S106 - UV-heated, quiescent molecular gas?
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Harris, A. I.↗
Infrared spectroscopy of radio-luminous OH/IR stars
Low-resolution 1.5-2.5-micron spectra for 21 radio-luminous OH/IR stars are presented. These spectra divide into two broad classes. Those with very strong water-vapor absorption closely resemble the spectra of classical Mira variables and are classified Type VM. Those with weaker water-vapor absorption, but still showing strong CO absorption, resemble the spectra of true core-burning supergiants and are classified Type SG. Comparison of the classification of 30 radio-luminous OH/IR stars with their Delta(V)s and luminosities suggests this classification is a good indicator of the intrinsic nature of the underlying star. There is some evidence, however, that some true supergiants (massive main-sequence progenitors) develop the pulsation properties and photospheric characteristics of the Mira-like OH/IR stars when they become optically obscured OH/IR stars.
Jones, Terry Jay↗
Near infrared spectroscopy of SN 1987A using the Kuiper Airborne Observatory
An IR spectrum (1.5-3.0 microns) of SN 1987A was obtained on UT April 16.3, 1987 with the University of Arizona Fourier-transform spectrometer on the NASA Kuiper Airborne Observatory. The dominant spectral features were a double-peaked P-alpha emission line and a sharp absorption edge in the continuum at 2.7 microns, both of which would have been obscured by strong telluric H2O absorptions at ground-based observatories. These IR features relate to models of the SN shell and to the role of dust in SN.
Larson, H. P.↗
Infrared spectroscopy, imaging, and 10 micron photometry of Giclas 29-38
An NIR spectrum and several images of Giclas 29-38, a white dwarf suspected to have a brown dwarf in orbit around it, are presented. There is no absorption feature in the spectrum that is deeper than 5 percent in the wavelength range 1.95-2.45 microns, from which it is inferred that there is no feature deeper than 10 percent at 2.4 microns from any brown dwarf companion. The IR spectrum does not yield any strong constraint on whether or not the thermal emission observed from G29-38 comes from a brown dwarf or dust. The 1.6- and 2.2-micron images of G29-38 appear indistinguishable from a point source with an upper limit of 0.4 arcsec for the separation of the white dwarf and the source of the excess IR emission. This corresponds to a projected linear separation of 5.6 AU. A 2sigma limit at 10 microns of 10 mJy constrains possible alternative models for the IR excess by emission from dust grains. While the present results do not show evidence for the suspected brown dwarf companion around G29-38, the presence of such an object cannot be ruled out.
Tokunaga, A. T.↗
High-resolution infrared spectroscopy of Io and possible surface materials
A comparison of new spectra of Io with laboratory-simulated frosts confirms that the dominant materials on Io are SO2 frost in conjunction with a spectrally neutral material presumed to be sulfur. While the 4-micron region spectra are largely explainable in these terms, attention is drawn to a shoulder in the spectrum at 4.04 microns that is suggestive of adsorbed SO2 gas; two shallow, unidentified bands are also noted at 3.85 and 3.91 microns. The isotopic ratios of oxygen and sulfur appear to be normal. The absence of distinct bands in the new spectra in the 5-micron region limits the abundance of sulfate and sulfite compounds.
Howell, Robert R.↗
Absolute infrared band strength measurement of the ClO radical by Fourier transform infrared spectroscopy
High-resolution (0.005/cm) FTIR spectra of the X2Pi(i)-X2Pi(i) (1-0) rovibrational bands of (C-35)(O-16) and (Cl-37)(O-16) were obtained in 1 torr of helium carrier gas. After measuring the strengths of approximately 830 individual IR lines from several spectra, a total band strength of 13.1 + or - 1.1/sq cm atm and a first Herman-Wallis coefficient of (4.12 + or - 0.62) x 10 to the -3rd were determined.
Lang, Valerie I.↗
The gas environment of the young stellar object GL 2591 studied by infrared spectroscopy
High-resolution M band (4.6 microns) spectroscopy of GL 2591 is presented. Physical structures noted include an absorption feature with an outflow velocity of about 17 km/s, cold gas (identified with the core of the molecular cloud within which the object is embedded), and very broad C-12O lines formed in a neutral wind. The detection of hot low-velocity gas together with warm high-velocity gas suggests the scenario of a warm neutral wind accelerating from an accretion disk.
Mitchell, George F.↗
Solid organic residues produced by irradiation of hydrocarbon-containing H2O and H2O/NH3 ices - Infrared spectroscopy and astronomical implications
Plasma-discharge irradiations were conducted for the methane clathrate expected in outer solar system satellites and cometary nuclei; also irradiated were ices prepared from other combinations of H2O with CH4, C2H6, or C2H2. Upon evaporation of the yellowish-to-tan irradiated ices, it is found that a colored solid film adheres to the walls of the reaction vessel at room temperature. These organic films are found to exhibit IR band identifiable with alkane, aldehide, alcohol, and perhaps alkene, as well as substituted aromatic functional groups. These spectra are compared with previous studies of UV- or photon-irradiated nonclathrated hydrocarbon-containing ices.
Khare, B. N.↗
Infrared spectroscopy of astrophysical ices - New insights in the photochemistry
The photochemical effects of the interstellar radiation field on the ice mantles of molecular-cloud dust grains are investigated by means of laboratory simulations. The apparatus and analytical methods described by Hagen et al. (1979) and Hagen (1982) are employed, and the results are presented as spectra and discussed in detail. Consideration is given to the strong IR absorption bands of OCN(-) and NH4(+) which appear after photolysis and heating of H2O/NH3/CO/O2 ices, the detection of similar bands toward W33A, the critical role of NH3 in the photochemical production of ions, and the use of calculated integrated absorption-band strengths to estimate astrophysical column densities.
Grim, R. J. A.↗
High resolution infrared spectroscopy of the sun and the earth's atmosphere from space
The FFT spectrometer used in the atmospheric trace molecule spectroscopy (ATMOS) experiment, flown for the first time aboard the Shuttle Spacelab 3 mission (in April 1985), is described together with the instrument's design parameters, the ATMOS's science objectives, and observational techniques used. The ATMOS experiment acquired more than 1000 atmospheric spectra with an equal number of 'solar only' scans, yielding absorption spectra of some 400 different atmospheric constituents. Data were obtained on such key reservoir species as COF2, HNO4, and N2O5; simultaneous vertical distributions of the minor gases from 5 to 140 km; the entire odd-nitrogen family in the stratosphere; and on most of the halogen-source gases with their corresponding reservoir and sink species.
Farmer, Crofton B.↗
Measurements of the D/H ratio in planetary atmospheres by ground based infrared spectroscopy
A systematic study of deuterium in the solar system using the molecules CH3D and HDO as tracers is carried out. For the outer solar system, ground-based spectra of Saturn, Uranus, Neptune and Titan in the region of CH3D absorptions near, 1.6 microns are obtained. The analyses of these spectra required extensive high-resolution laboratory studies of both CH4 and CH3D. For the terrestrial planets, the spectrum of Mars in the region of HDO absorption near 3.7 microns, is recorded. A similar study of Venus is underway. The values of D/H derived from these investigations are used to constrain models for the origin and evolution of the various atmospheres.
Debergh, C.↗