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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 325 records · Page 18
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

The modification stage of basin formation - Conditions of ring formation

The impact cratering process may be divided into three stages, including a short high pressure phase of initial contact between the projectile and target, a longer cratering flow phase during which material is both ejected and displaced to form the transient crater, and a still longer modification phase during which the transient crater is modified into the final observed form. The present investigation is concerned with the nature of the modification stage as constrained by the initial boundary condition which comprises the transient crater and its surroundings, and the final boundary condition which comprises the structure of observed craters and basins. A brief description is provided of an interpretation of basin ring structure based on geophysical, geological, and dimensional analysis of craters and basins on the moon, Mercury, and Mars, on structural observations of terrestrial impact and explosion craters, and on an empirical crater restoration model. A scenario of basin formation is constructed, and relations of this scenario to observed morphology are discussed.

Croft, S. K.↗
NASA NTRS1985

Formation of mesosiderites by low-velocity impacts as a natural consequence of planet formation

It is argued here that, during the period of planet formation, mesosiderites originated by the low-velocity collisions of large metallic core fragments with the surface of a differentiated asteroid-size body. Relative velocities of the asteroids native to this region were low because it was distant from massive protoplanets. However, a few differentiated asteroids were destroyed by high-velocity collisions with interlopers perturbed by protoplanets into high eccentric orbits. These collisions reduced mantles and crusts to small silicate fragments, but left cores in the form of large, durable metal fragments. Mesosiderite-like pyroxenite-basalt-metal mixtures were formed when large core fragments accreted at low velocities to the regolith of an intact asteroid. Most of the olivine in mesosiderite and howardite breccias are attributed here to the mantles of the disrupted parent bodies. The low olivine contents indicate that the amount of debris accreted from disrupted asteroids was small relative to the volumes of the regoliths.

Wasson, J. T.↗
NASA NTRS1989

Protostellar formation in rotating interstellar clouds. VIII - Inner core formation

The results are presented of a variety of spherically symmetric one-dimensional (1D) calculations intended to determine the robustness of the dynamical hiccup phenomenon in protostellar cores. The 1D models show that the phenomenon is relatively insensitive to changes in the equations of state, numerical resolution, initial density and temperature, and the radiative transfer approximation. In 1D, the hiccup results in an explosive destruction of the entire inner protostellar core. Inner core formation is studied with a sequence of three-dimensional models which show that rapid inner core rotation stabilizes the hiccup instability. Instead, the inner core becomes quite flat and undergoes a cycle of binary fragmentation, binary decay into a single object surrounded by a bar, breakup of the bar into a binary, etc. When lesser amounts of rotation are involved, the inner core does hiccup somewhat, but mass is ejected in only a few directions, leading to several broad streams of ejecta.

Boss, Alan P.↗
NASA NTRS2002

Magnetite Formation from Thermal Decomposition of Siderite: Implications for Inorganic Magnetite Formation in Martian Meteorite ALH84001

A biogenic mechanism for formation of a subpopulation magnetite in Martian meteorite ALH84001 has been suggested [McKay et al., 1996; Thomas-Keprta, et al., 2000]. We are developing experimental evidence for an alternating working hypothesis, that the subpopulation was produced inorganically by the thermal decomposition of siderite [Golden et al., 2000].

Morris, RIchard V.↗
DOE OSTI2018

Formation of β-NiAl Phase During Casting of a Ni-Based Superalloy

A high-refractory Ni-based superalloy prototype was melted on a research scale while simulating industry practices. Ingots were vacuum induction melted and subjected to a computationally optimized homogenization heat treatment prior to fabrication which consisted of forging and hot rolling. Failure of one of the ingots at the early stage of the forging process was attributed to the precipitation of the β-NiAl phase during melting which stabilized the eutectic constituent.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Understanding Film Formation Morphology and Orientation in High Member 2D Ruddlesden-Popper Perovskites for High-Efficiency Solar Cells

We report that 2D Ruddlesden–Popper (RP) perovskites have recently emerged as promising candidates for hybrid perovskite photovoltaic cells, realizing power-conversion efficiencies (PCEs) of over 10% with technologically relevant stability. To achieve solar cell performance comparable to the state-of-the-art 3D perovskite cells, it is highly desirable to increase the conductivity and lower the optical bandgap for enhanced near-IR region absorption by increasing the perovskite slab thickness. Here, the use of the 2D higher member (n = 5) RP perovskite (n-butyl-NH 3 ) 2 (MeNH 3 ) 4 Pb 5 I 16 in depositing highly oriented thin films from dimethylformamide/dimethylsulfoxide mixtures using the hot-casting method is reported. In addition, they exhibit superior environmental stability over thin films of their 3D counterpart. These films are assembled into high-efficiency solar cells with an open-circuit voltage of ≈1 V and PCE of up to 10%. This is achieved by fine-tuning the solvent ratio, crystal growth orientation, and grain size in the thin films. Finally, the enhanced performance of the optimized devices is ascribed to the growth of micrometer-sized grains as opposed to more typically obtained nanometer grain size and highly crystalline, densely packed microstructures with the majority of the inorganic slabs preferentially aligned out of plane to the substrate, as confirmed by X-ray diffraction and grazing-incidence wide-angle X-ray scattering mapping.

14 SOLAR ENERGY↗
DOE OSTI2016

Copper Causes Regiospecific Formation of C4F8-Containing Six-Membered Rings and their Defluorination/Aromatization to C4F4-Containing Rings in Triphenylene/1,4-C4F8I2 Reactions

The presence of Cu in reactions of triphenylene (TRPH) and 1,4-C4F8I2 at 360 °C led to regiospecific substitution of TRPH ortho C(β) atoms to form C4F8-containing rings, completely suppressing substitution on C(α) atoms. In addition, Cu caused selective reductive-defluorination/aromatization (RD/A) to form C4F4- containing aromatic rings. Without Cu, the reactions of TRPH and 1,4- C4F8I2 were not regiospecific and no RD/A was observed. These results, supported by DFT calculations, are the first examples of Cupromoted (i) regiospecific perfluoroannulation, (ii) preparative C–F activation, and (iii) RD/A. HPLC-purified products were characterized by X-ray diffraction, low-temperature PES, and 1H/19F NMR.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2021

Quantitative Microstructural Characterization of Plutonium Oxalate Auto-Degradation and Evidence for PuO2 Nanocrystal Formation

It has been known since the 1950s that plutonium oxalate powders change color and lose mass over time when stored at room temperature in air. Despite several studies monitoring these changes, there are still discrepancies in the literature regarding the speciation of intermediate and final products that result from this decomposition. Presented here for the first time is a comprehensive series of time-resolved powder X-ray diffraction experiments coupled with solid-state optical spectroscopy and electron microscopy of aged plutonium (III) and (IV) oxalate powders. These data provide fresh insight into the chemical and structural changes that occur in these solids over time at room temperature and represent new evidence suggesting both plutonium (III) and plutonium (IV) oxalates decompose to form nanocrystalline plutonium oxide in the solid state.

Corbey, Jordan F.↗
DOE OSTI2018

Spectroelectrochemical Sensor for Spectroscopically Hard-to-detect Metals by in situ Formation of a Luminescent Complex Using Ru(II) as a Model Compound

Fast, robust, and cost-effective means of detecting spectroscopically inactive metal species are necessary for field detection and applications within a variety of areas including industry and the nuclear safeguards fields. A sensor based on spectroelectrochemistry is an excellent candidate to meet these needs as it provides improved selectivity for specifically quantifying metal ions by simultaneously monitoring at least two physio-chemical properties. Ruthenium was chosen as a model system for this study due to its spectroscopic and electrochemical characteristics as well as its relevance within the fuel cycle and industrial fields. Aqueous Ru displays multiple redox couples in which all available oxidation states have poor sensitivity for detection by visible absorption spectroscopy because of the low molar absorptivities. Ru can, however, form complexes with sensitizing ligands such as 2,2'-bipyridine, where the resulting [Ru(ligand)3]2+ complex displays a red luminescence with a high quantum yield of emission. This significantly improves detection limits for Ru and allows for the spectroelectrochemical detection of the otherwise hard-to-detect metal ion. This work explores the in-situ generation of Ru(bpy)3 complexes in simulated field samples and their subsequent spectroelectrochemical sensing using our sensor methodology.

Lines, Amanda M.↗
DOE OSTI2018

A clarification and extension of our model of regolith formation on hillslopes: A clarification of our model of regolith formation on hillslopes

In this paper we clarify that our weathering model from 2013 did not explicitly describe weathering of soil moving downhill along hillslopes. Additionally, we re-analyze the role of the term that we neglected that describes loss of regolith mass through mineral dissolution. We derive an equation for this term by including lateral flow of water inside the model hill. For the revised hill model, we define a dimensionless parameter that allows estimation of the effect of lateral flow on the steady-state hillslope. This parameter is equal to the ratio of averaged advective flux of dissolved species out of the hill to the rate of total denudation. The parameter also yields a criterion for the existence of a steady state regolith thickness for systems experiencing unidirectional advection at a constant velocity: for a ridge, the rate of downward flow of water (qy) must be less than the rate of upward movement of rock (E) after normalization by a small parameter, α. This parameter is equal to the equilibrium aqueous concentration divided by the concentration of the reacting mineral in the rock. Alternately, a steady state may exist for the case of both vertical and lateral flow in a hill for any value of erosion rate if the Darcy velocities decrease with depth. Subsurface flow systems play an essential role in the existence of both steady-state hillslopes and steady-state regolith thicknesses.

54 ENVIRONMENTAL SCIENCES↗