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Sm(OH)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Sm3+ is bonded in a 9-coordinate geometry to nine equivalent O2- atoms. There are three shorter (2.49 Å) and six longer (2.50 Å) Sm–O bond lengths. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. O2- is bonded in a single-bond geometry to three equivalent Sm3+ and one H1+ atom.
Nd(OH)3 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Nd3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Nd–O bond distances ranging from 2.52–2.57 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three equivalent Nd3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three equivalent Nd3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three equivalent Nd3+ and one H1+ atom.
La(OH)3 crystallizes in the monoclinic Pm space group. The structure is three-dimensional. there are two inequivalent La3+ sites. In the first La3+ site, La3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of La–O bond distances ranging from 2.57–2.64 Å. In the second La3+ site, La3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of La–O bond distances ranging from 2.56–2.68 Å. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to three La3+ and one H1+ atom.
Sm(OH)3 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Sm3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Sm–O bond distances ranging from 2.47–2.59 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three equivalent Sm3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three equivalent Sm3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three equivalent Sm3+ and one H1+ atom.
Tb(OH)3 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Tb3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Tb–O bond distances ranging from 2.41–2.61 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three equivalent Tb3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three equivalent Tb3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three equivalent Tb3+ and one H1+ atom.
Pr(OH)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Pr3+ is bonded in a 9-coordinate geometry to nine equivalent O2- atoms. There are three shorter (2.55 Å) and six longer (2.57 Å) Pr–O bond lengths. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. O2- is bonded in a single-bond geometry to three equivalent Pr3+ and one H1+ atom.
Pr(OH)3 crystallizes in the monoclinic Pm space group. The structure is three-dimensional. there are two inequivalent Pr3+ sites. In the first Pr3+ site, Pr3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Pr–O bond distances ranging from 2.54–2.62 Å. In the second Pr3+ site, Pr3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Pr–O bond distances ranging from 2.53–2.66 Å. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three Pr3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three Pr3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three Pr3+ and one H1+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to three Pr3+ and one H1+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to three Pr3+ and one H1+ atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to three Pr3+ and one H1+ atom.
Eu(OH)3 crystallizes in the hexagonal P6_3/m space group. The structure is three-dimensional. Eu3+ is bonded in a 9-coordinate geometry to nine equivalent O2- atoms. There are six shorter (2.50 Å) and three longer (2.51 Å) Eu–O bond lengths. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. O2- is bonded in a single-bond geometry to three equivalent Eu3+ and one H1+ atom.
Lu(OH)3 crystallizes in the trigonal R-3 space group. The structure is three-dimensional. there are two inequivalent Lu3+ sites. In the first Lu3+ site, Lu3+ is bonded to six O2- atoms to form corner-sharing LuO6 octahedra. The corner-sharing octahedral tilt angles are 47°. There are four shorter (2.23 Å) and two longer (2.25 Å) Lu–O bond lengths. In the second Lu3+ site, Lu3+ is bonded to six equivalent O2- atoms to form corner-sharing LuO6 octahedra. The corner-sharing octahedral tilt angles are 47°. All Lu–O bond lengths are 2.24 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 1.00 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to two Lu3+ and one H1+ atom. In the second O2- site, O2- is bonded in a distorted single-bond geometry to two equivalent Lu3+ and one H1+ atom.
Eu(OH)3 crystallizes in the monoclinic P2_1/m space group. The structure is three-dimensional. Eu3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Eu–O bond distances ranging from 2.48–2.75 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. There are three inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three equivalent Eu3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three equivalent Eu3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three equivalent Eu3+ and one H1+ atom.
Zn(OH)2 crystallizes in the trigonal P-3m1 space group. The structure is two-dimensional and consists of one Zn(OH)2 sheet oriented in the (0, 0, 1) direction. Zn2+ is bonded to six equivalent O2- atoms to form edge-sharing ZnO6 octahedra. All Zn–O bond lengths are 2.14 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. O2- is bonded in a distorted single-bond geometry to three equivalent Zn2+ and one H1+ atom.
Zn(OH)2 crystallizes in the monoclinic C2 space group. The structure is two-dimensional and consists of one Zn(OH)2 sheet oriented in the (0, 0, 1) direction. Zn2+ is bonded to six equivalent O2- atoms to form edge-sharing ZnO6 octahedra. There are a spread of Zn–O bond distances ranging from 2.03–2.37 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. O2- is bonded in a distorted single-bond geometry to three equivalent Zn2+ and one H1+ atom.
Cd(OH)2 crystallizes in the trigonal P-3m1 space group. The structure is two-dimensional and consists of one Cd(OH)2 sheet oriented in the (0, 0, 1) direction. Cd2+ is bonded to six equivalent O2- atoms to form edge-sharing CdO6 octahedra. All Cd–O bond lengths are 2.35 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. O2- is bonded in a single-bond geometry to three equivalent Cd2+ and one H1+ atom.
Cd(OH)2 crystallizes in the trigonal P3m1 space group. The structure is two-dimensional and consists of one Cd(OH)2 sheet oriented in the (0, 0, 1) direction. Cd2+ is bonded in a distorted q6 geometry to three equivalent H1+ and six O2- atoms. All Cd–H bond lengths are 2.22 Å. There are three shorter (2.39 Å) and three longer (2.43 Å) Cd–O bond lengths. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to three equivalent Cd2+ and one O2- atom. The H–O bond length is 0.99 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three equivalent Cd2+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three equivalent Cd2+ and one H1+ atom.
Cd(OH)2 crystallizes in the monoclinic C2 space group. The structure is two-dimensional and consists of one Cd(OH)2 sheet oriented in the (0, 0, 1) direction. Cd2+ is bonded to six equivalent O2- atoms to form edge-sharing CdO6 octahedra. There are a spread of Cd–O bond distances ranging from 2.31–2.39 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. O2- is bonded in a distorted single-bond geometry to three equivalent Cd2+ and one H1+ atom.
Y(OH)3 crystallizes in the hexagonal P6_3 space group. The structure is three-dimensional. Y3+ is bonded in a 9-coordinate geometry to nine equivalent O2- atoms. There are a spread of Y–O bond distances ranging from 2.41–2.50 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. O2- is bonded in a single-bond geometry to three equivalent Y3+ and one H1+ atom.
Y(OH)3 crystallizes in the monoclinic Pm space group. The structure is three-dimensional. there are two inequivalent Y3+ sites. In the first Y3+ site, Y3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Y–O bond distances ranging from 2.40–2.64 Å. In the second Y3+ site, Y3+ is bonded in a 9-coordinate geometry to nine O2- atoms. There are a spread of Y–O bond distances ranging from 2.40–2.62 Å. There are six inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the second H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the third H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.97 Å. There are six inequivalent O2- sites. In the first O2- site, O2- is bonded in a single-bond geometry to three Y3+ and one H1+ atom. In the second O2- site, O2- is bonded in a single-bond geometry to three Y3+ and one H1+ atom. In the third O2- site, O2- is bonded in a single-bond geometry to three Y3+ and one H1+ atom. In the fourth O2- site, O2- is bonded in a single-bond geometry to three Y3+ and one H1+ atom. In the fifth O2- site, O2- is bonded in a single-bond geometry to three Y3+ and one H1+ atom. In the sixth O2- site, O2- is bonded in a single-bond geometry to three Y3+ and one H1+ atom.
La(OH)3 crystallizes in the hexagonal P6_3 space group. The structure is three-dimensional. La3+ is bonded in a 9-coordinate geometry to nine equivalent O2- atoms. There are a spread of La–O bond distances ranging from 2.53–2.68 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.98 Å. O2- is bonded in a single-bond geometry to three equivalent La3+ and one H1+ atom.